===================== Product Identification =====================
MSDS NAME:HFE-71DE 3M NOVEC ENGINEERED FLUID (SEE SUPPL)
NIIN:01-459-0069
Status Code:A
MSDS Number: CLPSX
=== Responsible Party ===
Company:MINNESOTA MINING AND MFG CO
Address:3M CENTER BLDG 224-5S-04
City:SAINT PAUL
State:MN
ZIP:55144-1000
Country:US
Info Phone Num:800-364-3577 OR 651-737-6501(24HR)
Emergency Phone Num:800-364-3577 OR 651-737-6501
Resp. Party Other MSDS Num.: DOCUMENT:07-7119-6
Preparer's Name:NOT PROVIDED
CAGE:76381
=== Contractor Identification ===
Company:MINNESOTA MINING AND MFG CO, DBA 3M
Address:3M CENTER BLDG 224-5S-04
Box:City:SAINT PAUL
State:MN
ZIP:55144-1000
Country:US
Phone:866-556 5712 / 612-733-1110
Contract Num:SP0450-02-M-M113
CAGE:76381
Company:MINNESOTA MINING AND MFG CO PERFOMANCE CHEM AND FLUIDS DIV
Address:3M CTR
Box:City:SAINT PAUL
State:MN
ZIP:55144-1000
Country:US
Phone:800-364-3577/651-737-6501
CAGE:28112
============= Composition/Information on Ingredients =============
Name:1,2-TRANS-DICHLOROETHYLENE
CAS:156-60-5
RTECS #:KV9400000
Minumum % Wt:49.
Maxumum % Wt:51.
Other REC Limits:75 PPM CMRG
OSHA PEL:200 PPM
ACGIH TLV:200 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:METHYL NONAFLU0ROISOBUTYL ETHER
CAS:163702-08-7
Minumum % Wt:25.
Maxumum % Wt:36.
Other REC Limits:750 PPM AIHA
OSHA PEL:NOT PROVIDED
ACGIH TLV:NOT PROVIDED
Name:METHYL NONAFLUOROBUTYL ETHER
CAS:163702-07-6
Minumum % Wt:15.
Maxumum % Wt:26.
Other REC Limits:750 PPM AIHA
OSHA PEL:NOT PROVIDED
ACGIH TLV:NOT PROVIDED
===================== Hazards Identification =====================
LD50 LC50 Mixture:ORAL TOXIC: (LD50 > 5G/KG IN ALBINO RAT)
Routes of Entry: Inhalation:YES Skin:YES Ingestion:NO
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE: IRRITATION: REDNESS, SWELLING
PAIN, TEARING, AND HAZY VISION. SKIN: IRRITATION. REDNESS,
SWELLING, ITCHING, DRYNESS. INHALATION: SINGLE OVEREXPOSURE;
CENTRAL NERVOUS SYSTEM DEPRESSION. HEADACHE, DIZZINESS,
DROWSINESS, INCOORDINATION, SLOWED REACTION TIME, SLURRED SPEECH,
GIDDINESS UNCONSCIOUSNESS. IRRITATION (UPPER RESPIRATORY): SORENESS
OF NOSE, THROAT, COUGHING, SNEEZING. INGESTION: NOT LIK ELY ROUTE
OF EXPOSURE. CENTRAL NERVOUS SYSTEM DEPRESSION, HEADACHE,
DIZZINESS, DROWSINESS, MUSCULAR WEAKNESS, INCOORDINATION, SLOWED
REACTION TIME, FATIGUE, BLURRED VISION, SLURRED SPEECH, GIDDINESS,
TREMORS AND CONVULSIONS.
Explanation of Carcinogenicity:NONE
Effects of Overexposure:EYE: IRRITATION: REDNESS, SWELLING PAIN,
TEARING, AND HAZY VISION. SKIN: IRRITATION: REDNESS, SWELLING,
ITCHING, DRYNESS. INHALATION: SINGLE OVEREXPOSURE; CENTRAL NERVOUS
SYSTEM DEPRESSION. HEADACHE, DIZZINESS, DROWSINESS,
INCOORDINATION, SLOWED REACTION TIME, SLURRED SPEECH, GIDDINESS
UNCONSCIOUSNESS. IRRITATION (UPPER RESPIRATORY): SORENESS OF NOSE,
THROAT, COUGHING, SNEEZING. INGESTION: CENTRAL NERVOUS SYSTEM
DEPRESSION, HEADACHE, DIZZINESS, DROWSINESS, MUSCULAR WEAKNESS,
INCOORDINATION, SLOWED REACTION TIME, FATIGUE, BLURRED VISION,
SPEECH, GIDDINESS, TREMORS AND CONVULSIONS.
Medical Cond Aggravated by Exposure:NOT PROVIDED
======================= First Aid Measures =======================
First Aid:EYE CONTACT: IMMEDIATELY FLUSH WITH LARGE AMOUNT OF WATER.
GET IMMEDIATE MEDICAL ATTENTION. SKIN CONTACT: FLUSH WITH LARGE
AMOUNT OF WATER. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION.
INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GET IMMEDIATE MEDICAL
ATTENTION. SWALLOWED: IF SWALLOWED, DO NOT INDUCE VOMITING. GIVE
VICTIM TWO GLASSES OF WATER. CALL A PHYSICIAN IMMEDIATELY. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Flash Point:NONE
Autoignition Temp:=410.C, 770.F
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:WATER, CARBON DIOXIDE, DRY CHEMICAL, DRY POWDER.
Fire Fighting Procedures:WEAR FULL PROTECTIVE CLOTHING, INCLUDING
HELMET, SELF CONTAINED, POSITIVE PRESSURE OR PRESSURE DEMAND
BREATHING APPARATUS, BUNKER COAT AND PANTS, BANDS AROUND ARMS,
WAIST AND LEGS, FACE MASK, AND PROT ECTIVE COVERING FOR EXPOSED
AREAS OF THE HEAD. KEEP CONTAINERS COOL WITH WATER SPRAY TO AVOID
RUPTURE.
Unusual Fire/Explosion Hazard:EXTREME CONDITIONS OF HEAT (WELDING, OPEN
FLAME) MAY PRODUCE DECOMPOSITION PRODUCTS THAT INCLUDE HYDROGEN
FLUORIDE. NO SMOKING.
================== Accidental Release Measures ==================
Spill Release Procedures:OBSERVE PRECAUTIONS FROM OTHER SECTIONS.
VENTILATE AREA. CONTAIN SPILL. COVER WITH ABSORBENT MATERIAL.
COLLECT SPILLED MATERIAL. CLEAN UP RESIDUE WITH AN APPROPRIATE
ORGANIC SOLVENT. READ AND FOLLOW S AFETY PRECAUTIONS ON THE SOLVENT
LABEL AND MSDS. PLACE IN METAL CONTAINER. SEAL THE CONTAINER. FOR
SPILLS RESULTING IN SIGNIFCANT RELEASE IN A CONFINED AREA, WARN
OTHERS AND LEAVE IMMEDIATELY.
Neutralizing Agent:NOT RELEVANT
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE AWAY FROM ACIDS, HEAT. KEEP
CONTAINER CLOSED WHEN NOT IN USE AND IN WELL-VENTILATED AREA. STORE
AT TEMPERATURES BELOW THE BOILING POINT OF 41C.
Other Precautions:PREVENTION OF ACCIDENTAL INGESTION: DO NOT EAT,
DRINK, OR SMOKE WHEN USING THIS PRODUCT. WASH EXPOSED AREAS
THOROUGHLY WITH SOAP AND WATER. NOT AN EXPECTED ROUTE OF EXPOSURE.
SMOKING WHILE USING THIS PRODUCT CAN RESULT IN CONTAMINATION OF
TOBACCO AND/OR SMOKE AND LEAD TO FORMATION OF HAZARDOUS DECO
MPOSITION PRODUCTS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:AVOID BREATHING OF VAPORS, MISTS OR SPRAY.
IFVENTILATION IS NOT ADEQUATE SELECT ONE OF FOLLOWING NIOSH
APPROVED RESPIRATORS BASED ON AIRBORNE CONCENTRATION OF
CONTAMINANTS AND IN ACCORDANCE WITH OSHA REGULATIONS: HALF-MASK.
Ventilation:USE IN A WELL-VENTILATED AREA. PROVIDE SUFFICIENT
VENTILATION TO MAINTAIN EMISSIONS BELOW RECOMMENDED LIMITS.
Protective Gloves:USE GLOVES FOR HANDLING PRODUCT.POLYETHYLENE/ETHYLENE
VINYL ALCOHOL RECOMMENDED
Eye Protection:WEAR VENTED GOGGLES AND/OR SAFETY GLASSES WITH SIDE
SHIELDS.
Other Protective Equipment:AVOID SKIN CONTACT. WEAR AN APRON.
Work Hygienic Practices:NOT PROVIDED
Supplemental Safety and Health
P/N: 98-0211-9221-2. AVOID EXPOSING MATERIAL TO EXTREME CONDITIONS OF
HEAT (>150C , OPEN FLAME). ID NUMBER / U.P.C.: 98-0211-9219-4;
98-0211-9221-0; 98-0211-9223-6; 00-51135-11050-8; 00-51135-11052-2;
00-51135-11054-6; 98-0211-9220-2; 98-0211-9222-8; 98-0212-1172-1;
00-51135-11051-5; 00-51135-11053-9; 00-51135-63036-5
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:=41.C, 105.8F
Decomp Temp:Decomp Text:NOT PROVIDED
Vapor Pres:383 MMHG @ 25 DEG C
Vapor Density:4.8 (AIR=1
Spec Gravity:1.37 G/ML
VOC Pounds/Gallon:685
Viscosity:0.45 CENTIPOISE
Evaporation Rate & Reference:59 BUOAC=1
Solubility in Water:SLIGHT
Appearance and Odor:CLEAR, COLORLESS LIQUID, SLIGHT ODOR.
Percent Volatiles by Volume:100
Corrosion Rate:NOT PROVIDED
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, STRONG BASES, STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:AVOID TEMPERATURES ABOVE THE BOILING
POINT.
Hazardous Decomposition Products:HYDROGEN FLUORIDE,
PERFLUOROISOBUTYLENE (PFIB).
=================== Toxicological Information ===================
Toxicological Information:THE TOXICITY INFORMATION ON
TRANS-DICHLOEOETHYLENE HAS BEEN LIMITED TO STUDIES OF QUESTIONABLE
QUALITY. THESE STUDIES SUGGESTED LIVER AND KIDNEY TOXICITY AT
ELEVATED CONCENTRATIONS. RECENTLY A 90-DAY INHALATION STUDY WAS
CONDUCTED TO CLARIFY THE TOXICITY OF TRANS-DICHLOROETHYLENE. NO
ADVERSE EFFECTS WERE SEEN IN THIS STUDY WHICH HAD A HIGH DOSE OF
4000 PPM. T0XICITY DATA FOR METHYLISOPERFLUOROBUTY L AND
METHYLPERFLUOROBUTYL COMPONENTS: ACUTE INHALATION LETHAL
CONCENTRATION: >100,000 PPM (4 HR). ORAL TOXICITY: PRACTICALLY
NON-TOXIC (LD50 > 5G/KG IN ALBANO RAT). DEVELOPMENTAL TOXICITY: NO
ABNORMA L (CONTD. SEE "TRANSPORT")
===================== Ecological Information =====================
Ecological:PRODUCT PRESENTS A LOW ENVIRONMENTAL HAZARD. PRODUCT IS
ESTIMATED TO HAVE MINIMAL TOXICITY TO AQUATIC ORGANISMS. THIS
ESTIMATE ASSUMES NO SYNERGISTIC, ANTAGONISTIC OR NONADDITIVE
EFFECTS. TAKE PRECAUT IONS TO PREVENT DIRECT RELEASE OF THIS
PRODUCT TO THE ENVIRONMENT. THE HIGH POTENTIAL OF THIS SUBSTANCE TO
MOVE FROM WATER TO THE ATMOSPHERE ACCOUNTS FOR ITS LOW TOXICITY AND
MAKE IT UNLIKELY THAT THI S SUBSTANCE WILL BIOCONCENTRATE IN
AEROBIC ENVIRONMENTS. 1,2-TRANS-DICHLOROETHYLENE IS UNLIKELY TO
BIOCONCENTRATE TO HIGH CONCENTRATIONS IN AQUATIC ORGANISMS BY
PARTITIONING INTO FAT.
==================== Disposal Considerations ====================
Waste Disposal Methods:INCINERATE IN PRESENCE OF COMBUSTIBLE MATERIAL
IN INDUSTRIAL OR COMMERCIAL FACILITY CAPABLE OF HANDLING
HALOGENATED WASTE. DISPOSE OF COMPLETELY ABSORBED WASTE PRODUCT IN
HAZARDOUS WASTE FACILITY. REC LAIM IF FEASIBLE. FOR INFORMATION ON
PRODUCT RETURN, CONTACT YOUR DISTRIBUTOR. U.S. EPA HAZARDOUS WA STE
NUMBER = NONE ( NOT U.S. EPA HAZARDOUS.)
=================== MSDS Transport Information ===================
Transport Information:NOT REGULATED FOR TRANSPORTATION.
===================== Regulatory Information =====================
SARA Title III Information:EPCRA 311/312 REPORTABLE QUANTITY = NOT
REPORTABLE.
Federal Regulatory Information:THE COMPONENTS OF THIS PRODUCT ARE IN
CONPLIANCE WITH THE CHEMICAL REGISTRATION REQUIREMENTS OF TSCA.
State Regulatory Information:NOT PROVIDED
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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