===================== Product Identification =====================
MSDS NAME:CR 4944, TURCAM INSECTICIDE
Status Code:A
MSDS Number: CLPTX
=== Responsible Party ===
Company:AGREVO USA COMPANY (LITTLE FALLS CENTRE ONE)
Address:2711 CENTERVILLE RD
City:WILMINGTON
State:DE
ZIP:19808-5000
Country:US
Info Phone Num:302-892-3000
Emergency Phone Num:800-228-5635X202 (24 HR)
Resp. Party Other MSDS Num.:000011
CAGE:GO606
=== Contractor Identification ===
Company:AGREVO USA COMPANY (LITTLE FALLS CENTRE ONE)
Address:2711 CENTERVILLE RD
City:WILMINGTON
State:DE
ZIP:19808-5000
Country:US
Phone:302-892-3000
CAGE:GO606
============= Composition/Information on Ingredients =============
Name:BENDIOCARB
CAS:22781-23-3
RTECS #:FC1140000
= Wt:76.
= Wt:24.
Name:AMORPHOUS SILICA (HYDRATED)
CAS:7631-86-9
OSHA PEL:6 MG/M3
ACGIH TLV:6 MG/M3
Name:ALKYLNAPHTHALENE SULFONIC ACID (POLYMERIZED-NA SALT)
CAS:9084-06-4
RTECS #:EC4850000
ACGIH TLV:2 MG/M3
===================== Hazards Identification =====================
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:EYE: NOT LIKELY TO CAUSE EYE
IRRITATION. MAY CAUSE TEMPORARY AND REVERSIBLE MIOSIS. SKIN: SLIGHT
SKIN IRRITANT. MAY BE ABSORBED THROUGH THE SKIN. NOT A SKIN
SENSITIZER. INGESSTION: HARMFUL OR FATAL IF SWALLOWED. INHALTION:
DUST INHALTION CAN CAUSE SYMPTOMS ASSOCIATED WITH OVEREXPOSURE.
Explanation of Carcinogenicity:BENDIOCARB TECHNICAL IS NOT LISTED AS
CARCINOGENIC
Effects of Overexposure:HARMFUL OR FATAL IF SWALLOWED. MAY BE POISONOUS
IF INHALED. OVEREXPOSURE TO BENDIOCARB PRODUCES SYMPTOMS ASSOCIATED
WITH CHOLINESTERASE INHIBITION. THE THRESHOLD DOSE FOR SYMPTOMS OF
CHOLINESTERASE IN HIBITION IN HUMANS WAS DETERMINED TO BE
0.15-0.2MG/KG AND THE NO-EFFECT-LEVEL IS 0.10MG/KG. SYMPTOMS ARE: A
SENSE OF TIGHTNESS IN CHEST, SWEATING, HEADACHE, NAUSEA, DIZZINESS,
CONSTRICTED PUPILS, REVE RSIBLE VISION IMPAIRMENT, SALIVATION,
VOMITING, ABDOMINAL CRAMPS, DIARRHEA, INCONTINENCE, MUSCULAR
INCOORDINATION AND TWITCHING.
Medical Cond Aggravated by Exposure:MAY POSSIBLY AGGRAVATE PRE-EXISTING
RESPIRATORY CONDITIONS.
======================= First Aid Measures =======================
First Aid:EYE: RINSE THOROUGHLY WITH CLEAN WATER (AT LEAST 15 MINS).
SKIN: WASH THOROUGHLY WITH SOAP & WATER. INGESTION: DRINK ONE OR
TWO GLASSES OF WATER & INDUCE VOMITING BY TOUCHING BACK OF VICTIM'S
THROAT W ITH FINGER. DO NOT INDUCE VOMITING OR GIVE ANYTHING BY
MOUTH TO AN UNCONSCIOUS PERSON. GET MEDICAL ATTENTION. INHALATION:
REMOVE PATIENT TO UNCONTAMINATED AREA. KEEP PATIENT STRICTLY AT
REST & TRANSFE R TO HOSPITAL IMMEDIATELY TO GET MEDICAL ATTENTION.
"SEE OTHER INFO"
===================== Fire Fighting Measures =====================
Extinguishing Media:DRY CHEMCIAL, FOAM, CARBON DIOXIDE, WATER.
Fire Fighting Procedures:WEAR POSITIVE PRESSURE SELF-CONTAINED
BREATHING APPARATUS. REMOVE PRODUCT FROM AREA OF FIRE AT FIRST
OPPORTUNITY. USE WATER TO COOL FIRE-EXPOSED CONTAINERS AND
PERSONNEL.
Unusual Fire/Explosion Hazard:WHEN HEATED TO THE POINT OF DECOMPOSITION
(ABOVE 140C/280F), BENDICARB GIVES OFF A TOXIC FUME WHICH IS
RAPIDLY ELIMINATED BY FIRE OR WATER. DISPERSION OF FINE DUST IN THE
AIR MAY FORM AN EXPLOSION MIX TURE.
================== Accidental Release Measures ==================
Spill Release Procedures:KEEP UNNECESSARY PEOPLE AWAY AND ISOLATE
HAZARD AREA. DO NOT BREATHE DUST. USE PROPER PROTECTIVE EQUIPMENT.
SWEEP UP, OR PREFERABLY, VACUUM WHILE AVOIDING THE FORMATION OF A
DUST CLOUD. PLACE MATERIAL IN A SUITABLE, DRY CONTAINER AND SEAL
FOR DISPOSAL. WASH CONTAMINATED AREAS WITH WATER AND DETERGENT, BUT
KEEP OUT OF SEWERS OR WATERCOURSES. INFORM PROPER AUTHORITIES IF
CONTAMINATION OCCURS.
====================== Handling and Storage ======================
Handling and Storage Precautions:DO NOT STORE NEAR FOOD OR FEED
PRODUCTS. STORE IN DRY PLACE. TURCAM IS STABLE UNDER NORMAL STORAGE
TEMPERATURES BUT MUST AVOID EXTREME HIGH TEMPERATURES. HARMFUL OR
FATAL IF SWALLOWED. MAY BE ABSORBED THROUGH THE SKIN. AVOID
CONTACT WITH EYES, SKIN & CLOTHING. WASH SKIN & CLOTHINGWITH SOAP &
WATER.
Other Precautions:WASH EYES WITH CLEAN WATER. DO NOT RUB EYE OR MOUTH
WITH HANDS. IF YOU FEEL SICK IN ANY WAY, STOP WORK & GET HELP RIGHT
AWAY. DO NOT USE ON OR CONTAMINATE FRUIT, VEGETABLES OR OTHER FEED
OR FOOD CROPS . **END-USE PRODUCT DESCRIPTION: INSECTICIDE FOR USE
ON TURF FOR CONTROL OR WHITE GRUBS AND OTHER PE STS.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:ENSURE GOOD VENTILOATION IN HANDLING AREA. USE A
SUITABLE DUST RESPIRATOR. USE OF SELF-CONTAINED BREATHING APPARATUS
OR AIRLINE HOOD OR MASK IS RECOMMENDED TO GIVE COMPLETE FACE
PROTECTION.
Ventilation:MUST MAINTAIN GOOD VENTILATION TO MINIMIZE EXPOSURE TO
BENDICARB. LOCAL EXHAUST VENTILATION MAY BE NECESSARY.
Protective Gloves:IMPERVIOUS (NEOPRENE, BUTYL RUBBER) GLOVES.
Eye Protection:SAFETY GLASSES; FACESHIELD.
Other Protective Equipment:USE SYNTHETIC (PVC) APRON DURING HANDLING
AND APPLICATION. COVERALLS OVER SHORT SLEEVED SHIRTS AND SHORT
PANTS. WATER PROOF GLOVES. CHEMICAL RESISTANT FOOTWEAR PLUS SOCKS.
CHEMICAL RESISTANT HEADGEAR.
Work Hygienic Practices:WASH HANDS BEFORE EATING, DRINKING, CHEWING
GUM, USING TOBACCO OR USING TOILET. DISCARD CLOTHING & OTHER
ABSORBENT MATERIALS THAT HAVE BEEN DRENCHED OR HEAVILY SOILED WITH
PRODUCT CONCENTRATE.
Supplemental Safety and Health
PRODUCT NAME: TURCAM INSECTICIDE. PRODUCT CODE: CR 4944. CHEMICAL NAME:
2,2-IMETHYL-1, 3-BENZODIOXOL-4-YL METHYL CARBAMATE (ACTIVE
INGREDIENT). CHEMICAL FAMILY: CARBAMATE. EPA REGISTRATION NO.:
45639- 59. SYNONYMS: CR 4944 (TURCAM 76WP). CANADIAN REG. NO.:
19728 P.C.P. ACT.
================== Physical/Chemical Properties ==================
HCC:T4
Melt/Freeze Pt:=128.9C, 264.F
M.P/F.P Text:128-130C
Decomp Temp:=140.C, 284.F
Vapor Pres:3.5X105MMHG
Vapor Density:N/VOLITILE
Appearance and Odor:SOLID SHITE POWDER; ODORLESS
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
NONE SPECIFIC; AVOID STRONG OXIDIZERS.
Stability Condition to Avoid:EXTREME HEAT OR MOISTURE. STABLE UP TO
280F(140C).
Hazardous Decomposition Products:WHEN HEATED TO THE POINT OF
DECOMPOSITION (ABOVE 140C OR 280F), BENDIOCARB GIVES OFF A TOXIC
FUMES WHICH IS RAPIDLY ELIMINATED BY FIRE OR WATER.
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:INHALATION LC50(RAT-4 HRS): DATA FROM AN
INHALATION STUDY IN RATS EXPOSED TO FICAM W FOR 4 HRS IS NOT
AVAILABLE. HOWEVER, A RELEVANT INHALATION LC50 DATA IS AVAILABLE
FOR THE CONCENTRATED BENDIOCARB T ECHNICAL (97.9%); THE LC50 (RAT-4
HRS): IS 0.55 MG/LITER OF AIR. THIS INDICATES THAT, FOR TURCAM
(76%TECHNICAL), THE LC50 (RAT-4 HRS) IS LIKELY TO BE:>0.55 MG/LITER
(HIGHLY TOXIC). THE STUDIES REPORTE D BELOW WERE CARRIED OUT WITH
BENDIOCARB TECHNICAL (>96%), THE ACTIVE INGREDIENT. SUBCHRONIC
(TARGET ORGAN EFFECTS): RESULTS FROM 90-DAY ANIMAL STUDIES SUGGEST
NO TARGET ORGAN EFFECTS UNDER THE CONDIT IONS FOR NORMAL HANDLING &
USE.
===================== Ecological Information =====================
Ecological:THIS PRODUCT IS TOXIC TO WILDLIFE. FOR TERRESTRIAL USES, DO
NOT APPLY DIRECTLY TO WATER, OR TO AREAS WHERE SURFACE WATER IS
PRESENT, OR TO INTERTIDAL AREAS BELOW THE MEAN HIGH WATER MARK.
RUNOFF FROM TREATED AREAS MAY BE HAZARDOUS TO AQUATIC ORGANISMS IN
NEIGHBORING AREAS. DO NOT CONTAMINATE WATER WHEN DISPOSING OF
EQUIPMENT WASHWATER. THIS PRODUCT IS HIGHLY TOXIC TO BEES EXPOSED
DIRECT TREATMENT ON BLOOMING CROPS OR WEEDS. DO NOT APPLY THIS
PRODUCT OR ALLOW IT TO DRIFT TO BLOOMING CROPS OR WEEDS IF BEES ARE
VISITING THE TREATMENT AREA.
==================== Disposal Considerations ====================
Waste Disposal Methods:USE PROPER PROTECTIVE EQUIPMENT TO MINIMIZE
EXPOSURE. TAKE ALL NECESSARY ACTION TO PREVENT AND TO REMEDY THE
ADVERSE EFFECT OF THE SPILL. NOTIFY THE APPROPRIATE AUTHORITIES
IMMEDIATELY. ENSURE THAT AL L THE DISPOSAL IS IN COMPLIANCE WITH
FEDERAL REQUIREMENTS AND STATE/LOCAL REGULATIONS.
=================== MSDS Transport Information ===================
Transport Information:PROPER SHIPPING NAME: CARBAMATE PESTICIDE, SOLID,
TOXIC, N.O.S., 6.1, UN2757, PG III, VOLUME IN NET POUNDS (USA) OR
KILOS (INTERNATIONAL) LIMITED QUANTITY. DOT SHIPPING LABEL:
HARMFUL, STOW AWAY FROM FOODSTUFFS. NOTE: FOR TRANSPORTATION
PURPOSES (49 CFR PART 173.132), THE CALCULATED LC50(RAT-1HR) IS:
>2.2 MG/L.
===================== Regulatory Information =====================
SARA Title III Information:SARA TITLE III, SECTION 302 (EHS)
INGREDIENTS: NOT LISTED. SARA TITLE, SECTION 304 (CERCLA & EHS)
INGREDIENTS (RQ): NOT LISTED. SARA TITLE III NOTIFICATION &
INFORMATION: SARA TITLE III-HAZARD CLASSES : ACUTE HEALTH
HAZARD:"YES". CHRONIC HEALTH HAZARD:"NO". FIRE HAZARD:"NO". SUDDEN
RELEASE OF PRESSURE HAZARD:"NO". REACTIVITY HAZARD:"NO". SARA TITLE
III-SECTION 313 SUPPLIER NOTIFICATION: BENDIOCARB, CAS#
22781-23-3, PERCENT BY WEIGHT: 76.0. THIS INFORMATION MUST BE
INCLUDED ON ALL MSDS THAT ARE COPIED AND DISTRIBUTED FOR THIS
MATERIAL.
Federal Regulatory Information:TCSA: EXEMPT FROM TSCA; A REGISTERED
PESTICIDE UNDER FIFRA.
State Regulatory Information:BENDIOCARB (NEW JERSEY RTK: SUBSTANCES
NO.=0191, DOT NO.=2757.
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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