===================== Product Identification =====================
MSDS NAME:PLIOBOND 30
NIIN:00-543-7170
Status Code:A
MSDS Number: CLPWR
=== Responsible Party ===
Company:ASHLAND CHEMICAL CO DIV OF ASHLAND OIL INC
Address:3849 FISHER RD
Box:2219
City:COLUMBUS
State:OH
ZIP:43216
Country:US
Info Phone Num:614-790-3333 / 800-325-3751
Emergency Phone Num:1-800-274-5263
Preparer's Name:ERNEST CARTER
Chemtrec Ind/Phone:(800)424-9300
CAGE:7L600
=== Contractor Identification ===
Company:ASHLAND CHEMICAL CO DIV OF ASHLAND OIL INC
Address:3849 FISHER RD
Box:2219
City:COLUMBUS
State:OH
ZIP:43216
Country:US
Phone:614-790-3333 / 800-325-3751
CAGE:7L600
============= Composition/Information on Ingredients =============
Name:NITRILE RUBBER
Minumum % Wt:14.
Maxumum % Wt:18.
Name:METHYL ETHYL KETONE
CAS:78-93-3
RTECS #:EL6475000
Minumum % Wt:69.
Maxumum % Wt:69.
OSHA PEL:590 MG/M3;200 PPM
ACGIH TLV:590 MG/M3;200 PPM
ACGIH STEL:885 MG/M3;300 PPM
EPA Rpt Qty:5000 LBS
DOT Rpt Qty:5000 LBS
Name:CALCIUM CARBONATE
CAS:471-34-1
RTECS #:FF9335000
Minumum % Wt:1.9
Maxumum % Wt:6.
Name:ALKYLPHENLIC RESIN
Minumum % Wt:8.
Maxumum % Wt:12.
Name:PHENOL
CAS:108-95-2
RTECS #:SJ3325000
Minumum % Wt:1.
Maxumum % Wt:1.
OSHA PEL:19 MG/M3;5 PPM
ACGIH TLV:19 MG/M3;5 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
Name:FORMALDEHYDE
CAS:50-00-0
RTECS #:LP8925000
Minumum % Wt:.1
Maxumum % Wt:.1
OSHA PEL:SEE 1910.1048
ACGIH STEL:C0.37 MG/M3;C0.3 PPM
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
===================== Hazards Identification =====================
Health Hazards Acute and Chronic:EYE: SYMPTOMS MAY INCLUDE STINGING,
TEARING, REDNESS, SWELLING, AND EYE DAMAGE. SKIN: MAY INCLUDE
REDNESS, BURNING, DRYING AND CRACKING, SKIN BURNS AND SKIN
DAMAGE.ALSO, ALLERGIC REACTION, ABSORPTION . SWALLOWING: SWALLOWING
LARGE AMOUNTS CAN BE HARMFUL. THIS MATERIAL CAN ENTER THE LUNGS
DURING SWALLOWING OR VOMITING AND CAUSE LUNG INFLAMMATION AND/OR
DAMAGE. INHALATION: SYMPTOMS ARE MORE TYPICALL Y SEEN AT AIR
CONCENTRATIONS EXCEEDING THE RECOMMENDED EXPOSURE LIMITS.
Effects of Overexposure:IRRITATION (NOSE, THROAT, ERSPIRATORY TRACT),
CENTRAL NERVOUS SYSTEM DEPRESSION (DIZZINESS, DROWSINESS, WEAKNESS,
FATIGUE, NAUSEA, HEADACHE, UNCONSCIOUSNESS),
======================= First Aid Measures =======================
Eyes: FLUSH EYES GENTLY WITH WATER FOR AT LEAST 15 MINUTES
WHILE HOLDING EYELIDS APART. SEEK IMMEDIATE MEDICAL ATTENTION.
SKIN: FLUSH EXPOSED AREA WITH LARGE AMOUNTS OF WATER. IF SKIN IS
DAMAGED OR SY MPTOMS PERSIST, SEEK IMMEDIATE MEDICAL ATTENTION.
SWALLOWING: DO NOT INDUCE VOMITING. IF INDIVIDUAL IS DROWSY OR
UNCONSCIOUS, PLACE ON LEFT SIDE WITH THE HEAD DOWN.SEEK MEDICAL
ATTENTION.INHALATION: I MMEDIATELY MOVE INDIVIDUAL AWAY FROM
EXPOSURE AND INTO FRESH AIR. SEEK IMMEDIATE MEDICAL ATTENTION; KEEP
PERSON WARM AND QUIET. IF PERSON IS NOT BREATHING, BEGIN ARTIFICIAL
RESPIRATION.
===================== Fire Fighting Measures =====================
Flash Point Method:SCC
Flash Point:=-5.4C, 22.F
Lower Limits:2.0%
Upper Limits:12.0%
Extinguishing Media:REGULAR FOAM, WATER FOG, CARBON DIOXIDE, DRY
CHEMICAL.
Fire Fighting Procedures:WEAR A SELF-CONTAINED BREATHING APPARATUS WITH
A FULL FACEPIECE OPERATED IN THE POSITIVE PRESSURE DEMAND MODE WITH
APPROPRIATE TURN-OUT GEAR AND CHEMICAL RESISTANT PERSONAL
PROTECTIVE EQUIPMENT.
Unusual Fire/Explosion Hazard:VAPORS ARE HEAVIER THAN AIR AND MAY
TRAVEL ALONG GROUND OR MOVED BY VENTILATION AND IGNITED BY PILOT
LIGHTS, OTHER FLAMES, SPARKS, HEATERS, SMOKING, ELECTRIC MOTORS,
STATIC DISCHARGE. NEVER USE WELDIN G OR CUTTING TORCH ON OR NEAR
DRUM. (EVEN EMPTY) BECAUSE PRODUCT (EVEN JUST RESIDUE) CAN IGNITE
EXPLOSIVELY.
================== Accidental Release Measures ==================
Spill Release Procedures:ELIMINATE ALL SOURCES OF IGNITION SUCH AS
(FLARES, FLAMES INCLUDING PILOT LIGHTS, ELECTRICAL SPARKS). ABSORB
LIQUID ON VERMICULITE, FLOOR ABSORBENT OR OTHER ABSORBENT MATERIAL.
STOP SPILL AT SOURCE. P REVENT FROM ENTERING DRAINS, SEWERS,
STREAMS OR OTHER BODIES OF WATER. PREVENT FROM SPREADING.
====================== Handling and Storage ======================
Handling and Storage Precautions:CONTAINERS OF THIS MATERIAL MAY BE
HAZARDOUS WHEN EMPTIED. SINCE EMPTIED CONTAINERS RETAIN PRODUCT
RESIDUES (VAPOR, LIQUID; AND /OR SOLID), ALL HAZARD PRECAUTIONS
GIVEN IN THE DATA SHEET MUST BE OBSER VED. ALL FIVE GALLON PAILS
AND LARGER METAL CONTAINERS INCLUDING TANK CARS AND TANK TRUCKS
SHOULD B
============= Exposure Controls/Personal Protection =============
Respiratory Protection:A NIOSH/MSHA APPROVED AIR SUPPLIED RESPIRATOR
IS ADVISED IN ABSENCE OF PROPER ENVIRONMENTAL CONTROL. OSHA
REGULATIONS ALSO PERMIT OTHER NIOSH/MSHA RESPIRATORS (NEGATIVE
PRESSURE TYPE) UNDER SPECIFIED CONDITIONS.
Ventilation:PROVIDE SUFFICIENT MECHANICAL (GENERAL AND/OR LOCAL
EXHAUST) VENTILATION.PRODUCT
Protective Gloves:WEAR RESISTANT GLOVES SUCH AS: NATURAL RUBBER,
Eye Protection:CHEMICAL SPLASH GOGGLES.
Other Protective Equipment:WEAR IMPERVIOUS CLOTHING AND BOOTS.
Supplemental Safety and Health
================== Physical/Chemical Properties ==================
Boiling Pt:=79.4C, 175.F
Vapor Pres:70.000 MMHG @760
Vapor Density:1.000
Spec Gravity:.894 @AIR=1
VOC Pounds/Gallon:894
VOC Grams/Liter:7.44
Evaporation Rate & Reference:SLOWER THAN ETHYL ETHER
Appearance and Odor:LIQUID TAN COLOR
Percent Volatiles by Volume:68.0-72.0%
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
AVOID CONTACT WITH: STRONG OXIDIZING AGENTS.
Hazardous Decomposition Products:CARBON DIOXIDE AND CARBON MONOXIDE,
HYDROGEN CYANIDE, NITROGEN COMPOUNDS, VARIOUS HYDROCARBONS.
Conditions to Avoid Polymerization:WILL NOT UNDERGO HAZARDOUS
POLYMERIZATION.
==================== Disposal Considerations ====================
Waste Disposal Methods:DESTROY BY LIQUID INCINERATION IN ACCORDANCE
WITH APPLICABLE REGULATIONS.
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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