===================== Product Identification =====================
MSDS NAME:AMDRY 9155, CDS 19155 & 4192, COBALT BASE ALLOY
Status Code:A
MSDS Number: CLPVF
=== Responsible Party ===
Company:SULZER METCO /WESTBURY/ INC
Address:1101 PROSPECT AVE
City:WESTBURY
State:NY
ZIP:11590-2724
Country:US
Info Phone Num:516-334-1300
Emergency Phone Num:(800)424-9300
Resp. Party Other MSDS Num.:REVISION 2
Chemtrec Ind/Phone:(800)424-9300
CAGE:01FK3
=== Contractor Identification ===
Company:SULZER METCO (US) INC
Address:1101 PROSPECT AVE
Box:City:WESTBURY
State:NY
ZIP:11590-2724
Country:US
Phone:516-334-1300
CAGE:01FK3
============= Composition/Information on Ingredients =============
Name:COBALT
CAS:7440-48-4
RTECS #:GF8750000
= Wt:59.
OSHA PEL:0.05 MG/M3
ACGIH TLV:0.05 MG/M3
Name:MOLYBDENUM
CAS:7439-98-7
RTECS #:QA4680000
= Wt:28.
OSHA PEL:10 MG/M3
ACGIH TLV:10 MG/M3
Name:CHROMIUM
CAS:7440-47-3
RTECS #:GB4200000
= Wt:8.
OSHA PEL:1 MG/M3
ACGIH TLV:0.5 MG/M3
EPA Rpt Qty:1 LB
DOT Rpt Qty:1 LB
Name:SILICON
CAS:7440-21-3
RTECS #:VW0400000
= Wt:3.
OSHA PEL:10 MG/M3
ACGIH TLV:10 MG/M3
Name:IRON
CAS:7439-89-6
RTECS #:NO4565500
= Wt:1.
OSHA PEL:10 MG/M3
ACGIH TLV:5 MG/M3
Name:NICKEL
CAS:7440-02-0
RTECS #:QR5950000
= Wt:1.
OSHA PEL:1 MG/M3
ACGIH TLV:1 MG/M3
EPA Rpt Qty:100 LBS
DOT Rpt Qty:100 LBS
===================== Hazards Identification =====================
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES
Health Hazards Acute and Chronic:COBALT: INHALATION MAY CAUSE
PROGRESSIVE, DIFFUSE PNEUMONIA, RESPIRATORY SENSITIZATION
CHARACTERIZED BY COUGH, WHEEZING AND SHORTNESS OF BREATH. INGESTION
MAY CAUSE IRRITATION TO THE RESPIRATORY SYSTE M AND GASTROINTETINAL
TRACT. SKIN CONTACT MAY CAUSE ALLERGIC DERMATITIS OR ECZEMA. EYE
CONTACT MAY CAUSE IRRITATION. TARGET ORGANS: RESPIRATORY SYSTEM,
GASTROINTESTINAL TRACT, SKIN, EYES.
Explanation of Carcinogenicity:COBALT: ACGIH CLASSIFIED A3 ANIMAL
CARCINOGEN. CHROMIUM: HEXAVALENT CHROMIUM IS ACGIH CLASSIFIED A1
CONFIRMED HUMAN CARCINOGEN & IARC CLASSIFICATION GROUP I CARCINOGEN
TO HUMANS. NTP CLASSIFIED HEXAVA LENT CHROMIUM AS KNOWN TO BE
CARCINOGENIC. NICKEL: ACGIH CLASSIFIED A1 CONFIRMED HUMAN
CARCINOGEN. IARC CLASSIFIED GROUP I CARCINOGENIC TO HUMANS.
Effects of Overexposure:EYE CONTACT-POSSIBLE CONJUNCTIVAL IRRITATION,
LACRIMATION. SKIN CONTACT-POSSIBLE IRRITATION, DERMATITIS, ECZEMA,
SENSITIZATION OR CHROME LESIONS, DISCOLORATION. INHALATION-POSSIBLE
IRRITATIOIN TO THE RESPIRATORY SYSTEM, MUCOUS MEMBRANE IRRITATION
OR ULCERTAION, SENSITIZATION CHARACTERIZED BY COUGH, WHEEZING,
SHORTNESS OF BREATH, DECREASED CHEST EXPANSION & LESSENED CAPACITY
FOR WORK. INGESTION-POS SIBLE IRRITATION TO THE RESPIRATORY SYSTEM
& GASTROINTESTINAL TRACT, LOSS OF MUSCULAR COORDINATION, CONFUSION
AND CONVULSIONS.
Medical Cond Aggravated by Exposure:CONSULT A PHYSICIAN.
======================= First Aid Measures =======================
First Aid:EYE: FLUSH EYE WITH WATER OR AT LEAST 15-20 MINUTES WHILE
HOLDING EYELID OPEN. IF IRRITATION PERSISTS, CONSULT A PHYSICIAN.
SKIN: WASH WITH SOAP AND WATER. IF IRRITATION PERSISTS, CONSULT A
PHYSICIAN. INHALATION: EXPOSE TO FRESH AIR. CONSULT A PHYSICIAN IF
IRRITATION OR RESPIRATORY DISTRESS PERSISTS. INGESTION: CONSULT A
PHYSICIAN.
===================== Fire Fighting Measures =====================
Extinguishing Media:USE CLASS D FIRE EXTINGUISHER.
Fire Fighting Procedures:TREAT AS A METALLIC FIRE. USE NIOSH/MSHA
APPROVED SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE
CLOTHING IF INVOLVED IN A FIRE. *SILCON MAY IGNITE IF EXPOSED TO
FLAME OR OXIDIZERS, DO NOT HEA T OR EXPOSE TO WATER.
Unusual Fire/Explosion Hazard:FINE METAL DUSTS ARE FLAMMABLE AND MAY
EXPLODE WHEN EXPOSED TO HEAT, FLAME OR OXIDIZERS. COBALT, CHROMIUM
AND IRON MAY IGNITE IF AIRBORNE IN THE PRESENCE OF AN IGNITION
SOURCE OR SPONTANEOUSLY. FINE M ETAL DUSTS OF MOLYBDENUM ARE
FLAMMABLE AND MAY EXPLODE IF EXPOSED TO HEAT, FLAME OR OXIDIZERS.
================== Accidental Release Measures ==================
Spill Release Procedures:VACUUM LOOSE POWDER ONLY WITH VACUUMS EQUIPPED
HEPA FILTRATION. VACUUMS APPROPRIATE FOR USE WITH METALLIC DUSTS
SHOULD BE UTILIZED. WIPE THE AREA CLEAN. DO NOT USE WATER FOR CLEAN
UP OPERATIONS. DO NO T SWEEP. AVOID GENERATING AIRBORNE DUST.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE AWAY FROM INCOMPATIBLES. STORE
PRODUCT CONTAINERS IN A WELL-VENTILATED, CLEAN, COOL AND DRY AREA.
STORE IN A MANNER TO MINIMIZE PUNCTURES AND BREAKAGE OF CONTAINERS.
Other Precautions:AVOID INGESTION, INHALATION AND EXCESSIVE SKIN
CONTACT.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:A RESPIRATOR APPROVED BY NIOSH WITH FILTER
CARTRIDGES APPROVED FOR DUST/FUMES/MISTS SHOULD BE WORN AT ALL
TIMES DURING THE THERMAL SPRAY PROCESS TO PROTECT THE OPERATOR FROM
EXPOSURE TO DUST AND FUMES . RESPIRATORS MAY ALSO BE WORN WHEN
PRODUCT HANDLING GENERATES DUST.
Ventilation:PRODUCT SHOULD BE USED WITH THE APPROPRIATE LOCAL EXHAUST
VENTILATION PROVIDED.
Protective Gloves:ALUMINIZED GLOVES DURING PLASMA SPRAY PROCESS, RUBBER
FOR OTHER PROCESSES.
Eye Protection:COMBUSTION SPRAYING SHADE#5, PLASMA SPRAYING UPTO 40KW
SHADE#9, 40-60KW SHADE .
Other Protective Equipment:EYE WASH STATION(S) IS/ARE RECOMMENDED. WASH
FACILITIES ARE RECOMMENDED. EAR PROTECTION MUST BE WORN WHEN THE
OPERATOR IS SUBJECTED TO EXCESSIVE NOISE LEVELS.
Work Hygienic Practices:RUBBER OR OTHER APPROPIAT GLOVES MAY BE WORN AS
NEEDED DURING OTHER PHASES OF PRODUCT HANDLING TO AVOID EXCESSIVE
SKIN CONTACT. GOGGLES MAY BE APPROPIATE DURING OTHER PHASES OF
PRODUCT HANDLING.
Supplemental Safety and Health
AN ALUMINIZED APRON IS TO BE WORN DURING THE PLASMA SPRAY PROCESS.
OTHER APPROPRIATE PROTECTIVE CLOTHING MAY BE WORN AS NECESSARY
DURING PRODUCT HANDLING TO AVOID EXCESSIVE CONTACT WITH THE SKIN.
================== Physical/Chemical Properties ==================
HCC:N1
Solubility in Water:INSOLUBLE
Appearance and Odor:GRAY POWDER, NO ODOR
================= Stability and Reactivity Data =================
SEE OTHER INFORMATION.
Hazardous Decomposition Products:OZONE & NITRIC OXIDE ARE FORMED BY
PLASMA FLAME(SIMILAR TO WELDING FUMES). THIS ACTION IS INDEPENDENT
OF METAL POWDER. WHEN MOLYBDENUM IS HEATED TO DECOMPOSITION, TOXIC
FUMES OF MOLYBDENUM ARE EMITTED.
Conditions to Avoid Polymerization:WILL NOT OCCUR
=================== Toxicological Information ===================
Toxicological Information:NOT PROVIDED
===================== Ecological Information =====================
Ecological:NOT PROVIDED
==================== Disposal Considerations ====================
Waste Disposal Methods:EMPTY PRODUCT CONTAINERS, PRODUCT WASTE AND
CLEANING MEDICAL SHOULD BE STORED AND DISPOSED OF ACCORDING TO THE
APPROPRIATE LOCAL, STATE AND FEDERAL REGULATORY GUIDELINES.
=================== MSDS Transport Information ===================
Transport Information:NOT PROVIDED
===================== Regulatory Information =====================
SARA Title III Information:COBALT, CHROMIUM, NICKEL: *INDICATES TOXIC
CHEMICAL(S) SUBJECT TO THE REPORTING REQUIREMENTS OF SECTION 313 OF
TITLE III OF THE SUPERFUND AMENDMENTS & REAUTHORIZATION ACT (SARA)
& SUPPLIER NOTIFICATIO N REQUIREMENTS (40 CFR PART 372).
Federal Regulatory Information:COBALT, CHROMIUM, NICKEL: +INDICATES ON
THE LIST OF HAZARDOUS AIR POLLUTANTS THAT ARE REGULATED UNDER
SECTION 112 OF THE EPA CLEAN AIR ACT, 1990.
State Regulatory Information:
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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