===================== Product Identification =====================
MSDS NAME:98-0211-9221-0, HFE-71DE 3M NOVEC ENGINEERED FLUID
NIIN:01-459-0070
Status Code:A
MSDS Number: CLPVW
=== Responsible Party ===
Company:MINNESOTA MINING AND MFG CO
Address:3M CENTER BLDG 224-5S-04
City:SAINT PAUL
State:MN
ZIP:55144-1000
Country:US
Info Phone Num:800-364-3577 OR 651-737-6501(24HR)
Emergency Phone Num:651-737-6501
Resp. Party Other MSDS Num.:07-7119-6
CAGE:76381
=== Contractor Identification ===
Company:MINNESOTA MINING AND MFG CO, DBA 3M
Address:3M CENTER BLDG 224-5S-04
Box:City:SAINT PAUL
State:MN
ZIP:55144-1000
Country:US
Phone:866-556 5712 / 612-733-1110
Contract Num:SP0450-02-M-M144
CAGE:76381
============= Composition/Information on Ingredients =============
Name:METHYL NONAFLUOROISOBUTYL ETHER
CAS:163702-08-7
Minumum % Wt:25.
Maxumum % Wt:36.
ACGIH TLV:750 PPM
Name:METHYL NONAFLUOROBUTYL ETHER
CAS:163702-07-6
Minumum % Wt:15.
Maxumum % Wt:26.
ACGIH TLV:750 PPM
Name:1,2-TRANS-DICHLOROETHYLENE
CAS:156-60-5
RTECS #:KV9400000
Minumum % Wt:49.
Maxumum % Wt:51.
OSHA PEL:200 PPM
ACGIH TLV:200 PPM
EPA Rpt Qty:1000 LBS
DOT Rpt Qty:1000 LBS
===================== Hazards Identification =====================
Health Hazards Acute and Chronic:EYE: MODERATE EYE IRRITATION. SKIN:
MODERATE SKIN IRRITATION. INHALATION: CENTRAL NERVOUS SYSTEM
DEPRESSION. IRRITATION OF UPPER RESPIRATORY. INGESTION: INGESTION
IS NOT A LIKELY ROUTE OF EXPOSURE TO THIS PRODUCT. INGESTION MAY
CAUSE CENTRAL NERVOUS SYSTEM DEPRESSION.
Effects of Overexposure:EYE:CAN INCLUDE REDNESS, SWELLING, PAIN,
TEARING, AND HAZY VISION. SKIN: CAN INCLUE REDNESS, SWELLING,
ITCHING, AND DRYNESS. INHALATION: CAN INCLUDE HEADACHE, DIZZINESS,
DROWSINESS, INCOORDINATION, SL OWED REACTION TIME, SLURRED SPEECH,
GIDDINESS & UNCONSCIOUSNESS, SORENESS OF THE NOSE & THROAT,
COUGHING & SNEEZING. INGESTION: CAN INCLUDE HEADACHE, DIZZINESS,
DROWSINESS, MUSCULAR WEAKNESS, INCOORDI NATION, SLOWED REACTION
TIME, FATIGUE, BLURRED VISION, SLURRED SPEECH, GIDDINESS, TREMORS &
CONVULSIONS.
======================= First Aid Measures =======================
First Aid:EYE: IMMEDIATELY FLUSH EYES WITH LARGE AMOUNTS OF WATER. GET
IMMEDIATE MEDIAL ATTENTION. SKIN: FLUSH SKIN WITH LARGE AMOUNTS OF
WATER. IF IRRITATION PERSISTS, GET MEDICAL ATTENTION. INHALATION:
REMOVE PERSON TO FRESH AIR. IF NOT BREATHING, GIVE ARTIFICIAL
RESPIRATION. IF BREATHING IS DIFFICULT, GET IMMEDIATE MEDICAL
ATTENTION. IF SWALLOWED: IF SWALLOWED, DO NOT INDUCE VOMITING. GIVE
VICTIM TWO GLA SSES OF WATER. CALL A PHYSICIAN IMMEDIATELY. NEVER
GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON.
===================== Fire Fighting Measures =====================
Autoignition Temp:=410.C, 770.F
Lower Limits:NONE
Upper Limits:NONE
Extinguishing Media:WATER, CARBON DIOXIDE, DRY CHEMICAL, DRY POWDER.
Fire Fighting Procedures:"SEE OTHER INFORMATION SECTION"
Unusual Fire/Explosion Hazard:EXTREME CONDITIONS OF HEAT (WELDING, OPEN
FLAME, MISUSE, OR EQUIPMENT FAILURE) MAY PRODUCE DECOMPSITION
PRODUCTS THAT INCLUDE HYDROGEN FLUORIDE. NO SMOKING. NFPA HAZARD
CODES: HEALTH: 3 FIRE: 1 REA CTIVITY: 0. UNUSUAL REACTION
HAZARD: NONE.
================== Accidental Release Measures ==================
Spill Release Procedures:CONTAIN SPILL. COVER WITH ABSORBENT MATERIAL.
COLLECT SPILLED MATERIAL. CLEAN UPRESIDUE WITH AN APPROPRIATE
ORGAINC SOLVENT. READ AND FOLLOW SAFETY PRECAUTIONS ON THE SOLVENT
LABEL AND MSDS. PLACE IN METAL CONTAINER. SEAL THE CONTAINER.FOR
SPILLS RESULTING IN LARGE RELEASE IN CONFINED AREA, WARN OTHERS &
LEAVE QUICKLYY. EXPOSURE TO EXCESS VAPOR IN CONFINED SPACES MAY
CAUSE SIGNIFICANT INJURY.
====================== Handling and Storage ======================
Handling and Storage Precautions:STORE AWAY FROM ACIDS. STORE AWAY FROM
HEAT. KEEP CONTAIN ER CLOSED WHEN NOT IN USE. KEEP CONTAINER IN
WELL-VENTILATED AREA. STORE AT TEMPERATURES BELOW THE BOILING POINT
OF 41C.
Other Precautions:NO SMOKING: SMOKING WHILE USING THIS PRODUCT CAN
RESULT IN CONTAMINATION OF TOBACCO &/OR SMOKE & LEAD TO FORMATION
OF HAZARDOUS DECOMPOSITION PRODUCTS CITED IN THE REACTIVITY DATA
SECTION OF THIS MSDS . FOR ADDITIONAL HEALTH & PRECAUTIONARY
INFORMATION, INCLUDING AIR MONITORING METHODOLOGY, CONTACT 3M.
============= Exposure Controls/Personal Protection =============
Respiratory Protection:AVOID BREATHING OF VAPORS, MISTS OR SPRAY.
SELECT ONE OF THE FOLLOWING NIOSH APPROVED RESPIRATORS BASED ON
AIRBORNE CONCENTRATION OF CONTAMINANTS AND IN ACCORDANCE WITH OSHA
REGULATIONS: HALF-MASKOR GANIC VAPOR RESPIRATOR, FULL-FACE ORGANIC
VAPOR RESPIRATOR. IF THERMAL DECOMPOSITION OCCURS WEAR SUPPLIED
AIR RESPIRATORY PROTECTION.
Ventilation:USE IN WELL-VENTILATED AREA. PROVIDE SUFFICIENT VENTILATION
TO MAINTAIN EMISSIONS BELOW RECOMMENDED EXPOSURE LIMITS.
Protective Gloves:POLYETHYLENE/ETHYLENE VINYL ALCOHOL.
Eye Protection:WEAR VENTED GOGGLES. WEAR SAFETY GLASSES WITH SIDE
SHIELDS.
Other Protective Equipment:AVOID SKIN CONTACT. WEAR APPROPRIATE GLOVES
WHEN HANDLING THIS MATERIAL. USE ONE OR MORE OF THE FOLLOWING
PERSONAL PROTECTION ITEMS AS NECESSARY TO PREVENT SKIN CONTACT:
APRON.
Work Hygienic Practices:DO NOT EAT, DRINK OR SMOKE WHEN USING THIS
PRODUCT. WASH EXPOSED AREAS THOROUGHLY WITH SOAP AND WATER. NOT AN
EXPECTED ROUTE OF EXPOSURE.
Supplemental Safety and Health
VENTILATION: IF EXHAUST VENTILATION IS NOT ADEQUATE, USE APPROPRIATE
RESPIRATORY PROTECTION. FOR SITUATIONS WHERE THE FLUID MIGHT BE
EXPOSED TO EXTREME OVERHEATING, USE WITH APPROPRIATE LOCAL EXHAUST
VENTILATION SUFFICIENT TO MAINTAIN LEVELS OF THERMAL DECOMPOSITION
PRODUCTS BELOW EXPOSURE GUIDELINES
================== Physical/Chemical Properties ==================
HCC:N1
Boiling Pt:=41.C, 105.8F
Vapor Pres:383 MMHG @ 25C
Vapor Density:CA. 4.8
Spec Gravity:1.37 G/ML
VOC Pounds/Gallon:685
Viscosity:0.45 CENTIPOISE
Evaporation Rate & Reference:59 (BUOAC=1)
Solubility in Water:SLIGHT
Appearance and Odor:CLEAR, COLORLESS LIQUID. SLIGHT ODOR.
Percent Volatiles by Volume:100
================= Stability and Reactivity Data =================
Stability Indicator/Materials to Avoid:YES
STRONG ACIDS, STRONG BASES, STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:STRONG ACIDS, STRONG BASES, STRONG
OXIDIZING AGENTS.
Hazardous Decomposition Products:HYDROGEN FLUORIDE,
PERFLUOROISOBUTYLENE (PFIB).
Conditions to Avoid Polymerization:WILL NOT OCCUR.
=================== Toxicological Information ===================
Toxicological Information:VOLATILE ORGANIC COMPOUNDS: 685 GMS/LITER
SOUTH COAST AIR QUALITY MGMT DIST METHOD. VOC LESS H2O & EXEMPT
SOLVENTS: N/A. THE TOXICITY INFORMATION ON TRANS-DICHLOROETHYLENE
HAS BEEN LIMITED TO STUDIES OF QUESTIONABLE QUALITY. THESE
STUDIES SUGGESTED LIVER & KIDNEY TOXICITY AT ELEVATED
CONCENTRATIONS. RECENTLY A 90-DAY INHALATION STUDY WAS CONDUCTED
TO CLARIFY THE TOXICITY OF TRANS-DICHLOROETHYLEN E. NO ADVERSE
EFFECTS WERE SEEN IN THIS STUDY WHICH HAD A HIGH DOSE OF 4000 PPM.
ANIMAL STUDIES REVEALED INCREASED LEVELS OF URINARY FLUORIDE AFTER
REPEATED EXPOSURE TO THE ETHER COMPONENTS.
===================== Ecological Information =====================
Ecological:THE ENVIRONMENTAL PROPERTIES OF THIS PRODUCT PRESENT A LOW
ENVIRONMENTAL HAZARD. THE COMPONENTS LABELED "RECALCITRANT" ARE
RESISTANT TO BIODEGRADATION. THEY ARE THEREFORE LIKELY TO PERSIST
IN THE ENVI RONMENT. THIS PRODUCT IS ESTIMATED TO HAVE MINIMAL
TOXICITY TO AQUATIC ORGANISMS (100 MG/L < LOWEST LC50, EC50, OR
IC50 < OR = 1000 MG/L). THE ESTIMATE ASSUMES NO SYNERGISTIC,
ANTAGONISTIC OR NONADDIT IVE EFFECTS. TAKE PRECAUTIONS TO PREVENT
DIRECT RELEASE OF THIS PRODUCT TO THE ENVIRONMENT. ATMOSPHERIC
DEGRADATION PRODUCTS ARE EXPECTED TO INCLUDE:FOR METHYL
NONAFLUOROISOBUTYL ETHER - C02, HF, CF3C 00H, & ISOPERFLUOROBUTYRIC
ACID.
==================== Disposal Considerations ====================
Waste Disposal Methods:AS A DISPOSAL ALTERNATIVE, INCINERATE IN THE
PRESENCE OF A COMBUSTIBLE MATERIAL IN AN INDUSTRIAL OR COMMERCIAL
FACILITY CAPABILE OF HANDLING HALOGENATED WASTE. DISPOSE OF
COMPLETELY ABSORBED WASTE PRO DUCT IN A HAZARDOUS WASTE FACILITY.
RECLAIM IF FEASIBLE. FOR INFORMATION ON PRODUCT RETURN, CONTACT
YOUR DISTRIBUTOR.
=================== MSDS Transport Information ===================
Transport Information:TRANSPORTATION INFORMATION: NOT REGULATED, ALL
TRANSPORTATION MODES.
===================== Regulatory Information =====================
SARA Title III Information:EPCRA HAZARD CLASS: FIRE HAZARD: NO
PRESSURE: NO; REACTIVITY: NO; ACUTE: YES; CHRONIC: YES. EPCRA
311/312 REPORTABLE QUANTITY = NOT REPORTABLE.
Federal Regulatory Information:THE COMPONENTS OF THIS PRODUCT ARE IN
COMPLIANCE WITH THE CHEMICAL NOTIFICATION REQUIREMENTS OF TSCA.
U.S. EPA HAZARDOUS WASTE N0=NONE (NOT U.S. EPA HAZARDOUS). THE
COMPONENTS OF THIS PRODUCT ARE IN C OMPLIANCE WITH THE CHEMICAL
REGISTRATION REQUIREMENTS OF TSCA, ELINCS, MITI. THE U.S.
ENVIRONMENTAL PROTECTION AGENCY (EPA) HAS LISTED THE INGREDIENTS OF
3M(TM) HFE-71DE AS ACCEPTABLE SUBSTITUTES FOR OZONE DEPLETING
SUBSTANCES IN SPECIFIC SOLVENT CLEANING & AEROSOL INDUSTRY
APPLICATIONS UNDER ITS SIGNIFICANT NEW ALTERNATIVES PROGRAM
(SNAP). SECTION 612 OF THE CLEAN AIR ACT REQUIRES THE EPA TO
ADMINISTER THIS PROGRAM .
======================= Other Information =======================
Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
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