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MSDS Material Safety Data Sheet
CAS

7440-31-5
7439-92-1
7440-36-0
7440-50-8
7440-22-4
7440-69-9
7440-66-6

File Name: MSDS_Lead_Solder_US_24Mar06.asp
                                                                                                                        Page 1/7
Material Safety Data Sheet
acc. to ISO/DIS 11014

Printing date 03/24/2006 Reviewed on 02/14/2006

* 1 Identification of substance

Product details

Trade name: SOLDER ALLOYS CONTAINING LEAD
Application of the substance / the preparation: Solder

Manufacturer/Supplier:
Kester Tel.(847) 297-1600
515 E. Touhy Ave. Fax.(847) 390-9338
Des Plaines, IL 60018

Information department:
MSDS Coordinator Tel. (847) 699-5755
Emergency information:
CHEMTREC 24-Hour Emergency Telephone Number: (800)424-9300
CHEMTREC 24-Hour Emergency Telephone Number (Outside of the U.S. and Canada): (703)527-3887


2 Composition/Data on components

Chemical characterization
Description: Mixture of the substances listed below with nonhazardous additions.
Dangerous components:
7440-31-5 tin 0-100%
7439-92-1 lead 0-100%
7440-36-0 antimony 0-100%
7440-50-8 copper 0-100%
7440-22-4 silver 0-100%
7440-69-9 bismuth 0-100%
7440-66-6 Zinc 0-100%
Additional information:
Composition and weight percent of solder alloys varies widely and can be determined by product label.


3 Hazards identification

WHMIS Hazard Symbols



=
Information pertaining to particular dangers for man and environment:
The product has to be labelled due to the calculation procedure of international guidelines.
Harmful by inhalation and if swallowed.
Danger of cumulative effects.
Possible risk of impaired fertility.
Contains lead. Should not be used on surfaces liable to be chewed or sucked by children.
(Contd. on page 2)
USA




DR
Page 2/7
Material Safety Data Sheet
acc. to ISO/DIS 11014

Printing date 03/24/2006 Reviewed on 02/14/2006

Trade name: SOLDER ALLOYS CONTAINING LEAD

(Contd. of page 1)
NFPA ratings (scale 0 - 4)
Health = 2
0 Fire = 0
2 0 Reactivity = 0
HMIS-ratings (scale 0 - 4)
HEALTH *2 Health = *2
Fire = 0
FIRE 0
Reactivity = 0
REACTIVITY 0




4 First aid measures

General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
After inhalation: Supply fresh air; consult doctor in case of complaints.
After skin contact: Immediately wash with water and soap and rinse thoroughly.
After eye contact: Rinse opened eye for several minutes under running water.
After swallowing: Seek immediate medical advice.


5 Fire fighting measures

Suitable extinguishing agents:
CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards caused by the material, its products of combustion or resulting gases:
Melted solder above 1000掳F will liberate toxic lead and/or antimony fumes.
Protective equipment: Wear self-contained respiratory protective device.


6 Accidental release measures

Person-related safety precautions: Ensure adequate ventilation
Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.
Measures for cleaning/collecting:
Melted solder will solidify on cooling and can be scraped up. Use caution to avoid breathing fumes if a gas torch is
used to cut up large pieces.
Dispose contaminated material as waste according to item 13.


7 Handling and storage

Handling:
Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Store in cool, dry place in tightly closed receptacles.
(Contd. on page 3)
USA




DR
Page 3/7
Material Safety Data Sheet
acc. to ISO/DIS 11014

Printing date 03/24/2006 Reviewed on 02/14/2006

Trade name: SOLDER ALLOYS CONTAINING LEAD

(Contd. of page 2)
Information about protection against explosions and fires: No special measures required.

Storage:
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: None.


8 Exposure controls and personal protection

Additional information about design of technical systems: No further data; see item 7.
Components with limit values that require monitoring at the workplace:
7440-31-5 tin
PEL 2 mg/m鲁
Metal
REL 2 mg/m鲁
Tin, Metal
TLV 2 mg/m鲁
7439-92-1 lead
PEL 0.05* mg/m鲁
as Pb
REL <0.1* mg/m鲁
as Pb; *Blood Pb <0.06 mg/100 g whole blood
TLV 0.05 mg/m鲁
as Pb; BEI
7440-36-0 antimony
PEL 0.5 mg/m鲁
REL 0.5 mg/m鲁
as Sb
TLV 0.5 mg/m鲁
7440-50-8 copper
PEL 0.1*;1** mg/m鲁
*fume **dusts & mists
REL 0.1*;1** mg/m鲁
*Copper fume, as Cu **Copper dusts & mists, as Cu
TLV 0.2*, 1** mg/m鲁
*fume; ** dusts&mists, as Cu
7440-22-4 silver
PEL 0.01 mg/m鲁
REL 0.01 mg/m鲁
TLV 0.1 mg/m鲁
Additional information:
PEL = Permissible Exposure Limit (OSHA)
REL= Recommended Exposure Limit (NIOSH)
TLV= Threshold Limit Value (ACGIH)
OSHA= Occupational Safety and Health Administration
ACGIH= American Conference of Governmental Industrial Hygienists
NIOSH= National Institute for Occupational Safety and Health
(Contd. on page 4)
USA




DR
Page 4/7
Material Safety Data Sheet
acc. to ISO/DIS 11014

Printing date 03/24/2006 Reviewed on 02/14/2006

Trade name: SOLDER ALLOYS CONTAINING LEAD

(Contd. of page 3)

Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
Immediately remove all soiled and contaminated clothing.
Store protective clothing separately.
Breathing equipment:
When ventilation is not sufficient to remove fumes from the breathing zone, a safety approved respirator or self-
contained breathing apparatus should be worn.
Protection of hands:



S Protective gloves


Material of gloves:
Cloth gloves
Nitrile rubber, NBR
Natural rubber, NR
Penetration time of glove material:
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:



R Tightly sealed goggles


Safety glasses


9 Physical and chemical properties

General Information

Form: Solid
Color: Silver grey
Odor: Mild

Change in condition
Melting point/Melting range: > 100掳C (> 212掳F)
Boiling point/Boiling range: 1740掳C (3164掳F)

Flash point: Not applicable.

Danger of explosion: Product does not present an explosion hazard.

Density at 20掳C (68掳F): > 7 g/cm鲁
(Contd. on page 5)
USA




DR
Page 5/7
Material Safety Data Sheet
acc. to ISO/DIS 11014

Printing date 03/24/2006 Reviewed on 02/14/2006

Trade name: SOLDER ALLOYS CONTAINING LEAD

(Contd. of page 4)

Solubility in / Miscibility with
Water: Insoluble.


10 Stability and reactivity

Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Materials to be avoided: Strong acids, strong oxidizers.
Dangerous reactions No dangerous reactions known.
Dangerous products of decomposition: No dangerous decomposition products known.


11 Toxicological information

Acute toxicity:
LD/LC50 values that are relevant for classification:
7440-69-9 bismuth
Oral LD50 5000 mg/kg (rat)
7440-36-0 antimony
Oral LD50 7000 mg/kg (rat)
Primary irritant effect:
on the skin: No irritant effect.
on the eye: Smoke during soldering can cause eye irritation.
through inhalation: May cause respiratory irritation.
through ingestion: May be harmful if swallowed.
Sensitization: No sensitizing effects known.
Additional toxicological information:
The product shows the following dangers according to internally approved calculation methods for preparations:
Harmful


12 Ecological information

General notes: Do not allow product to reach ground water, water course or sewage system.


13 Disposal considerations

Product:
Recommendation:
Must not be disposed of together with household garbage. Do not allow product to reach sewage system.

Uncleaned packagings:
Recommendation: Disposal must be made according to official regulations.
USA
(Contd. on page 6)




DR
Page 6/7
Material Safety Data Sheet
acc. to ISO/DIS 11014

Printing date 03/24/2006 Reviewed on 02/14/2006

Trade name: SOLDER ALLOYS CONTAINING LEAD

(Contd. of page 5)


14 Transport information

DOT regulations:
Hazard class: -
Not regulated.

Land transport ADR/RID (cross-border):
ADR/RID class: -
Not regulated.

Maritime transport IMDG:
IMDG Class: -
Not regulated.
Marine pollutant: No

Air transport ICAO-TI and IATA-DGR:
ICAO/IATA Class: -
Not regulated.


15 Regulations

USA The following information relates to product regulation specific to the USA.

SARA (Superfund Amendments and Reauthorization Act)
Section 355 (extremely hazardous substances):
None of the ingredient is listed.
Section 313 (Specific toxic chemical listings):
7439-92-1 lead
7440-36-0 antimony
7440-50-8 copper
7440-22-4 silver
TSCA (Toxic Substances Control Act):
All ingredients are listed.

California Proposition 65
Chemicals known to cause cancer:
WARNING: This product contains a chemical known to the State of California to cause cancer.
Chemicals known to cause reproductive toxicity:
WARNING: This product contains a chemical known to the State of California to cause birth defects and/or other
reproductive harm.

Carcinogenicity categories
EPA (Environmental Protection Agency)
7439-92-1 lead B2
IARC (International Agency for Research on Cancer)
7439-92-1 lead 2B
(Contd. on page 7)
USA




DR
Page 7/7
Material Safety Data Sheet
acc. to ISO/DIS 11014

Printing date 03/24/2006 Reviewed on 02/14/2006

Trade name: SOLDER ALLOYS CONTAINING LEAD

(Contd. of page 6)
NTP (National Toxicology Program)
None of the ingredients is listed.
TLV (Threshold Limit Value established by ACGIH)
None of the ingredients is listed.
NIOSH-Ca (National Institute for Occupational Safety and Health)
None of the ingredients is listed.
OSHA-Ca (Occupational Safety & Health Administration)
None of the ingredients is listed.

CANADA: The following information relates to product regulation specific to Canada.

Workplace Hazardous Materials Identification (WHMIS):
This product has been classified in accordance with the hazard criteria of the Canadian Controlled Products
Regulation (CPR) and the MSDS contains all of the information required by the CPR.
WHMIS Classification: D2A

EUROPEAN UNION
The following information relates to product regulation specific to the directives of the European Union.

Risk phrases:
Harmful by inhalation and if swallowed.
Danger of cumulative effects.
Possible risk of impaired fertility.

Safety phrases:
Keep out of the reach of children.
Wear suitable protective clothing and gloves.
If swallowed, seek medical advice immediately and show this container or label.
Dispose of this material and its container to hazardous or special waste collection point.

Special labeling of certain preparations:
Contains lead. Should not be used on surfaces liable to be chewed or sucked by children.


* 16 Other information
The information contained herein is based on data considered accurate and is offered solely for information,
consideration and investigation. Kester extends no warranties, makes no representations and assumes no
responsibilty as to the accuracy, completeness or suitability of this data for any purchaser's use. The data on this
Material Safety Data Sheet relates only to this product and does not relate to use with any other material or in any
process. All chemical products should be used only by, or under the direction of, technically qualified personnel
who are aware of the hazards involved and the necessity for reasonable care in handling. Hazard communication
regulations require that employees must be trained on how to use a Material Safety Data Sheet as a source for
hazard information.

Department issuing MSDS: Product Safety
* Data compared to the previous version altered.
USA




DR

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