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MSDS Material Safety Data Sheet
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31-78-6
75-45-6
354-33-6
74-98-6

File Name: msds_dupont_com---PEN_09004a2f806a3017.asp
SAFETY DATA SHEET              according to EC directive 2001/58/EC



DuPont鈩? SUVA庐 HP81 Refrigerant
Version 2.3
Revision Date 12.04.2006 Ref. 130000000382

This SDS adheres to the standards and regulatory requirements of Great Britain and may not meet the regulatory
requirements in other countries.

1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING

Product information
鈩? 庐
Product name : DuPont SUVA HP81 Refrigerant

Types : ASHRAE Refrigerant number designation: R-402B

Use of the : refrigerant
Substance/Preparation

Company Du Pont de Nemours (Nederland) B.V.
:
Baanhoekweg 22
NL-3313 LA Dordrecht
The Netherlands

Telephone : +31-78-630.1011

Telefax : +31-78-630.1181


Emergency telephone : +44-(0)8456-006.640
number


2. COMPOSITION/INFORMATION ON INGREDIENTS

Chemical Name CAS-No. EC-No. Classification Concentration [%]
Chlorodifluoromethane (R22) 75-45-6 200-871-9 N; R59 60

Pentafluoroethane (R125) 354-33-6 206-557-8 38
Propane 74-98-6 200-827-9 F+; R12 2

For the full text of the R phrases mentioned in this Section, see Section 16.

3. HAZARDS IDENTIFICATION

Dangerous for the ozone layer.
Rapid evaporation of the liquid may cause frostbite.
Vapours are heavier than air and can cause suffocation by reducing oxygen available for breathing.

4. FIRST AID MEASURES

General advice : If unconscious place in recovery position and seek medical advice. Never give
anything by mouth to an unconscious person. If breathing is irregular or
stopped, administer artificial respiration. If symptoms persist, call a physician.

Inhalation : Move to fresh air. Keep patient warm and at rest. Artificial respiration and/or
oxygen may be necessary.

Skin contact : Wash off with warm water. Take off all contaminated clothing immediately.



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SAFETY DATA SHEET according to EC directive 2001/58/EC



DuPont鈩? SUVA庐 HP81 Refrigerant
Version 2.3
Revision Date 12.04.2006 Ref. 130000000382

Eye contact : Rinse thoroughly with plenty of water, also under the eyelids. Consult a
physician.

Notes to physician
Treatment : Do not give adrenaline or similar drugs.


5. FIRE-FIGHTING MEASURES

Specific hazards during fire : pressure build-up
fighting

Special protective : In the event of fire, wear self-contained breathing apparatus.
equipment for fire-fighters

Further information : Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment. Cool containers / tanks with water spray.


6. ACCIDENTAL RELEASE MEASURES

Personal precautions : Evacuate personnel to safe areas. Ventilate the area. Refer to protective
measures listed in sections 7 and 8.

Environmental precautions : Should not be released into the environment.

Methods for cleaning up : Evaporates.


7. HANDLING AND STORAGE

Handling
Advice on safe handling : Provide sufficient air exchange and/or exhaust in work rooms. For personal
protection see section 8.

Advice on protection : No special protective measures against fire required.
against fire and explosion


Storage
Requirements for storage : Keep container tightly closed in a dry and well-ventilated place. Store in original
areas and containers container.

Advice on common storage : No materials to be especially mentioned.

German storage class : 2A : Compressed, liquefied or pressurised gas


8. EXPOSURE CONTROLS / PERSONAL PROTECTION

Components with workplace control parameters
Components CAS-No. Type Control Update Basis
Form of exposure parameters

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SAFETY DATA SHEET according to EC directive 2001/58/EC



DuPont鈩? SUVA庐 HP81 Refrigerant
Version 2.3
Revision Date 12.04.2006 Ref. 130000000382

Chlorodifluoromethane 75-45-6 TWA 3 590 mg/m3 2001 EH40 OES
(R22) 1 000 ppm


TWA 3 600 mg/m3 05 2001 EU ELV
1 000 ppm



Engineering measures
Ensure adequate ventilation, especially in confined areas.

Personal protective equipment
Respiratory protection : For rescue and maintenance work in storage tanks use self-contained breathing
apparatus. Vapours are heavier than air and can cause suffocation by reducing
oxygen available for breathing.

Hand protection : heat insulating gloves

Eye protection : safety glasses

Hygiene measures : Handle in accordance with good industrial hygiene and safety practice.


9. PHYSICAL AND CHEMICAL PROPERTIES


Form : Liquefied gas,

Colour : colourless,

Odour : slight, ether-like,

pH : neutral

Boiling point/range : -48 - -47 掳C at 1 013 hPa

Flash point : does not flash

Ignition temperature : 641 掳C

Vapour pressure : 12 600 hPa at 25 掳C

Vapour pressure : 35 020 hPa at 70 掳C

Density : 1,159 g/cm3 at 25 掳C, (as liquid)


10. STABILITY AND REACTIVITY

Conditions to avoid : The product is not flammable in air under ambient conditions of temperature and
pressure. When pressurised with air or oxygen the mixture may become
flammable. Certain mixtures of HCFCs or HFCs with chlorine may become
flammable or reactive under certain conditions.


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SAFETY DATA SHEET according to EC directive 2001/58/EC



DuPont鈩? SUVA庐 HP81 Refrigerant
Version 2.3
Revision Date 12.04.2006 Ref. 130000000382


Hazardous decomposition : hydrogen halides, carbon dioxide (CO2), Carbon monoxide, fluorocarbons,
products carbonyl halides


11. TOXICOLOGICAL INFORMATION
Acute inhalation toxicity
鈥? Chlorodifluoromethane : LC50/ 4 h/ rat : 778 mg/l
(R22)
LC50/ 0,25 h/ rat : 1 237 mg/l

LC50/ 0,5 h/ mouse : 990 mg/l

鈥? Pentafluoroethane (R125) : ALC/ 4 h/ rat : > 3 480 mg/l


Sensitization
鈥? Chlorodifluoromethane : Did not cause sensitization on laboratory animals.
(R22)
Carcinogenicity : Did not show carcinogenic effects in animal experiments.
assessment

Toxicity to reproduction : Did not show mutagenic or teratogenic effects in animal experiments.
assessment

Human experience : Excessive exposures may affect human health, as follows:

Inhalation
severe shortness of breath, narcosis, Irregular cardiac activity

Further information : Rapid evaporation of the liquid may cause frostbite.


12. ECOLOGICAL INFORMATION



Toxicity to fish
鈥? Chlorodifluoromethane : static test LC50 / 96 h/ Zebra fish : 777 mg/l
(R22)


Aquatic toxicity
鈥? Chlorodifluoromethane : / EC50/ 48 h/ Daphnia: 433 mg/l
(R22)

Global warming potential : 2 200
(GWP)


13. DISPOSAL CONSIDERATIONS

Product : Can be used after re-conditioning.



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SAFETY DATA SHEET according to EC directive 2001/58/EC



DuPont鈩? SUVA庐 HP81 Refrigerant
Version 2.3
Revision Date 12.04.2006 Ref. 130000000382

Contaminated packaging : Empty pressure vessels should be returned to the supplier.


14. TRANSPORT INFORMATION

ADR
Class: 2
Classification Code: 2A
HI No:: 20
UN-No: 1078
Labelling No.: 2.2
Proper shipping name: Refrigerant gas, n.o.s. (Chlorodifluoromethane, Pentafluoroethane)

IATA_C
Class: 2.2
UN-No: 1078
Labelling No.: 2.2
Proper shipping name: Refrigerant gas, n.o.s. (Chlorodifluoromethane, Pentafluoroethane)

IMDG
Class: 2.2
UN-No: 1078
Labelling No.: 2.2
Proper shipping name: Refrigerant gas, n.o.s. (Chlorodifluoromethane, Pentafluoroethane)


15. REGULATORY INFORMATION

Labelling according to EC Directives
Symbol(s) : N Dangerous for the environment


R-phrase(s) : R59 Dangerous for the ozone layer.


S-phrase(s) : S59 Refer to manufacturer / supplier for information on recovery /
recycling.



16. OTHER INFORMATION

Text of R phrases mentioned in Section 2
R12 Extremely flammable.
R59 Dangerous for the ozone layer.

Further information
Before use read DuPont鈥檚 safety information., For further information contact the local DuPont office or DuPont鈥檚

nominated distributors., DuPont鈥檚 registered trademark



The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at
the date of its publication. The information given is designed only as a guidance for safe handling, use, processing,

5/6
SAFETY DATA SHEET according to EC directive 2001/58/EC



DuPont鈩? SUVA庐 HP81 Refrigerant
Version 2.3
Revision Date 12.04.2006 Ref. 130000000382

storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such material used in
combination with any other materials or in any process, unless specified in the text.




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