MATERIAL SAFETY DATA SHEET
RAGE鈩? D-TECH HERBICIDE
MSDS Ref. No.: F18-62-6
Date Approved: 12/05/2007
Revision No.: 2
This document has been prepared to meet the requirements of the U.S. OSHA Hazard Communication
Standard, 29 CFR 1910.1200; the EC directive, 2001/58/EC and other regulatory requirements. The
information contained herein is for the concentrate as packaged, unless otherwise noted.
1. PRODUCT AND COMPANY IDENTIFICATION
RAGE鈩? D-TECH HERBICIDE
PRODUCT NAME:
6363
PRODUCT CODE:
Carfentrazone-ethyl*; 2,4-D 2-ethylhexyl Ester**
ACTIVE INGREDIENT(S):
Triazolinone*; Phenoxy Herbicide**
CHEMICAL FAMILY:
C15H14N3O3F3Cl2*; C16H22Cl2O3**
MOLECULAR FORMULA:
FMC 116426; F8426; Ethyl 2-chloro-3-[2-chloro-4-fluoro-5-[4-
SYNONYMS:
(difluoromethyl)-4,5-dihydro-3-methyl-5-oxo-1H-1,2,4-triazol-1-
yl]phenyl]-propanoate; IUPAC: 2-chloro-3-[2-chloro-5-(4-
difluoromethyl-3-methyl-5-oxo-4,5-dihydro-[1,2,4] triazol-1-yl)-4-
fluoro-phenyl] propionic acid ethyl ester, or Ethyl 2-chloro-3-[2-
chloro-5-(4-difluoromethyl-3-methyl-5-oxo-4,5-dihydro-[1,2,4]
triazol-1-yl)-4-fluoro-phenyl] propionate*;
2,4-dichlorohenoxy acetic acid, 2-ethylhexyl ester**
ADDITIONAL SYNONYMS: F6119 (formulation)
MANUFACTURER EMERGENCY TELEPHONE NUMBERS
FMC CORPORATION (800) 331-3148 (Medical - U.S.A. & Canada)
Agricultural Products Group (651) 632-6793 (Medical - Collect - All Other Countries)
1735 Market Street
Philadelphia, PA 19103
(215) 299-6000 (General Information) For leak, fire, spill, or accident emergencies, call:
msdsinfo@fmc.com (Email - General Information) (800) 424-9300 (CHEMTREC - U.S.A. & Canada)
(703) 527-3887 (CHEMTREC - Collect - All Other Countries)
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RAGE鈩? D-TECH HERBICIDE (F18-62-6) Date: 12/05/2007
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
鈥? Amber liquid with a phenolic odor.
鈥? Moderately combustible. May support combustion if heated above the product's flash point (see
Section 9, "Physical and Chemical Properties" below).
鈥? May react violently with strong oxidizing agents.
鈥? Thermal decomposition and burning may form toxic by-products.
鈥? For large exposures or fire, wear personal protective equipment.
鈥? Highly toxic to algae and toxic to fish and aquatic organisms. Keep out of drains and water courses.
鈥? Moderately irritating to the skin and eyes.
POTENTIAL HEALTH EFFECTS: Effects from overexposure may result from ingestion
or coming into contact with the skin or eyes. Symptoms of overexposure include lethargy and decreased
and labored respiration, burning sensation in the throad and chest, weakness, loss of appetite and weight,
and slight albuminuria.
MEDICAL CONDITIONS AGGRAVATED: None presently known.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Chemical Name CAS# Wt.% EC No. EC Class
Carfentrazone-ethyl 128639-02-1 1.44 None R50/53; S60-61
2,4-D 2-ethylhexyl Ester 1928-43-4 65.52 217-673-3 Not classified
Surfactant Blend <29 None Not classified
4. FIRST AID MEASURES
EYES: Flush with water for at least 15 minutes. If irritation occurs and persists, contact a medical
doctor.
SKIN: Remove contaminated clothing and thoroughly wash with soap and water. If irritation occurs and
persists, contact a medical doctor.
INGESTION: Drink 1 or 2 glasses of water. Never give anything by mouth to an unconscious
person. If any discomfort persists, obtain medical attention.
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RAGE鈩? D-TECH HERBICIDE (F18-62-6) Date: 12/05/2007
INHALATION: Remove to fresh air. If breathing difficulty or discomfort occurs and persists, obtain
medical attention.
NOTES TO MEDICAL DOCTOR: This product has low oral, dermal and inhalation
toxicity. It is moderately irritating to the skin and eyes. Treatment is otherwise controlled removal of
exposure followed by symptomatic and supportive care.
5. FIRE FIGHTING MEASURES
EXTINGUISHING MEDIA: Foam, CO2 or dry chemical. Soft stream water fog only if
necessary. Contain all runoff.
FIRE / EXPLOSION HAZARDS: Moderately combustible. When heated above the flash
point, this material releases vapors which, when mixed with air, can burn or be explosive.
FIRE FIGHTING PROCEDURES: Isolate fire area. Evacuate downwind. Wear full
protective clothing and self-contained breathing apparatus. Do not breathe smoke, gases or vapors
generated.
6. ACCIDENTAL RELEASE MEASURES
RELEASE NOTES: Isolate and post spill area. Wear protective clothing and personal protective
equipment as prescribed in Section 8, "Exposure Controls/Personal Protection". Keep unprotected persons
and animals out of the area.
Keep material out of lakes, streams, ponds and sewer drains. Large spills should be covered to prevent
dispersal. For dry material, use a wet sweeping compound or water to prevent the formation of dust. If
water is used, prevent runoff or dispersion of excess liquid by diking and absorbing with a non-combustible
absorbent such as clay, sand or soil. Vacuum, shovel or pump all waste material, including absorbent, into
a drum and label contents for disposal.
If spilled in soil, remove visibly contaminated soil and replace with clean fill. To clean and neutralize spill
area, tools and equipment, wash area with a suitable solution of caustic or soda ash and an appropriate
alcohol (i.e., methanol, ethanol or isopropanol). Follow this by washing with a strong soap and water
solution. Absorb, as above, any excess liquid and add to the drums of waste already collected. Repeat if
necessary. Dispose of drummed waste according to the method outlined in Section 13, "Disposal
Considerations".
7. HANDLING AND STORAGE
HANDLING AND STORAGE: Store in a cool, dry, well-ventilated place. Do not use or
store near heat, open flame or hot surfaces. Do not store near strong oxidizers. Store in original containers
only. Keep out of reach of children and animals. Do not contaminate other pesticides, fertilizers, water,
food or feed by storage or disposal.
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RAGE鈩? D-TECH HERBICIDE (F18-62-6) Date: 12/05/2007
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS: Use local exhaust at all process locations where vapor or
mist may be emitted. Ventilate all transport vehicles prior to unloading.
PERSONAL PROTECTIVE EQUIPMENT
EYES AND FACE: For splash, mist or spray exposure, wear chemical protective goggles
or a face shield with safety glasses.
RESPIRATORY: For splash, spray or mist exposure wear, as a minimum, a properly
fitted half-face or full-face air-purifying respirator with organic vapor cartridges (approved by U.S.
NIOSH/MSHA, EU CEN or comparable certification organization). Respirator use and selection
must be based on airborne concentrations.
PROTECTIVE CLOTHING: Depending upon concentrations encountered, wear
coveralls or long-sleeved uniform and head covering. For larger exposures as in the case of spills,
wear full body cover barrier suit, such as a PVC suit. Leather items - such as shoes, belts and
watchbands - that become contaminated should be removed and destroyed. Launder all work
clothing before reuse (separately from household laundry).
GLOVES: Wear chemical protective gloves made of materials such as nitrile or neoprene.
Thoroughly wash the outside of gloves with soap and water prior to removal. Inspect regularly for
leaks.
WORK HYGIENIC PRACTICES: Clean water should be available for washing in case of
eye or skin contamination. Wash skin prior to eating, drinking, chewing gum, or using tobacco. Shower at
the end of the workday.
COMMENTS:
NOTE: Personal protective recommendations for mixing or applying this product are prescribed on the
product label. Information stated above provides useful, additional guidance for individuals whose use or
handling of this product is not guided by the product label.
9. PHYSICAL AND CHEMICAL PROPERTIES
Phenolic
ODOR:
Amber liquid
APPEARANCE:
1.083 g/mL (9.04 lb/gal) at 20潞C (68潞F)
DENSITY / WEIGHT PER VOLUME:
> 110 掳C (> 230 掳F)
FLASH POINT:
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RAGE鈩? D-TECH HERBICIDE (F18-62-6) Date: 12/05/2007
412.2 (carfentrazone-ethyl) 333 (2,4-D 2-ethylhexyl
MOLECULAR WEIGHT:
Ester)
3.5 at 22.3潞C (72潞F)
pH:
32.6 cSt @ 25潞C (77潞F)
VISCOSITY:
10. STABILITY AND REACTIVITY
Excessive heat and fire. Strong oxidizing agents.
CONDITIONS TO AVOID:
Stable
STABILITY:
Will not occur
POLYMERIZATION:
Carbon monoxide, carbon dioxide, nitrogen oxides,
HAZARDOUS DECOMPOSITION PRODUCTS:
hydrogen chloride, hydrogen fluoride and
phosgene.
11. TOXICOLOGICAL INFORMATION
EYE EFFECTS: Moderately irritating (rabbit)
SKIN EFFECTS: Moderately irritating (rabbit)
DERMAL LD50: > 5,000 mg/kg (rat)
ORAL LD50: 3,110 mg/kg (rat)
INHALATION LC50: > 2.06 mg/l (4 h) (rat) Zero mortality
SENSITIZATION: (Skin) Sensitizing (guinea pig)
ACUTE EFFECTS FROM OVEREXPOSURE: This product has low oral, dermal
and inhalation toxicity. It is moderately irritating to the skin and eyes. Signs of toxicity in laboratory
animals may include hunched posture, ataxia, pilo-erection, lethargy, decreased respiratory rate,
chromodacryorrhea, ptosis, tremors and tonic convulsions.
Symptoms of exposure to 2,4-D 2-ethylhexyl ester may include a burning sensation in the throat and chest,
weakness, loss of appetite and weight, and slight albuminuria. Excessive exposure may cause liver, kidney,
gastrointestinal and muscular effects. Signs and symptoms of over exposure may be nausea, vomiting,
abdominal cramps and/or diarrhea.
CHRONIC EFFECTS FROM OVEREXPOSURE: No data available for the
formulation. In studies with laboratory animals, carfentrazone-ethyl did not cause reproductive toxicity,
teratogenicity, or carcinogenicity. An overall absence of genotoxicity has been demonstrated in tests of
mutagenicity, DNA damage and chromosome aberrations.
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RAGE鈩? D-TECH HERBICIDE (F18-62-6) Date: 12/05/2007
In studies with laboratory animals, chronic exposures to 2,4-D 2-Ethylhexyl Ester caused damage to the
liver, kidneys and nervous system with possible damage to striated muscle and the brain. Exposures having
no adverse effects on the mother had other harmful effects on the fetus. Animal mutagenicity studies were
predominantly negative; in-vitro mutagenicity studies were negative. Excessive dietary levels have caused
decreased weight and survival in offspring in a rat reproduction study. IARC lists Chloropheoxy Herbicides
(2,4-D 2-ethylhexyl ester) as a Class 2B carcinogen (limited evidence in humans). The Science Advisory
Panel of EPA has given it a Class D status (not classifiable as to human carcinogenicity).
CARCINOGENICITY:
Chemical Name IARC NTP OSHA Other
2,4-D 2-ethylhexyl Ester 2B Not listed Not listed (ACGIH) Not listed
12. ECOLOGICAL INFORMATION
ENVIRONMENTAL DATA: Carfentrazone-ethyl is rapidly degraded in soil (DT50 < 1.5
days) through microbial degradation, initially by hydrolysis to F8426-chloropropionic acid, and then
through further side-chain degradation to other acids. Based on field studies, carfentrazone-ethyl and its
major metabolite, F8426-chloropropionic acid, are confined to the top soil layer, indicating only slight
mobility in soil. Carfentrazone-ethyl is hydrolytically unstable in base (half-life of 5.1 hours), with stability
increasing with decreasing pH. It is susceptible to photolytic degradation in water, with a half-life of 8.3
days (pH 5). The Log Pow is 3.36 and the measured bioconcentration factor in whole fish is 159, both
indicating a low potential for accumulation. Its vapor pressure is 1.19 x 10-7 torr, indicating that volatility
is not a concern with this chemical.
2,4-D is expected to readily biodegrade in soils (reported half-life ranges from <1 day to several weeks). Its
adsorption to soil will likely depend on the amount of organic matter present and the pH of the soil (pKa =
2.64). Migration to groundwater may occur in course, sandy soils, and is enhanced at high pH. Degradation
in water is expected to occur rapidly, with reported half-life values from 10 to >50 days. In aquatic
sediments, the reported half-life is <1 day. 2,4-D is not expected to bioconcentrate in aquatic organisms.
ECOTOXICOLOGICAL INFORMATION: Carfentrazone-ethyl is very toxic to algae
(EC50: 5.7 to 17 碌g/L), and much less toxic to fish (LC50: 1.6 to 2.0 mg/L), and aquatic crustacea (LC50 >
9.8 mg/L). Care should be taken to avoid contamination of the aquatic environment. In a test with
earthworms, carfentrazone-ethyl was shown to cause no effects at concentrations up to 820 mg/kg in soil.
Carfentrazone-ethyl shows little toxicity to birds either orally (LD50 > 2,250 mg/kg), or in the diet (LC50 >
5,620 ppm). Similarly, carfentrazone-ethyl has low toxicity to bees (no death at 200 碌g/bee).
2,4-D 2-Ethylhexyl Ester is slightly toxic to aquatic organisms on an acute basis with LC50 between 10 and
100 mg/L in most sensitive species. It is not expected to bioconcentrate in aquatic organisms.
LC50 = 18.7 mg/L water flea (Daphnia magna); Maximum acceptable toxicant concentration (MATC) -
0.020 mg/L
LC50 > 5.0 mg/L fathead minnow (Pimephales promelas); Maximum acceptable toxicant concentration
(MATC) = 0.16 mg/L
LC50 > 5.0 mg/L rainbow trout (Oncorhynchus mykiss)
LC50 > 5.0 g/L bluegill (Lepommis macrochirus)
LC50 > 0.24 mg/L tidewater silverside (Menidia beryllina)
EC50 > 0.21 mg/L shell deposition inhibition in easter oyster (Crassostrea virginica)
2,4-D 2-Ethylhexyl Ester is slightly toxic to birds on an acute basis with LD50 between 501 and 2,000
mg/L. It is practically non-toxic to birds on a dietary basis with an LC50 > 5,000 ppm.
LD50 (oral) = 663 mg/kg mallard (Anas platyrhynchos)
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RAGE鈩? D-TECH HERBICIDE (F18-62-6) Date: 12/05/2007
LC50 (dietary) >5,620 ppm mallard (Anas platyrhynchos)
LC50 (dietary) >5,620 ppm bobwhite (Colinus virginianus)
LC50 > 0.14 mg/L grass shrimp (Palaemonetes pugio)
EC50 > 30 mg/L green alga (Selenastrum capricornutum)
EC50 = 0.5 mg/L duckweed (Lemna sp.)
13. DISPOSAL CONSIDERATIONS
DISPOSAL METHOD: Open dumping or burning of this material or its packaging is prohibited.
If spilled material cannot be disposed of by use according to label instructions, an acceptable method of
disposal is to incinerate in accordance with local, state and national environmental laws, rules, standards
and regulations. However, because acceptable methods of disposal may vary by location and regulatory
requirements may change, the appropriate agencies should be contacted prior to disposal.
EMPTY CONTAINER: Completely empty package into application equipment. Then dispose
of empty package in a sanitary landfill or by incineration, or if allowed by State and local authorities, by
burning. If burned, stay out of smoke.
14. TRANSPORT INFORMATION
U.S. DEPARTMENT OF TRANSPORTATION (DOT)
Non-Bulk
PACKAGING TYPE:
REMARKS: 2,4-D 2-ethylhexyl ester is in
ADDITIONAL INFORMATION:
an "RQ" quantity at 154 pounds (17
gallons). In packages less than 154 pounds
(17 gallons), this material is not regulated
for transportation.
Bulk
PACKAGING TYPE:
Environmentally hazardous substance,
PROPER SHIPPING NAME:
liquid, n.o.s.
2,4-D 2-ethylhexyl ester
TECHNICAL NAME(S):
9
PRIMARY HAZARD CLASS / DIVISION:
UN 3082
UN/NA NUMBER:
III
PACKING GROUP:
9
LABEL(S):
9
PLACARD(S):
UN 3082
MARKING(S):
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RAGE鈩? D-TECH HERBICIDE (F18-62-6) Date: 12/05/2007
2,4-D 2-ethylhexyl ester
REPORTABLE QUANTITY (RQ):
INTERNATIONAL MARITIME DANGEROUS GOODS (IMDG)
Non-Bulk
PACKAGING TYPE:
Environmentally hazardous substance,
PROPER SHIPPING NAME:
liquid, n.o.s.
2,4-D 2-ethylhexyl ester
TECHNICAL NAME(S):
9
PRIMARY HAZARD CLASS / DIVISION:
UN 3082
UN/NA NUMBER:
III
PACKING GROUP:
9
LABEL(S):
9
PLACARD(S):
Environmentally hazardous substance,
MARKING(S):
liquid, n.o.s. (2,4-D 2-ethylhexyl ester), UN
3082
EmS Number: F-A, S-F
ADDITIONAL INFORMATION:
REMARKS: 2,4-D 2-ethylhexyl ester is in
an "RQ" quantity at 154 pounds (17
gallons). In packages less than 154 pounds
(17 gallons), this material is not regulated
for transportation.
ADR - EUROPEAN AGREEMENT CONCERNING THE
INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD
Non-Bulk
PACKAGING TYPE:
Environmentally hazardous substance,
PROPER SHIPPING NAME:
liquid, n.o.s.
Carfentrazone-ethyl
TECHNICAL NAME(S):
9
PRIMARY HAZARD CLASS / DIVISION:
M6
CLASSIFICATION CODE:
UN3082
UN/NA NUMBER:
III
PACKING GROUP:
90
HAZARD IDENTIFICATION NUMBER:
Carfentrazone-ethyl
MARINE POLLUTANT:
9
LABEL(S):
9
PLACARD(S):
UN3082 + Marine Pollutant
MARKING(S):
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RAGE鈩? D-TECH HERBICIDE (F18-62-6) Date: 12/05/2007
INTERNATIONAL CIVIL AVIATION ORGANIZATION (ICAO) /
INTERNATIONAL AIR TRANSPORT ASSOCIATION (IATA)
Non-Bulk
PACKAGING TYPE:
Environmentally hazardous substance,
PROPER SHIPPING NAME:
liquid, n.o.s.
Carfentrazone-ethyl
TECHNICAL NAME(S):
9
PRIMARY HAZARD CLASS / DIVISION:
UN3082
UN/NA NUMBER:
III
PACKING GROUP:
9
LABEL(S):
Y911 / 30 kg G
LIMITED QUANTITY:
914 / 450 L
LIMITED QUANTITY: PASSENGER / CARGO:
914 / 450 L
LIMITED QUANTITY: CARGO:
Carfentrazone-ethyl is toxic to algae and is
ADDITIONAL INFORMATION:
considered a Marine Pollutant under ADR.
Air shipment from, to, or within ADR
member countries are shown under IATA
above. Shipment to, from, or with the USA
presently does not recognize the ADR
Marine Pollutant criterion of "toxic to
algae".
2,4-D 2-ethylhexyl ester is in an "RQ"
quantity at 154 pounds (17 gallons). For
shipments within, from, or to the USA "2,4-
D 2-ethylhexyl ester" must be identified as
"RQ" when in packages containing 154
pounds (17 gallons) of product.
Marks: Environmentally hazardous
substance, liquid, n.o.s. (carfentrazone-
ethyl), UN3082 + Marine Pollutant
RQ: 2,4-D 2-ethylhexyl ester
OTHER INFORMATION:
HARMONIZED SYSTEM
Import to the U.S.A.: 3808.93.1500
Export from the U.S.A.: 3808.93.0000
15. REGULATORY INFORMATION
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RAGE鈩? D-TECH HERBICIDE (F18-62-6) Date: 12/05/2007
UNITED STATES
SARA TITLE III (SUPERFUND AMENDMENTS AND REAUTHORIZATION ACT)
SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355, APPENDIX A):
Not listed
SECTION 311 HAZARD CATEGORIES (40 CFR 370):
Immediate, Delayed
SECTION 312 THRESHOLD PLANNING QUANTITY (40 CFR 370):
The Threshold Planning Quantity (TPQ) for this product, if treated as a mixture, is 10,000 lbs;
however, this product contains the following ingredients with a TPQ of less than 10,000 lbs.:
None
SECTION 313 REPORTABLE INGREDIENTS (40 CFR 372):
This product contains the following ingredients subject to Section 313 reporting requirements:
2,4-D 2-ethylhexyl ester
CERCLA (COMPREHENSIVE ENVIRONMENTAL RESPONSE COMPENSATION AND
LIABILITY ACT)
CERCLA DESIGNATION & REPORTABLE QUANTITIES (RQ) (40 CFR 302.4):
Listed
Chemical Name RQ
2,4-D 2-ethylhexyl Ester 100 lb
INTERNATIONAL LISTINGS
Australian Hazard Code: 3Z
HAZARD, RISK AND SAFETY PHRASE DESCRIPTIONS:
Carfentrazone-ethyl, (Index #607-309-00-5):
EC Symbols: N (Dangerous for the environment)
EC Risk Phrases: R50/53 (Very toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.)
EC Safety Phrases: S60 (This material and its container must be disposed of as
hazardous waste)
S61 (Avoid release to the environment. Refer to special
instructions/safety data sheets.)
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RAGE鈩? D-TECH HERBICIDE (F18-62-6) Date: 12/05/2007
16. OTHER INFORMATION
REVISION SUMMARY:
This MSDS replaces Revision #1, dated March 30, 2007.
Changes in information are as follows:
Section 1 (Product and Company Identification)
Section 11 (Toxicological Information)
Section 14 (Transport Information)
Section 15 (Regulatory Information)
Section 16 (Other Information)
RAGE and FMC Logo - Trademarks of FMC Corporation
漏 2007 FMC Corporation. All Rights Reserved.
FMC Corporation believes that the information and recommendations contained herein (including data and
statements) are accurate as of the date hereof. NO WARRANTY OF FITNESS FOR ANY PARTICULAR
PURPOSE, WARRANTY OF MERCHANTABILITY, OR ANY OTHER WARRANTY, EXPRESSED
OR IMPLIED, IS MADE CONCERNING THE INFORMATION PROVIDED HEREIN. The information
provided herein relates only to the specific product designated and may not be applicable where such
product is used in combination with any other materials or in any process. It is a violation of Federal law to
use this product in a manner inconsistent with its labeling. Further, since the conditions and methods of use
are beyond the control of FMC Corporation, FMC Corporation expressly disclaims any and all liability as
to any results obtained or arising from any use of the product or reliance on such information.
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