Material Safety Data Sheet
ID: C-375
Product Name: Pronto!鈩? Background Reduction Kit
S E C T I O N 1 . C H E M I C A L P R O D U C T A N D CO M PA N Y I D E N T I F I C AT I O N
Material Name:
Liquid Sodium Borohydride
Manufacturer Information
Corning Incorporated Phone: (607) 974-0234
Life Sciences Emergency #
271 County Road 64 24 Hr CHEMTREC: (800) 424-9300
Big Flats, NY 14814 24 Hr CHEMTREC International: (703) 527-3887
S E C T I O N 2 . CO M P O S I T I O N / I N F O R M AT I O N O N I N G R E D I E N T S
CAS # Component Percent
143-24-8 Tetraethylene glycol Dimethyl Ether 80-90
16940-66-2 Sodium borohydride 10-15
Component Information/Information on Non-Hazardous Components
This product has been evaluated under the criteria specified in 29 CFR 1910.1200 (Hazard Communication
Standard).
S E C T I O N 3 . H A Z A R D S I D E N T I F I C AT I O N
Emergency Overview
Product is a clear liquid. Component (Sodium borohydride) may react with water to release flammable gases.
Contact with this material can cause burns to the eyes, skin, respiratory system and gastrointestinal tract. Pro-
longed or repeated exposure may cause headache, nausea, drowsiness, dizziness, and kidney and liver damage.
Product may cause allergic skin sensitization reactions.
Potential Health Effects: Eyes
Contact can cause moderate to severe irritation and possible burns to the eyes.
Potential Health Effects: Skin
Skin contact with this product may result in severe irritation or skin burns. Prolonged or repeated contact may
cause headache, drowsiness, dizziness, blood disorder and kidney and liver damage. Product may cause allergic
skin sensitization reactions.
Potential Health Effects: Ingestion
Ingestion of this product is unlikely. However, if ingested, severe gastrointestinal irritation may occur with
more serious symptoms developing upon ingestion of larger amounts. May cause dizziness, incoordination,
headache, nausea, and vomiting. Prolonged or repeated ingestion may have effects on the liver and kidney.
Potential Health Effects: Inhalation
Inhalation of vapors of this product may cause severe irritation and burns to the respiratory tract. Inhalation of
mists or vapors can lead to nausea, vomiting, diarrhea, headache, drowsiness, dizziness, lung congestion. Acute
or prolonged inhalation can lead to central nervous system depression and liver and kidney damage.
HMIS Ratings: Health: 3* Fire: 0 Reactivity: 2 Pers. Prot.: Safety glasses, gloves
Hazard Scale: 0 = Minimal, 1 = Slight, 2 = Moderate, 3 = Serious, 4 = Severe, * = Chronic hazard
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Product Name: Pronto!鈩? Background Reduction Kit
S E C T I O N 4 . F I R ST A I D M E A S U R E S
First Aid: Eyes
In case of contact, immediately flush eyes with large amounts of water, continuing to flush for 15 minutes.
Seek medical attention immediately.
First Aid: Skin
Immediately flush exposed area with large amounts of water while removing contaminated clothing. Get
medical attention if irritation persists. Launder contaminated clothing before reuse.
First Aid: Ingestion
If ingested, get immediate medical attention. Do not induce vomiting unless instructed to do so by medical
personnel.
First Aid: Inhalation
If inhaled, remove person to fresh air. If symptoms develop or persist, get medical attention. Call a physician
immediately if any difficulty in breathing is observed.
First Aid: Notes to Physician
None.
SECTION 5. FIRE FIGHTING MEASURES
General Fire Hazards
See Section 9 for Flammability Properties.
Product is a slight fire hazard. Component (Sodium borohydride) may react with water to release flammable
gases.
Hazardous Combustion Products
Oxides of Carbon and Boron; Hydrogen.
Extinguishing Media
Dry chemical powder
DO NOT use water, foam, carbon dioxide or halocarbon extinguishers.
Fire Fighting Equipment/Instructions
Wear full protective clothing, including helmet, self-contained positive pressure or pressure demand breathing
apparatus, protective clothing and face mask.
NFPA Ratings: Health: 3 Fire: 0 Reactivity: 2 Other: W (water reactive)
Hazard Scale: 0 = Minimal, 1 = Slight, 2 = Moderate, 3 = Serious, 4 = Severe
S E C T I O N 6 . A CC I D E N TA L R E L E A S E M E A S U R E S
Containment Procedures
Stop the flow of material, if this is without risk. Eliminate sources of ignition.
Clean-Up Procedures
Wear appropriate protective equipment and clothing during clean-up. Ventilate area. Sweep up material and
place into a sealable, properly labeled container for disposal. Avoid creating dusts. Wash spill site after material
pick up is complete. Do not flush washings to sewer or other waterways.
Evacuation Procedures
Close off area. Keep unnecessary personnel away.
Special Procedures
Clean up and dispose of waste in accordance with all Federal, State and local regulations. Regulations vary.
Consult local authorities before disposal.
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Product Name: Pronto!鈩? Background Reduction Kit
S E C T I O N 7. H A N D L I N G A N D STO R A G E
Handling Procedures
Prevent all contact with skin and eyes. Do not breathe vapors or mists. Use only non-sparking tools. Keep away
from water.
Storage Procedures
Keep container tightly closed and in a cool, well-ventilated place away from incompatible materials. Keep away
from heat, sparks, open flame and other ignition sources. Avoid prolonged exposures to light.
S E C T I O N 8 . E X P O S U R E CO N T R O L S / P E R S O N A L P R OT E C T I O N
Exposure Guidelines
A: General Product Information
No exposure limits are available for this product, however, limit exposure to a minimum.
B: Component Exposure Limits
ACGIH, OSHA, and NIOSH have not developed exposure limits for any of this product鈥檚 components.
Engineering Controls
Use local exhaust ventilation to keep exposures to a minimum.
Personal Protective Equipment
Personal Protective Equipment: Eyes/Face
Wear safety glasses with side shields. Use chemical goggles and a face shield if gross contamination potential exists.
Personal Protective Equipment: Skin
Use impervious gloves when handling. Use of protective coveralls and long sleeves is recommended to prevent
skin contact.
Personal Protective Equipment: Respiratory
If ventilation is not sufficient to effectively prevent buildup of dust or fume, appropriate NIOSH respirator
protection must be provided. Respirators should be selected by and used under the direction of a trained health
and safety professional following requirements found in OSHA鈥檚 respirator standard (29 CFR 1910.134) and
ANSI鈥檚 standard for respiratory protection (Z88.2-1992).
Personal Protective Equipment: General
Eye wash fountain and emergency showers are recommended. Use good hygiene practices when handling this
material including changing and laundering work clothing after use.
S E C T I O N 9 . P H Y S I C A L & C H E M I C A L P R O P E RT I E S
Appearance: Clear Liquid Odor: Not Available
Physical State: Liquid pH: Not Available
Vapor Pressure: Not Available Vapor Density: Not Available
Boiling Point: 529掳F (276掳C)
(Tetraethylene Glycol Dimethyl Ether)
Melting Point: Not Available
Solubility (H2O): Not Available Density: 1.035g/cm
Auto Ignition: Not Available Flash Point: 210掳F (99掳C)
Lower Flammability Limit (LFL): Not Available
Upper Flammability Limit (UFL): Not Available
OSHA Flammability Classification: IIIB Combustible Liquid
Physical Properties: Additional Information
No information available.
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Product Name: Pronto!鈩? Background Reduction Kit
S E C T I O N 1 0. C H E M I C A L STA B I L I T Y & R E A C T I V I T Y I N F O R M AT I O N
Chemical Stability
Product is stable under recommended storage conditions.
Chemical Stability: Conditions to Avoid
Keep away from water, heat, and incompatible materials.
Incompatibility
Reacts violently with water. Reacts with metals to release flammable gas which may explode. Can react with
oxidizing agents and acids.
Hazardous Decomposition
Borane/boron oxides, sodium oxide, hydrogen gas
Hazardous Polymerization
Will not occur.
S E C T I O N 1 1 . TOX I CO LO G I C A L I N F O R M AT I O N
Acute Dose Effects
A: General Product Information
Acute exposure can lead to irritation and burns to the eyes, skin, gastrointestinal tract and respiratory tract.
Acute inhalation or ingestion can lead to central nervous system depression characterized by headache,
drowsiness, slurred speech, weakness and blurred vision. Product may cause allergic skin sensitization
reactions. Acute or prolonged exposure can lead to kidney and liver damage and blood disorders.
B: Component Analysis - LD50/LC50
Tetraethylene glycol Dimethyl Ether (143-24-8)
Oral LD50 Rat: 5140 mg/kg
Carcinogenicity
A: General Product Information
None identified.
B: Component Carcinogenicity
None of this product鈥檚 components are listed by ACGIH, IARC, OSHA, NIOSH, or NTP
S E C T I O N 1 2 . E CO LO G I C A L I N F O R M AT I O N
Ecotoxicity
A: General Product Information
No data for this product is available.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
No ecotoxicity data are available for this product鈥檚 components.
Environmental Fate
No data for this product is available.
S E C T I O N 1 3 . D I S P O S A L CO N S I D E R AT I O N S
US EPA Waste Number & Descriptions
A: General Product Information
This product, if discarded directly, meets the EPA characteristic of ignitability (waste number D001). You must
test your waste using methods described in 40 CFR Part 261 to determine if it meets applicable definitions of
hazardous wastes.
B: Component Waste Numbers
No EPA Waste Numbers are applicable for this product鈥檚 components.
Disposal Instructions
Waste must be handled in accordance with all federal, state, provincial, and local regulations. Purchaser is
advised to review regulations referenced for applicability as determined by purchaser鈥檚 use of the product.
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ID: C-375
Product Name: Pronto!鈩? Background Reduction Kit
S E C T I O N 1 4 . T R A N S P O RTAT I O N I N F O R M AT I O N
US DOT Information
Shipping Name: Corrosive liquids, water-reactive n.o.s. (Sodium borohydride)
UN/NA #: UN3094 Hazard Class: 8, (4.3) Packing Group: II
Required Label(s): Corrosive; Dangerous When Wet
TDG Information
Shipping Name: Corrosive liquid, water-reactive n.o.s. (Sodium borohydride)
UN/NA #: UN3094 Hazard Class: 8, (4.3) Packing Group: II
Required Label(s): Corrosive; Dangerous When Wet
S E C T I O N 1 5 . R E G U L ATO RY I N F O R M AT I O N
US Federal Regulations
A: General Product Information
All components are on the U.S. EPA TSCA Inventory List.
B: Component Analysis
None of this products components are listed under SARA Section 302 (40 CFR 355 Appendix A),
SARA Section 313 (40 CFR 372.65), or CERCLA (40 CFR 302.4).
State Regulations
A: General Product Information
Other state regulations may apply. Check individual state requirements.
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
Component CAS CA MA MN NJ PA RI
Sodium borohydride 16940-66-2 No No No Yes No No
Component Analysis - WHMIS IDL
No components are listed in the WHMIS IDL.
Additional Regulatory Information
A: General Product Information
No additional information.
B: Component Analysis - Inventory
Component CAS # TSCA DSL EINECS
Tetraethylene glycol Dimethyl Ether 143-24-8 Yes Yes Yes
Sodium borohydride 16940-66-2 Yes Yes Yes
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Product Name: Pronto!鈩? Background Reduction Kit
S E C T I O N 1 6 . OT H E R I N F O R M AT I O N
Other Information
Reasonable care has been taken in the preparation of this information, but Corning makes no warranty of
merchantability or any other warranty, expressed or implied, with respect to this information. Corning makes
no representations and assumes no liability for any direct, incidental or consequential damages resulting from
its use.
Revision information
New MSDS Version 1.000 Revision 1, 4/20/2006
Key/Legend
ACGIH = American Conference of Governmental Industrial Hygienists. CERCLA = Comprehensive
Environmental Response, Compensation and Liability Act. CFR = Code of Federal Regulations.
DSL = Canadian Domestic Substance List. EINECS = European Inventory of New and Existing Chemical
Substances. EPA = Environmental Protection Agency. HEPA = High Efficiency Particulate Air.
HMIS = Hazardous Material Identification System. IARC = International Agency for Research on Cancer.
NFPA = National Fire Protection Association. NIOSH = National Institute of Occupational Safety and Health.
NJTSR = New Jersey Trade Secret Registry. NTP = National Toxicology Program. OSHA = Occupational
Safety and Health Administration. NA = Not available or Not Applicable. SARA = Superfund Amendments
and Reauthorization Act. TLV = Threshold Limit Value. TSCA = Toxic Substance Control Act.
WHMIS = Workplace Hazardous Materials Information System.
Contact
Corporate Safety Management Services, phone (607) 974-6926
This is the end of MSDS # C-375
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