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MSDS Material Safety Data Sheet
CAS

6972-79-8
100-51-6

File Name: dixiechemical_com---13-Dibenzylglycerol_DBG_DIXIE_MSDS.asp
 
MATERIAL SAFETY DATA SHEET



                                                             DIXIE CHEMICAL COMPANY, INC.

                                                                                     P.O. Box 130410

                                                                              Houston, TX 77219-0410



                                                                                      (713) 863-1947

                                                                                 FAX: (713) 863-8316



SECTION 1 鈥? CHEMICAL IDENTIFICATION

Trade Name:       1,3-Dibenzylglycerol (DBG)           Date of Issue: August 3, 1995

Formula:          (C6H5OCH(OH)CH2O6H5)C17H20O3         Revised Date: February 6, 1998

Chemical Family:

Telephone Number:          Information       (281) 474-3271

Emergency Number:          Chemtrec          (800) 424-9300



HMIS Hazard Rating                                  4 = Extreme

Health:       2                                     3 = High

Fire:         1                                     2 = Moderate

Reactivity: 1                                       1 = Slight

PPE rating to be supplied by user                   0 = Least

depending on use conditions.



SECTION 2 鈥? COMPOSITION

Components                                     Percentage          TLV (ppm)             CAS #

1,3-Dibenzylglycerol                               97                N.E.               6972-79-8

Benzyl alcohol                                     <1                N.E.               100-51-6



                        Note: N.E. = Not Established    N/A = Not Applicable



SECTION 3 鈥? HAZARDS IDENTIFICATION

Eye Contact:    May cause slight irritation.

Skin Contact: May cause slight irritation.

Inhalation:     N.E.

Ingestion:      N.E.



SECTION 4 鈥? FIRST AID MEASURES

Eye Contact:    Immediately flush with plenty of water for at least 15 minutes. Get medical attention.

Skin Contact:   Immediately remove contaminated clothing and shoes. Wipe excess material from

                skin and flush with water for at least 15 minutes. Use soap if available or follow by

                washing with soap and water. Do not reuse contaminated clothing without

                laundering. If irritation persists, seek medical advice.

Inhalation:     Remove victim to fresh air. If breathing is difficult, give oxygen. If not breathing,

                                                                               1,3-Dibenzylglycerol (DBG), Page 2 of 4





                   administer artificial respiration. Get medical attention.

Ingestion:         Get medical attention immediately.



SECTION 5 鈥? FIREFIGHTING MEASURES

Extinguishing Media:        Use water, foam, dry chemical, or carbon dioxide (CO2).

Special Firefighting    Firefighters should wear NIOSH approved self-contained breathing apparatus.

Procedures/Precautions: Responders should wear protective clothing to prevent skin contact. Move

                        containers from fire area. If unable to move, cool sealed containers with water.

Unusual Fire and            None.

Explosion Information:

Environmental Note:         N/A.



SECTION 6 鈥? ACCIDENTAL RELEASE MEASURES

Contain and recover. Prevent from entering sewers and waterways. Clean-up personnel should wear

protective equipment to prevent contact.



SECTION 7 鈥? HANDLING AND STORAGE

Containers should be grounded and/or bonded when material is transferred. Store in a cool, dry place.

Keep away from heat, sparks, and flames.



SECTION 8 鈥? EXPOSURE CONTROLS AND PERSONAL PROTECTION

Respiratory Protection:     NIOSH approved respiratory protection for organic vapors.

Ventilation:                Utilize local exhaust to control vapors. Do not rely on general exhaust.

Protective Gloves:          Utilize appropriate impervious chemical gloves.

Eye Protection:             Chemical goggles and face shield.

Other Protective            Wear additional protective clothing to prevent skin contact. This may include

Equipment:                  aprons, chemical resistant boots, and chemical resistant suits.

Work Practices:             Use good personal hygiene practices. Wash hands before eating, drinking,

                            smoking or using toilet facilities. Promptly remove soiled clothing and wash

                            thoroughly before reuse. Shower after work using plenty of soap and water.



SECTION 9 鈥? PHYSICAL AND CHEMICAL PROPERTIES

                                     186oC @ 1 mm Hg

Boiling Point:

Volatility/Vol (%):                  N.E.

                                     2 @ 196oC

Vapor Pressure (mm Hg):

Vapor Density (Air = 1):             9.390

Solubility in H2O:                   1%

Appearance/Odor:                     Clear, pale yellow viscous liquid.

                                                                             1,3-Dibenzylglycerol (DBG), Page 3 of 4





Specific Gravity (H2O = 1):        1.093

Evap. Rate (Butyl Acetate = 1):    <1

                                   441oF (227oC) PMCC, ASTM D93

Flash Point:

Lower Explosive Limit:             N.E.

Upper Explosive Limit:             N.E.

Autoignition Temperature:          N.E.



SECTION 10 鈥? STABILITY AND REACTIVITY

Chemical Stability:             Stable.

Conditions to Avoid:            N/A.

Incompatible Materials:         Strong acids, oxidizing agents, and high heat.

Decomposition Products:         Benzyl alcohol and oxides of carbon.

Hazardous Polymerization:       Will not occur.



SECTION 11 鈥? TOXICOLOGICAL INFORMATION

ACGIH                        1,3-Dibenzylglycerol TLV:      N.E.            STEL:        N.E.

                                   Benzyl alcohol TLV:      N.E.            STEL:        N.E.

OSHA                         1,3-Dibenzylglycerol PEL:      N.E.            STEL:        N.E.

                                   Benzyl alcohol PEL:      N.E.            STEL:        N.E.



Irritation:    benzyl alcohol:

                    Skin: 16 mg/48H MLD (human)                              CTOIDG 94 (8), 41, 79 (1)

                    Skin: 10 mg/24H open MLD (rabbit)                          AMIHBC 4, 119, 51 (2)

                    Eyes: 750 mg open SEV (rabbit)                             AMIHBC 4, 119, 51 (3)

Inhalation:    benzyl alcohol:

                   LCLo: 2000 ppm/4H (rat)                                        JIDHAN 31, 343, 49 (8)

Ingestion:     benzyl alcohol:

                   LD50: 1230 mg/kg (rat)                                         FCTXAV 2, 327, 64 (7)

                   LD50: 1580 mg/kg (mouse)                                      FCTXAV 2, 327, 64 (12)

Intravenous:   benzyl alcohol:

                   LDLo: 50 mg/kg (dog)                                      TXAPA99 18, 60, 71 (14)

                   LD50: 53 mg/kg (rat)                                      TXAPA99 18, 60, 71 (11)

                   LD50: 324 mg/kg (mouse)                                   AIPTAK 135, 330, 62 (13)

Dermal:        benzyl alcohol:

                   LDLo: 10 g/kg (cat)                                           JPETAB 84, 358, 45 (16)

The toxicological effects of 1,3-Dibenzylglycerol (DBG) have not been thoroughly investigated.

Carcinogenicity listed by:    NTP: No             IARC: No                OSHA: No



SECTION 12 鈥? ECOLOGICAL INFORMATION

No data available.

                                                                                          1,3-Dibenzylglycerol (DBG), Page 4 of 4





SECTION 13 鈥? DISPOSAL INFORMATION

Place in a city, state, or federally permitted disposal facility. Handle in accordance with all applicable

regulations.



SECTION 14 鈥? TRANSPORTATION INFORMATION

DOT Shipping Name:           Not hazardous per DOT guidelines.





SECTION 15 鈥? REGULATORY INFORMATION

TSCA:                      All components are listed on the TSCA inventory.

SARA TITLE III

           Acute:          Yes

         Chronic:          No

             Fire:         No

       Reactivity:         No

         Pressure:         No



SECTION 16 鈥? OTHER INFORMATION

This chemical is for pharmaceutical use only.



                                         PPE Codes (NPCA-HMIS)

A 鈥? Glasses                                               G 鈥? Glasses, Gloves, Vapor Respirator

B 鈥? Glasses, Gloves                                       H 鈥? Goggles, Gloves, Apron, Vapor Respirator

C 鈥? Glasses, Gloves, Apron                                I 鈥? Glasses, Gloves, Dust/Vapor Respirator

D 鈥? Faceshield, Gloves, Apron                             J 鈥? Goggles, Gloves, Apron, Dust/Vapor Respirator

E 鈥? Glasses, Gloves, Dustmask                             K 鈥? Supplied Air, Gloves, Full Protective Suit, Boots

F 鈥? Glasses, Gloves, Apron, Dust Respirator



                                                    Disclaimer

      The information contained in the Material Safety Data Sheet is based on technical data that Dixie Chemical

      Company believes to be reliable and is provided to our customers at no cost. It is intended for use by persons

      having technical skill and at their own discretion and risk. Dixie Chemical Company will assume no liability

      in connection with any uses of this information and no warranties, expressed or implied, are made with

      regards to this information since conditions of use are outside Dixie Chemical Company鈥檚 control.
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