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MSDS Material Safety Data Sheet
CAS

67-64-1

File Name: dsc_dixie_edu---000100.asp
                     Material Safety Data Sheet
Acetone, 99+%
ACC# 99005

Section 1 - Chemical Product and Company Identification

MSDS Name: Acetone, 99+%
Catalog Numbers: AC177179090
Synonyms: 2-Propanone
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300

Section 2 - Composition, Information on Ingredients


CAS# Chemical Name Percent EINECS/ELINCS
67-64-1 Acetone 99+% 200-662-2
0-01-1 Formaldehyde unlisted

Hazard Symbols: XI F
Risk Phrases: 11 36 66 67

Section 3 - Hazards Identification


EMERGENCY OVERVIEW
Not available.
Target Organs: Kidneys, central nervous system, liver, respiratory system.


Potential Health Effects
Eye: Produces irritation, characterized by a burning sensation, redness, tearing, inflammation,
and possible corneal injury.
Skin: Exposure may cause irritation characterized by redness, dryness, and inflammation.
Ingestion: May cause irritation of the digestive tract. May cause central nervous system
depression, kidney damage, and liver damage. Symptoms may include: headache, excitement,
fatigue, nausea, vomiting, stupor, and coma.
Inhalation: Inhalation of high concentrations may cause central nervous system effects
characterized by nausea, headache, dizziness, unconsciousness and coma. Causes respiratory
tract irritation. May cause liver and kidney damage. May cause motor incoordination and speech
abnormalities.
Chronic: Prolonged or repeated skin contact may cause dermatitis. Chronic inhalation may cause
effects similar to those of acute inhalation.

Section 4 - First Aid Measures



Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and
lower eyelids. Get medical aid immediately.
Skin: Flush skin with plenty of water for at least 15 minutes while removing contaminated
clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid
immediately.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air
immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures



General Information: Containers can build up pressure if exposed to heat and/or fire. As in any
fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or
equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Use
water spray to keep fire-exposed containers cool.
Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam.
Flash Point: -20 deg C ( -4.00 deg F)
Autoignition Temperature: 465 deg C ( 869.00 deg F)
Explosion Limits, Lower:2.5
Upper: 13
NFPA Rating: 1 - health, 3 - flammability, 0 - instability

Section 6 - Accidental Release Measures



General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in
suitable container. Wear appropriate protective clothing to minimize contact with skin. Remove
all sources of ignition.

Section 7 - Handling and Storage



Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before
reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be dangerous.
Storage: Keep away from sources of ignition. Store in a tightly closed container.
Section 8 - Exposure Controls, Personal Protection



Engineering Controls: Use process enclosure, local exhaust ventilation, or other engineering
controls to control airborne levels below recommended exposure limits.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
250 ppm TWA; 590
500 ppm TWA; 750 ppm 1000 ppm TWA; 2400
Acetone mg/m3 TWA 2500 ppm
STEL mg/m3 TWA
IDLH
Formaldehyde none listed none listed none listed

OSHA Vacated PELs: Acetone: 750 ppm TWA; 1800 mg/m3 TWA Formaldehyde: No OSHA
Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Not available.
Skin: Wear appropriate gloves to prevent skin exposure. Wear appropriate protective gloves to
prevent skin exposure.
Clothing: Wear polyethylene gloves, apron, and/or clothing. Wear appropriate protective
clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European
Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when
necessary.

Section 9 - Physical and Chemical Properties



Physical State: Not available.
Appearance: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: 247mbar @20 deg C
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: 0.32 mPa s @20 deg C
Boiling Point: 56 deg C @760mmHg
Freezing/Melting Point:-94 deg C
Decomposition Temperature:Not available.
Solubility: Soluble.
Specific Gravity/Density:0.790
Molecular Formula:C3H6O
Molecular Weight:58.08

Section 10 - Stability and Reactivity
Chemical Stability: Stable.
Conditions to Avoid: High temperatures, temperatures above 220掳C.
Incompatibilities with Other Materials: Forms explosive mixtures with hydrogen peroxide,
acetic acid, nitric acid, nitric acid+sulfuric acid, chromic anhydride, chromyl chloride, nitrosyl
chloride, hexachloromelamine, nitrosyl perchlorate, nitryl perchlorate, permonosulfuric acid,
thiodiglycol+hydrogen peroxide.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide.
Hazardous Polymerization: May occur.

Section 11 - Toxicological Information



RTECS#:
CAS# 67-64-1: AL3150000
CAS# 0-01-1 unlisted.
LD50/LC50:
CAS# 67-64-1:
Dermal, guinea pig: LD50 = >9400 uL/kg;
Draize test, rabbit, eye: 10 uL Mild;
Draize test, rabbit, eye: 20 mg Severe;
Draize test, rabbit, eye: 20 mg/24H Moderate;
Draize test, rabbit, skin: 500 mg/24H Mild;
Inhalation, mouse: LC50 = 44 gm/m3/4H;
Inhalation, rat: LC50 = 50100 mg/m3/8H;
Oral, mouse: LD50 = 3 gm/kg;
Oral, rabbit: LD50 = 5340 mg/kg;
Oral, rat: LD50 = 5800 mg/kg;

CAS# 0-01-1:

Carcinogenicity:
CAS# 67-64-1:
ACGIH: A4 - Not Classifiable as a Human Carcinogen CAS# 0-01-1: Not listed by ACGIH, IARC,
NIOSH, NTP, or OSHA.
Epidemiology: No data available.
Teratogenicity: No information available.
Reproductive Effects: Fertility: post-implantation mortality. Ihl, mam: TCLo=31500
ug/m3/24H (1-13D preg)
Neurotoxicity: No information available.
Mutagenicity: Cytogenetic analysis: hamster fibroblast, 40 g/L Sex chromosome
loss/non-disjunction: S.cerevisiae, 47600 ppm
Other Studies: Blah Blah.

Section 12 - Ecological Information



Ecotoxicity: No data available. Hi there.
Environmental: Volatilizes, leeches, and biodegrades when released to soil.
Physical: No information available.
Other: None.
Section 13 - Disposal Considerations


Chemical waste generators must determine whether a discarded chemical is classified as a
hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts
261.3. Additionally, waste generators must consult state and local hazardous waste regulations
to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: CAS# 67-64-1: waste number U002 (Ignitable waste).

Section 14 - Transport Information


US DOT IATA RID/ADR IMO Canada TDG
No
No information
Shipping Name: information
available.
available.
Hazard Class:
UN Number:
Packing Group:


Section 15 - Regulatory Information


US FEDERAL
TSCA
CAS# 67-64-1 is listed on the TSCA inventory.
CAS# 0-01-1 is not listed on the TSCA inventory. It is for research and development use only.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
CAS# 67-64-1: 4/12b
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA

CERCLA Hazardous Substances and corresponding RQs
CAS# 67-64-1: 5000 lb final RQ; 2270 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 67-64-1: acute, chronic, flammable.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any
Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous Substances under the CWA. None
of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the
chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 67-64-1 can be found on the following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
CAS# 0-01-1 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XI F
Risk Phrases:
R 11 Highly flammable.
R 36 Irritating to eyes.
R 66 Repeated exposure may cause skin dryness or
cracking.
R 67 Vapors may cause drowsiness and dizziness.

Safety Phrases:
S 16 Keep away from sources of ignition - No
smoking.
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 9 Keep container in a well-ventilated place.

WGK (Water Danger/Protection)
CAS# 67-64-1: 0
CAS# 0-01-1: No information available.
Canada - DSL/NDSL
CAS# 67-64-1 is listed on Canada's DSL List.
Canada - WHMIS
WHMIS: Not available.
Canadian Ingredient Disclosure List
CAS# 67-64-1 is listed on the Canadian Ingredient Disclosure List.
Exposure Limits
CAS# 67-64-1: OEL-AUSTRALIA:TWA 500 ppm (1185 mg/m3);STEL 1000 ppm
OEL-AUSTRIA:TWA 750 ppm (1780 mg/m3) OEL-BELGIUM:TWA 750 ppm (1780 mg
/m3);STEL 1000 pp OEL-CZECHOSLOVAKIA:TWA 800 mg/m3;STEL 4000 mg/m3 O
EL-DENMARK:TWA 250 ppm (600 mg/m3) OEL-FINLAND:TWA 500 ppm (1200 mg/m
3);STEL 625 ppm (1500 mg/m3) OEL-FRANCE:TWA 750 ppm (1800 mg/m3) OEL
-GERMANY:TWA 1000 ppm (2400 mg/m3) OEL-HUNGARY:TWA 600 mg/m3;STEL 120
0 mg/m3 OEL-INDIA:TWA 750 ppm (1780 mg/m3);STEL 1000 ppm (2375 mg/m3)
OEL-JAPAN:TWA 200 ppm (470 mg/m3) OEL-THE NETHERLANDS:TWA 750 ppm (
1780 mg/m3) JAN9 OEL-THE PHILIPPINES:TWA 1000 ppm (2400 mg/m3) OEL-P
OLAND:TWA 200 mg/m3 OEL-RUSSIA:TWA 200 ppm;STEL 200 mg/m3 OEL-SWEDEN
:TWA 250 ppm (600 mg/m3);STEL 500 ppm (1200 mg/m3) OEL-SWITZERLAND:TW
A 750 ppm (1780 mg/m3) OEL-TURKEY:TWA 1000 ppm (2400 mg/m3) OEL-UNIT
ED KINGDOM:TWA 750 ppm (1810 mg/m3);STEL 1250 ppm OEL IN BULGARIA, CO
LOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SINGAPORE,
VIETNAM check ACGI TLV

Section 16 - Additional Information


MSDS Creation Date: 3/20/2003
Revision #0 Date: Original.
The information above is believed to be accurate and represents the best information currently available to us. However, we
make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume
no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for
their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.

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