SIGMA CHEMICAL COMPANY
A-ALDFIICH P O S T O F F T C EB O X 1 4 5 0 8
SAINT LOUIS, MTSSOURT 3L78, USA 5
ATTN: SAFETY DIRECTOR EMERGENCY ONE -314-77I.5765
PH 1
ST CLOUD STATE UNIV
AS I22 DATE 09/05/02
720 FOURTHAVE S C U S T: 0 : 4 9 ' 4 - 7 8 1 1
# 3
PO#: 98112
SAINT CLOUD MN 55301-4498
MATERIAL SAFETY DATA S.,HEET PAGE
- - -
+ - -..-
THIS MSDS IS FOR A COMPONENT CATALOG #:
OF 365-1
-CHEMICALIDSNTIFICATION.
.-+-
SECTIONl. ' r' =
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CAS #: 67-66-3
EC N0a 200-563-8
SYNONYMS
--CH-IO'd6FORM
(FRENCH) * CLOROFORMIO
(NCCTH:OSHA} * CHLOROFORME (TTAT,TAH)
X FORMYLTRICHLORIDE * METHANETRICHLORIDE X METHANE. TRICHLORO- *
METHENYLTRICHLORIDE X METHYL TRICHLORIDE * NCI _C02585 * R 20
( R E F R I G E R A N T )* . R C R A W A S T EN U M B E R O 4 4 * T R I C H L O O R M E T H A A N U T C H ) *
(D
U
(OSHA) *
*
(CZECH) t TRICHLOROFORM TRICHLOROMETHANE
TRICHLORMETHAN
r
TRTCLoRoMETANO rALrAN) * (r
r
U
H A Z A R D SI D E N T I F I C A T I O N
S E C T I O N3 .
LABEL PRECAUTIONARYSTATEMENTS
-dAiiMFur
HARMFUL
rF swALLowED.
IRRITATING TO EYES AND SKIN.
L I M I T E D E V I D E N C EO F C A R C I N O G E N I C F F E C T .
E
HARMFUL: DANGEROF SERIOUS DAMAGETO HEALTH BY PROTONGED
EXPOSUREltrBQgqE^lNH4LATrON AND IF SWALLOWED.
P R O B A B L E A R C I N O G E NU S )
(
C
POSSIBIE
MUTAGEN;-
T A R G E TO R G A N ( S ) :
LIVER
eAnDiovasqurAB_sysfEuN .
_
CALIF. PROP. 55 CARCINOGE
C A U S E SE Y E A N D S K I N I R R I T A T I O N . T : .
WEAR SUITABLE PROTECTIVECLOTHING AND GT,OVES.
S E C T I O N4 .
CONTAMINATIONOF ?HE EYES SUOUTP BE TREATED BY IIO{EDIATE AND PROLONGED
AMOUNTS OF WATER
IRRIGATION WITH COPTOUS
WASHOUT MOUTHWITH WATER PROVIDED PERSONIS CONSCIOUS.
IF SWALLOWED,
CALL A PHYS]CIAN.
I F T N H A L E D . _ B E I _ { Q V O F R E S H A r R . r F B R E A T H I N GB E C O M E S T F F T C U L T ,
TE D
CALL A PHYSICIAN.
IN CASE OF CONTACT, IMMEDIATELY WASH SKIN WITH SOAP AND COPIOUS
AMOUNTSOF WATER.
IN CASE OF CONTACTWITH EYES, FLUSH WITH COPIOUS AMOUNTS OF' WATER
FOR AT LEAST 15 MINUTES. ASSURE ADEQUATEFLUSHING BY SEPARATING
CONTINUED ON NEXT PAGE
195
T e c h n o l o g y a n d Se r u i c e .
Ve ore Cornnitted to the Success of our Custorners through Science,
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SIGMA CHEMICAL COMPANY
P O S T O F F T C EB O X 1 4 5 0 8
SAINT LOUIS, MISSOURI 63T78, USA
' 9UST#: 0-494-73811
Po#: 98112
M ATERIAL DATA
SAFETY SHEET PAGE
T H I S M S D S I S F O R A COMPONENT CATALOG 366-T
OF #:
C A T A L O G# :
NAME: CHLOROFORM
ACS GRADE
THE EYELIDS W I T H F I N G E R S . C A L L A P H Y S I C I A N .
SECTION5. FIRE FIGHTING MEASURES
E X ? I N G U I S H I N GM E D I A
WATERSPRAY.
powDER AppRopRrATE
Canscix-Didiioe, DRy cHEMTCAL FoAM.
oR
SPECIAL FIREFIGHTING PROCEDURES
_
WEAR SELF-CONTAINED EREATHTHGEpPanATuS AND PROTEcTIvE CLOTHING To
PREVEN?CONTACTWITH SKIN AND EYES.
-Fiur.rES-
-- --CoNDr
UNUSUALFIRE AND EXPLOSIONSHAZARDS
EMitS tOXrc- UNDEF- iiE
F'
r rr oNs.
- ACCIDENTAL RELEASE MEASURES-
SECTION 6.
w.qAR*gslF;.c,o{rArNED BREATT{rNGAPPARATUS, RUBBER'sOOrS AND HEAVY
RUBBERGLOVES.
WEARDISPOSABLE COVERALLSAND DISCARD THEM AFTER USE.
qN SAND OR VERMICULITE AND PLACE rN CLOSED CONTATNERS FOR
aDgQBE-
DI SPOSAL.
prcKup rs coMpr,Ers.
arya ANDwAsHsprlr. srrE AFTERMATERTAL
VENTIIATE
EVACUATEAREA.
SECTION 7. HANDLING AND STORAGE-
J E C T I O N8 .
sEcTroN 8. EXposuRE CoNTROtSIPERSONATT
PROTECTTON-
-EfE-sAfHl
USE ONLY IN A CHEMICAL FUME HOOD.
SAFetY-SHowER AND
WASHCONTAMINATED
CLOTHING BEFORE REUSE
nlasHrHoRQgql{ly-_4ITER
HANDLTNG.
DO NOT BREATHE VAPOR.
DO N9r GET -r_N__EyES, g[lN, _QN gL_OrHr .
_gN_ NG
- ^ -
AVOID,PROLONGED OR-REPEATED' EXPOSURE.
BEgprBA!oRIN NoNveNrrLATED
AREASano/on ron
N-rQqHAqHF:AppRQvED
EXPOSURE ABOVE THE ACGIH TLV.
COMPATIBLECHEMICAL-RESISTANTGLOVES,
CHEMICAL SAFETY GOGGLES
KEEP TIGHTLY CTOSED;
STORE IN A COOL DRY PLACE.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCEAND ODOR
LIQUID.
PHYSICAL PROPERTIES
50.5 -
BOILING POINT: 61.5 C
CONTINUED ON NEXT PAGE
r97
SIGMA CHEMICAL COMPANY
MA-ALDtrICH P O S T O F F T C EB O X 1 4 5 0 8
SAINT LOUTS, MTSSOURI 3178, USA 6
CUST# 0-494-73811
z
PO#: 98112
M ATERIAL DATA
SAFETY SHEET PAGE
T H I S M S D S I S FOR A COMPONENT CATALOG #:
OF 355-1
CATALOG # l
NAME: ACS GRADE
CHLOEOFORM
-53 C
MELTING POINT:
VAPOR PRESSURE: 1 5 0 M M H GG 2 0 C
SOLUBLI TY:
I
cARBoN - ,i , ,,," .
BENZENE. Mr
SSlHEF**l$"ti*t
SPECIFIC GRAVITY: 1.4.92
V A P O RD E N S IT Y : 4 . L c /' L 0 5
2
O D O RT H R E S H O L D : 307 PPM
VISCOSITY 0 . 5 5 P A S' :
SWISS POISONCLASSI':I , 1*,
.,,'t
,-
- _STABILITY AND REACTIVITY-
S E C T I O N1 0 .
::].
STABILITY
STABLE.
C O N D I T I O N ST O A V O I D
MAY DECOMPOSE EXPOSURE ON TO LIGHT.
^-LNCOMPATI LI TI ES
BI
l"sfR'bi.iG'6iini 2iNc AcENrs
|
-
HAZARDOUS PRODUCTS
OR DECOMPOSITION
COMBUSTION
CARBONMONOXTDE, .CA&lqN DIoXIDE
HAZARDOUS POLYMERIZATION
WILL NOT OCCUR.
SECTION 11. TOXICOLOGICAL NFORMATION
I
t,
ACUTE EFFECTS
ETPOSURECAN CAUSE:
VOMITI NG
NTESTINAL DI STURBANCES
GASTROI
oF ArcoHoL
ExFo-sufr'E-TO:ANDZpE-e0Ngtrdii6n
M A Y I N C R E A S ET O X I C E F F E C T S .
TO THE BEST OF OUR KNOWLEDGE, THE CHEMICAL, PHYSICAL, AND
TOXICOLOGICAL PROPERTIESHAVE NOT BEEN THOROUGHLY INVESTIGATED.
MAY CAUSE NERVOUSSYSTEMDISTURBANCES.
M A Y C A U S ES K I N I R R I T A T I O N .
MIV Fii-FAnEEUt_iF-ABSOBBSD
rHnoucHrHE sKrN.
MAY CAUSEEYE IRRITATION.
MATERIAL I-vI4Y_EE_IRRITATINGTO MUCOUSMEMBRANE$
AND UPPER
PI . _-----
RES BATOB_Y-_TBAET
MAY BE HARMFULIF INHALED.
MAY BE HARMFUL IF SWALLOWED.
CHRONIC EFFECTS
T A R G E TO R G A N ( S ) :
CARDIOVASCULAR SYSTEM
CENTRAL NERVOUS SYSTEM
BLOOD
CONTINUED ON NEXT PAGE
198
'We
to the Technology and S erotce.
are Committed Success of our Customers throrgh Science,
@ ssuPELco
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SIGMA CHEMICAL COMPANY
POST OFFTCEBOX 14508
sArNT LOUTS, MISSOURI 53178, USA
CUST#:0-494-73811
Po#: 98112
MATERIAL TA
SAFETY SHEET PAGE
DA
T H I S M S D S I S F O R A COMPONENT 356-1
OF CATALOG #:
CATALOG#:
NAME: CHLOROFORM
ACS GRADE
LIVER
KIDNEYS
LABORATORYEXPERIMENTS HAVE SHOWN MUTAGENTC EFFECTS.
T H I S I S O R C O N T A I N SA COMPONENT
THAT HAS BEEN REPORTEDTO BE
CARCINOGENICBASED ON I l s r A R c , o s H A , A c c I H , N T p O R E p A C L A S S I F I C A T I O N .
R T E C S# : F s 9 1 0 0 0 0 0
CHLOROFORM
- "SKti'jRBi"tb
IRRITATION DATA -
MrD AIHAAE23 a1srlg6z
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1 3 1, 6 9 7 . 1 9 t
1
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TOXICITY DATA
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TARGET ORGAN DATA
B E H A V I O R A L( C H A N G EI.N M O T O R C T I V I T Y )
A
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(E'E!,!ArE
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eN EMBRYo (orHER.UEAsuREs
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BEq,I
lBruqSl_DATA eRESENTED HERE. sEE AcfuAr ENfRy-iNFfEeS---FdR-
IS
COMPLETEINFORMATION.
.
SECTION 12. ECOLOGICALINF'ORMATION
DATA NOT YET AVAILABLE-
SECTION 13. DISPOSALCONSIDERATIONS
CONTINUED ON NEXT PAGE
199
SIGMA CHEMICAL COMPANY
POST OFFTCEBOX 14508
s A r N T L O U T S , M I S S O U R T6 3 L 7 8 , U S A
CUST#:0-494-73811
PO#: 981I2
MATERIAL DAf PAGE
SAFETY A
:::::
T H I S M S D S I S F O R A COMPONENT F C A T A L O G# :
O 366-1
CATALOG#:
NAME: CHLOROFORM
ACS GRADE
qONTA,qTA-!IqENSEE PROFESSIONAI,
WASTE DISPOSAL SERVICE TO DISPOSE OF
TEI S MATERIAL . -=.,
OBSERVEALL FEDERAL, STATE AND LOCAL ENVIRONMENTALREGULATIONS.
INFORMATION- -
SECTION 14. TRANSPORT
CONTACTSIGMA CHEMICAL COMPO*" 'O* i*O*S'O"'O''O* INF'ORMATION.
S E C T I O N1 5 .
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EUROPEANINFORMATION
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AND
8"5879+r
WEAR SUITABLE PROTECTIVECLOTHING AND GLOVES.
TLV AND SOURCE
FOR ETHYL ALCOHOL (ETHANOL):
ACGIH TLV-TWA: 1000 PPM (1880 MG,/M3.).
OSHAPEL: 8H TwA 1000 PPM (1900 l{G,/M3}.
REVIEWS, STANDARDS,AND REGULATIONS
t:.
OEL=MAK
pll,ygI U,ylEEI ,lggg
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I A R C C A N C E R E V I E W : A N I M A LS U F F I C I E N T E V I D E N C E I M E } I D T 2 0 , 4 0 1 , I 9 7 9
R
I A R C C A N C E R E V I E W : A N I M A L U F F I C I E N T E V I D E N C EI M E M D T7 3 ; 1 3 1 ; 1 9 9 9
R S
I A R C C A N C E RR E V I E W : H U M A NN A D E O U A T E V I D E N C E I M E M D T 2 0 . , 4 0 I . . T 9 7 9
E
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I A R C C A N C E RR E V I E I . t : H U M A N A D E O U A T E V I D E N C E I M E M D T 7 3 ' , 1 3 1 , 1 9 9 9
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I-ABE9ANQEB_BEVIEWi9RQUP_?B- ^ .240
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D T L W S *3 . 1 4 , 1 9 7 3
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(GE{_
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C F R G B RI , 5 0 - 2 0 4 . 5 0 , 1 9 9 4
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CONTINUED NEXT PAGE
ON
200
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SIGMA CHEMICAL COMPANY
P O S T O F F T C EB O X 1 4 5 0 8
SAINT LOUTS, MTSSOURT 3178, USA 6
CUST#: 0-494-7 3811
PO#: 98112
AL SAFETY DATA PAGE
MATERI SHEET
Eor-tpoxinr F
T H I S M S D S I S F ' O RA O C A T A L O G# : 365-1
CATALOG #:
NAMEI CHLOROFORM ACS GRADE
O E L - A U S T R A L I A : T W A 1 0 P P M ( 5 0 M G I M 3 ) . C A R C I N O G E NJ A N 1 9 9 3
.
OEL-AUSTRIA: MAK 10 PPM (50 MGIM3). SUSPECTED ARCINOGEN. AN1999 C J
QEL-BEL9IUM: MA IO_PPM,tq9 Yg' 43); cARqI_NocENAN1993 J
O E L - D E N M A R KT w A 2 P P M ( 1 0 M G I M 3 ) . ' J A N 1 9 9 9
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OEL-FINIAND: TwA r0 PPM (50 MGIM3), STEL 2A PPM, SKIN, CARCINOGEN,
JANI999
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O E L - I N D I A : T W A 1 0 P P M ( 5 0 M c , / M 3 ) . C A R C I N O G E NJ A N 1 9 9 3
.
O E L - J A P A N : O E L 1 0 P P M ( 4 9 M G 7 M 3 ) ; 2 8 C A R C I N O G E NJ A N 1 9 9 9
.
OEL-THE NETHERLANDS:MAC-TGG. PPM (5 MG/M3), MAC-K 5 PPM (25 MG/M3),
1
J A N 19 9 9
oEil:fr6flfrav: rwA 2 ppM (10 MG/M3). JAN]999
OEL-THE PHILIPPINES; TWA 50 PPM (240 MG1M3). JAN1993
OEL-POLAND:MAC(TwA) 50 MGIM3, MAC(STEtl 225 MG/t43. JAN1999
OEL-RUSSIAI TwA 50 PPM. JAN1993
o E L - S W E D E N :N G V 2 p p M ( 1 0 M c l M 3 ) , K T V 5 p p M ( 2 5 M G / M 3 ) , C A R C T N O G E N ,
J A N 19 9 9
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SIGMA CHEMICAL COMPANY
A-ALDFlICH P O S T O F F T C EB O X 1 4 5 0 8
S A I N T L O U I S , M I S S O U R T6 3 1 7 9 , U S A
CUST#: 0-494-73811
PO#; 98112
M ATERIAL SAFETY DATA SHEET PAGE 7
THIS MSDS IS FOR ; COMPONENT CATALOG#I
OF 355.1
' .' .
l.-. .-
C A T A L O G# : t:
NAME: CHLOROFORM
ACS GRADE
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U.S. INFORMATION
IHIS PB9D\IqI IS SqB.]ECT TO SARA $ECTION 313 REPORTINGREOUIREMENTS. -
T H _ I g P R o D U C T - I S o B C o N T A I N S C H E t { I c A t ( _ ') K N O W N o T H E - S T A f E 0 F
'S r
C A L I F O R N I A T O C A U S EC A N C E R .
- - OTHERINFORMATION-
SECTION 15.
THE ABOVE-INEORUATION IS BELIEVED TO BE CORRECT BUT DOES NOT PURPORTTO
BE ALL INCLUSIVE AND SHALL BE USED ONLY AS A GUIDE. SIGMA SHALL I{OT NE_
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