STOLLER ENTERPRISES, INC.
4001 W Sam Houston Pkwy N, Suite 100 Houston, Texas 77043 U.S.A.
Toll-Free: 1-800-539-5283 Tel.: 713-461-1493 Fax: 713-461-4467
MP鈩? COPPER MATERIAL SAFETY DATA SHEET (rev.1/04)
SECTION I PRODUCT IDENTIFICATION
NFPA HAZARD RATINGS
HEALTH HAZARD 3 FIRE HAZARD 1 REACTIVITY 0
SARA/TITLE III HAZARD CATEGORIES (See Section IX)
Immediate (ACUTE) Health: Yes Delayed (Chronic) Health: none
Reactive Hazard: none Fire Hazard: none Sudden Release of Pressure: not applicable
Company Name: STOLLER ENTERPRISES, INC.
Address: 4001 W Sam Houston Pkwy. N, Suite 100, Houston, Texas 77043 U.S.A.
Emergency Phone Number: CHEMTREC 1-800-424-9300
Phone Number for Information: 713-461-1493
Chemical Family: Metallic salts solution.
Chemical Name & Synonyms: Liquid fertilizer containing chelated copper.
Formula: Proprietary
鈩?
Trade name & Synonyms: MP COPPER (5% Cu)
SECTION II COMPOSITION/INGREDIENTS INFORMATION
INGREDIENTS: CAS # Approx. % TLV
1 mg/m3 as Cu
Copper Chloride 10125-13-0 10-15%
Sodium Gluconate 527-07-1 10-15 N/E
SECTION III PHYSICAL AND CHEMICAL CHARACTERISTICS
BOILING POINT: 220掳F (104掳C) VAPOR PRESSURE (mm/Hg): <1mm @ 68掳F (20掳C)
MELTING POINT: N/A VAPOR DENSITY (air = 1): 2.1
SPECIFIC GRAVITY: 1.19 REACTIVITY IN WATER: N/A
SOLUBILITY IN WATER: 100% EVAPORATION RATE: 0.1
APPEARANCE AND ODOR: dark blue-green solution, no odor.
OTHER:
SECTION IV FIRE AND EXPLOSION DATA
FLASH POINT: NOT ESTABLISHED
FLAMMABLE LIMITS: NOT ESTABLISHED LEL: UEL:
EXTINGUISHER MEDIA: Product is non-flammable. Use any means suitable to fight surrounding fire.
SPECIAL FIRE FIGHTING PROCEDURES: NONE
UNUSUAL FIRE AND EXPLOSION HAZARDS: NONE
SECTION V PHYSICAL HAZARDS (REACTIVITY DATA)
STABILITY: Stable
CONDITIONS TO AVOID: Stable under normal conditions.
INCOMPATIBILITY, MATERIALS TO AVOID: Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS: Carbon dioxide and other toxic fumes under fire conditions.
HAZARDOUS POLYMERIZATION: Will not occur.
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MP鈩? COPPER MSDS- (rev. 1/04)
SECTION VI HEALTH HAZARDS
A. EXPOSURE LIMITS
OSHA Permissible Exposure Limit (PEL): Not Established Threshold Limit Value (TLV): N/E
B. EFFECTS OF OVER EXPOSURE
1 ACUTE
EYES: Contact with product may cause severe irritation and possibly irreversible damage.
SKIN: Harmful if absorbed through broken skin. Large doses may cause liver and kidney damage. May cause,
discomfort, irritation, injury and death unless treated promptly.
INHALATION: Prolonged exposure to low concentration of vapors may cause temporary sore throat and headache.
INGESTION: May cause malaise, nausea, gastrointenstinal damage, or even death unless treated promptly.
2 CHRONIC; Not known.
C. EMERGENCY FIRST AID PROCEDURES:
EYES: Hold eyelids apart and immediately flush eyes with plenty of water for at least 15 minutes. Call a physician.
SKIN: Remove product and immediately wash affected area with soap and water for 15 minutes. Do not apply
greases or ointments. Launder contaminated clothing.
INHALATION: Move patient to fresh air. Supplemental oxygen may be indicated if patient has difficulty breathing.
Assure mucous does not obstruct airway. Call a physician if no improvement on patient condition.
INGESTION: If swallowed, call a physician immediately. Do not induce vomiting..
D. ADDITIONAL INFORMATION: Note to physician: symptomatic treatment.
SECTION VII SPECIAL PRECAUTIONS & SPILL/LEAK PROCEDURES
HANDLING AND STORAGE: Keep containers closed and away from oxidizing agents. Store only in shipping container:
Bulk material can be stored in polyethylene, aluminum or stainless steel tanks.
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED: It is necessary to contain spill into the smallest area
possible by diking, enclosing, etc.; replace liquid into plastic container. If liquid is absorbed onto dry carrier such as soil
or absorbent material, then this material should be put in covered labeled containers and dispose of as a dry waste.
WASTE DISPOSAL METHODS: Follow all applicable federal, state and local regulations regarding liquid fertilizers.
SECTION VIII - SPECIAL PROTECTION / CONTROL MEASURES
RESPIRATORY PROTECTION: Not specifically required. Use of a NIOSH/OSHA approved respirator is suggested.
LOCAL EXHAUST: Provide general or local exhaust ventilation. SPECIAL VENTILATION: Not applicable
PROTECTIVE GLOVES: Wear protective gloves and clothing impervious to this material.
EYE PROTECTION: Use chemical goggles. Use full faceshield when there is any likelihood of splashes.
OTHER SPECIAL EQUIPMENT: Eye wash fountain and safety shower should be located in immediate work area.
SECTION IX ENVIRONMENTAL EFFECTS DATA
This product may be toxic to fish; keep out of lakes, streams, or ponds. Otherwise, the available data on this plant nutrient
material does not indicate any undue hazard to the environment under anticipated use and storage. Any waste due to spillage
or leakage should be contained and disposed of as a Fertilizer (see above under Waste Disposal Methods). Due to its nutrient
value, may contribute to eutrophication in bodies of water.
SECTION X TRANSPORTATION DATA
PROPER SHIPPING NAME:
RQ, Environmentally hazardous substances, liquid, NOS (Copper chloride, solution), 9, UN3082, III
DOT HAZARD CLASS: 9 PLACARD: Miscellaneous (Also, Marine Pollutant if shipped by vessel)
Bill of Lading additional terminology:
鈥淲hen spilling 450 lt (119 gal) driver must report the spill immediately to the National Response Center at 1-800-424-8802鈥?
Note: Copper chloride solutions are severe marine pollutants as found on Appendix B of 49CFR 172.101, when shipped by
vessel, all packages must bear a marine pollutant marking, and the container must be placarded.
Stoller Enterprises, Inc., believes the information contained in this Material Safety Data Sheet is accurate, based on the
information supplied by reputable suppliers of our raw materials. The information contained herein is furnished without
warranty of any kind. Users should consider these data only as a supplement to other information gathered by them and must
make independent determination of suitability and completeness of information from all sources to assure proper use and
disposal of these materials and the safety and health of employees and customers.
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