MATERIAL SAFETY DATA SHEET
Emergency Phone: 800-992-5994
Dow AgroSciences LLC
Indianapolis, IN 46268
Effective Date: 19-Jun-06
Product Code: 109739
RALLY* 40WSP FUNGICIDE MSDS: 007705
NOTE TO PHYSICIAN: No specific antidote. Treatment of
1. PRODUCT AND COMPANY IDENTIFICATION:
exposure should be directed at the control of symptoms and
PRODUCT: Rally* 40WSP Fungicide the clinical condition of the patient.
5. FIRE FIGHTING MEASURES:
COMPANY IDENTIFICATION:
Dow AgroSciences, LLC
FLASH POINT: Not applicable
9330 Zionsville Road
Indianapolis, IN 46268-1189
FLAMMABLE LIMITS
LFL: Not applicable
2. HAZARDOUS IDENTIFICATIONS:
UFL: Not applicable
EMERGENCY OVERVIEW
EXTINGUISHING MEDIA: Use the following extinguishing
Tan powdered solid with a mild odor. May cause eye
media when fighting fires involving this material: carbon
irritation with corneal injury. May cause skin irritation. LD50
dioxide, dry chemical or water spray.
for skin absorption is >5000 mg/kg. Oral LD50 is >1000
mg/kg. Toxic to aquatic organisms and birds.
UNUSUAL HAZARDS: Pesticide particulates can become
EMERGENCY PHONE NUMBER: 800-992-5994
airborne. Combustion generates toxic fumes of the
following: hydrogen chloride. Dusts at sufficient
2. COMPOSITION/INFORMATION ON INGREDIENTS:
concentrations can form explosive mixtures with air. The
o
minimum ignition temperature of dust cloud is 945 F
COMPONENT CAS NUMBER W/W% o o o
(507 C) and of dust layer is 730 F (388 C).
Myclobutanil 088671-89-0 40.0
Titanium dioxide 13463-67-7 0.5-0.7 FIREFIGHTING EQUPMENT: Wear self-contained
breathing apparatus (pressure demand NIOSH approved or
Quartz 14808-60-7 0.6 鈥? 1.6
equivalent) and full protective gear.
Balance 56.9 鈥? 58.1
SPECIAL PROCEDURES: Contain run-off. Remain upwind.
4. FIRST AID: Avoid breathing smoke. Use water spray to cool containers
exposed to fire.
EYE: Hold eyes open and rinse slowly and gently with water
for 15-20 minutes. Remove contact lenses, if present, after 6. ACCIDENTAL RELEASE MEASURES:
the first 5 minutes, and then continue rinsing eyes. Call a
poison control center or doctor for treatment advice. ACTION TO TAKE FOR SPILLS/LEAKS: Sweep up small
spills and place in a suitable container for disposal. Report
SKIN: Take of contaminated clothing. Rinse skin large spills to Dow AgroSciences at 800-992-5994. Keep
immediately with plenty of water for 15-20 minutes. Call a dust to a minimum. Keep out of sewers and open bodies of
poison control center or doctor for treatment advice. water.
INGESTION: Call a poison control center or doctor Wear appropriate protective equipment when handling a
immediately for treatment advice. Have person sip a glass spill of this material. If exposed to material during clean-up
of water if able to swallow. Do not induce vomiting unless operations see Section 4 for actions to follow. Remove all
told to do so by the poison control center or doctor. Never contaminated clothing promptly. Wash all exposed skin
give anything by mouth to an unconscious person. areas with soap and water immediately after exposure.
Thoroughly launder clothing before reuse. Do not take
clothing home to be laundered.
INHALATION: Move person to fresh air. If person is not
breathing, call an emergency responder or ambulance, and
then give artificial respiration; if by mouth to mouth use
rescuer protection (pocket mask, etc.) Call a poison control
center or doctor for treatment advice.
*Trademark of Dow AgroSciences, LLC
1
MATERIAL SAFETY DATA SHEET
Emergency Phone: 800-992-5994
Dow AgroSciences LLC
Indianapolis, IN 46268
Effective Date: 19-Jun-06
Product Code: 109739
RALLY* 40WSP FUNGICIDE MSDS: 007705
ENGINEERING CONTROLS: Provide general and/or local
7. HANDLING AND STORAGE:
exhaust ventilation to control airborne levels below the
PRECAUTIONS TO BE TAKEN IN HANDLING AND exposure guidelines.
STORAGE:
RECOMMENDATIONS FOR MANUFACTURING,
HANDLING: Do not handle material near food, feed or COMMERCIAL BLENDING, AND PACKAGING
drinking water. Avoid high concentrations of dust in air and WORKERS:
accumulation of dust on equipment. An airborne dust of this
material can create a dust explosion. When handling and EYE/FACE PROTECTION: Use chemical goggles.
processing this material local exhaust ventilation may be
required to control dust and reduce exposure to vapors. To SKIN PROTECTION: Use protective clothing chemically
prevent dust explosions employ bonding and grounding for resistant to this material. Selection of specific items such as
operations capable of generating static electricity. Protect all face shield, boots, apron, or full body suit will depend on the
equipment from explosions by following the guidelines in task.
NFPA-68 and NFPA-69. For electrical equipment follow
local codes and electrical classification NFPA-70 (the HAND PROTECTION: Use gloves chemically resistant to
National Electrical Code), class II, division 2, group G. this material. Examples of preferred glove barrier materials
include: Neoprene, Nitrile, Polyvinyl Chloride (PVC or Vinyl).
STORAGE: Do not store this material near food, feed or
drinking water. Store in a well-ventilated area. Store in a dry RESPIRATORY PROTECTION: Atmospheric levels should
area. Store out of direct sunlight in a cool place. The be maintained below the exposure guideline. If respiratory
minimum recommended storage temperature for this irritation is experienced, use an approved air-purifying
o o
material is 34 F (1 C). The maximum recommended respirator. The following should be effective types of air-
o o
storage temperature for this material is 120 F (49 C). purifying respirators: organic vapor cartridge with a
particulate pre-filter.
OTHER: Completely empty bag into application equipment.
Dispose empty bag in a sanitary landfill or by incineration as APPLICATORS AND ALL OTHER HANDLERS: Refer to
allowed by state and local authorities. Avoid inhalation of the product label for personal protective clothing and
smoke if incinerated. equipment.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION: 9. PHYSICAL AND CHEMICAL PROPERTIES:
These precautions are suggested for conditions where the COLOR: Tan
potential for exposure exists. Emergency conditions may STATE: Powdered solid
require additional precautions. ODOR: Mild
pH: 7.5 to 8.5 Aqueous suspension
EXPOSURE GUIDELINE(S):
VISCOSITY: Not applicable
Myclobutanil: Dow AgroSciences Industrial Hygiene Guide is
SPECIFIC GRAVITY (Water = 1): 0.3 to 0.35 g/cc (bulk
3
1 mg/M3 TWA and 3 mg/M STEL.
density)
3
Clay: The ACGIH TLV is 2 mg/M , respirable, A4. The
VAPOR DENSITY (Air = 1): Not applicable
3 3
OSHA PEL is 15 mg/M total dust and 5 mg/M respirable
VAPOR PRESSURE: Not applicable
fraction.
MELTING POINT: Not available
3
Titanium Dioxide: ACGIH TLV is 10 mg/M . OSHA PEL is
BOILING POINT: Not applicable
3
15 mg/M , total dust.
SOLUBILITY IN WATER: Dispersible
3
Silica, crystalline (Quartz): ACGIH TLV is 0.1 mg/M
PERCENT VOLATILITY: 0%
3
respirable) for tripoli, and fused silica, 0.05 mg/M
(respirable) for cristobalite, tridymite, and quartz. Quartz has EVAPORATION RATE (BAc = 1): Not applicable
3
an A2 designation. OSHA PEL is (30 mg/M )/(%SiO2+2)
3
total dust, (250 mppcf)/(%SiO2+5) or (10 mg/M )/(%SiO2+2)
respirable for quartz, tripoli, and fused silica; the value for
cristobalite and tridymite is 1/2 the value calculated from the
respirable dust formula for quartz.
*Trademark of Dow AgroSciences, LLC
2
MATERIAL SAFETY DATA SHEET
Emergency Phone: 800-992-5994
Dow AgroSciences LLC
Indianapolis, IN 46268
Effective Date: 19-Jun-06
Product Code: 109739
RALLY* 40WSP FUNGICIDE MSDS: 007705
studies. Effects are believed to be due to overloading of the
10. STABILITY AND REACTIVITY:
normal respiratory clearance mechanisms caused by the
STABILITY: This material is stable under normal storage extreme study conditions. Workers exposed to titanium
conditions. dioxide in the workplace have not shown an unusual
incidence of chronic respiratory disease or lung cancer.
INCOMPATIBILITY: Avoid contact with strong oxidizing Titanium dioxide was not carcinogenic in laboratory animals
agents. in lifetime feeding studies.
HAZARDOUS DECOMPOSITION PRODUCTS: None TERATOLOGY (BIRTH DEFECTS): The active ingredient
known. did not cause birth defects in laboratory animals. Has been
toxic to the fetus in laboratory animals at doses non-toxic to
HAZARDOUS POLYMERIZATION: Not known to occur. the mother.
11. TOXICOLOGICAL INFORMATION: REPRODUCTIVE EFFECTS: The active ingredient, in
laboratory animal studies, effects on reproduction have
POTENTIAL HEALTH EFFECTS: This section includes
possible adverse effects, which could occur if this material is been seen only at doses that produced significant toxicity to
the parent animals.
not handled in the recommended manner.
MUTAGENICITY: The active ingredient, in-vitro and animal
EYE: May cause moderate eye irritation. May cause
genetic toxicity studies were negative.
moderate corneal injury. Dust may irritate eyes.
12. ECOLOGICAL INFORMATION:
SKIN: Brief contact may cause slight skin irritation with local
redness. Prolonged skin contact is unlikely to result in ENVIRONMENTAL FATE:
absorption of harmful amounts. The LD50 for skin absorption
in rabbits is estimated to be >5,000 mg/kg. MOVEMENT & PARTITIONING:
No relevant information found.
INGESTION: Low toxicity if swallowed. Small amounts
swallowed incidentally as a result of normal handling DEGRADATION AND PERSISTANCE:
operations are not likely to cause injury; however, No relevant information found.
swallowing larger amounts may cause injury. The oral LD50
for rats is estimated to be >1,600 mg/kg. ECOTOXICOLOGY:
Based largely or completely on information for myclobutanil.
INHALATION: Dust may cause irritation of the upper Material is highly toxic to aquatic organisms on an acute
respiratory tract (nose and throat) and lungs. basis (LC50 or EC50 is between 0.1 and 1 mg/L in the most
sensitive species tested).
SYSTEMIC (OTHER TARGET ORGAN) EFFECTS: For the Material is practically non-toxic to birds on a dietary basis
active ingredient, in animals, effects have been reported on (LC50 is >5000 ppm).
the following organs: liver, testes, adrenal gland, kidney and Material is slightly toxic to birds on an acute basis (LD50 is
thyroid. Repeated excessive exposure to crystalline silica between 501 and 2000 mg/kg).
may cause silicosis, a progressive and disabling disease of Acute contact LD50 in honeybee (Apis mellifera) is >100
the lungs. 碌g/bee.
CANCER INFORMATION: The active ingredient did not
cause cancer in laboratory animals. Crystalline silica has
been shown to cause cancer in laboratory animals and
humans. Lung fibrosis and tumors have been observed in
rats exposed to titanium dioxide in two lifetime inhalation
*Trademark of Dow AgroSciences, LLC
3
MATERIAL SAFETY DATA SHEET
Emergency Phone: 800-992-5994
Dow AgroSciences LLC
Indianapolis, IN 46268
Effective Date: 19-Jun-06
Product Code: 109739
RALLY* 40WSP FUNGICIDE MSDS: 007705
SARA HAZARD CATEGORY: This product has been
13. DISPOSAL CONSIDERATIONS:
reviewed according to the EPA "Hazard Categories"
DISPOSAL METHOD: If wastes and/or containers cannot promulgated under Sections 311 and 312 of the Superfund
be disposed of according to the product label directions, Amendment and Reauthorization Act of 1986 (SARA Title
disposal of this material must be in accordance with your III) and is considered, under applicable definitions, to meet
local or area regulatory authorities. This information the following categories:
presented below only applies to the material as supplied.
The identification based on characteristic(s) or listing may An immediate health hazard
not apply if the material has been used or otherwise A delayed health hazard
contaminated. It is the responsibility of the waste generator
to determine the toxicity and physical properties of the CALIFORNIA PROPOSITION 65: The following statement
material generated to determine the proper waste is made in order to comply with the California Safe Drinking
identification and disposal methods in compliance with Water and Toxic Enforcement Act of 1986:
applicable regulations. If the material as supplied becomes
a waste, follow all applicable regional, national and local WARNING: This product contains a chemical(s) known to
laws and regulations. the State of California to be a reproductive and
developmental toxic. The chemical is myclobutanil (CAS #
14. TRANSPORT INFORMATION:
088671-89-0).
U.S. DEPARTMENT OF TRANSPORTATION (DOT)
WARNING: This product contains a chemical known to
INFORMATION:
the State of California to cause cancer. The chemical is
crystalline silica (quartz) (CAS # 014808-60-7).
For all package sizes and modes of transportation:
This material is not regulated for transport
TOXIC SUBSTANCES CONTROL ACT (TSCA): All
15. REGULATORY INFORMATION: ingredients are on the TSCA inventory or are not required to
be listed on the TSCA inventory.
NOTICE: The information herein is presented in good faith
and believed to be accurate as of the effective date shown
STATE RIGHT-TO-KNOW: The following product
above. However, no warranty, express or implied, is given.
components are cited on certain state lists as mentioned.
Regulatory requirements are subject to change and may
Non-listed components may be shown in the composition
differ from one location to another; it is the buyer鈥檚
section of the MSDS.
responsibility to ensure that its activities comply with federal,
state or provincial, and local laws. The following specific
CHEMICAL NAME CAS NUMBER LIST
information is made for the purpose of complying with
MYCLOBUTANIL 088671-89-0 NJ2
numerous federal, state or provincial, and local laws and
regulations.
NJ2=New Jersey Environmental Hazardous Substance
(present at greater than or equal to 1.0%).
U.S. REGULATIONS
OSHA HAZARD COMMUNICATION STANDARD: This
SARA 313 INFORMATION: This product contains the
product is a "Hazardous Chemical" as defined by the OSHA
following substances subject to the reporting requirements
Hazard Communication Standard, 29 CFR 1910.1200.
of Section 313 of Title III of the Superfund Amendments and
Reauthorization Act of 1986 and 40 CFR Part 372:
NATIONAL FIRE PROTECTION ASSOCIATION (NFPA)
RATINGS:
CHEMICAL NAME CAS NUMBER CONCENTRATION
MYCLOBUTANIL 088671-89-0 40%
Health 2
Flammability 1
Reactivity 0
*Trademark of Dow AgroSciences, LLC
4
MATERIAL SAFETY DATA SHEET
Emergency Phone: 800-992-5994
Dow AgroSciences LLC
Indianapolis, IN 46268
Effective Date: 19-Jun-06
Product Code: 109739
RALLY* 40WSP FUNGICIDE MSDS: 007705
COMPREHENSIVE ENVIRONMENTAL RESPONSE
COMPENSATION AND LIABILITY ACT (CERCLA, or
SUPERFUND): To the best of our knowledge, this product
contains no chemical subject to reporting under CERCLA.
16. OTHER INFORMATION:
MSDS STATUS: Revised Sections: 2, 3, 4, 8, 11, 12, 13, 15
Reference: DR-0381-6180
Replaces MSDS Dated: 9/26/03
Document Code: D03-182-003
Replaces Document Code: D03-182-002
The Information Herein Is Given In Good Faith, But No
Warranty, Express or Implied, Is Made. Consult Dow
AgroSciences for Further Information.
*Trademark of Dow AgroSciences, LLC
5
|