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MSDS Material Safety Data Sheet
CAS

1305-62-0
7732-18-5

File Name: airgas_com---001085.asp
                                                                                                                    NFPA RATING
FLAMMABILITY



0


MATERIAL SAFETY DATA SHEET 1
3
HEALTH REACTIVITY


to U.S. OSHA, CMA, ANSI and Canadian WHMIS Standards
Prepared


OTHER




PART I What is the material and what do I need to know in an emergency?

1. PRODUCT IDENTIFICATION

CARBIDE LIME SLURRY
CHEMICAL NAME; CLASS:
Document Number: 001085
PRODUCT USE: By-product of Acetylene production from
Calcium Carbide

SUPPLIER/MANUFACTURER'S NAME: AIRGAS INC.
ADDRESS: 259 N. Radnor-Chester Road
Suite 100
Radnor, PA 19087-5283
BUSINESS PHONE: 1-610-687-5253
EMERGENCY PHONE: CHEMTREC: 1-800-424-9300
International: 703-527-3887 (Call Collect)
DATE OF PREPARATION: May 28, 1999
DATE OF REVISION: September 10, 2007


2. COMPOSITION and INFORMATION ON INGREDIENTS
CHEMICAL NAME CAS # mole % EXPOSURE LIMITS IN AIR

ACGIH OSHA

TLV STEL PEL STEL IDLH OTHER
ppm ppm ppm ppm ppm

3 3
Calcium Hydroxide 1305-62-0 30-60% 5 mg/m - 15 mg/m - - LD50 7340 mg/kg (rat)

Not applicable
Water 7732-18-5 40-70%



NE = Not Established C = Ceiling Limit See Section 16 for Definitions of Terms Used
NOTE: All WHMIS required information is included. It is located in appropriate sections based on the ANSI Z400.1-1993 format.




CARBIDE LIME - MSDS (Document # 001085) PAGE 1 OF 7
3. HAZARD IDENTIFICATION

EMERGENCY OVERVIEW: This material is irritating to the eyes, respiratory system and mucous membranes.
Prolonged contact may cause burns to the skin and eyes. Avoid inhalation of dried material (dust).

SYMPTOMS OF OVEREXPOSURE BY ROUTE OF EXPOSURE: The
most significant routes of occupational overexposure are by inhalation, HAZARDOUS MATERIAL INFORMATION
skin and eye contact. The symptoms of overexposure to Carbide Lime SYSTEM
are as follows:
HEALTH
INHALATION: Inhalation of Carbide Lime dust will cause irritation to the 3
(BLUE)
respiratory tract. The symptoms of such exposure can include nausea,
vomiting, coughing and chest discomfort. Prolonged inhalation may
cause inflammation and could cause pulmonary edema.
CONTACT WITH SKIN or EYES: Contact with the skin can cause
FLAMMABILITY 0
(RED)
irritation, swelling and possibly burns. Eye contact can be severely
irritating, causing pain and excessive tearing. Conjunctival edema, and
corneal edema could result.

INGESTION: Carbide Lime is corrosive by ingestion and may cause
REACTIVITY (YELLOW) 1
burns to the mouth, throat and mucous membranes, and give rise to
abdominal pain. Vomiting, abdominal pain and dysphagia may be
apparent.

PROTECTIVE EQUIPMENT C
TARGET ORGANS: Skin, eyes, respiratory system, digestive tract.

EYES HANDS BODY
RESPIRATORY



See See
Section 8 Section 8
For routine industrial applications


See Section 16 for Definition of Ratings




CARBIDE LIME - MSDS (Document # 001085) PAGE 2 OF 7
PART II What should I do if a hazardous situation occurs?
4. FIRST-AID MEASURES
SKIN EXPOSURE: If Carbide Lime contaminates the skin, immediately begin decontamination with running water.
Minimum flushing is for 15 minutes. Remove exposed or contaminated clothing, taking care not to contaminate eyes.
Wash thoroughly with soap and water. Victim must seek medical attention if any adverse reaction occurs.
EYE EXPOSURE: If Carbide Lime enters the eyes, open victim's eyes while under gentle running water. Use sufficient
force to open eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes. It may be necessary to remove solid
particles with a swab. Victim must seek immediate medical attention, preferably from an ophthalmologist.
INHALATION: If Carbide Lime is inhaled, remove victim to fresh air. If necessary, use artificial respiration to support vital
functions. Seek prompt medical attention.
INGESTION: If Carbide Lime is swallowed, victim should drink milk, egg whites, or water. Do not induce vomiting. If
vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Never induce vomiting or give diluents (milk
or water) to someone who is unconscious, having convulsions, or who cannot swallow. Use of acidic agents to neutralize
are contraindicated
Victims of chemical exposure must be taken for medical attention. Rescuers should be taken for medical attention, if
necessary. Take copy of label and MSDS to health professional with victim. Physicians should refer to Section 11
(Toxicological Information) for additional information on the treatment of Carbide Lime exposure.

5. FIRE-FIGHTING MEASURES
FLASH POINT (TCC): Not applicable
NFPA RATING
AUTOIGNITION TEMPERATURE: Not applicable
FLAMMABILITY
FLAMMABLE LIMITS (in air by volume, %):
Lower (LEL): Not applicable
0
Upper (UEL): Not applicable
FIRE EXTINGUISHING MATERIALS: 1
3
HEALTH REACTIVITY

The material is non-flammable. Use extinguishing media appropriate
for surrounding fire.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Carbide Lime is a by
product of Acetylene manufacture. As such, there could be Acetylene OTHER
See Section 16 for Definition of Ratings
present in solution in the Lime slurry. Acetylene is an extremely
flammable gas that can form explosive mixtures with air.
Explosion Sensitivity to Mechanical Impact: Not sensitive.
Explosion Sensitivity to Static Discharge: Not applicable.
SPECIAL FIRE-FIGHTING PROCEDURES: Structural firefighters must wear Self-Contained Breathing Apparatus and full
protective equipment. Water spray or fag can be used. Runoff water should be contained to prevent possible
environmental damage. If necessary, decontaminate fire-response equipment with soap and water solution.

6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by trained personnel using pre-planned
procedures. Proper protective equipment should be used. In case of a release, clear the affected area, protect people, and
respond with trained personnel.
In the event of a non-incidental release, minimum Personal Protective Equipment should be Level B: triple-gloves (rubber
gloves and nitrile gloves, over latex gloves), chemical resistant suit and boots, hard-hat, and Self-Contained
Breathing Apparatus.

SMALL SPILL: Carefully transfer the product to a clean dry container, using a shovel or scoop. Recovered Lime can be re-
used or disposed of (see Section 13). Avoid creating airborne dust from dried Lime. Small quantities may be flushed with
water into a sewer, if appropriate approvals are obtained.

LARGE SPILL: Clear the hazardous area. Remain upwind of dried material, and uphill of slurried material. Use of Personal
Protective Equipment is recommended, and personnel responding should be knowledgeable in the characteristics of Lime.
Creation of dust from dried material should be avoided and material must be prevented from entering waterways and
sewers.




CARBIDE LIME - MSDS (Document # 001085) PAGE 3 OF 7
PART III How can I prevent hazardous situations from occurring?
7. HANDLING and STORAGE
WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting Carbide Lime ON YOU or IN
YOU. Wash hands after handling chemicals. Do not eat or drink while handling chemicals. Remove contaminated clothing
immediately. Be aware of any signs of effects of exposure indicated in Section 3 (Hazard Identification); exposures to fatal
concentrations of Carbide Lime could occur rapidly.
STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to handle it safely.
Post 鈥淣O SMOKING鈥? signs, where appropriate in storage and use areas.
Store Carbide Lime in a cool, dry location, away from direct sunlight, sources of intense heat, or where freezing is possible.
Store containers away from incompatible chemicals. Consideration should be given to the possibility of Acetylene being
evolved from the slurry. Care should be taken that explosive atmospheres could not be created and that sources of ignition
are eliminated.
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in
Section 6 (Accidental Release Measures). Make certain application equipment is locked and tagged-out safely. Always
use Carbide Lime in areas where adequate ventilation is provided. Decontaminate equipment using soapy water before
maintenance begins. Collect all rinsates and dispose of according to applicable Federal, State, or local procedures.

8. EXPOSURE CONTROLS - PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation. Use a mechanical fan or vent area to
reduce dust concentrations. Ensure eyewash/safety shower stations are available near areas where Carbide Lime is used.

RESPIRATORY PROTECTION: Respiratory protection is not normally necessary when there is adequate ventilation. If
there is airborne dust, use a NIOSH approved respirator with dust cartridge.
EYE PROTECTION: Splash goggles or safety glasses with side shields.
HAND PROTECTION: For routine industrial use, wear rubber gloves when handling slurry, and leather gloves for dealing
with dried material.
BODY PROTECTION: Clothing, such as long sleeved shirts and long trousers, which cover the skin should be worn. Any
clothing that may come into contact with Carbide Lime should be thoroughly washed after use.

9. PHYSICAL and CHEMICAL PROPERTIES
0
pH @ 25 C: 12.4. SPECIFIC GRAVITY(water = 1): 2.24
FREEZING/MELTING POINT: 2570掳C (4658掳F) for Calcium Oxide
BOILING POINT: Dissociates at 580掳C (1076掳F) to Calcium Oxide and Water
SOLUBILITY IN WATER: 0.185 g/cc

APPEARANCE AND COLOR: Slurry 鈥? Gray/white thick suspension in water.
Dry 鈥? Gray/white powder, or soft lumps or granules.

ODOR: Odorless, but inhalation of dust can be irritating. Can have a slightly bitter, alkaline taste. Fresh Carbide Lime slurry
can have a garlic like odor due to small amounts of Acetylene being dissolved in solution. This odor dissipates on exposure
to air.

10. STABILITY and REACTIVITY
STABILITY: Stable at standard temperatures and pressures.
DECOMPOSITION PRODUCTS: When strongly heated Carbide Lime will break down to Calcium Oxide and Water.
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: Carbide Lime is incompatible with acidic materials,
phosphorus and copper. Explosive reaction can occur with maleic anhydride and organic nitro compounds.
HAZARDOUS POLYMERIZATION: Will not occur.




CARBIDE LIME - MSDS (Document # 001085) PAGE 4 OF 7
PART III How can I prevent hazardous situations from occurring?
11. TOXICOLOGICAL INFORMATION
TOXICITY DATA: The following toxicology data are for Carbide Lime.
LD50 (oral, rat) 7340 mg/kg

SUSPECTED CANCER AGENT: Carbide Lime is not found on the following lists: FEDERAL OSHA Z LIST, NTP, IARC,
or CAL/OSHA, and is therefore not considered to be, nor suspected to be, a cancer-causing agent by these agencies.
IRRITANCY OF PRODUCT: Carbide Lime can be irritating to contaminated tissue.
SENSITIZATION OF PRODUCT: Carbide Lime is not known to cause sensitization in humans after prolonged or repeated
exposures.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of Carbide Lime on the
human reproductive system.
Mutagenicity: Human mutation data are available for Carbide Lime; these data were obtained from studies in which specific
human cells were exposed to relatively high concentrations of this compound.
Embryotoxicity: Carbide Lime is not reported to cause embryotoxic effects in humans.
Teratogenicity: Carbide Lime is not reported to cause teratogenic effects in humans.
Reproductive Toxicity: Carbide Lime is not reported to cause adverse reproductive effects in humans.
A mutagen is a chemical which causes permanent changes to genetic material (DNA) such that the changes will propagate
through generation lines. An embryotoxin is a chemical which causes damage to a developing embryo (i.e. within the first
eight weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a
chemical which causes damage to a developing fetus, but the damage does not propagate across generational lines. A
reproductive toxin is any substance which interferes in any way with the reproductive process.

RECOMMENDATIONS TO PHYSICIANS:
INGESTION 鈥? Acidic neutralizing agents should not be used. Esophagoscopy should be performed within 12-24 hours of
ingestion. Care should be taken to prevent perforation of burned tissue.
EYE CONTACT 鈥? Use of EDTA solution to rinse the eyes may help to remove particles of Carbide Lime that may be
trapped in the eyes, and relieve some corneal opacification.
INHALATION 鈥? Administer Oxygen and check blood gases. Obtain a chest X-ray. Treat pulmonary edema if indicated.


12. ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
Carbide Lime may not be considered to be a highly hazardous material, but suitable precautions must be taken to ensure
that the material is prevented from entering rivers, lakes, streams and sewers. The alkalinity of Carbide Lime may cause it
to be subject to local regulations in certain areas.

AFFECT ON AQUATIC LIFE:

TLm (Mosquito Fish) 240 ppm/24 hr; 220 ppm/48 hr; 160 ppm/96 hr @ 69.8-73.40F (21-230C)


13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Recovered Carbide Lime can be collected and reused. If disposal is necessary,
it must be done in accordance with all federal, state and local regulations.

14. TRANSPORTATION INFORMATION
PROPER SHIPPING NAME: Calcium Hydroxide
HAZARD CLASS NUMBER and DESCRIPTION: Not applicable
UN IDENTIFICATION NUMBER: Not applicable
DOT LABEL(S) REQUIRED: Not applicable
NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER (1996): 154




CARBIDE LIME - MSDS (Document # 001085) PAGE 5 OF 7
15. REGULATORY INFORMATION
U.S. SARA REPORTING REQUIREMENTS: Carbide Lime is subject to the reporting requirements of Sections 302, 304
and 313 of Title III of the Superfund Amendments and Reauthorization Act, as follows:
CHEMICAL NAME SARA 302 SARA 304 SARA 313
(40 CFR 355, Appendix A) (40 CFR Table 302.4) (40 CFR 372.65)
Carbide Lime NO NO NO

U.S. SARA THRESHOLD PLANNING QUANTITY: Not applicable.
U.S. CERCLA REPORTABLE QUANTITIES (RQ): Not applicable.
U.S. TSCA INVENTORY STATUS: Lime is listed on the TSCA Inventory.
OTHER U.S. FEDERAL REGULATIONS: Depending on specific operations involving the use of Carbide Lime, the
regulations of the Process Safety Management of Highly Hazardous Chemicals may be applicable (29 CFR 1910.119).
Under this regulation, Carbide Lime is not listed in Appendix A.



16. OTHER INFORMATION
PREPARED BY: Airgas SAFECOR


The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the
accuracy of these data or the results to be obtained from the use thereof. AIRGAS, Inc. assumes no responsibility for injury to the vendee or
third persons proximately caused by the material if reasonable safety procedures are not adhered to as stipulated in the data sheet.
Additionally, AIRGAS, Inc. assumes no responsibility for injury to vendee or third persons proximately caused by abnormal use of the material
even if reasonable safety procedures are followed. Furthermore, vendee assumes the risk in his use of the material.




CARBIDE LIME - MSDS (Document # 001085) PAGE 6 OF 7
DEFINITIONS OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these which are commonly used include the following:

CAS #: This is the Chemical Abstract Service Number which uniquely identifies each constituent. It is used for computer-related searching.

EXPOSURE LIMITS IN AIR: FLAMMABILITY LIMITS IN AIR:
Much of the information related to fire and explosion is derived from
ACGIH - American Conference of Governmental Industrial
Hygienists, a professional association which establishes exposure the National Fire Protection Association (NFPA). Flash Point -
limits. Minimum temperature at which a liquid gives off sufficient vapors to
form an ignitable mixture with air. Autoignition Temperature: The
TLV - Threshold Limit Value - an airborne concentration of a
minimum temperature required to initiate combustion in air with no
substance which represents conditions under which it is generally
other source of ignition. LEL - the lowest percent of vapor in air, by
believed that nearly all workers may be repeatedly exposed without
volume, that will explode or ignite in the presence of an ignition
adverse effect. The duration must be considered, including the 8-
source. UEL - the highest percent of vapor in air, by volume, that will
hour Time Weighted Average (TWA), the 15-minute Short Term
explode or ignite in the presence of an ignition source.
Exposure Limit, and the instantaneous Ceiling Level. Skin
absorption effects must also be considered.
TOXICOLOGICAL INFORMATION:
OSHA - U.S. Occupational Safety and Health Administration.
Possible health hazards as derived from human data, animal
PEL - Permissible Exposure Limit - This exposure value means
studies, or from the results of studies with similar compounds are
exactly the same as a TLV, except that it is enforceable by OSHA.
presented. Definitions of some terms used in this section are: LD50 -
The OSHA Permissible Exposure Limits are based in the 1989
Lethal Dose (solids & liquids) which kills 50% of the exposed
PELs and the June, 1993 Air Contaminants Rule (Federal Register:
animals; LC50 - Lethal Concentration (gases) which kills 50% of the
58: 35338-35351 and 58: 40191). Both the current PELs and the
exposed animals; ppm concentration expressed in parts of material
vacated PELs are indicated. The phrase, 鈥淰acated 1989 PEL,鈥? is 3
per million parts of air or water; mg/m concentration expressed in
placed next to the PEL which was vacated by Court Order.
weight of substance per volume of air; mg/kg quantity of material,
IDLH - Immediately Dangerous to Life and Health - This level
by weight, administered to a test subject, based on their body weight
represents a concentration from which one can escape within 30-
in kg. Data from several sources are used to evaluate the cancer-
minutes without suffering escape-preventing or permanent injury.
causing potential of the material. The sources are: IARC - the
The DFG - MAK is the Republic of Germany鈥檚 Maximum Exposure
International Agency for Research on Cancer; NTP - the National
Level, similar to the U.S. PEL. NIOSH is the National Institute of
Toxicology Program, RTECS - the Registry of Toxic Effects of
Occupational Safety and Health, which is the research arm of the
Chemical Substances, OSHA and CAL/OSHA. IARC and NTP rate
U.S. Occupational Safety and Health Administration (OSHA).
chemicals on a scale of decreasing potential to cause human
NIOSH issues exposure guidelines called Recommended Exposure
cancer with rankings from 1 to 4. Subrankings (2A, 2B, etc.) are
Levels (RELs). When no exposure guidelines are established, an
also used. Other measures of toxicity include TDLo, the lowest dose
entry of NE is made for reference.
to cause a symptom and TCLo the lowest concentration to cause a
HAZARD RATINGS: symptom; TDo, LDLo, and LDo, or TC, TCo, LCLo, and LCo, the
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM: Health lowest dose (or concentration) to cause death. BEI - Biological
Exposure Indices, represent the levels of determinants which are
Hazard: 0 (minimal acute or chronic exposure hazard); 1 (slight
most likely to be observed in specimens collected from a healthy
acute or chronic exposure hazard); 2 (moderate acute or significant
worker who has been exposed to chemicals to the same extent as a
chronic exposure hazard); 3 (severe acute exposure hazard;
worker with inhalation exposure to the TLV.
onetime overexposure can result in permanent injury and may be
fatal); 4 (extreme acute exposure hazard; onetime overexposure
REGULATORY INFORMATION:
can be fatal). Flammability Hazard: 0 (minimal hazard); 1 (materials
This section explains the impact of various laws and regulations on
that require substantial pre-heating before burning); 2 (combustible
the material. EPA is the U.S. Environmental Protection Agency.
liquid or solids; liquids with a flash point of 38-93掳C [100-200掳F]); 3
WHMIS is the Canadian Workplace Hazardous Materials
(Class IB and IC flammable liquids with flash points below 38掳C
Information System. DOT and TC are the U.S. Department of
[100掳F]); 4 (Class IA flammable liquids with flash points below 23掳C Transportation and the Transport Canada, respectively. Superfund
[73掳F] and boiling points below 38掳C [100掳F]. Reactivity Hazard: 0 Amendments and Reauthorization Act (SARA); the Canadian
(normally stable); 1 (material that can become unstable at elevated Domestic Substances List (DSL); the U.S. Toxic Substance
temperatures or which can react slightly with water); 2 (materials Control Act (TSCA); Marine Pollutant status according to the DOT;
that are unstable but do not detonate or which can react violently California's Safe Drinking Water Act (Proposition 65); the
with water); 3 (materials that can detonate when initiated or which Comprehensive Environmental Response, Compensation, and
can react explosively with water); 4 (materials that can detonate at Liability Act (CERCLA or Superfund); and various state
normal temperatures or pressures). regulations. This section also includes information on the
NATIONAL FIRE PROTECTION ASSOCIATION: Health Hazard: 0 precautionary warnings which appear on the materials package
(material that on exposure under fire conditions would offer no label.
hazard beyond that of ordinary combustible materials); 1 (materials
that on exposure under fire conditions could cause irritation or minor
residual injury); 2 (materials that on intense or continued exposure
under fire conditions could cause temporary incapacitation or
possible residual injury); 3 (materials that can on short exposure
could cause serious temporary or residual injury); 4 (materials that
under very short exposure could cause death or major residual
injury). Flammability Hazard and Reactivity Hazard: Refer to
definitions for 鈥淗azardous Materials Identification System鈥?.




CARBIDE LIME - MSDS (Document # 001085) PAGE 7 OF 7

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