Material Safety Data Sheet
Product Name: SOLVENT BASED TOUCH UP PAINT ID: 1017
* * * Section 1 - Chemical Product and Company Identification * * *
Chemical Formula: Mixture
Other Designations: LH Polypro Tie Coat, 272-C07; LH Gaffney Black 220-919; LH Gaffney Brown, 5434D10024; LH
Gaffney Green, 5434G10011; LH Gaffney Gray, 5434E10010; LH Gaffney Brittany Blue, 5434A10016; LH Gaffney Red,
5434R10010; LH Vent White, 5434W10005; LH Pebblestone Clay, 5434D10016; LH Dark Spruce, 5434G10016; LH
Winestone, 5434R10014; LH Reducer, 5461C00047; LH Siding White, 5434W10210; LH Dark Navy Blue, 5434A10037;
LH Cedar White, 5434W10008
Alcoa Inc. Phone: Health and Safety: 1-412-553-4649
201 Isabella Street
Pittsburgh, PA 15212-5858
Manufacturer/Supplier
Alcoa Home Exteriors, Inc. Phone: 412-249-6000 or 866-496-0370
1590 Omega Drive
Pittsburgh, PA 15205
Emergency Information:
USA: Chemtrec: 1-800-424-9300 or 1-703-527-3887 Alcoa: 1-412-553-4001
* * * Section 2 - Composition / Information on Ingredients * * *
CAS # Component Percent
108-21-4 Isopropyl acetate 0-40
110-19-0 Isobutyl acetate 0-40
13463-67-7 Titanium dioxide 0-30
67-64-1 Acetone 0-30
67-63-0 Isopropyl alcohol 0-30
64742-89-8 Naphtha, light aliphatic 0-30
107-98-2 Propylene glycol monomethyl ether (PGMME) 0-20
111-76-2 2-Butoxyethanol 0-20
1309-37-1 Iron oxide 0-8
64742-88-7 Naphtha, medium aliphatic 0-8
64742-95-6 Naphtha, light aromatic 0-8
71-36-3 n-Butyl alcohol 0-8
14807-96-6 Talc 0-8
1333-86-4 Carbon black 0-4
1330-20-7 Xylenes 0-4
88230-35-7 Oxo-hexyl acetate 0-4
95-63-6 1,2,4-Trimethyl benzene 0-4
97-85-8 Isobutyl isobutyrate 0-1.5
100-41-4 Ethyl benzene 0-1
Component Related Regulatory Information
This product may be regulated, have exposure limits or other information identified as the following: Glycol ethers.
Component Information
Exact composition will vary. Unless additional information is available, processor should assume that all potential
ingredients are present.
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Page 1 of 12 Issue Date: 09/22/03 Revision: 2.0000 Print Date: 9/22/2003
Material Safety Data Sheet
Product Name: SOLVENT BASED TOUCH UP PAINT ID: 1017
* * * Section 3 - Hazards Identification * * *
Emergency Overview
Liquid. Various colors. Solvent odor. Flammable. Solvent vapors may form explosive air/vapor mixtures at room
temperature.
Direct contact can cause irritation of eyes and skin. Vapors and mists can cause irritation of eyes and respiratory
tract. Can cause central nervous system effects (nausea, dizziness and loss of coordination). Can be absorbed
through the skin.
Potential Health Effects
Eyes
Direct contact can cause irritation.
Skin
Can cause irritation. Prolonged or repeated contact can cause dermatitis. Can be absorbed through the skin.
Ingestion
Can cause irritation and central nervous system effects (nausea, dizziness and loss of coordination). Harmful or
fatal if swallowed.
Inhalation
Can cause irritation of nose, throat and respiratory tract. Can cause central nervous system effects (nausea,
dizziness and loss of coordination) and other health effects listed below.
Health Effects of Ingredients
Solvents Can cause irritation of eyes, mucous membranes, skin and respiratory tract. Skin contact (prolonged
or repeated): Can cause defatting of the skin and dermatitis. Acute overexposures: Can cause headaches,
drowsiness (narcosis), liver damage, kidney damage and central nervous system effects (nausea, dizziness, loss
of coordination and loss of consciousness). Chronic overexposures: Can cause loss of coordination, reduction in
reaction times and central nervous system damage.
Acetone Can cause irritation of eyes, mucous membranes, skin and respiratory tract. Acute and chronic
overexposures: Can cause central nervous system effects (nausea, dizziness and loss of consciousness).
Isopropanol (Isopropyl alcohol) Can cause severe irritation and corneal damage to eyes. Can cause skin
irritation. Skin contact: Can cause non-allergic dermatitis. Can be absorbed through the skin. Acute
overexposures: Can cause central nervous system effects (nausea, dizziness and loss of coordination) and
drowsiness (narcosis). Chronic overexposures: Can cause cardiovascular system effects and kidney damage.
1-Methoxy-2-propanol (Propylene glycol monomethyl ether) Can cause irritation of eyes, skin and respiratory
tract. Skin contact: Can be absorbed through the skin in toxic amounts. Acute overexposures: Can cause central
nervous system effects (nausea, dizziness and loss of consciousness). Chronic overexposures: Can cause liver
damage and kidney damage.
2-Butoxyethanol (Butyl cellosolve, EGMBE) Can cause irritation of eyes, skin and respiratory tract. Skin
contact: Can be absorbed through the skin in toxic amounts. Acute and chronic overexposures: Can cause
central nervous system effects (nausea, dizziness and loss of consciousness), fluid in the lungs (pulmonary
edema), blood cell damage, kidney damage and liver damage.
Butyl alcohol (Butanol) Can cause irritation of eyes, skin and respiratory tract. Skin contact: Can be absorbed
through the skin. Acute overexposures: Can cause central nervous system effects (nausea, dizziness and loss
of consciousness), blurred vision and corneal damage. Chronic overexposures: Can cause inner ear damage
resulting in vertigo (dizziness) and hearing loss.
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Material Safety Data Sheet
Product Name: SOLVENT BASED TOUCH UP PAINT ID: 1017
Xylene Can cause irritation of eyes, mucous membranes, skin and respiratory tract. Skin contact: Can be
absorbed through the skin. Acute overexposures: Can cause central nervous system effects (nausea, dizziness,
loss of coordination and loss of consciousness), coma and death. Can pass through the placenta. Chronic
overexposures: Can cause reversible damage to the eyes, memory loss, abnormal heart rhythms (arrhythmia),
liver damage, kidney damage, fetal toxicity and reproductive harm.
Trimethyl benzene Can cause irritation of eyes, skin and upper respiratory tract. Acute overexposures: Can
cause bronchitis, central nervous system effects (nausea, dizziness, loss of coordination and loss of
consciousness) and death. Chronic overexposures: Can cause asthma-like bronchitis, blood cell damage and
blood disorders. Additional information: Can pass through the placenta.
Ethyl benzene Can cause irritation of eyes, skin and respiratory tract. Acute overexposures: Can cause central
nervous system effects (nausea, dizziness and loss of coordination). Chronic overexposures: Can cause central
nervous system damage, liver damage, kidney damage and reproductive harm. IARC/NTP: The NTP reports
clear evidence for carcinogenicity in some experimental animals. Additional information: Studies with
experimental animals by inhalation have found kidney cancer, liver cancer, lung cancer and testicular cancer.
Talc (asbestos-free and <1% silica) Can cause irritation of eyes, skin and upper respiratory tract. Chronic
overexposures: Can cause lung damage.
Titanium dioxide Can cause irritation of eyes and respiratory tract. Chronic overexposures: Can cause chronic
bronchitis.
Iron oxide Chronic overexposures: Can cause benign lung disease (siderosis). Ingestion: Can cause irritation of
gastrointestinal tract, bleeding, changes in the pH of the body fluids (metabolic acidosis) and liver damage.
Carbon black Can cause mechanical irritation of eyes, skin and upper respiratory tract. Chronic overexposures:
Can cause chronic bronchitis and lung disease. IARC/NTP: Listed as possibly carcinogenic to humans by IARC
(Group 2B)*. Additional information: Studies with experimental animals (rats) by inhalation have found lung
tumors and skin tumors.
*IARC Classification Definitions
Group 2B: The agent is possibly carcinogenic to humans. Generally includes agents for which there is limited
evidence in the absence of sufficient evidence in experimental animals.
Medical Conditions Aggravated By Exposure to the Product
Asthma, chronic lung disease, and skin rashes.
* * * Section 4 - First Aid Measures * * *
First Aid: Eyes
Flush eyes with plenty of water or saline for at least 15 minutes. Consult a physician.
First Aid: Skin
Remove contaminated clothing. Wash skin with soap and water for at least 15 minutes. Consult a physician if
irritation persists.
First Aid: Ingestion
If swallowed, dilute by drinking large amounts of water. Never give anything by mouth to a convulsing or
unconscious person. Do not induce vomiting. Get emergency medical care. Contact the local Poison Control
Center, if available.
First Aid: Inhalation
Remove to fresh air. If unconscious or severely injured, check for clear airway, breathing and presence of pulse.
Perform CPR if there is no pulse or respiration. Consult a physician.
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Page 3 of 12 Issue Date: 09/22/03 Revision: 2.0000 Print Date: 9/22/2003
Material Safety Data Sheet
Product Name: SOLVENT BASED TOUCH UP PAINT ID: 1017
* * * Section 5 - Fire Fighting Measures * * *
1潞F (-17潞C)
Flash Point:
12.0
UEL:
0.9
LEL:
Flammable liquid - Class IB
Flamm Class:
Flammable/Combustible Properties
Flammable.
Fire/Explosion
Solvent vapors may form explosive mixtures in air at room temperature. Vapors are heavier than air and may
travel considerable distances along the ground to a source of ignition. Closed containers may burst or explode
when exposed to extreme heat. Explosions can cause cans to "rocket" into non-burning areas which can spread
the fire beyond the area of origin. Material and rags contaminated with solvents can be combustible.
Extinguishing Media
Use Class B extinguishers [Carbon Dioxide, Dry Chemical (ABC or BC), or universal Aqueous Film Forming
Foam (AFFF)] designed to extinguish Class I flammable liquid fires. Water spray may be ineffective and may
spread flames. If water is used, fog nozzles are preferable. Use water spray to minimize vapors and cool
containers exposed to heat or flame. Move undamaged containers away from heat or flame, if possible. Water
spray may be used to flush spills away from ignition sources.
Fire Fighting Equipment/Instructions
Fire fighters should wear NIOSH approved, positive pressure, self-contained breathing apparatus and full
protective clothing when appropriate.
* * * Section 6 - Accidental Release Measures * * *
Small/Large Spill
Use adequate ventilation to reduce vapor concentration. Avoid all ignition sources around spill. Use non-sparking
handling equipment. Do not allow material to enter sewers or streams. Dike and transfer spill to container for
reuse and reprocessing. Absorb remainder with absorbent material. Notify spill coordinator. Notify environmental
personnel.
* * * Section 7 - Handling and Storage * * *
Handling/Storage
Avoid eye and skin contact. Use adequate ventilation to reduce vapor concentration. Store in tightly closed
containers in a cool, dry area. Store away from heat, sparks, flames, oxidizers, and other incompatible
substances. Use non-sparking handling equipment. Prohibit smoking.
Containers should be bonded and grounded during pouring or transfer to prevent static discharge which could
ignite material. Avoid freefall of liquid in excess of a few inches. Empty containers may contain residual product.
Do not cut or weld on containers.
* * * Section 8 - Exposure Controls / Personal Protection * * *
Engineering Controls
Use with adequate explosion-proof ventilation to meet the limits listed in Section 8, Exposure Guidelines.
Personal Protective Equipment
Respiratory Protection
Use NIOSH-approved respiratory protection as specified by an Industrial Hygienist or other qualified professional
if concentrations exceed the limits listed in Section 8, Exposure Guidelines. Suggested respiratory protection:
Organic vapor cartridge
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Material Safety Data Sheet
Product Name: SOLVENT BASED TOUCH UP PAINT ID: 1017
Eye Protection
Wear safety goggles or face shield to avoid direct eye contact.
Skin Protection
Wear impervious gloves/apron to prevent any skin contact.
Exposure Guidelines
A: General Product Information
No information available for product.
B: Component Exposure Limits
Isopropyl acetate (108-21-4)
ACGIH 100 ppm TWA
ACGIH 200 ppm STEL
OSHA 250 ppm TWA; 950 mg/m3 TWA
Isobutyl acetate (110-19-0)
ACGIH 150 ppm TWA
OSHA 150 ppm TWA; 700 mg/m3 TWA
Titanium dioxide (13463-67-7)
ACGIH 10 mg/m3 TWA
OSHA 15 mg/m3 TWA (total dust)
Acetone (67-64-1)
ACGIH 500 ppm TWA
ACGIH 750 ppm STEL
OSHA 1000 ppm TWA; 2400 mg/m3 TWA
Isopropyl alcohol (67-63-0)
ACGIH 200 ppm TWA
ACGIH 400 ppm STEL
OSHA 400 ppm TWA; 980 mg/m3 TWA
Propylene glycol monomethyl ether (PGMME) (107-98-2)
ACGIH 100 ppm TWA
ACGIH 150 ppm STEL
2-Butoxyethanol (111-76-2)
ACGIH 20 ppm TWA
OSHA prevent or reduce skin absorption
OSHA 50 ppm TWA; 240 mg/m3 TWA
Iron oxide (1309-37-1)
ACGIH 5 mg/m3 TWA (dust and fume, as Fe)
OSHA 10 mg/m3 TWA
n-Butyl alcohol (71-36-3)
ACGIH 20 ppm TWA
OSHA 100 ppm TWA; 300 mg/m3 TWA
Talc (14807-96-6)
ACGIH 2 mg/m3 TWA (respirable fraction, particulate matter containing no asbestos and
<1% crystalline silica)
OSHA 20 mppcf TWA (containing no asbestos and <1% quartz)
Carbon black (1333-86-4)
ACGIH 3.5 mg/m3 TWA
OSHA 3.5 mg/m3 TWA
Xylenes (1330-20-7)
ACGIH 100 ppm TWA
ACGIH 150 ppm STEL
OSHA 100 ppm TWA; 435 mg/m3 TWA
Ethyl benzene (100-41-4)
ACGIH 100 ppm TWA
ACGIH 125 ppm STEL
OSHA 100 ppm TWA; 435 mg/m3 TWA
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Page 5 of 12 Issue Date: 09/22/03 Revision: 2.0000 Print Date: 9/22/2003
Material Safety Data Sheet
Product Name: SOLVENT BASED TOUCH UP PAINT ID: 1017
* * * Section 9 - Physical & Chemical Properties * * *
Liquid Various colors
Physical State: Appearance:
180-374潞F (82-190潞C) Not determined
Boiling Point: Melting Point:
1.8 mm Hg (aliphatic Heavier than air
Vapor Pressure: Vapor Density:
naphtha)
Soluble Not determined
Solubility in Water: Specific Gravity:
Not determined Not applicable
Density: pH Level:
Solvent Not determined
Odor: Odor Threshold:
Not determined
Octanol-Water Coefficient:
* * * Section 10 - Chemical Stability & Reactivity Information * * *
Stability
Stable under normal conditions of use, storage, and transportation.
Conditions to Avoid
Avoid exposures to sparks, open flames, hot surfaces and all other sources of heat or ignition.
Incompatibility
Strong oxidizers and strong acids.
Hazardous Decomposition
Includes carbon monoxide, carbon dioxide, oxides of nitrogen and partially oxidized hydrocarbons.
Hazardous Polymerization
Will not occur.
* * * Section 11 - Toxicological Information * * *
Health Effects of Ingredients
A: General Product Information
No information available for product.
B: Component Analysis - LD50/LC50
Isopropyl acetate (108-21-4)
Inhalation LC50 Rat: 50600 mg/m3/8H; Oral LD50 Rat: 6750 mg/kg; Dermal LD50 Rabbit: >20 mL/kg
Isobutyl acetate (110-19-0)
Oral LD50 Rat: 13400 mg/kg; Dermal LD50 Rabbit: >17400 mg/kg
Acetone (67-64-1)
Inhalation LC50 Rat: 50100 mg/m3/8H; Inhalation LC50 Mouse: 44 gm/m3/4H; Oral LD50 Rat: 5800 mg/kg; Oral
LD50 Mouse: 3 gm/kg
Isopropyl alcohol (67-63-0)
Inhalation LC50 Rat: 16000 ppm/8H; Oral LD50 Rat: 5045 mg/kg; Oral LD50 Mouse: 3600 mg/kg; Dermal LD50
Rabbit: 12800 mg/kg
Propylene glycol monomethyl ether (PGMME) (107-98-2)
Inhalation LC50 Rat: 10000 ppm/5H; Oral LD50 Mouse: 11700 mg/kg; Dermal LD50 Rabbit: 13 gm/kg
2-Butoxyethanol (111-76-2)
Inhalation LC50 Rat: 450 ppm/4H; Inhalation LC50 Mouse: 700 ppm/7H; Oral LD50 Rat: 470 mg/kg; Oral LD50
Mouse: 1230 mg/kg; Dermal LD50 Rabbit: 220 mg/kg
Naphtha, light aromatic (64742-95-6)
Oral LD50 Rat: 8400 mg/kg
n-Butyl alcohol (71-36-3)
Inhalation LC50 Rat: 8000 ppm/4H; Oral LD50 Rat: 790 mg/kg; Oral LD50 Mouse: 2680 mg/kg; Dermal LD50
Rabbit: 3400 mg/kg
Carbon black (1333-86-4)
Oral LD50 Rat: >15400 mg/kg; Dermal LD50 Rabbit: >3 gm/kg
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Material Safety Data Sheet
Product Name: SOLVENT BASED TOUCH UP PAINT ID: 1017
Xylenes (1330-20-7)
Inhalation LC50 Rat: 5000 ppm/4H; Oral LD50 Rat: 4300 mg/kg; Dermal LD50 Rabbit: >1700 mg/kg
1,2,4-Trimethyl benzene (95-63-6)
Inhalation LC50 Rat: 18 gm/m3/4H; Oral LD50 Rat: 5 gm/kg
Isobutyl isobutyrate (97-85-8)
Inhalation LC50 Rat: 5000 ppm/6H; Oral LD50 Rat: 12800 mg/kg; Dermal LD50 Rabbit: >8600 mg/kg
Ethyl benzene (100-41-4)
Oral LD50 Rat: 3500 mg/kg; Dermal LD50 Rabbit: 17800 uL/kg
Carcinogenicity
A: General Product Information
No information available for product.
B: Component Carcinogenicity
Titanium dioxide (13463-67-7)
ACGIH A4 - Not Classifiable as a Human Carcinogen
IARC Monograph 47, 1989
Acetone (67-64-1)
ACGIH A4 - Not Classifiable as a Human Carcinogen
Isopropyl alcohol (67-63-0)
ACGIH A4 - Not Classifiable as a Human Carcinogen
IARC Monograph 71, 1999; Supplement 7, 1987; Monograph 15, 1977
2-Butoxyethanol (111-76-2)
ACGIH A3 - Animal Carcinogen
Iron oxide (1309-37-1)
ACGIH A4 - Not Classifiable as a Human Carcinogen (dust and fume, as Fe)
IARC Supplement 7, 1987; Monograph 1, 1972
Talc (14807-96-6)
ACGIH A4 - Not Classifiable as a Human Carcinogen (containing no asbestos fibers); A1 -
Confirmed Human Carcinogen (containing asbestos fibers)
IARC Supplement 7, 1987; Monograph 42, 1987
Carbon black (1333-86-4)
ACGIH A4 - Not Classifiable as a Human Carcinogen
IARC Monograph 65, 1996
Xylenes (1330-20-7)
ACGIH A4 - Not Classifiable as a Human Carcinogen
IARC Monograph 71, 1999; Monograph 47, 1989
Ethyl benzene (100-41-4)
ACGIH A3 - Animal Carcinogen
IARC Monograph 77, 2000
* * * Section 12 - Ecological Information * * *
Ecotoxicity
A: General Product Information
No information available for product.
B: Component Analysis - Ecotoxicity - Aquatic Toxicity
Isobutyl acetate (110-19-0)
96 Hr LC50 bluegill: 100 mg/L (Static)
Acetone (67-64-1)
96 Hr LC50 rainbow trout: 5540 mg/L (Static);96 Hr LC50 fathead minnow: 6210 mg/L (flow-through);96 Hr LC50
bluegill: 8300 mg/L (Static)
48 Hr LC50 water flea: 0.0039 mg/L;48 Hr EC50 water flea: 12700 mg/L (Static)
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Material Safety Data Sheet
Product Name: SOLVENT BASED TOUCH UP PAINT ID: 1017
Isopropyl alcohol (67-63-0)
96 Hr LC50 fathead minnow (29 days old):94900 mg/L (flow-through);96 Hr LC50 fathead minnow (31 days
old):61200 mg/L (flow-through)
5 min EC50 Photobacterium phosphoreum: 35390 mg/L
Propylene glycol monomethyl ether (PGMME) (107-98-2)
96 Hr LC50 rainbow trout: 19202 mg/L;96 Hr LC50 fathead minnow: 15886 mg/L;96 Hr LC50 bluegill: 21742 mg/L
96 Hr EC50 water flea: 10457 mg/L
2-Butoxyethanol (111-76-2)
96 Hr LC50 bluegill: 1490 mg/L (Static);24 Hr LC50 goldfish:1650 mg/L
24 Hr LC50 water flea: 1720 mg/L
n-Butyl alcohol (71-36-3)
96 Hr LC50 fathead minnow (33 days old):1510 mg/L (Static)
5 min EC50 Photobacterium phosphoreum: 2056 mg/L; 30 min EC50 Photobacterium phosphoreum: 2186 mg/L
Xylenes (1330-20-7)
96 Hr LC50 fathead minnow: 13.4 mg/L (flow-through);96 Hr LC50 rainbow trout: 8.05 mg/L (flow-through);96 Hr
LC50 bluegill: 16.1 mg/L (flow-through)
24 hr EC50 Photobacterium phosphoreum: 0.0084 mg/L
48 Hr EC50 water flea: 3.82 mg/L
1,2,4-Trimethyl benzene (95-63-6)
96 Hr LC50 fathead minnow: 7.72 mg/L (flow-through)
Ethyl benzene (100-41-4)
96 Hr LC50 rainbow trout: 14.0 mg/L (Static);96 Hr LC50 fathead minnow: 9.09 mg/L (flow-through);96 Hr LC50
bluegill: 150.0 mg/L (Static)
30 min EC50 Photobacterium phosphoreum: 9.68 mg/L
48 Hr EC50 water flea: 2.1 mg/L
Environmental Fate
No information available for product.
* * * Section 13 - Disposal Considerations * * *
Disposal Instructions
Reuse or recycle material whenever possible. Empty containers should be recycled or disposed of through an
approved waste management facility.
US EPA Waste Number & Descriptions
A: General Product Information
RCRA Hazardous Waste No.: D001 if disposed of "as is". Otherwise, characterize in accordance with applicable
regulations (40 CFR 261 or state equivalent in the U.S.)
B: Component Waste Numbers
RCRA waste codes other than described under Section A may apply depending on use of product. Refer to 40
CFR 261 or state equivalent in the U.S.
* * * Section 14 - Transportation Information * * *
Special Transportation
PSN #1 PSN #2 PSN #3 PSN #4
Notes: (1) (2) (3)
Proper Shipping Name: Consumer Consumer Paint
commodity, ORM-D commodity
Hazard Class: - 9 3
UN NA Number: - ID 8000 UN 1263
Packing Group: - - II
RQ: - - RQ
Other - Tech Name: - ICAO (xylenes)
Other - Marine Pollutant: - - -
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Material Safety Data Sheet
Product Name: SOLVENT BASED TOUCH UP PAINT ID: 1017
Notes:
(1) For U.S. domestic air, in not more than 1.0 liter inner packages under DOT via Fedex or UPS and U.S. land
transportation, follow DOT Consumer commodity rules for packages up to 66 lb. gross weight.
(2) For IATA and International air transportation, Packing Instructions 910 apply to inner packages not more
than 0.5 liter.
(3) For packages greater than outlined in notes (1) and (2) above, follow this classification. Delete "RQ, (xylene)"
reference for packages less than 2,500 lbs.
Canadian TDG Hazard Class & PIN: PSN#1 & PSN#2: Consumer commodity, 9, ID 8000; PSN#3: 3, UN 1263
* * * Section 15 - Regulatory Information * * *
US Federal Regulations
A: General Product Information
In reference to Title VI of the Clean Air Act of 1990, this material does not contain nor was it manufactured using
ozone-depleting chemicals.
B: Component Analysis
This material contains one or more of the following chemicals required to be identified under SARA Section 302
(40 CFR 355 Appendix A), SARA Section 313 (40 CFR 372.65) and/or CERCLA (40 CFR 302.4).
Isobutyl acetate (110-19-0)
CERCLA: 5000 lb final RQ (Listed under Butyl acetate); 2270 kg final RQ (Listed under Butyl
acetate)
Acetone (67-64-1)
CERCLA: 5000 lb final RQ; 2270 kg final RQ
Isopropyl alcohol (67-63-0)
SARA 313: 1.0 percent de minimis concentration (only if manufactured by the strong acid process,
no supplier notification)
2-Butoxyethanol (111-76-2)
SARA 313: 1.0 percent de minimis concentration (applies to R-(OCH2CH2)n-OR' ethers, where n
= 1,2, or 3, R=alkyl C7 or less or R = phenyl or alkyl subst. phenyl, R' = H or alkyl C7
or less, or OR' consisting of carboxylic acid ester, sulfate, phosphate, nitrate, or
sulfonate, Chemical Category N230) (related to Glycol ethers)
n-Butyl alcohol (71-36-3)
SARA 313: 1.0 percent de minimis concentration
CERCLA: 5000 lb final RQ; 2270 kg final RQ
Xylenes (1330-20-7)
SARA 313: 1.0 percent de minimis concentration
CERCLA: 100 lb final RQ; 45.4 kg final RQ
1,2,4-Trimethyl benzene (95-63-6)
SARA 313: 1.0 percent de minimis concentration
Ethyl benzene (100-41-4)
CERCLA: 1000 lb final RQ; 454 kg final RQ
SARA 311/312 Physical and Health Hazard Categories:
Yes
Immediate (acute) Health Hazard:
Yes
Delayed (chronic) Health Hazard:
Yes
Fire Hazard:
No
Sudden Release of Pressure:
No
Reactive:
State Regulations
A: General Product Information
No information available for product.
B: Component Analysis - State
The following components appear on one or more of the following state hazardous substances lists:
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Page 9 of 12 Issue Date: 09/22/03 Revision: 2.0000 Print Date: 9/22/2003
Material Safety Data Sheet
Product Name: SOLVENT BASED TOUCH UP PAINT ID: 1017
Component CAS # CA FL MA MN NJ PA
Isopropyl acetate 108-21-4 Yes No Yes Yes Yes Yes
Isobutyl acetate 110-19-0 Yes No Yes Yes Yes Yes
Titanium dioxide 13463-67-7 No No Yes Yes Yes Yes
Acetone 67-64-1 Yes No Yes Yes Yes Yes
Isopropyl alcohol 67-63-0 Yes No Yes Yes Yes Yes
Propylene glycol monomethyl ether (PGMME) 107-98-2 Yes No Yes Yes Yes Yes
2-Butoxyethanol 111-76-2 Yes No Yes Yes Yes Yes
Iron oxide 1309-37-1 Yes No Yes Yes Yes Yes
n-Butyl alcohol 71-36-3 Yes No Yes Yes Yes Yes
Talc 14807-96-6 Yes No Yes Yes Yes Yes
Carbon black 1333-86-4 Yes No Yes Yes Yes Yes
Xylenes 1330-20-7 Yes No Yes Yes Yes Yes
1,2,4-Trimethyl benzene 95-63-6 No No Yes No Yes Yes
Isobutyl isobutyrate 97-85-8 No No No No Yes No
Ethyl benzene 100-41-4 Yes No Yes Yes Yes Yes
The following statement(s) are provided under the California Safe Drinking Water and Toxic Enforcement Act of 1986
(Proposition 65):
WARNING! This product contains a chemical known to the state of California to cause cancer.
Other Regulations
A: General Product Information
Material meets the criteria for inclusion in WHMIS B2, D1A, D2A and D2B.
B: Component Analysis - WHMIS IDL
The following components are identified under the Canadian Hazardous Products Act Ingredient Disclosure List:
Component CAS # Minimum Concentration
Isopropyl acetate 108-21-4 1% (English Item 906, French Item 22)
Isobutyl acetate 110-19-0 1% (English Item 888, French Item 21)
Acetone 67-64-1 1% (English Item 10, French Item 41)
Isopropyl alcohol 67-63-0 1% (English Item 904, French Item 1050)
Propylene glycol monomethyl ether (PGMME) 107-98-2 1% (English Item 1364, French Item 833)
2-Butoxyethanol 111-76-2 1% (English Item 721, French Item 824)
Iron oxide 1309-37-1 1% (English Item 762, French Item 1327)
n-Butyl alcohol 71-36-3 1% (English Item 234, French Item 354)
Carbon black 1333-86-4 1% (English Item 309, French Item 1271)
1,2,4-Trimethyl benzene 95-63-6 0.1% (English Item 1640, French Item 1684)
Ethyl benzene 100-41-4 0.1% (English Item 697, French Item 854)
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Material Safety Data Sheet
Product Name: SOLVENT BASED TOUCH UP PAINT ID: 1017
C: Component Analysis - Inventory
Component CAS # TSCA DSL EINECS AUST. MITI
Isopropyl acetate 108-21-4 Yes Yes Yes Yes Yes
Isobutyl acetate 110-19-0 Yes Yes Yes Yes Yes
Titanium dioxide 13463-67-7 Yes Yes Yes Yes Yes
Acetone 67-64-1 Yes Yes Yes Yes Yes
Isopropyl alcohol 67-63-0 Yes Yes Yes Yes Yes
Naphtha, light aliphatic 64742-89-8 Yes Yes Yes Yes No
Propylene glycol monomethyl ether (PGMME) 107-98-2 Yes Yes Yes Yes Yes
2-Butoxyethanol 111-76-2 Yes Yes Yes Yes Yes
Iron oxide 1309-37-1 Yes Yes Yes Yes Yes
Naphtha, medium aliphatic 64742-88-7 Yes Yes Yes Yes No
Naphtha, light aromatic 64742-95-6 Yes Yes Yes Yes No
n-Butyl alcohol 71-36-3 Yes Yes Yes Yes Yes
Talc 14807-96-6 Yes Yes Yes Yes No
Carbon black 1333-86-4 Yes Yes Yes Yes Yes
Xylenes 1330-20-7 Yes Yes Yes Yes Yes
Oxo-hexyl acetate 88230-35-7 Yes Yes No Yes No
1,2,4-Trimethyl benzene 95-63-6 Yes Yes Yes Yes Yes
Isobutyl isobutyrate 97-85-8 Yes Yes Yes Yes Yes
Ethyl benzene 100-41-4 Yes Yes Yes Yes Yes
* * * Section 16 - Other Information * * *
MSDS History
Original: March 16, 1998
Supersedes: May 17, 2001
Revised: September 22, 2003
MSDS Status
Changes in Sections 1 and 15.
Prepared By
Hazardous Materials Control Committee
Preparer: Jon N. Peace, 412-553-2293
MSDS System Number
147603
Other Information
* NFPA 30, Flammable and Combustible Liquids Code
* NFPA 321, Standard on Basic Classification of Flammable and Combustible Liquids.
* Guide to Occupational Exposure Values-2003, Compiled by the American Conference of Governmental
Industrial Hygienists (ACGIH).
* Documentation of the Threshold Limit Values and Biological Exposure Indices, Sixth Edition, 1991, Compiled by
the American Conference of Governmental Industrial Hygienists, Inc. (ACGIH).
* NIOSH Pocket Guide to Chemical Hazards, U.S. Department of Health and Human Services, June 1994.
* Dangerous Properties of Industrial Materials, Sax, N. Irving, Van Nostrand Reinhold Co., Inc., 1984.
* Patty鈥檚 Industrial Hygiene and Toxicology: Volume II: Toxicology, 4th ed., 1994, Patty, F. A.; edited by Clayton,
G. D. and Clayton, F. E.: New York: John Wiley & Sons, Inc.
* Integrated Index(R), MICROMEDEX, Inc., 2003
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Page 11 of 12 Issue Date: 09/22/03 Revision: 2.0000 Print Date: 9/22/2003
Material Safety Data Sheet
Product Name: SOLVENT BASED TOUCH UP PAINT ID: 1017
Key-Legend:
ACGIH American Conference of Governmental Industrial Hygienists
AICS Australian Inventory of Chemical Substances
CAS Chemical Abstract Service
CERCLA Comprehensive Environmental Response, Compensation, and Liability Act
CFR Code of Federal Regulations
CPR Cardio-pulmonary Resuscitation
DOT Department of Transportation
DSL Domestic Substances List (Canada)
EINECS European Inventory of Existing Commercial Chemical Substances
EPA Environmental Protection Act
IARC International Agency for Research on Cancer
LC50 Lethal concentration (50 percent kill)
LCLo Lowest published lethal concentration
LD50 Lethal dose (50 percent kill)
LDLo Lowest published lethal dose
LFL Lower Flammable Limit
MITI Ministry of International Trade & Industry
NFPA National Fire Protection Association
NIOSH National Institute for Occupational Safety and Health
NTP National Toxicology Program
OEL Occupational Exposure Limit
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
PIN Product Identification Number
PSN Proper Shipping Name
RCRA Resource Conservation and Recovery Act
SARA Superfund Amendments and Reauthorization Act
STEL Short Term Exposure Limit
TCLP Toxic Chemicals Leachate Program
TDG Transportation of Dangerous Goods
TLV Threshold Limit Value
TSCA Toxic Substance Control Act
TWA Time Weighted Average
UFL Upper Flammable Limit
WHMIS Workplace Hazardous Materials Information System
atm atmosphere
cm centimeter
g, gm gram
in inch
kg kilogram
lb pound
m meter
mg milligram
ml, ML milliliter
mm millimeter
mppcf million particles per cubic foot
n.o.s. not otherwise specified
ppb parts per billion
ppm parts per million
psia pounds per square inch absolute
u micron
ug microgram
INFORMATION HEREIN IS GIVEN IN GOOD FAITH AS AUTHORITATIVE AND VALID; HOWEVER, NO
WARRANTY, EXPRESS OR IMPLIED, CAN BE MADE.
This is the end of MSDS # 1017
____________________________________________________________
Page 12 of 12 Issue Date: 09/22/03 Revision: 2.0000 Print Date: 9/22/2003
SOLVENT BASED TOUCH UP PAINT
WARNING
Hazards: Flammable. Solvent vapors are heavier than air and may travel long distances to
an ignition source. Vapors may form explosive air/vapor mixtures at room temperature,
particularly in confined or poorly ventilated areas. Closed containers may explode or burst
due to build-up of pressure when exposed to extreme heat.
Can cause eye, skin and respiratory tract irritation. Can be absorbed through the skin. Harmful
or fatal if swallowed.
Overexposure to vapor and mist can cause central nervous system effects (nausea, dizziness
and loss of coordination), lung diseases, liver damage and kidney damage.
Precautions: Keep away from heat, sparks, and flame. Keep container closed. Use with
adequate ventilation. Keep away from children.
Use appropriate eye (goggles/face shield) and skin (impervious gloves/apron) protection to
prevent contact. Wear appropriate respiratory protection (organic vapor cartridge) if
concentrations exceed the permissible limits.
First Aid: EYES: Flush with plenty of water or saline for at least 15 minutes. Consult a
physician. SKIN: Remove contaminated clothing. Wash with soap and water for at least 15
minutes. Consult a physician if irritation persists. INHALATION: Remove to fresh air. If
unconscious or severely injured, check for clear airway, breathing and presence of pulse.
Perform CPR if there is no pulse or respiration. Consult a physician. INGESTION: If
swallowed, dilute by drinking large amounts of water. Never give anything by mouth to a
convulsing or unconscious person. Do not induce vomiting. Get emergency medical care.
Contact the local Poison Control Center, if available.
See Alcoa Material Safety Data Sheet No. 1017 for more information about use and disposal.
Emergency Phone: (412) 553-4001.
INGREDIENTS: INGREDIENTS:
CAS NUMBERS: CAS NUMBERS:
Isopropyl acetate (108-21-4) Naphtha, medium aliphatic (64742-88-7)
Isobutyl acetate (110-19-0) Naphtha, light aromatic (64742-95-6)
Titanium dioxide (13463-67-7) n-Butyl alcohol (71-36-3)
Acetone (67-64-1) Talc (14807-96-6)
Isopropyl alcohol (67-63-0) Carbon black (1333-86-4)
Naphtha, light aliphatic (64742-89-8) Xylenes (1330-20-7)
Propylene glycol (107-98-2) Oxo-hexyl acetate (88230-35-7)
monomethyl ether 1,2,4-Trimethylbenzene (95-63-6)
2-Butoxyethanol (111-76-2) Isobutyl isobutyrate (97-85-8)
Iron oxide (1309-37-1) Ethyl benzene (100-41-4)
Alcoa Home Exteriors, Inc.
1590 Omega Drive, Pittsburgh, PA 15205 USA
09/03 1017
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