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MSDS Material Safety Data Sheet
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File Name: airgas_com---001112.asp
                Material Safety Data Sheet
Bromine Trifluoride

Section 1. Chemical product and company identification
: Bromine Trifluoride
Product Name
: AIRGAS INC., on behalf of its subsidiaries
Supplier
259 North Radnor-Chester Road
Suite 100
Radnor, PA 19087-5283
1-610-687-5253
: trifluorure de brome
Synonym
: 001112
MSDS#
Date of : 9/22/2006.
Preparation/Revision
: 1-866-734-3438
In case of emergency

Section 2. Hazards identification
: Liquid.
Physical state
: Danger!
Emergency overview
CAUSES RESPIRATORY TRACT, EYE AND SKIN BURNS.
OXIDIZER.
SPILLAGE MAY CAUSE FIRE OR LIBERATE POISONOUS GAS.
CONTACT WITH WATER MAY CAUSE FLASH FIRE.
CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE.
Do not get in eyes, on skin or clothing. Do not breathe vapor or mist. Keep away from
heat, sparks and flame. Will react with water or steam to produce heat and toxic fumes.
Store in tightly closed container. Avoid contact with combustible materials. Use only
with adequate ventilation. Wash thoroughly after handling.
Potential acute health effects
Corrosive to eyes.
Eyes :
Corrosive to the skin.
Skin :
Corrosive to the respiratory system.
Inhalation :
May cause burns to mouth, throat and stomach.
:
Ingestion
CARCINOGENIC EFFECTS Not available.
:
Potential chronic health :
: Not available.
effects MUTAGENIC EFFECTS
TERATOGENIC EFFECTS Not available.
:
: Repeated or prolonged contact with spray mist may produce chronic eye irritation and
Medical conditions
aggravated by overexposure severe skin irritation. Repeated or prolonged exposure to spray mist may produce
respiratory tract irritation leading to frequent attacks of bronchial infection. Repeated
exposure to a highly toxic material may produce general deterioration of health by an
accumulation in one or many human organs.
See toxicological Information (section 11)

Section 3. Composition, Information on Ingredients
United States
Exposure limits
bromine trifluoride 7787-71-5 100

Section 4. First aid measures
: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes.
Eye contact
Get medical attention immediately.
: In case of contact, immediately flush skin with plenty of water for at least 15 minutes
Skin contact
while removing contaminated clothing and shoes. Wash clothing before reuse.
Thoroughly clean shoes before reuse. Get medical attention immediately.
: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is
Inhalation
difficult, give oxygen. Get medical attention immediately.
Bromine Trifluoride

: Do NOT induce vomiting unless directed to do so by medical personnel. Never give
Ingestion
anything by mouth to an unconscious person. Get medical attention immediately.

Section 5. Fire fighting measures
Flammability of the product : Non-flammable.
: These products are halogenated compounds, hydrogen fluoride.
Products of combustion
: Use dry chemical or CO 2. Do not use water or foam.
Fire fighting media and
instructions
Will react with water or steam to produce heat and toxic fumes. This material increases
the risk of fire and may aid combustion. Contact with combustible material may cause
fire.
: Fire fighters should wear appropriate protective equipment and self-contained breathing
Special protective
apparatus (SCBA) with a full facepiece operated in positive pressure mode.
equipment for fire-fighters

Section 6. Accidental release measures
: Immediately contact emergency personnel. Eliminate all ignition sources. Keep
Personal precautions
unnecessary personnel away. Use suitable protective equipment (Section 8). Do not
touch or walk through spilled material.
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
: If emergency personnel are unavailable, contain spilled material. For small spills add
Methods for cleaning up
absorbent (soil may be used in the absence of other suitable materials) and use a non-
sparking or explosion proof means to transfer material to a sealed, appropriate container
for disposal. For large spills dike spilled material or otherwise contain material to ensure
runoff does not reach a waterway. Place spilled material in an appropriate container for
disposal.

Section 7. Handling and storage
: Do not get in eyes, on skin or on clothing. Keep container closed. Use only with
Handling
adequate ventilation. Do not breathe vapor or mist. Store in tightly closed container.
Avoid contact with combustible materials. Keep away from heat, sparks and flame. Will
react with water or steam to produce heat and toxic fumes. Wash thoroughly after
handling.
: Store in a segregated and approved area. Keep container in a cool, well-ventilated area.
Storage
Keep container tightly closed and sealed until ready for use.

Section 8. Exposure Controls, Personal Protection
: Provide exhaust ventilation or other engineering controls to keep the airborne
Engineering controls
concentrations of vapors below their respective occupational exposure limits. Ensure
that eyewash stations and safety showers are proximal to the work-station location.
Personal protection
: Safety eyewear complying with an approved standard should be used when a risk
Eyes
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts.
: Personal protective equipment for the body should be selected based on the task being
Skin
performed and the risks involved and should be approved by a specialist before handling
this product.
: Use a properly fitted, air-purifying or air-fed respirator complying with an approved
Respiratory
standard if a risk assessment indicates this is necessary.Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
: Chemical-resistant, impervious gloves or gauntlets complying with an approved standard
Hands
should be worn at all times when handling chemical products if a risk assessment
indicates this is necessary.
Personal protection in case : Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self-contained breathing
apparatus should be used to avoid inhalation of the product. Suggested protective
of a large spill
clothing might not be sufficient; consult a specialist BEFORE handling this product.
Product name Exposure limits
Bromine Trifluoride

United States
bromine trifluoride

Section 9. Physical and chemical properties
Liquid.
Physical state :
Yellow or Gray
Color :
EXTREMELY IRRITATING
Odor :
136.91 g/mole
Molecular weight :
Br-F3
Molecular formula :
127掳C (260.6掳F)
Boiling/condensation point :
8.8掳C (47.8掳F)
Melting/freezing point :

Section 10. Stability and reactivity
: The product is stable.
Stability and reactivity
Incompatibility with various : Highly reactive with combustible materials, metals.
substances
Hazardous decomposition : These products are halogenated compounds, hydrogen fluoride.
products

Section 11. Toxicological information
: No specific information is available in our database regarding the other toxic effects of
Other toxic effects on
this material for humans.
humans
Specific effects
: No known significant effects or critical hazards.
Carcinogenic effects
: No known significant effects or critical hazards.
Mutagenic effects
: No known significant effects or critical hazards.
Reproduction toxicity

Section 12. Ecological information
: These products are halogenated compounds.
Products of degradation
: The products of degradation are less toxic than the product itself.
Toxicity of the products of
biodegradation

Section 13. Disposal considerations
: The generation of waste should be avoided or minimized wherever possible. Avoid
Waste disposal
dispersal of spilled material and runoff and contact with soil, waterways, drains and
sewers. Disposal of this product, solutions and any by-products should at all times
comply with the requirements of environmental protection and waste disposal legislation
and any regional local authority requirements.
Consult your local or regional authorities.

Section 14. Transport information
Regulatory UN number Proper shipping Class Packing group Label Additional
information name information
DOT Classification UN1746 BROMINE 5.1 I Limited
TRIFLUORIDE quantity
OXIDIZER

Yes.
5.1




Packaging
instruction
POISON



Passenger
6


Aircraft
Quantity
limitation:
CORROSIVE


8
Forbidden.
Bromine Trifluoride
Cargo Aircraft
Quantity
limitation:
Forbidden.

Special
provisions
2, B9, B14,
B32, B74, T22,
TP2, TP12,
TP13, TP38,
TP45


Explosive
TDG Classification UN1746 BROMINE 5.1 I
TRIFLUORIDE Limit and
Limited
5.1


Quantity Index
0

ERAP Index
6


1000

Passenger
Carrying Ship
8



Index
Forbidden

Passenger
Carrying Road
or Rail Index
Forbidden



UN1746 BROMINE 5.1 I Limited
Mexico
TRIFLUORIDE quantity
Classification OXIDIZER

Yes.
5.1




Packaging
instruction
POISON


Passenger
6


Aircraft
Quantity
limitation:
CORROSIVE


Forbidden.
8




Cargo Aircraft
Quantity
limitation:
Forbidden.

Special
provisions
2, B9, B14,
B32, B74, T22,
TP2, TP12,
TP13, TP38,
TP45
Bromine Trifluoride


Section 15. Regulatory information
United States
: Oxidizing material
HCS Classification
Water reactive material
Corrosive material
: TSCA 8(b) inventory: bromine trifluoride
U.S. Federal regulations
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: bromine trifluoride
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: bromine
trifluoride: Fire hazard, reactive, Immediate (Acute) Health Hazard
Clean Water Act (CWA) 307: No products were found.
Clean Water Act (CWA) 311: No products were found.
Clean air act (CAA) 112 accidental release prevention: No products were found.
Clean air act (CAA) 112 regulated flammable substances: No products were found.
Clean air act (CAA) 112 regulated toxic substances: No products were found.
: Pennsylvania RTK: bromine trifluoride: (generic environmental hazard)
State regulations
Massachusetts RTK: bromine trifluoride
New Jersey: bromine trifluoride
Canada
: Class C: Oxidizing material.
WHMIS (Canada)
Class D-1A: Material causing immediate and serious toxic effects (VERY TOXIC).
Class E: Corrosive liquid.
CEPA NDSL: bromine trifluoride

Section 16. Other information
: CAUSES RESPIRATORY TRACT, EYE AND SKIN BURNS.
Label Requirements
OXIDIZER.
SPILLAGE MAY CAUSE FIRE OR LIBERATE POISONOUS GAS.
CONTACT WITH WATER MAY CAUSE FLASH FIRE.
CONTACT WITH OTHER MATERIAL MAY CAUSE FIRE.
3
Hazardous Material : Health
Information System (U.S.A.) 0
Fire hazard
3
Reactivity
C
Personal protection
National Fire Protection :
Flammability
0
Association (U.S.A.)
3 0
Health Instability
Special

Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above named
supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.

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