World Headquarters
Hach Company
P.O.Box 389 MSDS No: M00053
Loveland, CO USA 80539
(970) 669 -3050
SAFETY DATA SHEET
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Product Name: CyaniVer 庐 5 Cyanide Reagent
Catalog Number: 1404169
HACH LANGE GmbH Emergency Telephone Numbers:
Willst盲tterstrasse 11 (Poison Information Center Main)
40549 D 眉sseldorf, Germany (+49 (0) 6131 19240) 24 HR
+49 -(0)211 -52880
SDS Number: M00053
Chemical Name: Not applicable
Chemical Formula: Not applicable
Chemical Family: Not applicable
Use of the substance/preparation: Determination of cyanid e
CAS No.: Not applicable
Hazard: May cause irritation.
Date of MSDS Preparation:
Day: 12
Month: 01
Year: 2006
Additional Emergency Response Numbers: Austria: +49 (0)6131 19240, Belgium: +32 -(0)70 -245245, France: +33
-
(0)1 -40370404, Italy: +39 -0266101029, Netherlands: +31
- -(0)30 -2748888, Switzerland: +41 -(0)1 -2515151
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2. COMPOSITION / INFORMATION ON I NGREDIENTS
Potassium Phosphate, Monobasic
EEC Number: 2319134
CAS No.: 7778770
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Percent Range: 35,0 - 45,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
3 mg/m 3, Inhalable dust
EU Occupational Exposure Limits:
Sodium Phosphate, Dibasic
EEC Number: 2314487
CAS No.: 7558794
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Percent Range: 35,0 - 45,0
Percent Range Units: weight / we ight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
3 mg/m 3, Inhalable dust
EU Occupational Exposure Limits:
Sodium Sulfate
EEC Number: 2318209
CAS No.: 7757826
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Percent Range: 10,0 - 20,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not applicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PE L: Not established
3 mg/m 3, Inhalable dust
EU Occupational Exposure Limits:
3-Methyl -1-phenyl -2-pyrazolin -5-one
EEC Number: 2018910
CAS No.: 89258
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Percent Range: 5,0 - 15,0
Percent Range Units: weight / weight
Ingredient EEC Symbol: Not ap plicable
Ingredient R phrase(s) (R phrase details given in Heading 16): Not applicable
TLV: Not established
PEL: Not established
3 mg/m 3, Inhalable dust
EU Occupational Exposure Limits:
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3. HAZARDS IDENTIFI CATION
Emergency Overview:
Appearance: White powder
Odor: Not determined
EU Symbols: Not applicable
R PHRASES: Not applicable
Protective Equipment:
Potential Health Effects:
Eye Contact (EC): May cause irritation
Skin Contact (EC): May cause irritation May cause allergic reaction
Skin Absorption (EC): None Reported
Target Organs (SA E): None Reported
Ingestion (EC): May cause: nausea vomiting diarrhea lethargy fever gastrointestinal tract irrit ation
Target Organs (Ing E): None Reported
Inhalation: May cause: respiratory tract irritation
Target Organs (Inh E): None Reported
Medical Conditions Aggravated: Allergies or sensitivity to pyrazolone.
Chronic Effects: Chronic overexp osure may cause allergic skin reactions
Cancer / Reproductive Toxicity Information:
This product does NOT contain any IARC listed chemicals.
Additional Cancer / Reproductive Toxicity Information: None reported
Toxicologically Synergistic Pro ducts: None reported
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4. FIRST AID MEASURES
Eye Contact: Immediately flush eyes with water for 15 minutes. Call physician.
Skin Contact (First Aid): Remove contaminated clothing. Wash skin with soap and plenty of water.
Ingestion (First Aid): Give large quantities of water. Call physician immediately.
Inhalation: Remove to fresh air. Give artificial respiration if necessary. Call physician.
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5. FIRE FIGHTING MEASURES
Flammable Properties: During a fire, this product decomposes to form toxic gases.
Hazardous Combust ion Products: Toxic fumes of: sulfur oxides. nitrogen oxides. phosphorus oxides
Fire / Explosion Hazards: May react violently with: aluminum / aluminum compounds strong oxidizers
Static Discharge: None reported.
Mechanical Impact: None repor ted
Extinguishing Media: Water. Carbon dioxide Dry chemical.
Extinguishing Media NOT To Be Used: Not applicable Not applicable Not applicable
Fire Fighting Instruction: As in any fire, wear self -contained breathing apparatus pressure -demand and full protective
gear.
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6. ACCIDENTAL RELEASE MEASURES
Spill Response Notice:
Only persons properly qualified to respond to an emergency involving hazardous substances should respond to a spill
involving c hemicals. See Section 13, Special Instructions for disposal assistance.
Containment Technique: Stop spilled material from being released to the environment.
Clean -up Technique: Scoop up spilled material into a large beaker and dissolve with water. Flush the spilled material to
the drain with a large excess of water. Decontaminate the area of the spill with a soap solution.
Evacuation Procedure: Evacuate local area (15 foot radius or as directed by your facility's emergency response plan)
when : a pound or more of loose powder is spilled. If conditions warrant, increase the size of the evacuation.
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7. HANDLING AND STORAGE
Handling: Avoid contact with eyes skin clothing Do not breathe dust. Wash thoroughly after handling. Maintain
general industrial hygiene practices when using this product.
Storage: Keep container tightly closed when not in use. Protect from: heat moisture Keep away from: oxidizers
Special Packaging Instructions: N ot applicable
Use of the substance/preparation: Determination of cyanide
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8. EXPOSURE CONTROLS / PROTECTIVE EQUIPMENT
Engineering Controls: Have an eyewash station nearby. Maintain general industrial hygiene practices when using this
product.
Personal Protective Equipment:
Eye Protection: safety glasses with top and side shields
Skin / Hand Protection: disposable latex gloves lab coat
Inhalation Protection: adequate ven tilation
Precautionary Measures: Avoid contact with: eyes skin clothing Do not breathe: dust Wash thoroughly after handling.
Keep away from: oxidizers
TLV: Not established
PEL: Not established
EU Occupational Exposure Limits: 3 mg/m 3, Inh alable dust
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9. PHYSICAL / CHEMICAL PROPERTIES
Appearance: White powder
Physical State: Solid
Odor: Not determined
pH: of 5% solution = 6,20
Vapor Pressure: Not applicable
Vapor Density (air = 1): Not applicable
Boiling Point: Not applicable
Melting Point: Decomposes at 100掳C (212掳F)
Flash Point: Not applicable
Method: Not applicable
Autoignition Temperature: Not determined
Flammability Limits:
Lower Explosion Limits: Not applicable
Upper Explosion Limits: Not applicable
Specific Gravity (water = 1): 2,16
Evaporation Rate (water = 1): Not applicable
Volatile Organic Compounds Content: Not determined
Partition Coefficient (n -octanol / water): Not applicable
Solubility:
Water : Soluble
Acid: Not determined
Other: Not determined
Metal Corrosivity:
Steel: Not determined
Aluminum: Not determined
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10. STABILITY / REACTIVITY
Chemical Stability: Stable when stored under proper condi tions.
Conditions to Avoid: Contact with heat, sparks, open flames or other ignition sources. Excess moisture Heating to
decomposition.
Reactivity / Incompatibility: Incompatible with: oxidizers aluminum
Hazardous Decomposition: Heating to decomposition releases: phosphorus oxides nitrogen oxides sulfur oxides
Hazardous Polymerization: Will not occur.
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11. TOXICOLOGICAL INFORMATION
Product Toxicological Data:
LD50: None reported
LC50: None reported
Dermal Toxicity Data: None reported
Skin and Eye Irritation Data: None reported
Mutation Data: None reported
Reproductive Effects Data: None reported
--
Ingredient Toxicological Data: Sodium Phosphate Dibasic: Oral rat LD 50 = 17 g/kg, Potassium Phosphate Monobasic:
Oral rat LD 50 = 7100 mg/kg, Sodium Sulfate: Oral mouse LD 50 = 5989 mg/kg, Pyrazalone: Oral rat LD 50 = 3500 mg/kg
This product does NOT contain any IARC listed chemicals.
_______________________________ _______
12. ECOLOGICAL INFORMATION
Product Ecological Information: --
No ecological data available for this product.
Ingredient Ecological Information: --
No ecological data available for the ingredients of this product.
______________________ ________________
13. DISPOSAL CONSIDERATIONS
NOTICE (Disposal): These disposal guidelines are based on federal regulations and may be superseded by more stringent
state or local requirements. Please consult your local environmental regulators for more information. In Europe: Chemical
and analysis solutions must be disposed of in compliance with the respective national regulations. Product packaging must
be disposed of in compliance with the country -specific regulations or must be passed to a packagi ng return system.
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14. TRANSPORT INFORMATION
I.C.A.O.:
I.C.A.O. Proper Shipping Name: Not Currently Regulated
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ICAO Hazard Class: NA
ICAO Subsidiary Risk: NA
ICAO UN/ID Number: NA
ICAO Packing Group: NA
I.M.O.:
I.M.O. Proper Shipping Name: Not Currently Regulated
--
I.M.O. Hazard Class: NA
I.M.O. Subsidiary Risk: NA
I.M.O. UN Number: NA
I.M.O. Packing Group: NA
A.D.R.:
A.D.R. Proper Shipping Name: Not Currently Regu lated
--
A.D.R Hazard Class: NA
A.D.R. Subsidiary Risk: NA
A.D.R. UN -Number:: NA
A.D.R. Packing Group: NA
Additional Information: This product may be shipped as part of a chemical kit composed of various compatible
dangerous goods for an alytical or testing purposes. This kit would have the following classification: Proper Shipping
Name: Chemical Kit Hazard Class: 9 UN Number 3316
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15. REGULATORY INFORMATION
National Inventories:
EEC Inventory Status: All ingredients used to make this product are listed on EINECS / ELINCS.
EEC Number: Not applicable
EEC LABEL COPY:
EU Symbols: Not applicable
R PHRASES: Not applicable
S PHRASES: Not applicable
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16. OTHER INFORMATION
References: 29 CFR 1900 - 1910 (Code of Federal Regulations - Labor). Air Contaminants, Federal Register, Vol. 54,
No. 12. Thursday, January 19, 1989. pp. 2332 -2983. TLV's Threshold Limi t Values and Biological Exposure Indices for
1992 -1993. American Conference of Governmental Industrial Hygienists, 1992. Technical Judgment. In -house
information. Fire Protection Guide on Hazardous Materials, 10th Ed. Quincy, MA: National Fire Protec tion Fire
Protection Guide on Hazardous Materials, 10th Ed. Quincy, MA: National Fire Protection Association, 1991.
R PHRASES: Not applicable
Use of the substance/preparation: Determination of cyanide
Revision Summary: Updates in Section(s) 14,
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Legend:
NA - Not Applicable w/w - weight/weight
ND - Not Determined w/v - weight/volume
NV - Not Available v/v - volume/volume
USER RESPONSIBILITY: Each user should read and understand this information and i ncorporate it in individual site safety
programs in accordance with applicable hazard communication standards and regulations.
THE INFORMATION CONTAINED HEREIN IS BASED ON DATA CONSIDERED TO BE ACCURATE.
HOWEVER, NO WARRANTY IS EXPRESSED OR IMPLIED REGARD ING THE ACCURACY OF THESE DATA
OR THE RESULTS TO BE OBTAINED FROM THE USE THEREOF.
HACH COMPANY 漏2006
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