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MSDS Material Safety Data Sheet
CAS

7647-01-0
7732-18-5

File Name: camlab_co_uk---silicaLRMSDS.asp
                                                                                                          MSDS
MATERIAL SAFETY DATA SHEET
P.O. Box 329 - 802 Washington Avenue Chestertown, MD 21620 - USA
TELEPHONE # FOR INFORMATION 410 778-3100
24 HOUR EMERGENCY NUMBER (CHEM-TEL): USA, Canada, Puerto Rico 800-255-3924;
Outside North American Continent 813-248-0585 (call Collect)

1. Product Identification Manufactured By: LaMotte Company
Product Code: V-4466 802 Washington Avenue
Product Description: Silica Reagent #1 (TRL) Chestertown, MD 21620



2. Composition/Information On Ingredients
Hazard CAS#/Name
TLV
% PEL
7647-01-0 20 C 5 ppm C 2 ppm
Yes
Hydrochloric Acid

No 7732-18-5 to 100%
Water




3. Hazards Overview
Primary Route Of Entry: Skin Ingestion Inhalation
Poison! Danger! Corrosive. Liquid and mist cause severe burns to all body tissue. Inhalation may cause coughing, chest pains, damage to
lungs. Harmful or fatal if swallowed.



HMIS Hazard
Scale: 4 = Extreme, 3 = High, 2 = Moderate, 1= Slight, 0 = Least
Health: 3 Flammability: 0 Reactivity: 2


Carcinogenicity: None:


Other Health Related Comments:




1
Product Code: V-4466 Product Description: Silica Reagent #1 (TRL)


4. First Aid Measures
Eye Contact: Immediately flush with water for at least 15 minutes. Consult a physician.
Skin Contact: Immediately flush w/ water for at least 15 minutes while removing affected clothing. Wash skin with soap & water.
Consult a physician.
Ingestion: Do not induce vomiting. Rinse out mouth. Drink plenty of water. Call a physician immediately.

Inhalation: Remove to fresh air. Give artificial respiration if breathing has stopped. If breathing is difficult, give oxygen.

5. Fire Fighting Measures

Flash Point (Method Used): LEL: N/A UEL: N/A
N/A

Not a fire hazard
Extinguishing Media:
Firefighters wear self-contained breathing apparatus
Special Fire Fighting Procedures:

Contact with metals may produce flammable hydrogen gas.
Unusual Fire & Explosion Hazard:




6. Accidental Release Measures
Wear gloves and eye protection. Cover with sodium bicarbonate or soda ash/calcium hydroxide mixture. Mix and
carefully add water to form slurry. Scoop up and wash down drain with excess water.




7. Handling & Storage
Store in cool, dry, storage area away from such incompatible materials as metals, bases, ammonia, sulfides, and cyanides.




2
Product Code: V-4466 Product Description: Silica Reagent #1 (TRL)


8. Exposure Controls/Personal Protection
Ventilation
Mechanical Respiratory
With larger quantities, work in chemical fume hood to avoid inhalation.




Protection When Handling
Eye Protection Gloves Lab Coat




Avoid contact with skin and clothing. Wash after handling.
Work/Hygenic Practices:




9. Physical & Chemical Properties

Clear Colorless Liquid 1.3 (Air=1)
Appearance: Vapor Density:
Soluble Unknown
Solubility In Water: Vapor Pressure:
Slight chlorine 110 deg C
Odor: Boiling Point:
<1 N/A
pH: Melting Point:



10. Stability & Reactivity
Yes
Stable:
Heat
Conditions To Avoid:
Metals, strong caustics, sulfides and sulfites. Contact with metals causes formation of
Incompatibility (Materials To Avoid):
flammable and explosive hydrogen gas.
HCl gas
Hazardous Decomposition Products:



11. Toxicological Information
Oral rabbit LD50: 900 mg/kg for hydrochloric acid, conc. Investigated as a tumorigen, mutagen, reproductive effector.



Corrosive to all body parts Respiratory System Skin
Target Organs:




3
Product Code: V-4466 Product Description: Silica Reagent #1 (TRL)



12. Ecological Information
When released into the soil, this material is not expected to biodegrade. It may leach into groundwater. This material is expected to be
toxic to aquatic life.



13. Disposal Considerations
Wear gloves and eye protection. Add very slowly with stirring to a large volume of soda ash & calcium hydroxide. Pour
neutralized solution down drain with excess water. Dispose according to federal, state and local regulations.




14. Transportation Information
Proper Shipping Name:
DOT: HYDROCHLORIC ACID

IATA: HYDROCHLORIC ACID


Hazard Class/Div:
DOT: 8
IATA: 8

UN: 1789
Packing Group: II


15. Regulatory Information
Chemical Inventory Status
USA Europe --- Canada ---
TSCA EC
Hazard Ingredient DSL NDSL Australia Japan

Yes 7647-01-0 Yes Yes Yes No Yes Yes
Hydrochloric Acid

No 7732-18-5 Yes Yes Yes No Yes Yes
Distilled Water

Federal, State, & International Regulations
--- SARA 302 --- --------- SARA 313 ---------
RCRA TSCA
Listed
Ingredient RQ TPQ Chemical Category CERCLA 261.33 8(D)
7647-01-0 5000 500 Yes No 5000 No No
Hydrochloric Acid

7732-18-5 No No No No No No No
Distilled Water




4
Product Code: V-4466 Product Description: Silica Reagent #1 (TRL)



--- SARA 311/312 --- -------- Australia -------
Hazchem Poison This MSDS Is
Hazard Categories
WHMIS Compliant
Acute Chronic Fire Pressure Reactivity Code Schedule
Ingredient
7647-01-0 Yes Yes No No No 2R None Allocated
Hydrochloric Acid

7732-18-5 No No No No No None Allocated None Allocated
Distilled Water

Yes Yes No No No 2R None Allocated Yes
product
V-4466
as a whole

16. Other Information



Prepared By: IP, Regulatory Affairs Department
Revised: 5/12/2006




5
MSDS
Material Safety Data Sheet
PO Box 329 鈥? 802 Washington Avenue 鈥? Chestertown, MD 21620 鈥? USA
Telephone Number For Information 410-778-3100
24 Hour Emergency Number (CHEM-TEL) : USA, Canada, Puerto Rico 800-255-3924;
Outside North American continent: 813-248-0585 (call collect)

1. Product Identification Manufactured By: LaMotte Company
V-4468 802 Washington Avenue
Product Code:
Silica Reagent #3
Product Description: Chestertown, MD 21620

2. Composition/Information on Ingredients

Hazardous Name CAS # % OSHA ACGIH
PEL TLV
Yes Oxalic Acid, dihydrate 6153-56-6 10 1 mg/cubic m 1 mg/cubic m
No Water to 100% 7732-18-5 90

3. Hazards Overview
Primary Route of Entry: Ingestion Skin

Poison! Danger! May be fatal if swallowed. Corrosive. Causes severe irritation and burns to skin, eyes, and
respiratory tract. Very toxic, primary skin irritant. Harmful if inhaled or absorbed through skin.

HMIS Hazard: (Scale: 4 = Extreme, 3 = High, 2 = Moderate, 1 = Slight, 0 = Least)
Health: 2 Flammability: 0 Reactivity: 1

Carcinogenicity: None
Other Health Related Comments: (See Section 11.)

4. First Aid Measures
Eye Contact: Flush thoroughly with water for 15 minutes. Get prompt medical advice.
Skin Contact: In case of contact, wipe off excess from skin then immediately flush skin thoroughly
with water for at least 15 minutes while removing contaminated clothing and shoes.
Wash with soap and water. Consult physician.
Ingestion: Rinse out mouth. Do not induce vomiting. Drink several glasses of milk or water. Call a
doctor immediately!
Inhalation: Remove to fresh air. If symptoms of respiratory irritation appear, call a doctor.


5. Fire Fighting Measures
Oxalic Acid is a combustible solid below 101C (215F)
Flash Point: N/A LEL: N/A UEL: N/A
Fire Rating
Extinguishing Media: Not a fire hazard
Special Fire Fighting Procedures: N/A
Hazardous Combustion and/or Decomposition Products: May form CO, CO2, when heated to decomposition.
May also form formic acid.
Unusual Fire & Explosion Hazard: N/A

1
Product Code: V-4468 Product Description: Silica Reagent #3

6. Accidental Release Measures
Wear appropriate personal protective equipment: gloves, safety glasses, body-covering clothing. Cover
contaminated surfaces with soda ash or sodium bicarbonate to neutralize the acid. Scoop up neutralized slurry and wash
down drain with excess water.

7. Handling & Storage
Store in a cool, ventilated area away from sources of heat and incompatibles.

8. Exposure Controls/Personal Protection

Ventilation
Use with adequate ventilation.

Protection When Handling
Gloves Eye Protection Lab Coat

Work/Hygienic Practices: Avoid contact with skin. Wash after handling.

9. Physical & Chemical Properties

Appearance: Colorless Clear Liquid Boiling Point: Unknown
Melting Point: N/A
pH: 1
Odor: None Vapor Density: Unknown
Solubility in Water: Soluble Vapor Pressure: <17 mm @ 20 deg C

10. Stability & Reactivity
Yes
Stable:
Conditions to Avoid: N/A
Finely powdered metals and silver compounds, strong reducers and bases,
Materials to Avoid:
oxidizing agents and hypochlorites (bleaches).
Hazardous Decomposition Products: COx, formic acid

11. Toxicological Information

Oral rat LD50: 375 mg/kg for oxalic acid. Very toxic. Oxalic acid is corrosive to tissue. When ingested, oxalic
acid removes calcium from the blood. May cause kidney damage as calcium is removed from the blood in the form of
calcium oxalate. The calcium oxalate then obstructs the kidney tubules. Investigated as a reproductive effector.

Target Organs: Corrosive to all body parts

12. Ecological Information
Information not Available

13. Disposal Considerations
Neutralize with sodium bicarbonate or soda ash. Scoop up slurry and wash down drain with excess water.
Dispose according to federal, state and local regulations.

2
Product Code: V-4468 Product Description: Silica Reagent #3

14. Transport Information

Proper Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC N.O.S. (10% OXALIC ACID DIHYDRATE)
Hazard Class/Div: 8
UN3265
Packing Group: II

15. Regulatory Information
Chemical Inventory Status
USA Europe ---Canada--- Australia Japan
Ingredient TSCA EC DSL NDSL
Oxalic Acid, anhydrous (144-62-7) Yes Yes Yes No Yes Yes

Water to 100%




Federal, State, & International Regulations
---SARA 302--- - -------- SARA 313 --------- RCRA TSCA
Ingredient RQ TPQ Listed Chemical Category CERCLA 261.33 8(D)
Oxalic Acid, anhydrous No No No No No No No
(144-62-7)

Water to 100%


----------- Australia -----------
------ SARA 311/312 ------ Hazchem Poison This MSDS is
Ingredient Hazard Categories Code Schedule WHMIS Compliant
Oxalic Acid, anhydrous Acute: Yes Chronic: Yes Fire: No 2X S6
(144-62-7) Pressure: No Reactivity: No
(Pure/solid)

Water to 100%

Acute: Yes Chronic: Yes Fire: No 2X S6 YES
For #V-4468 liquid
Pressure: No Reactivity: No
mixture, taken as a whole
(Liquid/mixture)



16. Other Information

Prepared By: IP

Revised: 6/13/2005




3
MSDS
Material Safety Data Sheet
PO Box 329 鈥? 802 Washington Avenue 鈥? Chestertown, MD 21620 鈥? USA
Telephone Number For Information 410-778-3100
24 Hour Emergency Number (CHEM-TEL) : USA, Canada, Puerto Rico 800-255-3924;
Outside North American continent: 813-248-0585 (call collect)

1. Product Identification Manufactured By: LaMotte Company
V-4467 802 Washington Avenue
Product Code:
Silica Reagent #2
Product Description: Chestertown, MD 21620

2. Composition/Information on Ingredients

Hazardous Name CAS # % OSHA ACGIH
PEL TLV
Yes Ammonium Molybdate tetrahydrate 12054-85-2 10 5 mg/cubic m as 5 mg/cubic m as
Mo Mo

Yes Potassium Hydroxide 1310-58-3 2.4 C 2 mg/cubic m C 2 mg/cubic m

No Water to 100% 7732-18-5

3. Hazards Overview
Primary Route of Entry: Skin

Warning! May be irritating to skin. Harmful if swallowed.

HMIS Hazard: (Scale: 4 = Extreme, 3 = High, 2 = Moderate, 1 = Slight, 0 = Least)
Health: 1 Flammability: 0 Reactivity: 0

Carcinogenicity: None

Other Health Related Comments:

4. First Aid Measures
Flush thoroughly with water for 15 minutes. Consult a physician.
Eye Contact:
Flush thoroughly with water. Remove affected clothing and wash skin with soap and water.
Skin Contact:
Rinse out mouth. Drink glass of water. Consult a physician.
Ingestion:
N/A
Inhalation:


5. Fire Fighting Measures

Flash Point: N/A LEL: N/A UEL: N/A
Fire Rating
Extinguishing Media: Not a fire hazard
Special Fire Fighting Procedures: N/A
Hazardous Combustion and/or Decomposition Products: N/A
Unusual Fire & Explosion Hazard: N/A


1
Product Code: V-4467 Product Description: Silica Reagent #2

6. Accidental Release Measures
Pour down drain with excess water.

7. Handling & Storage
Store in cool, dry area away from heat and incompatible materials.

8. Exposure Controls/Personal Protection

Ventilation
Use with adequate ventilation.

Protection When Handling
Gloves Eye Protection Lab Coat

Work/Hygienic Practices: Avoid repeated contact with skin and clothing.

9. Physical & Chemical Properties

Appearance: Colorless slightly cloudy or clear LiquidBoiling Point: >100 deg C
Melting Point: N/A
pH: 8
Odor: None Vapor Density: Unknown
Solubility in Water: Soluble Vapor Pressure: Unknown

10. Stability & Reactivity
Yes
Stable:
Conditions to Avoid: N/A
Materials to Avoid: N/A

Hazardous Decomposition Products: N/A

11. Toxicological Information
Oral rat LD50: 333 mg/kg for ammonium molybdate anhydrous. Investigated as a mutagen.

Target Organs: Ammonium molybdate can affect blood, kidneys

12. Ecological Information
Information not Available

13. Disposal Considerations
Pour down drain with excess water. Dispose according to federal, state and local regulations.

14. Transport Information
Not regulated for transport.



2
Product Code: V-4467 Product Description: Silica Reagent #2

15. Regulatory Information
Chemical Inventory Status
USA Europe ---Canada--- Australia Japan
Ingredient TSCA EC DSL NDSL
Ammonium Molybdate, anhydrous Yes Yes Yes No Yes Yes
(12027-67-7)

Potassium Hydroxide Yes Yes Yes No Yes Yes

Water to 100%

Federal, State, & International Regulations
---SARA 302--- - -------- SARA 313 --------- RCRA TSCA
Ingredient RQ TPQ Listed Chemical Category CERCLA 261.33 8(D)
Ammonium Molybdate, No No No No No No No
anhydrous (12027-67-7)

Potassium Hydroxide No No No No 1000 No No

Water to 100%

----------- Australia -----------
------ SARA 311/312 ------ Hazchem Poison This MSDS is
Ingredient Hazard Categories Code Schedule WHMIS Compliant
Ammonium Molybdate Acute: Yes Chronic: Yes Fire: No None None Allocated
(12027-67-7) Pressure: No Reactivity: No Allocated
(Pure/Solid)

Potassium Hydroxide Acute: Yes Chronic: Yes Fire: No 2R S6
Pressure: No Reactivity: Yes
(Pure/Solid)
Water to 100%

Acute: Yes Chronic: Yes Fire: No None None Allocated Yes
For #V-4467 liquid
Pressure: No Reactivity: No Allocated
mixture, as a whole
(Mixture/Liquid)



16. Other Information

Prepared By: IP
Revised: 6/13/2005




3
MSDS
Material Safety Data Sheet
PO Box 329 鈥? 802 Washington Avenue 鈥? Chestertown, MD 21620 鈥? USA
Telephone Number For Information 410-778-3100
24 Hour Emergency Number (CHEM-TEL) : USA, Canada, Puerto Rico 800-255-3924;
Outside North American continent: 813-248-0585 (call collect)

1. Product Identification Manufactured By: LaMotte Company
V-6284 802 Washington Avenue
Product Code:
Silica Reagent #4
Product Description: Chestertown, MD 21620

2. Composition/Information on Ingredients

Hazardous Name CAS # % OSHA ACGIH
PEL TLV
Yes D(-)-Isoascorbic Acid; D-Araboascorbic 89-65-6 10 N/E N/E
acid

No Sucrose 57-50-1 90 15 mg/cubic m 10 mg/cubic m
(total dust) (total dust)

3. Hazards Overview
Primary Route of Entry: Inhalation
Dust may irritate eyes, skin, respiratory tract.

HMIS Hazard: (Scale: 4 = Extreme, 3 = High, 2 = Moderate, 1 = Slight, 0 = Least)
Health: 1 Flammability: 1 Reactivity: 0

Carcinogenicity: None

Other Health Related Comments: See Section 11.

4. First Aid Measures
Flush with water for 15 minutes.
Eye Contact:
Rinse skin. Wash with soap and water.
Skin Contact:
Rinse out mouth. Drink plenty of water. Consult a physician if symptoms develop.
Ingestion:
Remove to fresh air.
Inhalation:


5. Fire Fighting Measures

Flash Point: N/A LEL: N/A UEL: N/A
Fire Rating
Extinguishing Media: Water spray
Special Fire Fighting Procedures: Firefighters wear self-contained breathing apparatus
Hazardous Combustion and/or Decomposition Products: COx
Unusual Fire & Explosion Hazard: Fine dust dispersed in air in sufficient concentrations, and in the presence
of an ignition source is a potential dust explosion hazard. Emits toxic fumes under fire conditions. Contact with
chemically active metals(Al, Zn, Mg, Cu) can generate flammable hydrogen gas.


1
Product Code: V-6284 Product Description: Silica Reagent #4

6. Accidental Release Measures
Avoid raising dust. Sweep up, dissolve in water. Wash down drain with excess water.

7. Handling & Storage
Store tight closed in cool, dry, ventilated area, away from incompatibles.

8. Exposure Controls/Personal Protection

Ventilation
Use with adequate ventilation.

Protection When Handling
Gloves Eye Protection Lab Coat

Avoid skin contact and inhalation of powder. Wash after handling.
Work/Hygienic Practices:

9. Physical & Chemical Properties

Appearance: White Powder Boiling Point: N/A
Melting Point: 165-185C decomposes
pH: 2-3 (0.1g/10mL water)
Odor: None Vapor Density: N/A
Solubility in Water: Soluble Vapor Pressure: N/A

10. Stability & Reactivity
Yes
Stable:
Conditions to Avoid: Heat, flame, ignition sources, moisture and incompatibles.
Materials to Avoid: strong oxidizers, bases, sulfuric and nitric acids, chemically active metals
(aluminum, copper, magnesium, zinc)

Hazardous Decomposition Products: COx, irritating fumes.

11. Toxicological Information
Oral rat LD50: 29700 mg/kg for sucrose. Investigated as a mutagen, reproductive effector.
D-Araboascorbic Acid investigated as a mutagen.
In normal and recommended use product #V-6284 is non-toxic.
Target Organs: N/A

12. Ecological Information
Information not Available

13. Disposal Considerations
Dissolve in water. Wash down drain with excess water. Dispose according to federal, state and local regulations.

14. Transport Information
Not regulated for transport

2
Product Code: V-6284 Product Description: Silica Reagent #4

15. Regulatory Information
Chemical Inventory Status
USA Europe ---Canada--- Australia Japan
Ingredient TSCA EC DSL NDSL
D(-)-Isoascorbic Acid Yes Yes Yes No Yes Yes

Sucrose Yes Yes Yes No Yes No



Federal, State, & International Regulations
---SARA 302--- - -------- SARA 313 --------- RCRA TSCA
Ingredient RQ TPQ Listed Chemical Category CERCLA 261.33 8(D)
D(-)-Isoascorbic Acid No No No No No No No

Sucrose No No No No No No No

----------- Australia -----------
------ SARA 311/312 ------ Hazchem Poison This MSDS is
Ingredient Hazard Categories Code Schedule WHMIS Compliant
D(-)-Isoascorbic Acid Acute: Yes Chronic: No Fire: No None None Allocated
Pressure: No Reactivity: No Allocated
(Pure/Solid)

Sucrose Acute: No Chronic: No Fire: Yes None None Allocated
Pressure: No Reactivity: No Allocated
(Pure/Solid)

Acute: No Chronic: No Fire: Yes None None Allocated Yes
For product #V-6284
Pressure: No Reactivity: No Allocated
mixture, as a whole



16. Other Information

Prepared By: IP

Revised: 6/16/2005




3

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