Material Safety Data Sheet
Page 1 of 6 Issue date: September 2004
M-BOND CURING AGENT 600/610
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Davidson Measurement Pty. Ltd
ACN: 005 031 961 ABN: 29 005 031 961
Phone: 03 9580 4366
Fax: 03 9580 6499
Email: info@davidson.com.au
Web: www.davidson.com.au
Address: 1-3 Lakewood Boulevard,
Braeside, Victoria, 3195.
Product Name: M -BOND CURING AGENT 600/610
Manufacturer's Product Code: MGM013J
Use: Curing agent for M-Bond 600/610 epoxy resins.
2. HAZARDS IDENTIFICATION
Classified as hazardous according to the EU criteria
Hazard Category: Harmful (Xn), Irritant (Xi), Flammable (F)
Hazard Classification: HAZARDOUS SUBSTANCE, DANGEROUS GOODS.
RISK PHRASES
R11 Highly flammable
R36 Irritating to eyes.
R42 May cause sensitisation by inhalation.
R43 May cause sensitisation by skin contact.
SAFETY PHRASES
S2 Keep out of reach of children.
S16 Keep away from sources of ignition - No smoking.
S25 Avoid contact with eyes.
S29 Do not empty into drains.
S37/39 Wear suitable gloves and eye/face protection.
Poison Schedule: None allocated [Aust]
Warning Statement:
Highly flammable liquid. May cause sensitation by skin contact and by inhalation leading to allergic reactions.
3. COMPOSITION / INFORMATION ON INGREDIENTS
SUBSTANCE NAME Proportion CAS Number
TETRAHYDROFURAN > 80 % 109-99-9
PYROMELLITIC DIANHYDRIDE 1 to < 10 % 89-32-7
PYROMELLITIC ACID 1 to < 5 % 89-05-4
All other ingredients determined not to be hazardous according to the EU criteria.
4. FIRST AID MEASURES
Swallowed:
If swallowed, DO NOT induce vomiting. If conscious, give 1 to 2 glasses of water to drink. Seek immediate medical
assistance.
Eye:
If material is splashed into eyes, immediately, flush with plenty of water for 15 minutes, ensuring eye lids are held
open. If irritation persists transport to hospital or doctor.
Material Safety Data Sheet
Page 2 of 6 Issue date: September 2004
M-BOND CURING AGENT 600/610
4. FIRST AID MEASURES (Continued)
Skin:
If material is splashed onto the skin, remove any contaminated clothing and wash skin thoroughly with soap and water.
If irritation persists transport to hospital or doctor.
Inhaled:
Move victim to fresh air. Apply resuscitation if victim is not breathing.
First Aid Facilities:
Eye wash fountain, safety shower and normal wash room facilities.
Advice to Doctor:
Treat symptomatically.
In case of poisoning, contact Poisons Information Centre
In Australia call Tel: 131126
In New Zealand Tel: 034747000
5. FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA: Use dry chemical, carbon dioxide or foam.
HAZARDS FROM COMBUSTION PRODUCTS: On combustion or on thermal decomposition (pyrolysis), there
will be a release of oxides of carbon and noxious smoke.
PRECAUTIONS FOR FIRE FIGHTERS AND SPECIAL PROTECTIVE EQUIPMENT: Self-contained
breathing apparatus (SCBA) required for fire -fighting personnel. If possible to do so safely, shut off fuel to fire. Use
water spray to spray to cool fire-exposed surfaces and to protect personnel.
Hazchem Code: 3[Y]E [Aust]
Flammability:
This material is a HIGHLY FLAMMABLE liquid.
Flash Point: -14掳C
Flammability Limits (vol / vol %): Lower: 1.8 Upper: 11.8
6. ACCIDENTAL RELEASE MEASURES
Emergency Procedures:
Highly flammable liquid. Avoid all sources of ignition. Keep unnecessary people away; Isolate hazard area and deny
entry. Ventilate area. Wear suitable protective equipment as outlined under personal protection in this MSDS.
Methods and Materials for Containment and Clean Up Procedures:
Throw vermiculite or diatomaceous earth onto spill. DO NOT use sawdust. Use non-sparking tools or HEPA vacuum
system to pick up. Place into labelled drum(s) for later disposal.
Emergency information(Transport):
Dangerous Goods - Initial Emergency Response Guide (IERG) (SAA/SNZ HB76:1997)
For LIQUIDS - Highly flammable, Guide No: 14
7. HANDLING AND STORAGE
Precautions for Safe Handling:
Highly flammable liquid. Avoid ignition sources. Do not get in eyes. Avoid direct or prolonged contact with skin.
Provide adequate ventilation.
Conditions for Safe Storage:
Keep containers tightly closed, when not using the product. Store in original packages as approved by manufacturer.
Store in an area that is dry and well-ventilation away from ignition sources. Store below 278 C. The floor of the depot
should be impermeable. Store away from strong alkalis, acids and oxidizing agents. For further information please refer
to the Engineering Controls of this MSDS.
Material Safety Data Sheet
Page 3 of 6 Issue date: September 2004
M-BOND CURING AGENT 600/610
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Standards
No exposure standards are available for this product, however, the following exposure standards have been assigned by
[NOHSC] to the following component of the product:
TETRAHYDROFURAN
[NOHSC]
[TWA]100 ppm 295 mg/m3
Notices: A
PYROMELLITIC ACID
(Unknown Source)
3
[TWA] 0.25 mg/m
Engineering Controls
Highly flammable liquid. Maintain adequate ventilation at all times. Prevent accumulation of vapours in hollows or
sumps. Eliminate any sources of ignition. Elevated temperature or mechanical action may form vapours, mists or fumes
which may require local exhaust ventilation systems.
Personal Protection Equipment
GLOVES: The use of neoprene gloves is recommended.
EYES : Chemical goggles or spectacles to protect eyes.
RESPIRATORY PROTECTION: Avoid breathing of vapours. Select and use respirators in accordance with AS/NZS
1715/1716. When vapours exceed the exposure standards then the use of a half-face respirator fitted with an organic
vapour cartridge is recommended. For high concentration use an atmosphere-supplied, positive pressure demand self-
contained or airline breathing apparatus, complying with the requirements of AS/NZS 1715 is recommended. Filter
capacity and respirator type depends on exposure levels and type of contaminant.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Colorless to amber coloured liquid with ether-like odour.
Boiling Point: 66掳C
Vapour Pressure: 145 mmHg @ 15掳C
Specific Gravity: 0.90
Flash Point: - 14掳C
Flammability Limits: LEL: 1.8 % UEL: 11.8 %
Solubility in Water: Complete.
Other Properties
Vapor Density (Air = 1): 2.5
Evaporation Rate (BuAc = 1): 14.5
Volatile Organic Compounds : 705 g/L
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY:
Stable under normal conditions of use.
CONDITIONS TO AVOID:
Heat, flames, ignition sources, light and air.
HAZARDOUS DECOMPOSITION PRODUCTS:
Emits oxides of carbon when heated to decomposition.
Material Safety Data Sheet
Page 4 of 6 Issue date: September 2004
M-BOND CURING AGENT 600/610
10. STABILITY AND REACTIVITY (Continued)
INCOMPATIBLE MATERIALS:
Strong oxidizing agents, strong bases, strong reducing agents.
HAZARDOUS REACTIONS:
Will not occur.
11. TOXICOLOGICAL INFORMATION
ACUTE HEALTH EFFECTS
Swallowed:
May cause gastrointestinal irritation, which may lead to nausea, vomiting and diarrhoea.
Eye:
Will cause irritation to the eyes, with effects including: tearing, pain, stinging and blurred vision. Depending upon
duration of exposure, eye damage may occur.
Skin:
Harmful by skin contact. Will cause irritation to the skin, with effects including; Redness, itchiness, and possible
drying/defatting. There is some evidence to suggest that a component of this product will cause sensitisation by skin
contact, which could lead to allergic contact dermatitis.
Inhaled:
Harmful if inhaled. Will cause irritation to the respiratory system with effects including: Dizziness, headache,
coughing, loss of co-ordination and chest pains. This product will cause allergic reactions, such as asthama in some
susceptible individuals.
Chronic:
Prolonged or repeated skin contact may lead to dermatitis. Prolonged contact may cause permanent eye damage.
Prolonged or repeated exposure or deliberately concentrating and inhaling the vapour may result in lung function
incapacity or death.
TETRAHYDROFURAN:
Oral LD50(rat): > 2,000 mg/kg
Inhalation LC50(rat): 21,000 ppm/3H
PYROMELLITIC DIANHYDRIDE:
Oral LD50(rat): 2,250 mg/kg
12. ECOLOGICAL INFORMATION
No information is available for this product, however, large quantities should not be discharged to waterways, sewers or
drains.
13. DISPOSAL CONSIDERATIONS
Refer to appropriate authority in your State. Dispose of material through a licensed waste contractor. Advise flammable
nature.
Material Safety Data Sheet
Page 5 of 6 Issue date: September 2004
M-BOND CURING AGENT 600/610
14. TRANSPORT INFORMATION
Road Transport:
UN Number: 1993
Proper Shipping Name: FLAMMABLE LIQUID, N.O.S.(Contains TETRAHYDROFURAN)
Dangerous Goods Class: 3
Packing Group: II
Labels: Harmful (Xn), Irritant (Xi), Flammable (F)
Air Transport:
UN Number: 1993
Proper Shipping Name: FLAMMABLE LIQUID, N.O.S.(Contains TETRAHYDROFURAN)
Dangerous Goods Class: 3
Packing Group: II
Labels: Harmful (Xn), Irritant (Xi), Flammable (F)
Marine Transport:
UN Number: 1993
Proper Shipping Name: FLAMMABLE LIQUID, N.O.S.(Contains TETRAHYDROFURAN)
Dangerous Goods Class: 3
Packing Group: II
Labels: Harmful (Xn), Irritant (Xi), Flammable (F)
15. REGULATORY INFORMATION
Poison Schedule: None allocated [Aust]
Inventory Status:
Australia (AICS) Y
United States (TSCA) Y
Canada (DSL) Y
Europe (EINECS/ELINCS) Y
Japan (MITI) Y
South Korea (KECL) Y
Y = all ingredients are on the inventory.
16. OTHER INFORMATION
Date of Preparation:
Issue date: September 13, 2004 Supercedes: March 29, 2004 (update) and September 23, 2003
Reasons for Update:
nd
1. Alignment with the 2 Edition of National Code of Practice for the Preparation of Material Safety Data Sheets
[NOHSC:2001(2003)].
2. Changes and /or addition made to all sections.
Key Legend Information:
NOHSC - National Occupational Health & Safety Commission [Aust]
TWA - Time Weighted Average [Int]
STEL - Short Term Exposure Limit [Int]
AICS - Australian Inventory of Chemical Substances
EPA - Environmental Protection Agency [Int]
NIOSH - National Institute for Occupational Safety and Health [US]
AS/NZS 1715 - Selection, use and maintenance of respiratory protective devices. [Aust]
AS/NZS 1716 - Respiratory protective devices. [Aust]
IATA - International Aviation Transport Authority [Int]
Material Safety Data Sheet
Page 6 of 6 Issue date: September 2004
M-BOND CURING AGENT 600/610
16. OTHER INFORMATION (Continued)
ICAO - International Civil Aviation Organization
IMO - International Maritime Organisation. [Int]
IMDG - International Maritime Dangerous Goods
United Nations Recommendations for the Transport of Dangerous Goods and Globally Harmonized System for the
classification and labelling of Chemicals. [Int]
EU - European Union
[Aust/NZ] = Australian/New Zealand
[Int] = International
[US] = United States of America
Principal References:
Information supplied by manufacturer.
Disclaimer
To the best of our knowledge, the information provided above meets the requirements of European Union directives for
hazardous substances which have been tested as a whole. The data provided on this Material Safety Data Sheet is from
manufacturers of the original components. All animal test data has been obtained from the public domain, NO
ANIMAL TESTS have been conducted by Davidson Pty Ltd. Davidson Pty Ltd specifically disclaims any and all form
of liability and/or responsibility for the application of this product.
End of MSDS
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