MATERIAL SAFETY DATA SHEET
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAMES: Size Prod #
Green Light Wipe-Out Concentrate Pint 12316
Green Light Wipe-Out Concentrate Quart 12332
Green Light Wipe-Out Hose-End Concentrate (RTS) Quart 12632
GENERAL USE: Herbicide
EPA Reg. No. 869-123
PRODUCT DESCRIPTION: Clear liquid, phenolic odor.
MANUFACTURER'S NAME DATE PREPARED: March 4, 2002
Page 1 of 4
Green Light Company SUPERSEDES: New
ADDRESS (NUMBER, STREET, P.O. BOX) TELEPHONE NUMBER FOR INFORMATION
P.O. Box 17985 (210) 494-3481
(CITY, STATE AND ZIP CODE) COUNTRY EMERGENCY TELEPHONE NUMBER
Infotrac (800) 535-5053 Outside USA (352) 323-3500
San Antonio, TX 78217-0985 USA
DISTRIBUTOR'S NAME
Same
ADDRESS (NUMBER, STREET, P.O. BOX) TELEPHONE NUMBER FOR INFORMATION
(CITY, STATE AND ZIP CODE) COUNTRY EMERGENCY TELEPHONE NUMBER
SECTION 2 - HAZARDOUS INGREDIENTS
OSHA PEL ACGIH TWA
% SARA RQ
HAZARDOUS COMPONENTS CAS # TITLE III LBS
MG/M3 MG/M3
(by weight) PPM PPM
Trimec 878 Herbicide Concentrate EPA Reg. No. 2217-571
Contains Dimethylamine salt of following:
6.89
2,4-Dichlorophenoxyacetic acid 94-75-7 10 10
2-(2-Methyl-4-chlorophenoxy) propionic acid 93-65-2 6.89 not established
3,6-Dichloro-0-anisic acid (a) 1918-00-9 0.84 not established
Dimethylamine (b,c,d,e) 124-40-3 8.52 10 5 1000
(a,c) See Section 15
(a) Indicates this product is not listed on the Canadian DSL or NDSL.
(b) Indicates that the Resource Conservation and Recovery Act (RCRA) has determined the waste for this chemical is listed as hazardous and must be handled
according to regulations in 40 CFR 260-281.
(d) OSHA proposed a regulation (29 CFR 1910.119) to monitor and control safety at certain types of industrial facilities. Compliance is triggered by specified
quantities of specific chemicals. Minimum threshold quantity for this Highly Hazardous Chemical is 2500 lbs.
(e) Indicates listing in Table Z - 2, 29 CFR 1910.1000, value shown is 8-hour Time Weighted Average. See table for acceptable ceiling concentration limits and
acceptable maximum peak above the acceptable ceiling concentration.
SECTION 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Avoid breathing mist and/or vapor. May cause eye and skin irritation. Do not get in eyes or on skin. Wash thoroughly after handling. Wear
goggles or face shield, rubber gloves, and protective clothing when handling. Hazard symbols - Xn. Risk phrase - R28
POTENTIAL HEALTH EFFECTS
INHALATION: Inhalation of mists or vapors may cause irritation to upper respiratory tract and mucous membranes. Prolonged inhalation of this
product may cause irritation to the lungs.
SKIN: Prolonged contact with skin may cause irritation, dermatitis.
EYES: Contact with eyes may cause pain and irritation. Repeated contact with eyes may cause conjunctival irritation.
INGESTION: This substance is slightly toxic to internal organs if swallowed. Signs and symptoms may include, but may not be limited to,
headache, dizziness, weakness, nausea, vomiting, diarrhea and abdominal cramps.
CARCINOGENICITY No No No
NTP? IARC MONOGRAPHS? OSHA REGULATED?
MATERIAL SAFETY DATA SHEET
PRODUCT NAMES: Green Light Wipe-Out Concentrate
Page 2 of 4
March 4, 2002
SECTION 4 - FIRST AID MEASURES
INHALATION: Remove affected person to fresh air; wash mouth and nasal passages with water repeatedly; if breathing difficulties persist seek
medical attention.
SKIN: Wash contacted area with soap and water; DO NOT attempt to neutralize with chemical agents; if irritation persists, seek medical
attention.
EYES: Remove contact lenses. Immediately flush eyes for 15 minutes in clear running water while holding eyelids open; seek medical attention
immediately.
INGESTION: If swallowed, call a physician of Poison Control Center immediately. Drink 1 or 2 glasses of water and induce vomiting by touching
the back of throat with a finger. Do not give anything by mouth to an unconscious or convulsing person.
SECTION 5 - FIRE FIGHTING MEASURES
FLAMMABLE LIMITS LEL: Not applicable UEL: Not applicable
FLASH POINT (METHOD USED)
AUTOIGNITION TEMPERATURE: Not determined NFPA CLASS:
Non-flammable None
GENERAL HAZARDS: Product is not considered flammable or combustible. Products of combustion include compounds of carbon, hydrogen
and oxygen, including carbon monoxide.
EXTINGUISHING MEDIA
Carbon dioxide, or dry chemical. Avoid using water or chemical foam to prevent spreading of material.
FIRE FIGHTING PROCEDURES
Keep containers cool with water spray to prevent container rupture due to steam buildup.
UNUSUAL FIRE AND EXPLOSION HAZARDS
None
HAZARDOUS COMBUSTION PRODUCTS
Smoke, toxic fumes, oxides of carbon
SECTION 6 - ENVIRONMENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Small spills - wash to sanitary sewer with plenty of water.. Large
spills - confine spill, soak up with approved absorbent, shovel product into approved container for disposal. For spills in excess of allowable
limits (RQ) notify the National Response Center (800) 424 - 8802; refer to CERCLA 40 CFR 302 for complete regulations concerning reporting
requirements.
SECTION 7 - HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Keep container closed when not in use; protect containers from abuse;
protect from extreme temperatures. Keep this and other chemicals out of reach of children.
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
ENGINEERING CONTROLS
The use of local exhaust ventilation is recommended. No other special controls are indicated.
PERSONAL PROTECTION:
RESPIRATORY PROTECTION (SPECIFY TYPE): None required while threshold limits are kept below maximum allowable concentrations; if
TWA exceeds standard workplace limits, NIOSH approved respirator must be worn. Refer to 29 CFR 1910.134 or European Standard EN 149
for complete regulations.
PROTECTIVE GLOVES: Neoprene or rubber gloves with cuffs.
EYE PROTECTION: Goggles with side shields; safety eyebath nearby. Refer to 29 CFR 1910.133 or European Standard EN166.
OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Coveralls, apron, or other equipment should be worn to minimize skin contact.
WORK / HYGIENIC PRACTICES: Practice safe workplace habits. Minimize body contact with this, as well as all chemicals in general.
MATERIAL SAFETY DATA SHEET
PRODUCT NAMES: Green Light Wipe-Out Concentrate
Page 3 of 4
March 4, 2002
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
VAPOR PRESSURE (MM Hg) VAPOR DENSITY (AIR = 1)
17 mm Hg @ 20 掳 C Not determined
SPECIFIC GRAVITY (WATER = 1) EVAPORATION RATE (WATER = 1)
1.024 Not determined
SOLUBILITY IN WATER FREEZING POINT
Complete 32掳 F (0掳 C)
pH APPEARANCE AND ODOR
7.0 Clear liquid, phenolic odor
BOILING POINT PHYSICAL STATE
226掳 F (108掳 C) Liquid
VISCOSITY VOLATILE ORGANIC COMPOUNDS (Total VOC's)
Not determined None
SECTION 10 - STABILITY AND REACTIVITY
CONDITIONS TO AVOID: Extreme temperatures
STABILITY UNSTABLE:
STABLE: XXX
INCOMPATIBILITY (MATERIALS TO AVOID): Strong oxidizers, strong acids
HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Decomposition will not occur if handled and stored properly. In case of a fire, oxides of
carbon, hydrocarbons, fumes, and smoke may be produced.
CONDITIONS TO AVOID: None
HAZARDOUS POLYMERIZATION MAY OCCUR:
WILL NOT OCCUR: XXX
SECTION 11 - TOXICOLOGICAL INFORMATION
LD50 of Ingredient LC50 of Ingredient
Hazardous Ingredients % CAS # (Specify Species and Route) (Specify Species)
Trimec 878 Herbicide Concentrate EPA Reg. No. > 8000 not established
2217-571 Oral - rat
Contains Dimethylamine salt of following:
not established not established
2,4-Dichlorophenoxyacetic acid 1.98 94-75-7
not established not established
2-(2-Methyl-4-chlorophenoxy) propionic acid 6.89 93-65-2
not established not established
3,6-Dichloro-0-anisic acid (a) 0.84 1918-00-9
698 mg / kg 4540 ppm / 6H
Dimethylamine (b,c,d,e) 8.52 124-40-3
Oral - rat Inhalation - rat
SECTION 12 - ECOLOGICAL INFORMATION
Do not feed treated foliage to livestock or graze treated areas. Do not spray or allow to drift onto vegetables, ornamentals or other desirable
plants. Do not apply when weather conditions favor drift from target area. Do not apply directly to water. Do not contaminate water by cleaning
of equipment or disposal of wastes.
SECTION 13 - DISPOSAL CONSIDERATIONS
WASTE DISPOSAL METHOD: Dispose of in accordance with Local, State, and Federal Regulations. This product should not be discharged
into soil, lakes, ponds, streams or public waters. Product is classified as non - hazardous, however, non-hazardous materials may become
hazardous waste upon contact with other products. Refer to "40 CFR Protection of Environment Parts 260 - 299" for complete waste disposal
regulations. Consult your local, state, or Federal Environmental Protection Agency before disposing of any chemicals.
SECTION 14 - TRANSPORT INFORMATION
PROPER SHIPPING NAME: Not Regulated
DOT HAZARD CLASS / Pack Group: Not regulated IATA HAZARD CLASS / Pack Group: Not regulated
REFERENCE: Not Applicable IMDG HAZARD CLASS: Not regulated
UN / NA IDENTIFICATION NUMBER: None RID/ADR Dangerous Goods Code: Not regulated
LABEL: None Required UN TDG Class / Pack Group: Not regulated
HAZARD SYMBOLS: None
Note: Transportation information provided is for reference only. Client is urged to consult CFR 49 parts 100 - 177, IMDG, IATA, EC, United
Nations TDG, and WHMIS (Canada) TDG information manuals for detailed regulations and exceptions covering specific container sizes,
packaging materials and methods of shipping.
MATERIAL SAFETY DATA SHEET
PRODUCT NAMES: Green Light Wipe-Out Concentrate
Page 4 of 4
March 4, 2002
SECTION 15 - REGULATORY INFORMATION
TSCA (Toxic Substance Control Act)
Components of this product are listed on the TSCA Inventory.
SARA TITLE III (Superfund Amendments and Reauthorization Act)
311/312 Hazard Categories
Health, acute, chronic
313 Reportable Ingredients:
None
CERCLA (Comprehensive Response Compensation and Liability Act)
(c) The Comprehensive Environmental Response, Compensation, and Liability Act (CERCLA) has notification requirements for releases or
spills to the environment of the Reportable Quantity (RQ for this mixture = 12,000 lbs) or greater amounts, according to 40 CFR 302.
EPA (Environmental Protection Agency)
Use of this product is regulated by the U.S. Environmental Protection Agency (EPA) through the approved label copy. It is a violation of
Federal law to use this product in a manner inconsistent with its labeling.
CPR (Canadian Controlled Products Regulations)
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all the
information required by the Controlled Products Regulations
IDL (Canadian Ingredient Disclosure List)
Components of this product identified by CAS number and listed on the Canadian Ingredient Disclosure List are shown in Section 2.
DSL / NDSL (Canadian Domestic Substances List / Non-Domestic Substances List)
3,6-Dichloro-0-anisic acid (1918-00-9) is not listed on the DSL or NDSL. All other components of this product identified by CAS number are
listed on the DSL or NDSL. Only ingredients classified as "hazardous" are listed in Section 2 unless otherwise indicated.
EINECS (European Inventory of Existing Commercial Chemical Substances)
Components of this product identified by CAS numbers are on the European Inventory of Existing Commercial Chemical Substances.
EC Risk Phrases EC Safety Phrases
R28 Very toxic if swallowed. S2 Keep out of the reach of children.
S24 Avoid contact with skin.
S25 Avoid contact with eyes.
SECTION 16 - OTHER INFORMATION
No specific notes
HEALTH 0 = INSIGNIFICANT 3 = HIGH
HMIS HAZARD RATINGS 1
FLAMMABILITY 1 = SLIGHT 4 = EXTREME
0
REACTIVITY 2 = MODERATE
0
PERSONAL PROTECTIVE EQUIPMENT Safety Glasses, Gloves, Apron
C
REVISION SUMMARY:
This MSDS has been revised in the following No revisions available
sections:
MSDS Prepared by: Comprehensive Data Base, Inc.
P.O. Box 5604
Lakeland, FL 33807 USA
(863) 644 - 3298 www.compdatabase.com
The information contained herein is believed to be accurate but is not warranted to be so. Data and calculations are based on information furnished by the
manufacturer of the product and manufacturers of the components of the product. Users are advised to confirm in advance of need that information is current,
applicable and suited to the circumstances of use. Vendor assumes no responsibility for injury to vendee or third persons proximately caused by the material if
reasonable safety procedures are not adhered to as stipulated in the data sheet. Furthermore, vendor assumes no responsibility for injury caused by abnormal use
of this material even if reasonable safety procedures are followed. Any questions regarding this product should be directed to the manufacturer of the product as
described in Section 1.
|