MATERIAL SAFETY DATA SHEET
Section 1. Chemical product and company identification
Product Name: Halotron I
Synonym: Clean Agent
Manufacturer: H3R Performance, Inc.
Internet Address: www.h3rperformance.com
Address: 483 Magnolia Ave.
Larkspur, CA 94939
Telephone: (415) 945-0800
Emergency Contacts: Chemtrec 1(800) 424-9300 or
(703) 527-3887
Revised: January, 2004
Section 2. Hazard identification and emergency overview
Emergency overview: Colorless highly volatile liquid with a slightly sweet, ether-like odor.
Adverse health effects and symptoms: Central nervous system (CNS) depression at 0.5% in air,
heartbeat irregularities above 2% concentration in air 鈥? may be fatal. Also an eye irritant, with effects
from prolonged skin exposure including defatting and frostbite.
Exposure guidelines:
Ingredients OSHA PEL ACGIH TLV DFG MAK * OTHER LIMITS
2,2-dichloro-1,1,1-trifluoroethane NR** NR NR AIHA WEEL*** 50 ppm TWA
Proprietary ingredients NR NR NR NA
*German regulatory limits ** NR = Not Regulated *** American Industrial Hygiene Association (AIHA) Workplace
Environmental Exposure Level (WEEL). All values are 8 hour time weighted average concentrations.
Hazard symbols: WHMIS (Canadian workplace hazardous materials identification system)
Compressed gas
High concentration may cause asphyxiation
May produce irritating fumes
Use dilution ventilation in confined areas
Section 3. Composition/information on ingredients
Name/Compound Weight % CAS #
2,2-dichloro-1,1,1-trifluoroethane (HCFC-123) > 93 306-83-2
Proprietary gas mixture <7 Not available
Section 4. First Aid Measures
Eye Exposure: irrigate eyes at eye wash station and repeat for 15 minutes or until pain free. Seek
medical attention if irritation develops or persists, or if visual changes occur.
Skin Exposure: in case of repeated contact, wash with plenty of soap and water. Use a skin
moisturizer. Seek medical attention if irritation develops or persists.
Inhalation: If respiratory irritation or distress occurs remove victim to fresh air. Give artificial
respiration if breathing stops. Give oxygen under qualified personnel. DO NOT give epinephrine.
Seek medical attention if irritation develops or persists.
Ingestion: do not induce vomiting, or give stimulants. Seek immediate medical attention. Do not
leave victim unattended. To prevent aspiration of swallowed product, lay victim on side with head
lower than waist. If vomiting occurs and the victim is conscious, give water to further dilute the
chemical.
Medical conditions possibly aggravated by exposure: inhalation of product may aggravate existing
chronic respiratory problems such as asthma, emphysema, or bronchitis. Skin contact may
aggravate existing skin disease.
Section 5. Fire fighting measures
Extinguishing media: at normal pressure and temperature this product is non combustible and non
flammable 鈥? product is an extinguishing agent.
Unusual fire/explosion hazards: In the heat of fire this product may decompose, releasing
hydrochloric acid, and hydrofluoric acid (see Section 10).
Insensitive to mechanical impact or static discharge.
HMIS (hazardous materials identification system) rankings: health: 1, fire: 0, reactivity: 1, personal
protective equipment (B): appropriate respirator above exposure limit, and eye protection (see
Section 8).
Section 6. Accidental release measures
o
Upon release of large amounts of product into confined areas that would exceed 2% at 120 F,
evacuate and ventilate. Product will produce large volumes of heavier than air vapor. Responders
need SCBA or SAR level of respiratory protection (see Section 8). Large spills (cylinders of 250 lbs.
or more) should be addressed by hazardous materials technicians following a site-specific emergency
response plan and trained in the appropriate use of PPE. Prevent material from entering surface or
ground water. Keep containers away from heat sources that might cause rupture since these
containers are under pressure. Dike spill area, then use sorbents or pump product directly into
drums. Handle and dispose of as a hazardous waste unless testing indicates otherwise. Clean spill
area with wet vac, decontaminate with detergent and water. If product is used and/or contaminated,
use PPE and containment appropriate to the nature of the mixture.
Section 7. Handling and storage
Avoid skin, eye, or respiratory exposure. Use appropriate exposure controls (proper ventilation, etc.)
when maintaining extinguisher, and wash thoroughly after handling (see Section 8). Keep product in
original container or extinguisher. Contents are under pressure 鈥? inspect for extinguisher rust
periodically to insure container integrity. Do not mix with other extinguishing agents.
Section 8. Exposure controls/ personal protection
Respiratory protection: for extended periods of exposure (over 30 minutes), use air-purifying
respirator (APR) or powered air-purifying respirator (PAPR) with organic vapor cartridges or canisters
at concentrations above 50 ppm. For levels above 2000 ppm use supplied air respirator (SAR) or
SCBA.
Eye protection: wear chemical goggles whenever the potential for eye exposure exists.
Skin protection: if product is expected to contact skin, use neoprene, PVC, or PVA gloves and
coveralls, both to avoid contact and frostbite. Good personal hygiene practices essential, such as
avoiding food, tobacco products, or other hand-to-mouth contact when handling. Wash thoroughly
after handling.
Section 9. Physical and chemical properties
o
Appearance: colorless liquid under 81 F with a slightly sweet, ether-like odor.
Specific gravity: ~ 1.48 (liquid)
Vapor density: 5.3
o
Solubility: 0.39% by weight @ 25 C
Non 鈥揻lammable
Flash point: none
Vapor pressure: liquid : ~580 mm Hg (11.2 psig) bulk tank pressure 95 psig
pH: neutral
o
Boiling point: 81 F
No explosive or oxidizing properties
Section 10. Stability and reactivity
Stability: stable
Incompatibles: oxidizers, powdered or abraded aluminum will cause a reaction generating heat, also
reacts with alkali and alkaline earth metals.
Decomposition products: heat of fire may release hydrochloric acid, hydrofluoric acid, and carbonyl
halides.
Possibility of hazardous reactions: none
Section 11. Toxicological information
Acute toxicity: 2,2-dichloro-1,1,1-trifluoroethane
LC 鈥? 4 hour (rat): 3.2% in air,
50
Approximate lethal dose, oral (human): 9 g/kg body weight,
Cardiac sensitization threshold (dog): ~2.1% in air,
LOAEL (lowest observed adverse effect level): 2% in air.
Target organs in man: heart (acute), liver (chronic). This product is an irritant to
the eyes, and causes defatting of the skin that can lead to contact dermatitis.
Chronic toxicity: A three week study of 6 hours/day, 7 days/week exposure to guinea pigs, dogs, and
monkeys via inhalation of 1000 ppm induced mild liver damage with altered
enzyme levels. A two year study of 6 hours/day and 5 days/week exposure: 300
ppm, inhalation (rat): benign testicular and liver tumor formation; 1000 ppm:
benign pancreatic tumor formation, also weight loss, retinal atrophy, increased
urinary fluoride levels. This product鈥檚 ingredients are not considered as
鈥減robable鈥? or 鈥渟uspected鈥? carcinogens by OSHA, IARC, or ACGIH.
Reproductive toxicity: Two generation inhalation reproductive study on rats showed no negative
effects other than weight loss. Teratology testing was negative on rats and
rabbits @ 5,000 and 10,000 ppm.
Section 12. Ecological information
Ecotoxicity: negative effects on vegetation, Daphnia Magna LC = 17.3 mg/L
50
Rainbow Trout LC = 55.5 mg/L Green Algae LC = 96.6 mg/L
50 50
Octanol water partition coefficient (est): Log P = 2.0 鈥? 2.8
OW
Persistence/Degradability: degrades very slowly
Bioaccummulation: extent unknown
Mobility in soil: unknown
Section 13. Disposal considerations
This product is not a RCRA characteristically hazardous or listed hazardous waste. Dispose of
according to state or local laws, which may be more restrictive than federal laws or regulations.
Used product may be altered or contaminated, creating different disposal considerations.
Section 14. Transportation information
DOT shipping name: Compressed Gases, N.O.S. (contains tetrafluoromethane, argon)
DOT Class/Division: 2.2 IMCO Class: 2.2 DOT Shipping Label: Nonflammable Gas
This product is classified as a hazardous material by Transport Canada鈥檚 Transportation of
Dangerous Goods regulations.
Section 15. Regulatory information
International Inventory Status:
All ingredients are on the following inventories
Country(ies) Agency Status
United States of America TSCA Yes
Canada DSL Yes
Europe EINECS/ELINCS Yes
South Korea KECL Yes
European Risk and Safety phrases:
EU Classification: Harmful.
R Phrases: 20/21/22 Harmful if inhaled, by skin contact, or swallowed.
36 Irritating to eyes
59 Dangerous to the ozone layer
67 Vapors may cause drowsiness and dizziness
S Phrases: 3 Keep in a cool place
23/24/25 Avoid inhalation, skin, and eye contact
26 In case of contact with eyes, rinse immediately with plenty of water and seek
medical advice.
36 Wear suitable protective clothing.
38 Where ventilation is insufficient, wear suitable respiratory equipment .
U.S. federal regulatory information:
2,2-dichloro-1,1,1-trifluoroethane is under SARA reporting requirements under EPCRA Section 313
(40 CFR Part 372). This product is subject to the inventory update rule under TSCA 8(a). This
product has no ingredients with SARA threshold planning quantities (TPQs) or CERCLA reportable
quantities (RQs).
State regulatory information:
Chemicals in this product are covered under specific State regulations, as denoted below:
Alaska - Designated Toxic and Hazardous Substances: None
California 鈥? Permissible Exposure Limits for Chemical Contaminants: None
Florida 鈥? Substance List: None
Illinois 鈥? Toxic Substance List: None
Kansas 鈥? Section 302/303 List: None
Massachusetts 鈥? Substance List: None
Minnesota 鈥? List of Hazardous Substances: None
Missouri 鈥? Employer Information/Toxic Substance List: None
New Jersey 鈥? Right to Know Hazardous Substance List: None
North Dakota 鈥? List of Hazardous Chemicals, Reportable Quantities: None
Pennsylvania 鈥? Hazardous Substance List: None
Rhode Island 鈥? Hazardous Substance List: None
Texas 鈥? Hazardous Substance List: No
West Virginia 鈥? Hazardous Substance List: None
Wisconsin 鈥? Toxic and Hazardous Substances: None
California Proposition 65: No component is listed on the California Proposition 65 lists.
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Section 16. Other information
This MSDS conforms to requirements under U.S., U.K., Canadian, Australian, and EU regulations or
standards, and conforms to the proposed 2003 ANSI Z400.1 format.
The information herein is given in good faith but no warranty, expressed or implied, is made.
The information herein is given in good faith but no warranty, expressed or implied, is made. Updated
by Lindsay R. Hill, CIH
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