HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCX 049 RedOx Puffer/ORB buffer solution 460 mV
Print date : 03.05.2008 Product code : LCX049-1 Page 1 of 5
1. Identification of the substance/preparation and of the company/undertaking
Identification of the substance or preparation
LCX 049 RedOx Puffer/ORB buffer solution 460 mV
Use of the substance/preparation
Water analysis
Company/undertaking identification
HACH LANGE GmbH
Company name :
Willst盲tterstr. 11
Street :
Place : D-40549 D眉sseldorf
+49 (0)211 5288-383
Telephone :
marion.ives@hach-lange.de
e-mail :
www.hach-lange.com
Internet :
Inquiry office : HACH LANGE Ltd.
Pacific Way
Salford Manchester M50 1DL - United Kingdom
Tel. +44 (0) 161 872 1487
e-Mail: martin.butterfield@hach-lange.co.uk
HACH LANGE Ltd.
Unit 1, Chestnut Road Western Industrial Estate
Dublin 12 - Ireland
Tel. +353 (0)1 4602522
e-Mail: joseph.diver@hach-lange.ie
2. Hazards identification
Classification
The product does not need to be labelled in accordance with EC directives or respective national
laws.
3. Composition/information on ingredients
Chemical characterization ( preparation )
Hazardous components
CAS-No. Chemical name Quantity Classification
EC-No.
231-791-2 7732-18-5 Water 90-99 %
231-595-7 hydrochloric acid ... % 1-5 % C, Xi R34-37
Full text of each relevant R phrase can be found in heading 16.
4. First aid measures
General information
Take off all contaminated clothing immediately.
After inhalation
Move to fresh air.
After contact with skin
Wash off immediately with soap and plenty of water.
Revision no. : 1.00 GB - EN Revision date : 27.08.2007
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCX 049 RedOx Puffer/ORB buffer solution 460 mV
Print date : 03.05.2008 Product code : LCX049-1 Page 2 of 5
After contact with eyes
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Consult a
physician.
After ingestion
If conscious, drink plenty of water.
Advice to doctor
Treat symptomatically.
5. Fire-fighting measures
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment.
Special exposure hazards arising from substance or preparation itself, combustion products, resulting
gases
Fire may liberate hazardous vapours.
Special protective equipment for fire-fighters
In the case of respirable dust and/or fumes, use self-contained breathing apparatus and dust
impervious protective suit.
Additional information
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local
regulations.
6. Accidental release measures
Personal precautions
Use personal protective equipment.
Environmental precautions
Do not flush into surface water or sanitary sewer system.
Methods for cleaning up/taking up
Sweep up or vacuum up spillage and collect in suitable container for disposal.
7. Handling and storage
Handling
Advice on safe handling
Avoid contact with skin and eyes.
Storage
Requirements for storage rooms and vessels
Keep container tightly closed in a dry and well-ventilated place.
8. Exposure controls/personal protection
Exposure limit values
Exposure limits (EH40)
CAS-No. Chemical name ml/m鲁 mg/m鲁 F/ml Category Origin
7647-01-0 Hydrogen chloride (gas and aerosol mists) 1 2 TWA (8 h) WEL
5 8 STEL (15 min) WEL
Exposure controls
Revision no. : 1.00 GB - EN Revision date : 27.08.2007
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCX 049 RedOx Puffer/ORB buffer solution 460 mV
Print date : 03.05.2008 Product code : LCX049-1 Page 3 of 5
Protective and hygiene measures
The type of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Hand protection
Use barrier skin cream. Wash hands before breaks and at the end of workday. The selected
protective gloves have to satisfy the specifications of EU Directive 89/689/EEC and the standard EN
374 derived from it.
Eye protection
Safety glasses with side-shields
9. Physical and chemical properties
General information
liquid
Physical state :
colourless
Colour :
odourless
Odour :
Important health, safety and environmental information
Test method
approx. 2
pH-Value (at 20 掳C) :
Changes in the physical state
Explosive properties
not applicable
Oxidizing properties
not applicable
Density (at 20 掳C) : 1 g/cm鲁
soluble
Water solubility :
(at 20 掳C)
10. Stability and reactivity
Conditions to avoid
Stable under recommended storage conditions.
Hazardous decomposition products
No dangerous reaction known under conditions of normal use.
11. Toxicological information
Acute toxicity
No data is available on the product itself.
12. Ecological information
Ecotoxicity
No data is available on the product itself.
13. Disposal considerations
Advice on disposal
In accordance with local and national regulations.
Revision no. : 1.00 GB - EN Revision date : 27.08.2007
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCX 049 RedOx Puffer/ORB buffer solution 460 mV
Print date : 03.05.2008 Product code : LCX049-1 Page 4 of 5
Waste disposal number of waste from residues/unused products
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including
mixtures of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of used product
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including
mixtures of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of contaminated packaging
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including
mixtures of laboratory chemicals
Classified as hazardous waste.
14. Transport information
Land transport (ADR/RID)
3316
UN number :
9
ADR/RID class :
Warning plate
9
Hazard label :
ADR/RID packing group : II
Description of the goods
Chemical kit
Inland waterways transport
Other applicable information (inland waterways transport)
Not tested
Marine transport
3316
UN number :
9
IMDG code :
--
Marine pollutant :
II
IMDG packing group :
Description of the goods
Chemical kit
Air transport
3316
UN/ID number :
9
ICAO/IATA-DGR :
II
ICAO packing group :
Description of the goods
Chemical kit
15. Regulatory information
Labelling
Additional advice on labelling
Classification according to European directive on classification of hazardous preparations
1999/45/EC.
EU regulatory information
Revision no. : 1.00 GB - EN Revision date : 27.08.2007
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCX 049 RedOx Puffer/ORB buffer solution 460 mV
Print date : 03.05.2008 Product code : LCX049-1 Page 5 of 5
Additional information
The product does not need to be labelled in accordance with EC directives or respective national
laws.
National regulatory information
Water contaminating class (D) : 1 - slightly water contaminating
16. Other information
Full text of R-phrases referred to under sections 2 and 3
34 Causes burns.
37 Irritating to respiratory system.
Further Information
The information is based on present level of our knowledge. It does not, however, give assurances of
product properties and establishes no contract legal rights.
(The data for the hazardous ingredients were taken respectively from the last version of the sub-contractor's
safety data sheet.)
Revision no. : 1.00 GB - EN Revision date : 27.08.2007
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCX 049 RedOx Puffer Chinhydron/ORB buffer Quinhydrone 460 mV
Print date : 03.05.2008 Product code : LCX049-2 Page 1 of 5
1. Identification of the substance/preparation and of the company/undertaking
Identification of the substance or preparation
LCX 049 RedOx Puffer Chinhydron/ORB buffer Quinhydrone 460 mV
Use of the substance/preparation
Water analysis
Company/undertaking identification
HACH LANGE GmbH
Company name :
Willst盲tterstr. 11
Street :
Place : D-40549 D眉sseldorf
+49 (0)211 5288-383
Telephone :
marion.ives@hach-lange.de
e-mail :
www.hach-lange.com
Internet :
Inquiry office : HACH LANGE Ltd.
Pacific Way
Salford Manchester M50 1DL - United Kingdom
Tel. +44 (0) 161 872 1487
e-Mail: martin.butterfield@hach-lange.co.uk
HACH LANGE Ltd.
Unit 1, Chestnut Road Western Industrial Estate
Dublin 12 - Ireland
Tel. +353 (0)1 4602522
e-Mail: joseph.diver@hach-lange.ie
2. Hazards identification
Classification
Indications of danger : Harmful, Dangerous for the environment
R-phrases :
Harmful if swallowed.
Very toxic to aquatic organisms.
3. Composition/information on ingredients
Chemical characterization ( substance )
Hazardous components
CAS-No. Chemical name Quantity Classification
EC-No.
203-387-6 106-34-3 Quinhydrone 100 % Xn, N R22-50
Full text of each relevant R phrase can be found in heading 16.
4. First aid measures
General information
Take off all contaminated clothing immediately.
After inhalation
Move to fresh air.
After contact with skin
Wash off immediately with soap and plenty of water.
Revision no. : 1.00 GB - EN Revision date : 27.08.2007
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCX 049 RedOx Puffer Chinhydron/ORB buffer Quinhydrone 460 mV
Print date : 03.05.2008 Product code : LCX049-2 Page 2 of 5
After contact with eyes
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Consult a
physician.
After ingestion
If conscious, drink plenty of water.
Advice to doctor
Treat symptomatically.
5. Fire-fighting measures
Suitable extinguishing media
Use extinguishing measures that are appropriate to local circumstances and the surrounding
environment.
Special exposure hazards arising from substance or preparation itself, combustion products, resulting
gases
Fire may liberate hazardous vapours.
Special protective equipment for fire-fighters
In the case of respirable dust and/or fumes, use self-contained breathing apparatus and dust
impervious protective suit.
Additional information
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local
regulations.
6. Accidental release measures
Personal precautions
Use personal protective equipment.
Environmental precautions
Do not flush into surface water or sanitary sewer system.
Methods for cleaning up/taking up
Sweep up or vacuum up spillage and collect in suitable container for disposal.
7. Handling and storage
Handling
Advice on safe handling
Avoid contact with skin and eyes.
Storage
Requirements for storage rooms and vessels
Keep container tightly closed in a dry and well-ventilated place.
8. Exposure controls/personal protection
Exposure limit values
Exposure controls
Protective and hygiene measures
The type of protective equipment must be selected according to the concentration and amount of the
dangerous substance at the specific workplace.
Respiratory protection
Breathing apparatus only if aerosol or dust is formed.
Revision no. : 1.00 GB - EN Revision date : 27.08.2007
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCX 049 RedOx Puffer Chinhydron/ORB buffer Quinhydrone 460 mV
Print date : 03.05.2008 Product code : LCX049-2 Page 3 of 5
Hand protection
Use barrier skin cream. Wash hands before breaks and at the end of workday. The selected
protective gloves have to satisfy the specifications of EU Directive 89/689/EEC and the standard EN
374 derived from it.
Eye protection
Safety glasses with side-shields
9. Physical and chemical properties
General information
solid
Physical state :
dark green
Colour :
characteristic
Odour :
Important health, safety and environmental information
Test method
no data available
pH-Value :
Changes in the physical state
Explosive properties
not applicable
Oxidizing properties
not applicable
Density (at 20 掳C) : 1,4 g/cm鲁
Water solubility : 4 g/L
(at 20 掳C)
10. Stability and reactivity
Conditions to avoid
To avoid thermal decomposition, do not overheat.
Sensitive to air.
Materials to avoid
strong oxidizing agents
Hazardous decomposition products
No dangerous reaction known under conditions of normal use.
Additional information
Stable under recommended storage conditions.
11. Toxicological information
Acute toxicity
LD50/oral/rat = 225 mg/kg (RTECS)
Corrosive and irritant effects
The product causes irritation of eyes, skin and mucous membranes.
12. Ecological information
Ecotoxicity
Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
13. Disposal considerations
Revision no. : 1.00 GB - EN Revision date : 27.08.2007
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCX 049 RedOx Puffer Chinhydron/ORB buffer Quinhydrone 460 mV
Print date : 03.05.2008 Product code : LCX049-2 Page 4 of 5
Advice on disposal
In accordance with local and national regulations.
Waste disposal number of waste from residues/unused products
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including
mixtures of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of used product
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including
mixtures of laboratory chemicals
Classified as hazardous waste.
Waste disposal number of contaminated packaging
160506 WASTES NOT OTHERWISE SPECIFIED IN THE LIST; gases in pressure containers and discarded
chemicals; laboratory chemicals, consisting of or containing dangerous substances, including
mixtures of laboratory chemicals
Classified as hazardous waste.
14. Transport information
Land transport (ADR/RID)
3316
UN number :
9
ADR/RID class :
Warning plate
9
Hazard label :
ADR/RID packing group : II
Description of the goods
Chemical kit
Inland waterways transport
Other applicable information (inland waterways transport)
Not tested
Marine transport
3316
UN number :
9
IMDG code :
--
Marine pollutant :
II
IMDG packing group :
Description of the goods
Chemical kit
Air transport
3316
UN/ID number :
9
ICAO/IATA-DGR :
II
ICAO packing group :
Description of the goods
Chemical kit
Further Information
These transport data apply to the entire pack
15. Regulatory information
Labelling
Revision no. : 1.00 GB - EN Revision date : 27.08.2007
HACH LANGE GmbH
Safety Data Sheet
according to Regulation (EU) No. 1907/2006
LCX 049 RedOx Puffer Chinhydron/ORB buffer Quinhydrone 460 mV
Print date : 03.05.2008 Product code : LCX049-2 Page 5 of 5
Xn - Harmful; N - Dangerous for the environment
Danger symbols :
Xn - Harmful N - Dangerous for the
environment
Hazardous component(s) to be indicated on label
Quinhydrone
R phrases
22 Harmful if swallowed.
50 Very toxic to aquatic organisms.
S phrases
61 Avoid release to the environment. Refer to special instructions / Safety data sheets.
24/25 Avoid contact with skin and eyes.
Additional advice on labelling
Classification according to European directive on classification of hazardous preparations
1999/45/EC.
National regulatory information
Employment restrictions : Observe employment restrictions for young people. Observe employment
restrictions for child bearing mothers and nursing.
Water contaminating class (D) : 2 - water contaminating
16. Other information
Full text of R-phrases referred to under sections 2 and 3
22 Harmful if swallowed.
50 Very toxic to aquatic organisms.
Further Information
The information is based on present level of our knowledge. It does not, however, give assurances of
product properties and establishes no contract legal rights.
Revision no. : 1.00 GB - EN Revision date : 27.08.2007
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