Material Safety Data Sheet Page 1 of 4
R
HAZTECH
NFPA HMIS PPE (See Section 15)
SYSTEMS,
3 Health Hazard 2
INC. TM
20 Fire Hazard 3
Reactivity 0
Section 1. Chemical Product and Company Identification
Cobalt Test
Trade Name Part # RE2029
CAS # 67-56-1 / 540-72-7
Haztech Systems, Inc.
Manufacturer
RTECS PC1400000 / XL2275000
PO Box 929
Mariposa, CA 95338 TSCA TSCA 8(b) inventory:
methyl alcohol
Commercial Name sodium thiocyanate
Synonyms CI #
In case of emergency contact CHEMTREC
Chemcal Family (24 hours) at 800-424-9300
HazTech Systems, Inc. 800-543-5487
CH3OH, NaCNS
Chemical Formula
Spectrum Chemical Mfg. Corp. 310-516-8000
Spectrum Chemical Mfg. Corp.
Supplier
14422 S. San Pedro St.
Gardena, CA 90248
Section 2. Composition and Information on Ingredients
Exposure Limits
Name CAS # TWA (mg/m3) STEL CEIL (mg/m3) % by Weight
Methyl alcohol 67-56-1 260 325 79%
Sodium thiocyanate 540-72-7 21%
Toxicological Methyl alcohol: Sodium thiocyanate :
Data on ORAL (LD50): Acute: 5628 mg/kg (Rat.). ORAL (LD50): Acute: 764 mg/kg (Rat). 362 mg/kg (Mouse).
Ingredients DERMAL (LD50): Acute: 15800 mg/kg (Rabbit.).
Section 3. Hazards Identification
Very hazardous in case of ingestion. Hazardous in case of skin contact (irritant), of eye contact (irritant), of
Potential Acute
inhalation. Slightly hazardous in case of skin contact (permeator). Severe over-exposure can result in death.
Health Effects
CARCINOGENIC EFFECTS: Classified 4 (No evidence.) by NTP, None. by OSHA.
Potential Chronic
MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Classified POSSIBLE for human.
Health Effects
DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female, Development toxin [POSSIBLE].
The substance is toxic to the nervous system, gastrointestinal tract, eyes.
The substance may be toxic to blood, kidneys, lungs, the reproductive system, liver, heart, brain, cardiovascular
system, skin, central nervous system (CNS), pancreas.
Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure to a highly
toxic material may produce general deterioration of health by an accumulation in one or many human organs.
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漏2002 Haztech Systems, Inc., PO Box 929, Mariposa, CA 95338 (800) 5ID-KITS FAX (209) 966-8089 www.hazcat.com
Cobalt Test Page 2 of 4
Section 4. First Aid Mearsures
Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes,
Eye Contact
keeping eyelids open. Cold water may be used. Get medical attention.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing contaminated
Skin Contact
clothing and shoes. Cover the irritated skin with an emollient. Cold water may be used.Wash clothing before
reuse. Thoroughly clean shoes before reuse. Get medical attention immediately.
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get
Inhalation
medical attention immediately.
If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by
Ingestion
mouth to an unconscious person. Loosen tight clothing such as a collar, tie, belt or waistband. Get medical
attention immediately.
Section 5. Fire and Explosion Data
Flammability Flammable. (methanol)
Auto-Ignition Temperature 464藲C (867.2藲F) (methanol)
Flash Point CLOSED CUP: 12藲C (53.6藲F). OPEN CUP: 16藲C (60.8藲F). (methanol)
Flammable Limits LOWER: 6% UPPER: 36.5% (methanol)
Products of Combustion These products are carbon oxides (CO, CO2). Some metallic oxides.
Fire Hazards in Presence Highly flammable in presence of open flames and sparks, of heat, of combustible materials.
of Various Substances
Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available.
of Various Substances Risks of explosion of the product in presence of static discharge: Not available.
Fire Fighting Media Flammable liquid, soluble or dispersed in water.
and Instructions SMALL FIRE: Use DRY chemical powder.
Special Remarks on Fire Hazards CAUTION: MAY BURN WITH NEAR INVISIBLE FLAME. Explosive when mixed with
Choroform + sodium methoxide and diethyl zinc. It boils violently and explodes.
Section 6. Accidental Release Measures
Dilute with water and mop up, or absorb with an inert dry material and place in an appropriate waste disposal container.
Small Spill
Section 7. Handling and Storage
Keep away from sources of accidental ignition. Do not ingest. Do not breathe gas/fumes/ vapor/spray. If ingested, seek
Precautions
medical advice immediately and show the container or the label. Avoid contact with skin and eyes.
Storage Keep in HazCat Kit.
Section 8. Exposure Controls/Personal Protection
Engineering Controls Use in a well ventilated area.
Personal Protection Gloves and goggles.
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漏2002 Haztech Systems, Inc., PO Box 929, Mariposa, CA 95338 (800) 5ID-KITS FAX (209) 966-8089 www.hazcat.com
Page 3 of 4
Cobalt Test
Section 9. Physical and Chemical Properties
Physical State and Appearance Clear liquid Volatility Not available.
Molecular Weight Not available Odor Threshold Not available
pH (1% Solution in Water) Not available Water/Oil Dist. Coeff. Not available.
Boiling Point 64.5藲C (148.1藲F) (methanol) Ionicity (in Water) Not available
Melting Point Not available Dispersion Properties See solubility in water, methanol.
Critical Temperature Not available Solubility Easily soluble in water, methanol.
Specific Gravity Not available Odor Alcohol like.
Vapor Pressure Not available Taste Not available.
Vapor Density Not available Color Colorless.
Section 10. Stability and Reactivity Data
Stability Product is stable. Corrosivity Non-corrosive in
presence of glass.
Instability Temperature Not available. Special Remarks Not available.
on Corrosivity
Conditions of Instability Not available.
Polymerization Will not polymerize.
Incompatability with Highly reactive with oxidizing agents.
Various Substances Reactive with metals.
Special Remarks on Violent reaction with alkyl aluminum salts, acetyl bromide, chloroform + sodium methoxide, chromic
Reactivity anhydride, cyanuirc chlorite, lead perchlorate, phosphorous trioxide, nitric acid. Exothermic reaction
with sodium hydroxide + chloroform. Incompatible with beryllium dihydride, metals (potassium and
magnesium), oxidants (barium perchlorate, bromine, sodium hypochlorite, chlorine, hydrogen
peroxide), potassium tert-butoxide, carbon tetrachloride, metals (aluminum, magnesium, zinc), and
dichlormethane. May attack some plastics, rubber, and coatings.
Section 11. Toxicological Information
Route of Entry Absorbed through skin. Eye contact. Inhalation. Ingestion. Methanol: Acute
Toxicity to Animals oral toxicity (LD50): 5628 mg/kg (Rat.). Acute dermal toxicity (LD50):
15800 mg/kg (Rabbit.). Acute toxicity of the vapor (LC50): 64000 4 hours (Rat.).
Sodium thiocyanate: Acute oral toxicity (LD50): 362 mg/kg (Mouse).
Very hazardous in case of ingestion, of inhalation. Slightly hazardous in case of skin
contact (irritant).
Chroinc Effects on Humans CARCINOGENIC EFFECTS: Classified 4 (No evidence.) by NTP, None.
by OSHA. TERATOGENIC EFFECTS: Classified POSSIBLE for human.
DEVELOPMENTAL TOXICITY: Classified Reproductive system/toxin/female,
Development toxin [POSSIBLE].
Causes damage to the following organs: the nervous system, gastrointestinal
tract, eyes. May cause damage to the following organs: blood, kidneys, lungs,
the reproductive system, liver, heart, brain, cardiovascular system, skin, central
nervous system (CNS), pancreas. Causes damage to the following organs:
lungs, mucous membranes.
Other Toxic Effects on Humans Very hazardous in case of ingestion. Hazardous in case of skin contact (irritant),
of ingestion, of inhalation. Slightly hazardous in case of skin contact (permeator).
Special Remarks on Toxicity to Animals Not available.
Special Remarks on Chronic Effects on Humans Not available.
Special Remarks on Other Toxic Effects on Humans Not available.
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Cobalt Test Page 4 of 4
Section 12. Ecological Information
Ecotoxicity Not available.
BOD5 and COD Not available.
Products of Biodegradation Possibly hazardous short term degradation products are not likely. However,
long term degradation products mayarise.
Toxicity of the Products of Biodegradation The products of degradation are more toxic.
Special Remarks on the Products of Biodegradation Not available.
Section 13. Disposal Considerations
Waste Disposal Recycle to process, if possible. Consult your local or regional authorities.
Section 14. Transport Information
DOT Classification CLASS 3: Flammable liquid.
Identification Methanol, 3, UN1230, II
Special Provisions Not available.
for Transport
Section 15. Other Regulatory Information and Pictograms
Federal and State Regulations Rhode Island RTK hazardous substances: Methyl alcohol
Pennsylvania RTK: Methyl alcohol
Minnesota: Methyl alcohol
Massachusetts RTK: Methyl alcohol
New Jersey: Methyl alcohol
California Directors List of Hazardous Substances (8CCR 339): Methyl alcohol
Tennesse Hazardous Right to Know : Methyl alcohol
TSCA 8(b) inventory: Methyl alcohol
SARA 313 toxic chemical notification and release reporting: Methyl alcohol
CERCLA: Hazardous substances.: Methyl alcohol: 5000 lbs. (2268 kg)
TSCA 8(b) inventory: Sodium thiocyanate
California Proposition 65 Warnings
Other Regulation OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
Other classifications WHMIS (Canada) CLASS B-2: Flammable liquid with a flash point lower than 37.8藲C (100藲F).
CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC).
CLASS D-2A: Material causing other toxic effects (VERY TOXIC).
CLASS D-1B: Material causing immediate and serious toxic effects (TOXIC).
DSCL (EEC) R11- Highly flammable. R23/24/25- Toxic by inhalation, in contact with skin
and if swallowed. R22- Harmful if swallowed. R36/38- Irritating to eyes and skin.
Section 16. Other Information
Part Number(s) RE2029
References Not available.
Other Special Considerations Not available.
Validated by R. Houghton 10/9/02
Verified by R. Turkington
Call 1-800-543-5487
Notice to Reader
All chemicals may pose unknown hazards and should be used with caution. This Material Safety Data Sheet (MSDS) applies only to the material as packaged. If this product is
combined with other materials, deteriorates, or becomes contaminated, it may pose hazards not mentioned in this MSDS. It shall be the user's responsibility to develop proper methods
of handling and personal protection based on the actual conditions of use. While this MSDS is based on technical data judged to be reliable, Haztech Systems, Inc. assumes no
responsibility for the completeness or accuracy of the information contained herein.
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漏2002 Haztech Systems, Inc., PO Box 929, Mariposa, CA 95338 (800) 5ID-KITS FAX (209) 966-8089 www.hazcat.com
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