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FLEXSYS
Material Safety Data Sheet
Last Revision: 04/27/2007
Printing Date: 05/03/2007
1. CHE DCOMPANYIDENTIFICATION
Product Name: PERKACIT@ TETD
FLXP0023
MSDS NO.
Chemical Name: Tetraethylthiuram Disulfide
Disulfide, bis(diethylthiocarbamoyl); Thioperoxydicarbonic diamide, tetraethyl-; Ethyl
Synonyms:
Thiuram; Antabuse
Use: Accelerator.
Manufactured By: Flexsys America L.P. 260 Springside Drive Akron OH 44333-2433 USA
Emergency Telephone: HEMTREC: 1-800-424~9300 [TOLLFREE - USA and Temtones]
703-527 ~3887 [ELSEWHERE - Collect Calls Accepted]
CANUTEC: 613-996~666 [Canada]
'-00~2141Mexico
Prepared By: Flexsys America Product Safety: Phone (330) 668-8281 FAX (330) 668-8345
E:mail sharen.b.breyer@flexsys.com
2. HAZARDS IDENTIFICATION
WARNING!Dust may be irritatingto eyes and upper respiratorytract. Finedust
Emergency Overview:
clouds may form explosive mixtures with air. Highly toxic to fish and aquatic
invertebrates. May cause sensitization by skin contact. May cause alcohol
intolerance.
Causes mild eye irritation. MildEye Irritation: signs/symptoms can include redness,
Eye Contact:
swelling, pain and tearing.
Skin Contact: May cause an allergic skin reaction. May be absorbed through the skin and product
effects similiar to those caused by inhalation and/or ingestion. May cause skin
defatting with prolonged exposure.
Inhalation: Exposure to dust particles generated from this material may cause irritation of the
respiratory tract. Inhalation may cause alcohol intolerance
Ingestion: May cause alcohol intolerance (Antabuse Effect). May cause headache, dizziness,
nausea, vomiting, gastrointestinal irritation.
NFORMATION ON INGREDIENTS
CAS-No
97-77-8
68439-50-9
4. FIRSTAIDMEASURES
In case of contact, immediately flush eyes with plenty of water for at least 15 minutes
In Eyes:
and get medical attention if irritation persists.
MARKETED BY
FLXP0023
HARWICK STANDARD
DISTRIBUTION CORPORATION
60 S. Seiberling Street. Akron, Ohio 44305
4. -PIRSTAID- MEA.SURES
On Skin: In case of contact, immediately flush skin with plenty of soap and water for at least 15
minutes. Get medical attention. Remove contaminated clothing and launder before
reuse. Get medical attention if irritation persists.
Inhaled: Remove person to fresh air. If not breathing, give artificial respiration. If breathing is
difficult, get immediate medical attention.
Swallowed: If swallowed, call a physician immediately. Only induce vomiting at the instruction of
a physician. Never give anything by mouth to an unconscious person.
Notes To Physician: Treat symptomatically. Exposure by ingestion, inhalation or skin absorbtion may
cause alcohol intolerance (Antabuse Effect).
5. ..FIRE FIGHTING MEASURES
Not Determined
Flash Point (OF/C):
Flash Point Method: Not Determined
240 - 280掳C
Autoignition Temp. (OF/C):
Lower Explosion Limit (LEL): 20 g/m3
Not Determined.
Upper Explosion Limit (UEL):
Extinguishing Media: Use water fog, carbon dioxide, foam or dry chemical.
Special Exposure Hazards: Fight fire from a safe distance and from a protected location. Use water spray to cool
fire exposed surfaces. Decomposition in fire may produce toxic gases. Do not allow
runoff to enter waterways.
Special Protective Equipment: Full protective clothing and approved self-contained breathing apparatus required for
fire fighting personnel.
Unusual Fire/Explosion Hazards: Toxic emissions may result if product is involved in a fire. Dust Class = ST 1.
Minimum Ignition Energy [MIE] = < 10 mJ. Kst = 150 bar.m/sec Rmax = 552 barfs
Pmax = 6.8 bar
6:-'ACcIDE.~rfACRELEASE-MEASURe-S
Spill Procedures: Wear protective equipment specified. Avoid the generation of dust. Sweep, vacuum,
or shovel and place into closable container for disposal.
Procedure for Isolate area and remove sources of friction, impact, heat, low level electrical current,
Cleaning/Absorption: and RF energy. Scoop up and remove solids. Do NOT spread spilled product with
water.
Not Applicable
CERCLA Reportable Quantity
(RQ):
7. AANOUNGANDSTORAGE
Handling: Avoid contact with eyes, skin and clothing. Avoid generating or breathing dust.
Wash thoroughly with soap and water after handling. Wash hands before eating,
drinking, chewing gum, using tobacco or using the toilet. Reclose containers of
unused product. Keep containers tightly closed when not in use. Do not reuse this
container.
Storage: Store closed containers in a cool, dry, well-ventilated area. Store away from strong
oxidizing materials. Avoid exposure to direct sunlight.
8. EXPOSURECONTROLS fPERS1:n
Eye Protection: Wear safety glasses or goggles to protect against exposure.
Skin Protection: Normal work coveralls. Launder contaminated clothing before reuse.
Gloves: Use gloves as a standard industrial handling procedure. Appropriate chemical
resistant gloves should be worn.
FLXP0023
_ _ ~E~CQNTR()LS.1IPERSONALPR()TECTION .. ..;
Respiratory Protection: Use in a well ventilated area. Use approved NIOSH respiratory protection if TLV
exceeded or if overexposure is likely. Appropriate respiratory protection shall be
worn when applied engineering controls are not adequate to protect against
inhalation exposure.
Ventilation: General; local exhaust ventilation as necessary to control any air contaminants to
within their exposure limits during the use of this product.
Airborne Exposure Limits: OSHA PEU8-Hr TWA: None Established. NIOSH REU8-Hr TWA: 2 mg/m3.
ACGIH TLV/8-HrTWA: 2 mg/m3.
9~~~PHYSlCA[- AND CHEMICAL PROPERTfES
Appearance: White to off-white powder or Granules.
Odor: SLIGHT AMINE
pH: Not Applicable
Specific Gravity: 1.31 @20掳C
Not Determined.
Density:
Bulk Density: 610-650 kg/m3 @20掳C
147掳F /64掳C
Melting Point (OF/C):
117掳C
Boiling Point (OF/C):
Vapor Pressure: Negligible @ 20掳C
Vapor Density (Air=1): Not Applicable.
% Volatile by Volume: <0.5% by weight
Solubility in Water: 0.02 g/100ml
Other Solubility: Soluble in: Benzene Carbon Disulfide Organic liquids, including fats and oils
Ethanol
Viscosity: Not Applicable.
Other Data: See Section 5 for Dust Explosion Data.
296.54
Molecular Weight:
Molecular Formula: C 10-H20-N2-S4
10._8
Chemical Stability: Stable when stored at room temperature in closed, original container. Stable under
normal conditions of handling, use and transportation.
WILL NOT OCCUR
Hazardous Polymerization:
Conditions to Avoid: Not determined.
Materials to Avoid: Avoid contact with acidic, basic or oxidizing agents.
Hazardous Decomposition Carbon monoxide. Oxides of nitrogen. Oxides of sulfur.
Products:
Additional Guidelines: Not Applicable
11.. TOXlCOIJOGICAL INFORMATION
4573 mg/kg
Acute Oral LD50 (mg/kg):
2050 mg/kg
Acute Dermal LD50 (mg/kg):
Not determined
Acute Inhalation LC50 (mg/l):
Target Organs / Principle Routes of Exposure: Dermal- skin. Inhalation.
Ingestion: May cause alcohol intolerance (Antabuse Effect). May cause headache, dizziness,
nausea, vomiting, gastrointestinal irritation.
Skin Contact: May cause an allergic skin reaction. May be absorbed through the skin and product
effects similiar to those caused by inhalation and/or ingestion. May cause skin
defatting with prolonged exposure.
Inhalation: Exposure to dust particles generated from this material may cause irritation of the
respiratory tract. Inhalation may cause alcohol intolerance
FLXP0023
' '".J1j0XICOLdGrc~N~ORMA,.ION
Eye Contact: Causes mild eye irritation. Mild Eye Irritation: signs/symptoms can include redness,
swelling, pain and tearing.
Aggravated Conditions: Alcohol consumption problems. IMPORTANT NOTE: Perkacit TETD and the
prescription alcohol aversion drug "Antabuse" are the same chemical.
Carcinogenicity Comment: This product, or one of its ingredients present at 0.1 % or more, is NOT listed as a
carcinogen or suspected carcinogen by NTP, IARC or OSHA. NOTE: May react with
nitrosating agents during rubber vulcanization to form nitrosamines. Some
nitrosamines are suspect human carcinogens.
Other Information: Ingestion of the product may result in vomiting.
Primary Irritation Effect: Practically non-irritating
Carcinogenicity: Negative in standard tests using bacteria and/or yeast cells.
None
Genotoxicity:
Reproductive/Developmental No evidence of teratogenicity in animal studies using rats, mice and/or hamsters.
Toxicity:
12. E
Acute Fish Toxicity: 96Hr LC50 Bluegill Sunfish: 0.07 mg/I 96Hr LC50 Guppy: 0.32 mgll
Acute Crustaceans Toxicity: 48Hr LC50 Daphnia Magna: 0.12 mgll
Acute Algae Toxicity: 96Hr EC50 Algae: 1.80 mgll
OctanollWater Coefficient: 3.88 log P
Chemical Fate Information: Not Determined.
Other Information: Not Applicable
13. -DISPOSAL CONSIDE
Disposal of Waste Method: This product, if disposed as received, is a non-hazardous waste. Bury in a licensed
landfill or burn in an approved incinerator according to federal, state, and local
regulations. Federal, state and local disposal laws and regulations will determine the
proper waste disposallrecycling/reclamation procedure. Disposal requirements are
dependent on the hazard classification and will vary by location and the type of
disposal selected.
Contaminated Packaging: If empty container retains product residues, all label precautions must be observed.
Transport with all closures in place. Return for reuse or dispose according to
national or local regulations. Do NOT reuse container. Dispose of container
according to national or local regulations.
DOT: UN 3077, EnvironmentallyHazardousSubstance, Solid, N.O.S., (Tetraethylthiuram
Disulfide), 9, III
None
DOTReportable Quantity (Ibs):
ICAO/IATA: See DOT
See DOT
IMDG:
No
Marine Pollutant:
See DOT
TDG (Canada):
Remarks: None
15. REG
Worldwide Inventory Status
Listed
USA (TSCA):
Listed
Canada (DSL):
Canada (NDSL): Not Applicable. Listed on the DSL.
FLXP0023
15. REGtlLATORYINFORMAT'ON
Listed
European Union (EINECS/ELlNCS):
Listed
Japan (ENCS):
Listed
Korea (ECL):
Listed
Australia (AICS):
Listed
New Zealand (NZ):
Listed
Phillipines (PICCS):
Listed.
China (CLECS):
US Regulatory Rules
SARA Section 302: Not Applicable / None
SARA 311/312 Hazard Catagories: Immediate Delayed
SARA 313 Chemical: Not Applicable / None
RCRA Status: Not a RCRA waste.
Other Regulations:
NONE
California Proposition 65:
Listed NJ Substance ID# 0811.
New Jersey Right-to-Know List:
Listed
Pennsylvania Right to Know List:
Florida Right to Know: Not Applicable.
Listed as "Disulfiram"
Minnesota Right to Know:
Listed
Massachusetts Right to Know Law:
FDA Status 21 CFR: Regulated for Use under the following sections of 21 CFR:
177.2600 Rubber Articles Intended for Repeated Use in
Food Contact. 175.105 Components of Adhesives.
IMPORTANT NOTE: FDA information applies to the -pdr
and -pdr-s product forms (no dedusting additive) ONLY.
Canadian Regulations
WHMIS Hazard Class: D2B TOXIC MATERIALS / Materials Causing Other Toxic
Effects
NPRI: Not Listed. [Canada]
16::--o-TAER INFORMA T'
Hazard Rating Systems:
HMISClassification: HEALTH 2, FLAMMABILITY 1, REACTIVITY 0
HEALTH 2, FLAMMABILITY 1, REACTIVITY 0
NFPA Rating:
The following has been revised New MSDS format. Transport information or classification has been
since the last issue of this MSDS: changed/corrected.
Additional Information: WHMIS Ingredient Disclosure List (Canada): WHMIS Concentration threshold = 1%.
This product has been classified and appears on the Mexico Hazard Identification
Guidance List.
Important Note: This information is fumished without warranty, expressed or implied, as to accuracy or completeness.
The information is obtained from various sources including the manufacturer and other third party sources. The
information may not be valid under all conditions nor if this material is used in combination with other materials or in any
process. Final determination of suitability of any material is the sole responsibility of the user.
***END OF MSDS***
FLXP0023
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