Page 1/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 01.02.2006 Reviewed on 01.02.2006
1 Identification of substance:
路 Product details: Reagent for water analysis
路 Product name: Vario Phosphate RGT F 10 ml
路 Catalog number: 00531559, 531550, 531553
路 Supplier:
Tintometer GmbH
Schleefstra脽e 8a-12
D - 44287 Dortmund phone: +49(0)231 94510-0
Made in Germany
路 Informing department: Department Laboratory
路 Emergency information:
Poison Center Berlin, Germany
phone: +49(0)30 19240
2 Composition/Data on components:
路 Chemical characterization
路 Description: Mixture of the substances listed below with harmless additions.
路 Dangerous components:
CAS: 5329-14-6 sulphamidic acid @ Xi; R 36/38-52/53 20-25%
G
EINECS: 226-218-8
EC Number: 016-026-00-0
路 Additional information For the wording of the listed risk phrases refer to section 16.
3 Hazards identification
路 Hazard designation:
@
G Xi Irritant
路 Information pertaining to particular dangers for man and environment
The product has to be labelled due to the calculation procedure of the "General Classification guideline for preparations of the
EU" in the latest valid version.
R 36/38 Irritating to eyes and skin.
路 Classification system
The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by
information furnished by supplier companies.
4 First aid measures
路 General information Instantly remove any clothing soiled by the product.
路 After inhalation Supply fresh air; consult doctor in case of symptoms.
路 After skin contact Instantly wash with water and soap and rinse thoroughly.
路 After eye contact
Rinse opened eye for several minutes under running water.
Seek medical treatment.
(Contd. on page 2)
GB
DR
Page 2/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 01.02.2006 Reviewed on 01.02.2006
Product name: Vario Phosphate RGT F 10 ml
(Contd. of page 1)
路 After swallowing
Rinse out mouth and then drink plenty of water.
Seek immediate medical advice.
路 Information for doctor
路 The following symptoms may occur:
after inhalation:
irritation
coughing
breathing difficulty
after swallowing:
gastric or intestinal trouble
sickness
vomiting
mucous membrane irritation
5 Fire fighting measures
路 Suitable extinguishing agents Use fire fighting measures that suit the environment.
路 Special hazards caused by the material, its products of combustion or resulting gases:
Formation of toxic gases is possible during heating or in case of fire.
Nitrogen oxides (NOx)
Sulphur oxides (SOx)
ammonia
路 Protective equipment: Wear self-contained breathing apparatus.
路 Additional information
Dispose of fire debris and contaminated fire fighting water in accordance with official regulations.
Collect contaminated fire fighting water separately. It must not enter drains.
Ambient fire may liberate hazardous vapours.
6 Accidental release measures
路 Person-related safety precautions:
Avoid causing dust.
Wear protective equipment. Keep unprotected persons away.
路 Measures for environmental protection: Do not allow product to reach sewage system or water bodies.
路 Measures for cleaning/collecting:
Dispose of contaminated material as waste according to item 13.
Collect mechanically.
Ensure adequate ventilation.
7 Handling and storage
路 Handling
路 Information for safe handling:
Thorough dedusting.
Ensure good ventilation/exhaustion at the workplace.
路 Information about protection against explosions and fires: The product is not flammable
路 Storage
路 Requirements to be met by storerooms and containers: Store in cool location.
路 Information about storage in one common storage facility:
Store away from water.
Store away from metals.
路 Further information about storage conditions:
Keep container tightly sealed.
Protect from heat and direct sunlight.
(Contd. on page 3)
GB
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Page 3/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 01.02.2006 Reviewed on 01.02.2006
Product name: Vario Phosphate RGT F 10 ml
(Contd. of page 2)
Store under dry conditions.
Protect from humidity and keep away from water.
Protect from the effects of light.
* 8 Exposure controls and personal protection
路 Additional information about design of technical systems: No further data; see item 7.
路 Components with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at the workplace.
路 Additional information: The lists that were valid during the compilation were used as basis.
路 Personal protective equipment
路 General protective and hygienic measures
Keep away from foodstuffs, beverages and food.
Take off immediately all contaminated clothing
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes and skin.
路 Breathing equipment: Use breathing protection against the effects of fumes/dust/aerosol.
路 Recommended filter device for short term use: Filter P2
路 Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
After use of gloves apply skin-cleaning agents and skin cosmetics.
路 Material of gloves
nitrile rubber, NBR
Recommended thickness of the material: 鈮? 0.11 mm
路 Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
Value for the permeation: Level 鈮? 6 (480 min)
路 Eye protection: Tightly sealed safety glasses.
路 Body protection: Protective work clothing.
9 Physical and chemical properties:
Powder
路 Form:
White
路 Colour:
Odourless
路 Odour:
路 Melting point/Melting range: Not determined
路 Boiling point/Boiling range: 1689掳C
Not applicable
路 Flash point:
Product is not explosive.
路 Danger of explosion:
2.373 g/cm鲁
路 Density at 20掳C
路 Solubility in / Miscibility with
Soluble
Water:
1.2
路 pH-value (30 g/l) at 20掳C:
路 Solvent content:
0.0 %
Organic solvents:
100.0 %
路 Solids content:
GB
(Contd. on page 4)
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 01.02.2006 Reviewed on 01.02.2006
Product name: Vario Phosphate RGT F 10 ml
(Contd. of page 3)
* 10 Stability and reactivity
路 Thermal decomposition / conditions to be avoided: To avoid thermal decomposition do not overheat.
路 Materials to be avoided:
alkalis
acids
metals
halogen compounds
nitrates
oxidizing agents
路 Dangerous reactions
Reacts with water
Corrosive action on metals
Forms hydrogen in aqueous solution with metals
Aqueous solution reacts acidic.
路 Dangerous products of decomposition: see chapter 5
11 Toxicological information
路 Acute toxicity: Quantitative data on the toxicity of the preparation are not available.
路 LD/LC50 values that are relevant for classification:
5329-14-6 sulphamidic acid
Oral LD50 3160 mg/kg (rat)
50-81-7 ascorbic acid
Oral LD50 11900 mg/kg (rat)
10043-35-3 boric acid, crude natural, containing not more than 85 per cent of H3BO3 calculated on the dry weight
Oral LD50 2660 mg/kg (rat)
Dermal LD50 > 2000 mg/kg (rat)
10102-40-6 sodium molybdate
Oral LD50 4233 mg/kg (rat)
Dermal LD50 > 2000 mg/kg (rat)
路 Primary irritant effect:
路 on the skin: Irritant to skin and mucous membranes.
路 on the eye: Strong irritant with the danger of severe eye injury.
路 Sensitization: No sensitizing effect known.
路 Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for
Preparations as issued in the latest version:
Irritant
The aerosol is corrosive to the eyes, the skin and the respiratory tract. Inhalation of sulfamic acid aerosols may cause lung
oedema.
12 Ecological information:
路 Information about elimination (persistence and degradability):
路 Other information: Quantitative data on the ecological effect of this product are not available.
路 Behaviour in environmental systems:
5329-14-6 sulphamidic acid
log P(o/w) -4.34 (.)
50-81-7 ascorbic acid
log P(o/w) -2.15 (.)
(Contd. on page 5)
GB
DR
Page 5/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 01.02.2006 Reviewed on 01.02.2006
Product name: Vario Phosphate RGT F 10 ml
(Contd. of page 4)
10043-35-3 boric acid, crude natural, containing not more than 85 per cent of H3BO3 calculated on the dry weight
log P(o/w) 0.76 (25掳C) (.)
路 Ecotoxical effects:
路 Acquatic toxicity:
5329-14-6 sulphamidic acid
LC50 70.3 mg/l/96h (Pimephales promelas)
50-81-7 ascorbic acid
LC50 33000 (Merck) mg/l/48h (Leuciscus idus)
1020 mg/l/96h (Onchorhynchus mykiss)
10043-35-3 boric acid, crude natural, containing not more than 85 per cent of H3BO3 calculated on the dry weight
EC50 133 mg/l/48h (Daphnia magna)
LC50 5600 mg/l/96h (Gambusia affinis)
10102-40-6 sodium molybdate
EC50 330 mg/l/48h (Daphnia magna)
LC50 7600 mg/l/96h (Onchorhynchus mykiss)
路 Remark:
Harmful effect due to pH shift.
Toxic for fish:
sulphates > 7 g/l
路 Algea toxicity: CAS-No. 10102-40-6: Selenastrum capricornutum IC50: > 100 mg/l/72 h
路 Bacterial toxicity:
sulphates toxic > 2.5 g/l
CAS-No. 10102-40-6: Pseudomonas putida EC10: 50 mg/l/18 h
路 General notes:
Water hazard class 1 (German Regulation) (Self-assessment acc. VwVwS Annex 4): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
Must not reach sewage water or drainage ditch undiluted or unneutralized.
Rinse off of bigger amounts into drains or the aquatic environment may lead to decreased pH-values. A low pH-value harms
aquatic organisms. In the dilution of the use-level the pH-value is considerably increased, so that after the use of the product the
aqueous waste, emptied into drains, is only low water-dangerous.
13 Disposal considerations
路 Product:
路 Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
路 European waste catalogue
16 05 06 laboratory chemicals, consisting of or containing dangerous substances, including mixtures of laboratory chemicals
路 Uncleaned packagings:
路 Recommendation: Disposal must be made according to official regulations.
路 Recommended cleaning agent: Water, if necessary with cleaning agent.
14 Transport information
路 Land transport ADR/RID (cross-border)
o
}
c
a
d
路 ADR/RID-GGVS/E Class: 8 (C2) Corrosive substances.
(Contd. on page 6)
GB
DR
Page 6/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 01.02.2006 Reviewed on 01.02.2006
Product name: Vario Phosphate RGT F 10 ml
(Contd. of page 5)
80
路 Kemler Number:
2967
路 UN-Number:
III
路 Packaging group:
8
路 Label
路 Maritime transport IMDG:
o
}
c
a
d
8
路 IMDG Class:
2967
路 UN Number:
8
路 Label
III
路 Packaging group:
F-A,S-B
路 EMS Number:
No
路 Marine pollutant:
SULPHAMIC ACID, mixture
路 Correct technical name:
路 Air transport ICAO-TI and IATA-DGR:
}
o
c
a
d
8
路 ICAO/IATA Class:
2967
路 UN/ID Number:
8
路 Label
III
路 Packaging group:
SULPHAMIC ACID, mixture
路 Correct technical name:
15 Regulatory information
路 Designation according to EC guidelines:
The product has been classified and labelled in accordance with EC Directives / Ordinance on Hazardous Materials (GefStoffV)
路 Code letter and hazard designation of product:
Xi Irritant
路 Risk phrases:
36/38 Irritating to eyes and skin.
路 Safety phrases:
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
37 Wear suitable gloves.
60 This material and its container must be disposed of as hazardous waste.
路 National regulations
路 Information about limitation of use: Employment restrictions concerning young persons must be observed.
16 Other information
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features
and shall not establish a legally valid contractual relationship.
路 Relevant R-phrases
36/38 Irritating to eyes and skin.
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
路 Department issuing data specification sheet: Technical Department
路 * Data compared to the previous version altered.
GB
DR
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