Creation Date: 03-07-07
Revision Date: 03-07-07
Version #: 02
SAFETY DATA SHEET
according to EC Directive 2001/58/EC
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE
COMPANY/UNDERTAKING
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1.1. Identification of the Method - Ketones 8260B
Substance or Preparation
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Mixture
CAS #
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N9331043
Item #
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1.2. Use of the
substance/preparation
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Methanol solution containing trace elements
Synonym(s)
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PerkinElmer N.V./S.A.
1.3.
Imperiastraat 8, Bus1
Company/undertaking
1930 Zaventem
identification
Belgium
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Fax (32) 0800 40858
Tel. (32) 0800 40859
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(32) 0800 40859
1.4 Emergency
CHEMTREC 1-703-527-3887
Telephone Number
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2. Composition / Information on Ingredients
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Ingredients CAS # Percent EU #
Acetone 918-00-3 < 0.01
2-Hexanone 591-78-6 < 0.01 209-731-1
T
R10, R62, R48/23, R67
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2-Butanone 78-93-3 < 0.01 201-159-0
Xi, F,
R11, R36, R66, R67
4-methyl-2-pentanone 108-10-1 < 0.01 203-550-1
Xi, Xn, F,
R11, R20, R36/37, R66
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Methanol 67-56-1 > 90 200-659-6
T, F,
R11, R23/24/25, R39/23/24/25
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Refer to Section 16 for the risk phrases.
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3. Hazards Identification
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T; Toxic: danger of very serious irreversible effects through inhalation, in
Hazard and Risk Codes
contact with skin and if swallowed.(R39/23/24/25), Possible risks of
irreversible effects.(R68)
Material ID 16938 Item # N9331043 Print Date: 03-07-07
Material Name METHOD - KETONES 8260B SDS UK
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4. First Aid Measures
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General advice
Immediate medical attention is required
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First Aid
Skin contact
Wash off immediately with soap and plenty of water removing all contaminated clothes and
shoes. Consult a physician.
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Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Consult a
physician.
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Inhalation
Move to fresh air. Oxygen or artificial respiration if needed.
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Ingestion
Rinse mouth. Never give anything by mouth to an unconscious person. Call a physician
immediately.
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5. Fire Fighting Measures
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Suitable extinguishing media
water spray.
carbon dioxide (CO2), dry powder or foam
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Specific hazards
In the event of fire toxic fumes may be formed.
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Special protective equipment for firefighters
Wear suitable protective equipment
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6. Accidental Release Measures
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Evacuation Procedures
Evacuate personnel to safe areas.
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Personal precautions
Remove all sources of ignition. Ensure adequate ventilation. Use personal protective equipment.
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Methods for cleaning up
Neutralise with dry-lime, sand, or soda ash Clean contaminated surface thoroughly. Keep in
suitable, closed containers for disposal.
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7. Handling and Storage
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7.1 Handling
Use only in area provided with appropriate exhaust ventilation. wear personal protective equipment
Keep away from heat and sources of ignition. Do not breathe vapours or spray mist. Avoid contact
with skin and eyes.
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7.2 Storage
Keep tightly closed. Keep away from heat. Keep in a dry, cool place.
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7.3 Specific Use(s)
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8. Exposure Controls / Personal Protection
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8.1 Exposure Limits Values
Not applicable
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8.2 Exposure Controls
Material ID 16938 Item # N9331043 Print Date: 03-07-07
Material Name METHOD - KETONES 8260B SDS UK
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8.2.1 Occupational Exposure Controls
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin,
eyes and clothing. Keep away from food and drink. Wash hands before breaks and immediately
after handling the product.
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8.2.1.1 Respiratory Protection
No personal respiratory protective equipment normally required.
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8.2.1.2 Hand Protection
solvent-resistant gloves
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8.2.1.3 Eye Protection
safety glasses with side-shields
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8.2.1.4 Skin Protection
Lab coat.
Remove and wash contaminated clothing before re-use. Discard contaminated shoes.
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8.2.2 Environmental Exposure Controls
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9. Physical & Chemical Properties
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9.1 General Information
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Colour
colorless
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Odour
slight
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Form
liquid
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9.2 Important health, safety and environmental information
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0 estimated
Specific Gravity
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0 % estimated
Volatile Organic
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9.3 Other Information
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10. STABILITY AND REACTIVITY
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10.1 Conditions to Avoid
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10.2 Materials to Avoid
acids; acid chlorides; acid anhydrides; alkali metals; reducing agents
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10.3 Hazardous Decomposition Products
carbon oxides
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11. Toxicological Information
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Acute toxicity
Irritating to eyes, respiratory system and skin.
Toxic by inhalation, in contact with skin and if swallowed.
Methyl Alcohol may be fatal or cause blindness if swallowed.
Cannot be made non-poisonous.
Ingestion may provoke the following symptoms:
nausea, headache, and vomiting
gastrointestinal disturbance, dizziness, weakness, and
Unconsciousness
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12. Ecological Information
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12.1 Ecotoxicity
Material ID 16938 Item # N9331043 Print Date: 03-07-07
Material Name METHOD - KETONES 8260B SDS UK
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12.2 Mobility
Not available
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12.3 Persistence and Degradability
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12.4. Bioaccumulative potential
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12.5 Other Adverse Effects
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13. Disposal Considerations
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Disposal Instructions
In accordance with local and national regulations.
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Waste from residues / unused products
In accordance with local and national regulations.
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14. TRANSPORT INFORMATION
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ADR
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ICAO
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IMDG
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IATA
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Other information
DOT regulated, small quantity provisions apply (see 49CFR173.4)
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15. Regulatory Information
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T
Toxic
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Toxic: danger of very serious irreversible effects through inhalation
Risks
in contact with skin and if swallowed.(R39/23/24/25)
Possible risks of irreversible effects.(R68)
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Do not breathe spray.(S23)
Safety
Avoid contact with skin and eyes.(S24/25)
Do not empty into drains.(S29)
Wear suitable protective clothing and gloves.(S36/37)
This material and its container must be disposed of as hazardous
waste.(S60)
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16. Other information
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R39/23/24/25 Toxic: danger of very serious irreversible effects through
Material Risk Phrase(s)
inhalation, in contact with skin and if swallowed.
R68 Possible risks of irreversible effects.
Material ID 16938 Item # N9331043 Print Date: 03-07-07
Material Name METHOD - KETONES 8260B SDS UK
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2-Butanone
Ingredient Risk Phrase(s)
- R11 Highly flammable.
- R36 Irritating to eyes.
- R66 Repeated exposure may cause skin dryness or cracking.
- R67 Vapours may cause drowsiness and dizziness.
2-Hexanone
- R10 Flammable.
- R48/23 Toxic: danger of serious damage to health by prolonged
exposure through inhalation.
- R62 Possible risk of impaired fertility.
- R67 Vapours may cause drowsiness and dizziness.
4-methyl-2-pentanone
- R11 Highly flammable.
- R20 Harmful by inhalation.
- R36/37 Irritating to eyes and respiratory system.
- R66 Repeated exposure may cause skin dryness or cracking.
Methanol
- R11 Highly flammable.
- R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
- R39/23/24/25 Toxic: danger of very serious irreversible effects
through inhalation, in contact with skin and if swallowed.
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Recommended use
For research use only.
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Disclaimer
The information provided in this Material Safety Data Sheet is based on our present knowledge,
and believed to be correct at the date of publication. However, no representation is made
concerning its accuracy and completeness. It is intended as guidance only, and is not to be
considered a warranty or quality specification. All materials may present unknown hazards, and
should be used with caution. Although certain hazards are described, we cannot guarantee that
these are the only hazards which exist. PerkinElmer Life and Analytical Sciences shall not be held
liable for any damage resulting from handling or from contact with the product.
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PerkinElmer LAS (UK) Ltd
Legal Entity Address
Chalfont Road,
Seer Green,
Beaconsfield,
Bucks HP9 2FX
United Kingdom
Tel. (44) 0800-89 60 46
Fax (44) 0800-89 17 14
Material ID 16938 Item # N9331043 Print Date: 03-07-07
Material Name METHOD - KETONES 8260B SDS UK
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