Creation Date: 08-23-2007
Revision Date: 08-31-2007
Material Safety Data Sheet
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1. Chemical Product and Company Identification
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Material Name Mix A Method 624
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02
Version #
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Mixture
CAS #
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N9331060
Item #
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Methanol solution containing trace elements.
Synonym(s)
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PerkinElmer Life and Analytical Sciences
Identification Of The
710 Bridgeport Avenue
Company/Undertaking
Shelton, CT 06484
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Technical Support 800-762-4000
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CHEMTREC 800-424-9300
Emergency Telephone
Emergency Phone 800-762-4000
Number
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2. Composition / Information on Ingredients
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Hazardous component(s) CAS # Percent PEL TLV
1,1,1-TRICHLOROETHYLENE 79-01-6 0.1 - 1 50 ppm 50
CARBON TETRACHLORIDE, 99.9% 56-23-5 0.1 - 1 2 ppm 5
CHLOROFORM 67-66-3 0.1 - 1 2 ppm 10
DICHLOROMETHANE 75-09-2 0.1 - 1 500 ppm 50
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1,1,2,2-TETRACHLOROETHANE 79-34-5 0.1 - 1 1 ppm 1
BROMOFORM 75-25-2 0.1 - 1 0.5 ppm 0.5
CHLOROBENZENE 108-90-7 0.1 - 1 75 ppm 10
DENSITY STANDARD 1623 kg/m3 127-18-4 0.1 - 1 25 ppm 25
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1,1,2-Trichloroethane 79-00-5 0.1 - 1 10 ppm 10
1,2-DICHLOROPROPANE 78-87-5 0.1 - 1 75 ppm 75
METHANOL (METHYL ALCOHOL) 67-56-1 > 90 200 ppm 200
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Non-hazardous component(s) CAS # Percent
CHLORODIBROMOMETHANE 124-48-1 0.1 - 1
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1,1-DICHLOROETHANE 75-34-3 0.1 - 1
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trans-1,2-Dichloroethene 156-60-5 0.1 - 1
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3. Hazards Identification
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Health: 2*
HMIS RATINGS
Flammability: 3
Physical hazard: 0
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Health: 2
NFPA RATINGS
Flammability: 3
Instability: 0
Material ID 17558 Material Name Mix A Method 624
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MSDS US
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4. First Aid Measures
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First Aid
Skin contact
If skin irritation persists, call a physician. Wash off immediately with soap and plenty of water
removing all contaminated clothes and shoes.If skin irritation persists, call a physician and
Wash off immediately with soap and plenty of water removing all contaminated clothes and
shoes.
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Eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.Rinse
thoroughly with plenty of water for at least 15 minutes and consult a physician.
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Inhalation
Oxygen or artificial respiration if needed. Move to fresh air. Call a physician or Poison Control
Centre immediately.
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Ingestion
If swallowed, seek medical advice immediately and show this container or label. If a person
vomits when lying on his back, place him in the recovery position.
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5. Fire Fighting Measures
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Specific methods
In the event of fire, cool tanks with water spray.
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6. Accidental Release Measures
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Personal precautions
Use personal protective equipment. Keep people away from and upwind of spill/leak.
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Environmental precautions
Prevent further leakage or spillage if safe to do so.
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Methods for cleaning up
Dam up. Soak up with inert absorbent material. Shovel into suitable container for disposal.
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7. Handling and Storage
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Handling
Keep away from heat and sources of ignition.
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Material ID 17558 Material Name Mix A Method 624
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MSDS US
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8. Exposure Controls / Personal Protection
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Exposure Limit Values
Material TWA STEL
Mix A Method 624 200 ppm 250 ppm
ACGIH - Threshold Limits Values - Time Weighted Averages (TLV-TWA)
1,1,1-TRICHLOROETHYLENE79-01-6 50 ppm TWA
1,1,2,2-TETRACHLOROETHANE
79-34-5 1 ppm TWA
1,2-DICHLOROPROPANE 78-87-5 75 ppm TWA
BROMOFORM 75-25-2 0.5 ppm TWA
CARBON 56-23-5 5 ppm TWA
TETRACHLORIDE,
99.9%
CHLOROBENZENE 108-90-7 10 ppm TWA
CHLOROFORM 67-66-3 10 ppm TWA
DENSITY STANDARD 127-18-4 25 ppm TWA
1623 kg/m3
DICHLOROMETHANE 75-09-2 50 ppm TWA
OSHA - Final PELs - Time Weighted Averages (TWAs)
1,1,1-TRICHLOROETHYLENE79-01-6 100 ppm TWA
1,1,2,2-TETRACHLOROETHANE
79-34-5 5 ppm TWA; 35 mg/m3 TWA
1,2-DICHLOROPROPANE 78-87-5 75 ppm TWA; 350 mg/m3 TWA
BROMOFORM 75-25-2 0.5 ppm TWA; 5 mg/m3 TWA
CARBON 56-23-5 10 ppm TWA
TETRACHLORIDE,
99.9%
CHLOROBENZENE 108-90-7 75 ppm TWA; 350 mg/m3 TWA
DENSITY STANDARD 127-18-4 100 ppm TWA
1623 kg/m3
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Exposure Controls
Engineering measures to reduce exposure
Provide adequate ventilation.
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Respiratory protection
In the case of respirable dust and/or fumes, use self-contained breathing apparatus. Wear a
positive-pressure supplied-air respirator.
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Hand protection
gloves
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Eye protection
goggles If splashes are likely to occur, wear:
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9. Physical & Chemical Properties
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Important health, safety and environmental information
51.8 掳F (11 掳C) estimated
Flash Point
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867.2 掳F (464 掳C) estimated
Auto Ignition
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Flammable IB
Flammability Class
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148.1 掳F (64.5 掳C) estimated
Boiling Point
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2.1 (butyl acetate = 1)
Evaporation Rate
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-144.4 掳F (-98 掳C) estimated
Melting Point
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Characteristic pungent odor
Odor Threshold
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0.79 g/l 1.1 (air = 1)
Vapor Density
Material ID 17558 Material Name Mix A Method 624
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MSDS US
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126.3227 hPa estimated
Vapor Pressure
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98.6 % estimated
Volatile Organic
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10. Chemical Stability & Reactivity Information
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Further information
Stable at normal conditions
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11. Toxicological Information
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Dermal LD50 (Rabbit): 15800 mg/kg
Other Toxicological
Inhalation LC50 (Rat): 64000 mg/kg/4h
Information
Oral LD50 (Mouse): 7300 mg/kg
Oral LD50 (Rat): 5628 mg/kg
Potential Dermal Absorption
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Acute Toxicity
NIOSH - Selected LD50s and LC50s
1,1,1-TRICHLOROETHYLENE
79-01-6 Inhalation LC50 Mouse: 8450 ppm/4H; Oral LD50
Rat: 5650 mg/kg; Oral LD50 Mouse: 2402 mg/kg;
Dermal LD50 Rabbit: >20 g/kg
1,1,2,2-TETRACHLOROETHANE
79-34-5 Inhalation LC50 Mouse: 4500 mg/m3/2H; Oral LD50
Rat: 250 mg/kg
1,2-DICHLOROPROPANE
78-87-5 Inhalation LC50 Rat: 14 g/m3/8H; Oral LD50 Rat:
1947 mg/kg; Oral LD50 Mouse: 860 mg/kg; Dermal
LD50 Rabbit: 8750 L/kg
BROMOFORM 75-25-2 Oral LD50 Rat: 933 mg/kg; Oral LD50 Mouse: 1072
mg/kg
CARBON 56-23-5 Inhalation LC50 Rat: 8000 ppm/4H; Inhalation LC50
TETRACHLORIDE, Mouse: 9526 ppm/8H; Oral LD50 Rat: 2350 mg/kg;
99.9% Oral LD50 Mouse: 8263 mg/kg; Dermal LD50 Rabbit:
>20 g/kg
CHLOROBENZENE 108-90-7 Oral LD50 Rat: 1110 mg/kg; Oral LD50 Mouse: 2300
mg/kg
CHLOROFORM 67-66-3 Inhalation LC50 Rat: 47702 mg/m3/4H; Oral LD50
Rat: 908 mg/kg; Oral LD50 Mouse: 36 mg/kg; Dermal
LD50 Rabbit: >20 g/kg
DENSITY STANDARD 127-18-4 Inhalation LC50 Rat: 34200 mg/m3/8H; Inhalation
1623 kg/m3 LC50 Mouse: 5200 mg/kg/4H; Oral LD50 Rat: 2629
mg/kg; Oral LD50 Mouse: 8100 mg/kg
DICHLOROMETHANE 75-09-2 Inhalation LC50 Mouse: 14400 mg/kg/7H; Oral LD50
Rat: 1600 mg/kg
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Carcinogenicity
OSHA - Hazard Communication Carcinogens
1,1,1-TRICHLOROETHYLENE
79-01-6 Present
CARBON 56-23-5 Present
TETRACHLORIDE,
99.9%
CHLOROFORM 67-66-3 Present
DENSITY STANDARD 127-18-4 Present
1623 kg/m3
DICHLOROMETHANE 75-09-2 Present
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Carcinogenicity Data
OSHA Select Carcinogen
Material
NTP Suspected Carcinogen
Material ID 17558 Material Name Mix A Method 624
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MSDS US
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1,1,1-TRICHLOROETHYLENE
Ingredient(s)
- OSHA Select Carcinogen
- OSHA Possible Select Carcinogen
- ACGIH Not Suspected Carcinogen
- NTP Suspected Carcinogen
1,1,2,2-TETRACHLOROETHANE
- ACGIH Animal Carcinogen
1,2-DICHLOROPROPANE
- ACGIH Not Classified Carcinogen
BROMOFORM
- ACGIH Animal Carcinogen
CARBON TETRACHLORIDE, 99.9%
- OSHA Select Carcinogen
- OSHA Possible Select Carcinogen
- ACGIH Suspected Carcinogen
- NTP Suspected Carcinogen
CHLOROBENZENE
- ACGIH Animal Carcinogen
CHLOROFORM
- OSHA Select Carcinogen
- OSHA Possible Select Carcinogen
- ACGIH Animal Carcinogen
- NTP Suspected Carcinogen
DENSITY STANDARD 1623 kg/m3
- OSHA Select Carcinogen
- ACGIH Animal Carcinogen
- NTP Suspected Carcinogen
DICHLOROMETHANE
- OSHA Select Carcinogen
- OSHA Possible Select Carcinogen
- ACGIH Animal Carcinogen
- NTP Suspected Carcinogen
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Symptoms and Target Organs
NIOSH - Pocket Guide - Target Organs
1,1,1-TRICHLOROETHYLENE
79-01-6 respiratory system, heart, liver, eyes, CNS, skin,
kidneys (in animals: liver and kidney cancer)
1,1,2,2-TETRACHLOROETHANE
79-34-5 CNS, liver, kidneys, skin, GI tract (in animals: liver
tumors)
1,2-DICHLOROPROPANE
78-87-5 skin, eyes, respiratory system, liver, kidneys, CNS (in
animals: liver and mammary gland tumors)
BROMOFORM 75-25-2 skin, liver, kidneys, respiratory system, CNS, eyes
CARBON 56-23-5 CNS, eyes, lungs, liver, kidneys, skin (in animals:
TETRACHLORIDE, liver cancer)
99.9%
CHLOROBENZENE 108-90-7 respiratory system, eyes, skin, CNS, liver
CHLOROFORM 67-66-3 liver, kidneys, heart, eyes, skin, CNS (in animals:
liver and kidney cancer)
DENSITY STANDARD 127-18-4 liver, kidneys, eyes, CNS, respiratory system, skin (in
1623 kg/m3 animals: liver tumors)
DICHLOROMETHANE 75-09-2 skin, CVS, eyes, CNS (in animals: lung, liver, salivary
and mammary gland tumors)
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Material ID 17558 Material Name Mix A Method 624
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MSDS US
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12. Ecological Information
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Ecotoxicity
Ecotoxicity - Freshwater Algae Data
CARBON 56-23-5 24 Hr EC50 freshwater algae (Tetrahymena
TETRACHLORIDE, pyriformis): 830 mg/L
99.9%
CHLOROBENZENE 108-90-7 96 Hr EC50 freshwater algae (Selanastrum
capricornutum): 12.5 mg/L
Ecotoxicity - Freshwater Fish Species Data
1,1,1-TRICHLOROETHYLENE79-01-6 96 Hr LC50 fathead minnow: 44.1 mg/L
(flow-through)
1,1,2,2-TETRACHLOROETHANE
79-34-5 96 Hr LC50 fathead minnow: 20.3 mg/L
(flow-through)
1,2-DICHLOROPROPANE 78-87-5 96 Hr LC50 fathead minnow: 127 mg/L (flow-through)
CARBON 56-23-5 96 Hr LC50 fathead minnow: 41.4 mg/L
TETRACHLORIDE, (flow-through);96 Hr LC50 bluegill: 27 mg/L (Static)
99.9%
CHLOROBENZENE 108-90-7 96 Hr LC50 fathead minnow: 16.9 mg/L
(flow-through);48 Hr LC50 rainbow trout: 4.1 mg/L;96
Hr LC50 bluegill: 16 mg/L
CHLOROFORM 67-66-3 96 Hr LC50 fathead minnow: 70.7 mg/L
(flow-through);96 Hr LC50 rainbow trout: 43.8 mg/L
(Static)
DENSITY STANDARD 127-18-4 96 Hr LC50 rainbow trout: 5.28 mg/L (Static, 12
1623 kg/m3 degrees C);96 Hr LC50 fathead minnow: 13.4 mg/L
(flow-through);96 Hr LC50 bluegill: 12.9 mg/L (Static)
DICHLOROMETHANE 75-09-2 96 Hr LC50 fathead minnow: 330 mg/L
(flow-through);96 Hr LC50 rainbow trout: 10.95 mg/L
(flow-through);96 Hr LC50 bluegill: 220 mg/L (static)
Ecotoxicity - Microtox Data
1,2-DICHLOROPROPANE 78-87-5 5 min EC50 Photobacterium phosphoreum: 58.9
mg/L; 30 min EC50 Photobacterium phosphoreum:
93.4 mg/L
CARBON 56-23-5 5 min EC50 Photobacterium phosphoreum: 5.6 mg/L;
TETRACHLORIDE, 10 min EC50 Photobacterium phosphoreum: 34 mg/L
99.9%
CHLOROBENZENE 108-90-7 5 min EC50 Photobacterium phosphoreum: 9.36
mg/L; 15 min EC50 Photobacterium phosphoreum:
11.5 mg/L; 30 min EC50 Photobacterium
phosphoreum: 11.3 mg/L
CHLOROFORM 67-66-3 5 min EC50 Photobacterium phosphoreum: 520
mg/L; 15 min EC50 Photobacterium phosphoreum:
670 mg/L; 30 min EC50 Photobacterium
phosphoreum: 670 mg/L
DENSITY STANDARD 127-18-4 30 min EC50 Photobacterium phosphoreum: 120.0
1623 kg/m3 mg/L
DICHLOROMETHANE 75-09-2 15 min EC50 Photobacterium phosphoreum: 1000
mg/L
Ecotoxicity - Water Flea Data
CARBON 56-23-5 24 Hr EC50 water flea: 20763 mg/L
TETRACHLORIDE,
99.9%
CHLOROFORM 67-66-3 48 Hr EC50 water flea: 28.9 mg/L (Static)
DICHLOROMETHANE 75-09-2 48 Hr EC50 water flea: 140 mg/L (Static)
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Material ID 17558 Material Name Mix A Method 624
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MSDS US
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13. Disposal Considerations
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Disposal Instructions
In accordance with local and national regulations.
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14. Transportation Information
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US DOT
Methanol
Proper shipping name DOT
3
Hazard class
UN1230
UN number
II
Packaging group
IB2, T7, TP2
Special provisions
150
Packaging exceptions
202
Packaging non bulk
242
Packaging bulk
1L
Quantity limits
DOT
passenger
60 L
Quantity limits cargo
B
Vessel stowage
location
40
Vessel stowage other
3
Labels required
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Other Information
According to IATA respectively ICAO exempt from regulations up to 1 per each inner packaging and
15 per each outer packaging. DOT regulated, small quantity provisions apply (see 49CFR173.4)
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15. Regulatory Information
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CERCLA/SARA Section 313
Mix A Method 624
Material
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METHANOL (METHYL ALCOHOL)
Ingredient(s)
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US Federal Regulations
CERCLA/SARA - Hazardous Substances and their Reportable Quantities
1,1,1-TRICHLOROETHYLENE
79-01-6 100 lb final RQ; 45.4 kg final RQ
1,1,2,2-TETRACHLOROETHANE
79-34-5 100 lb final RQ; 45.4 kg final RQ
1,2-DICHLOROPROPANE 78-87-5 1000 lb final RQ; 454 kg final RQ
BROMOFORM 75-25-2 100 lb final RQ; 45.4 kg final RQ
CARBON 56-23-5 10 lb final RQ; 4.54 kg final RQ
TETRACHLORIDE,
99.9%
CHLOROBENZENE 108-90-7 100 lb final RQ; 45.4 kg final RQ
CHLOROFORM 67-66-3 10 lb final RQ; 4.54 kg final RQ
DENSITY STANDARD 127-18-4 100 lb final RQ; 45.4 kg final RQ
1623 kg/m3
DICHLOROMETHANE 75-09-2 1000 lb final RQ; 454 kg final RQ
CERCLA/SARA - Section 302 Extremely Hazardous Substances TPQs
CHLOROFORM 67-66-3 10000 lb TPQ
CERCLA/SARA - Section 313 - Emission Reporting
1,1,1-TRICHLOROETHYLENE
79-01-6 0.1 % de minimis concentration
1,1,2,2-TETRACHLOROETHANE
79-34-5 1.0 % de minimis concentration
1,2-DICHLOROPROPANE 78-87-5 1.0 % de minimis concentration
BROMOFORM 75-25-2 1.0 % de minimis concentration
CARBON 56-23-5 0.1 % de minimis concentration
TETRACHLORIDE,
99.9%
CHLOROBENZENE 108-90-7 1.0 % de minimis concentration
CHLOROFORM 67-66-3 0.1 % de minimis concentration
DENSITY STANDARD 127-18-4 0.1 % de minimis concentration
1623 kg/m3
DICHLOROMETHANE 75-09-2 0.1 % de minimis concentration
OSHA - Specifically Regulated Chemicals
DICHLOROMETHANE 75-09-2 25 ppm TWA (8 hr); 125 ppm STEL (15 min); 12.5
ppm Action Level (See 29 CFR 1910.1052)
TSCA (Toxic Substances Control Act) - Section 12(b) - Export Notification
1,2-DICHLOROPROPANE 78-87-5 Section 4
CHLOROBENZENE 108-90-7 Section 4
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State Regulations
California - Proposition 65 - No Significant Risk Levels (NSRL)
1,1,1-TRICHLOROETHYLENE 79-01-6 50 g/day NSRL (oral); 80 g/day NSRL (inhalation)
1,1,2,2-TETRACHLOROETHANE
79-34-5 3 g/day NSRL
BROMOFORM 75-25-2 64 g/day NSRL
CARBON 56-23-5 5 g/day NSRL
TETRACHLORIDE,
99.9%
CHLOROFORM 67-66-3 20 g/day NSRL (oral); 40 g/day NSRL (inhalation)
DENSITY STANDARD 127-18-4 14 g/day NSRL
1623 kg/m3
DICHLOROMETHANE 75-09-2 200 g/day NSRL (inhalation); 50 g/day NSRL
(except inhalation)
Massachusetts - Right To Know List
1,1,1-TRICHLOROETHYLENE 79-01-6 Carcinogen; Extraordinarily hazardous
1,1,2,2-TETRACHLOROETHANE
79-34-5 Carcinogen; Extraordinarily hazardous
1,2-DICHLOROPROPANE 78-87-5 Present
BROMOFORM 75-25-2 Present
CARBON 56-23-5 Carcinogen; Extraordinarily hazardous
TETRACHLORIDE,
99.9%
CHLOROBENZENE 108-90-7 Present
CHLOROFORM 67-66-3 Carcinogen; Extraordinarily hazardous
DENSITY STANDARD 127-18-4 Carcinogen; Extraordinarily hazardous
1623 kg/m3
DICHLOROMETHANE 75-09-2 Carcinogen; Extraordinarily hazardous
Massachusetts - Toxics Use Reduction Act
1,1,1-TRICHLOROETHYLENE 79-01-6 CERCLA and 313 chemical
1,1,2,2-TETRACHLOROETHANE
79-34-5 CERCLA and 313 chemical
1,2-DICHLOROPROPANE 78-87-5 CERCLA and 313 chemical
BROMOFORM 75-25-2 CERCLA and 313 chemical
CARBON 56-23-5 CERCLA and 313 chemical
TETRACHLORIDE,
99.9%
CHLOROBENZENE 108-90-7 CERCLA and 313 chemical
CHLOROFORM 67-66-3 CERCLA and 313 chemical
DENSITY STANDARD 127-18-4 CERCLA and 313 chemical
1623 kg/m3
DICHLOROMETHANE 75-09-2 CERCLA and 313 chemical
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International Regulations
Canada - WHMIS - Ingredient Disclosure List
1,1,1-TRICHLOROETHYLENE
79-01-6 1 % (English Item 1612, French Item 1646)
1,1,2,2-TETRACHLOROETHANE
79-34-5 1 % (English Item 1513, French Item 1575)
1,2-DICHLOROPROPANE 78-87-5 1 % (English Item 1361, French Item 683)
BROMOFORM 75-25-2 1 % (English Item 220, French Item 326)
CARBON 56-23-5 0.1 % (English Item 314, French Item 1579)
TETRACHLORIDE,
99.9%
CHLOROBENZENE 108-90-7 1 % (English Item 346, French Item 414)
CHLOROFORM 67-66-3 0.1 % (English Item 363, French Item 429)
DENSITY STANDARD 127-18-4 1 % (English Item 1249, French Item 1356)
1623 kg/m3
DICHLOROMETHANE 75-09-2 0.1 % (English Item 1044, French Item 508)
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16. Other Information
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Disclaimer
The information provided in this Material Safety Data Sheet is based on our present knowledge,
and believed to be correct at the date of publication. However, no representation is made
concerning its accuracy and completeness. It is intended as guidance only, and is not to be
considered a warranty or quality specification. All materials may present unknown hazards, and
should be used with caution. Although certain hazards are described, we cannot guarantee that
these are the only hazards which exist. PerkinElmer Life and Analytical Sciences shall not be held
liable for any damage resulting from handling or from contact with the product.
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Material ID 17558 Material Name Mix A Method 624
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