Creation Date: 08-23-2007
Revision Date: 08-31-2007
Material Safety Data Sheet
.
1. Chemical Product and Company Identification
space
Material Name Mix A Method 624
space
02
Version #
space
Mixture
CAS #
space
N9331060
Item #
space
Methanol solution containing trace elements.
Synonym(s)
space
PerkinElmer Life and Analytical Sciences
Identification Of The
710 Bridgeport Avenue
Company/Undertaking
Shelton, CT 06484
space
Technical Support 800-762-4000
space
CHEMTREC 800-424-9300
Emergency Telephone
Emergency Phone 800-762-4000
Number
.
2. Composition / Information on Ingredients
space
Hazardous component(s) CAS # Percent TWA TLV
CARBON TETRACHLORIDE, 99.9% 56-23-5 0.1 - 1 200 ppm 200
CHLOROFORM 67-66-3 0.1 - 1 200 ppm 200
space
DENSITY STANDARD 1623 kg/m3 127-18-4 0.1 - 1 200 ppm 200
DICHLOROMETHANE 75-09-2 0.1 - 1 200 ppm 200
space
METHANOL (METHYL ALCOHOL) 67-56-1 > 60 200 ppm 200
space
Non-hazardous component(s) CAS # Percent
1,1,1-TRICHLOROETHYLENE 79-01-6 0.1 - 1
1,1,2,2-TETRACHLOROETHANE 79-34-5 0.1 - 1
CHLOROBENZENE 108-90-7 0.1 - 1
space
1,1-DICHLOROETHANE 75-34-3 0.1 - 1
BROMOFORM 75-25-2 0.1 - 1
CHLORODIBROMOMETHANE 124-48-1 0.1 - 1
space
1,1,2-Trichloroethane 79-00-5 0.1 - 1
1,2-DICHLOROPROPANE 78-87-5 0.1 - 1
trans-1,2-Dichloroethene 156-60-5 0.1 - 1
space
.
3. Hazards Identification
space
Specific hazards
Avoid contact with the skin. Highly flammable.
space
Health: 2*
HMIS RATINGS
Flammability: 3
Physical hazard: 0
space
Health: 2
NFPA RATINGS
Flammability: 3
Instability: 0
Material ID 17558 Material Name Mix A Method 624
1/ 7
MSDS CANADA
.
4. First Aid Measures
space
First Aid
Skin contact
If skin irritation persists, call a physician. Wash off immediately with soap and plenty of water
removing all contaminated clothes and shoes.If skin irritation persists, call a physician and
Wash off immediately with soap and plenty of water removing all contaminated clothes and
shoes.
space
Eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.Rinse
thoroughly with plenty of water for at least 15 minutes and consult a physician.
space
Inhalation
Oxygen or artificial respiration if needed. Move to fresh air. Call a physician or Poison Control
Centre immediately.
space
Ingestion
If swallowed, seek medical advice immediately and show this container or label. If a person
vomits when lying on his back, place him in the recovery position.
space
.
5. Fire Fighting Measures
space
867.2 掳F (464 掳C) estimated
Auto Ignition
space
Flammable IB
Flammability Class
space
51.8 掳F (11 掳C) estimated
Flash Point
space
Specific methods
In the event of fire, cool tanks with water spray.
.
6. Accidental Release Measures
space
Personal precautions
Use personal protective equipment. Keep people away from and upwind of spill/leak.
space
Environmental precautions
Prevent further leakage or spillage if safe to do so.
space
Methods for cleaning up
Dam up. Soak up with inert absorbent material. Shovel into suitable container for disposal.
space
.
7. Handling and Storage
space
Handling
Keep away from heat and sources of ignition.
space
.
8. Exposure Controls / Personal Protection
space
Exposure Limit Values
Material TWA STEL
Mix A Method 624 200 ppm 250 ppm
space
Exposure Controls
Engineering measures to reduce exposure
Provide adequate ventilation.
space
Respiratory protection
In the case of respirable dust and/or fumes, use self-contained breathing apparatus. Wear a
positive-pressure supplied-air respirator.
Material ID 17558 Material Name Mix A Method 624
2/ 7
MSDS CANADA
space
Hand protection
gloves
space
Eye protection
goggles If splashes are likely to occur, wear:
space
.
9. Physical & Chemical Properties
space
Important health, safety and environmental information
51.8 掳F (11 掳C) estimated
Flash Point
space
867.2 掳F (464 掳C) estimated
Auto Ignition
space
Flammable IB
Flammability Class
space
148.1 掳F (64.5 掳C) estimated
Boiling Point
space
2.1 (butyl acetate = 1)
Evaporation Rate
space
-144.4 掳F (-98 掳C) estimated
Melting Point
space
Characteristic pungent odor
Odor Threshold
space
0.9577 estimated
Specific Gravity
space
0.79 g/l 1.1 (air = 1)
Vapor Density
space
126.3227 hPa estimated
Vapor Pressure
space
98.6 % estimated
Volatile Organic
space
.
10. Chemical Stability & Reactivity Information
space
Further information
Stable at normal conditions
.
11. Toxicological Information
space
Dermal LD50 (Rabbit): 15800 mg/kg
Other Toxicological
Inhalation LC50 (Rat): 64000 mg/kg/4h
Information
Oral LD50 (Mouse): 7300 mg/kg
Oral LD50 (Rat): 5628 mg/kg
Potential Dermal Absorption
space
Carcinogenicity Data
OSHA Select Carcinogen
Material
NTP Suspected Carcinogen
Material ID 17558 Material Name Mix A Method 624
3/ 7
MSDS CANADA
space
1,1,1-TRICHLOROETHYLENE
Ingredient(s)
- OSHA Select Carcinogen
- OSHA Possible Select Carcinogen
- ACGIH Not Suspected Carcinogen
- NTP Suspected Carcinogen
1,1,2,2-TETRACHLOROETHANE
- ACGIH Animal Carcinogen
1,2-DICHLOROPROPANE
- ACGIH Not Classified Carcinogen
BROMOFORM
- ACGIH Animal Carcinogen
CARBON TETRACHLORIDE, 99.9%
- OSHA Select Carcinogen
- OSHA Possible Select Carcinogen
- ACGIH Suspected Carcinogen
- NTP Suspected Carcinogen
CHLOROBENZENE
- ACGIH Animal Carcinogen
CHLOROFORM
- OSHA Select Carcinogen
- OSHA Possible Select Carcinogen
- ACGIH Animal Carcinogen
- NTP Suspected Carcinogen
DENSITY STANDARD 1623 kg/m3
- OSHA Select Carcinogen
- ACGIH Animal Carcinogen
- NTP Suspected Carcinogen
DICHLOROMETHANE
- OSHA Select Carcinogen
- OSHA Possible Select Carcinogen
- ACGIH Animal Carcinogen
- NTP Suspected Carcinogen
space
.
12. Ecological Information
space
.
13. Disposal Considerations
space
Disposal Instructions
In accordance with local and national regulations.
space
Material ID 17558 Material Name Mix A Method 624
4/ 7
MSDS CANADA
.
14. Transportation Information
space
US DOT
Methanol
Proper shipping name DOT
3
Hazard class
UN1230
UN number
II
Packaging group
IB2, T7, TP2
Special provisions
150
Packaging exceptions
202
Packaging non bulk
242
Packaging bulk
1L
Quantity limits
DOT
passenger
60 L
Quantity limits cargo
B
Vessel stowage
location
40
Vessel stowage other
3
Labels required
space
CTDG
Methanol
Proper shipping name CTDG
3
Hazard class
UN1230
UN number
II
Packaging group
IB2, T7, TP2
Special provisions
150
Packaging exceptions
202
Packaging non bulk
242
Packaging bulk
1L
Quantity limits
CTDG
passenger
60 L
Quantity limits cargo
B
Vessel stowage
location
40
Vessel stowage other
3
Labels required
space
Other Information
According to IATA respectively ICAO exempt from regulations up to 1 per each inner packaging and
15 per each outer packaging. DOT regulated, small quantity provisions apply (see 49CFR173.4)
.
15. Regulatory Information
space
CERCLA/SARA Section 313
Mix A Method 624
Material
space
METHANOL (METHYL ALCOHOL)
Ingredient(s)
Material ID 17558 Material Name Mix A Method 624
5/ 7
MSDS CANADA
space
International Regulations
Canada - CEPA - Schedule I - List of Toxic Substances
1,1,1-TRICHLOROETHYLENE
79-01-6 Present
CARBON 56-23-5 Present
TETRACHLORIDE,
99.9%
DENSITY STANDARD 127-18-4 Present
1623 kg/m3
DICHLOROMETHANE 75-09-2 Present
Canada - WHMIS - Classifications of Substances
1,1,1-TRICHLOROETHYLENE
79-01-6 D1B, D2A
1,1,2,2-TETRACHLOROETHANE
79-34-5 D1A
1,2-DICHLOROPROPANE 78-87-5 B2
BROMOFORM 75-25-2 D1B
CARBON 56-23-5 D1A, D2A, D2B
TETRACHLORIDE,
99.9%
CHLOROBENZENE 108-90-7 B2, D1B, D2B
CHLOROFORM 67-66-3 D2A
DENSITY STANDARD 127-18-4 D1B, D2A
1623 kg/m3
DICHLOROMETHANE 75-09-2 D1B, D2A, D2B
Canada - WHMIS - Ingredient Disclosure List
1,1,1-TRICHLOROETHYLENE
79-01-6 1 % (English Item 1612, French Item 1646)
1,1,2,2-TETRACHLOROETHANE
79-34-5 1 % (English Item 1513, French Item 1575)
1,2-DICHLOROPROPANE 78-87-5 1 % (English Item 1361, French Item 683)
BROMOFORM 75-25-2 1 % (English Item 220, French Item 326)
CARBON 56-23-5 0.1 % (English Item 314, French Item 1579)
TETRACHLORIDE,
99.9%
CHLOROBENZENE 108-90-7 1 % (English Item 346, French Item 414)
CHLOROFORM 67-66-3 0.1 % (English Item 363, French Item 429)
DENSITY STANDARD 127-18-4 1 % (English Item 1249, French Item 1356)
1623 kg/m3
DICHLOROMETHANE 75-09-2 0.1 % (English Item 1044, French Item 508)
Material ID 17558 Material Name Mix A Method 624
6/ 7
MSDS CANADA
space
Canada Regulations
Canada - CEPA - Schedule I - List of Toxic Substances
1,1,1-TRICHLOROETHYLENE
79-01-6 Present
CARBON 56-23-5 Present
TETRACHLORIDE,
99.9%
DENSITY STANDARD 127-18-4 Present
1623 kg/m3
DICHLOROMETHANE 75-09-2 Present
Canada - WHMIS - Classifications of Substances
1,1,1-TRICHLOROETHYLENE
79-01-6 D1B, D2A
1,1,2,2-TETRACHLOROETHANE
79-34-5 D1A
1,2-DICHLOROPROPANE 78-87-5 B2
BROMOFORM 75-25-2 D1B
CARBON 56-23-5 D1A, D2A, D2B
TETRACHLORIDE,
99.9%
CHLOROBENZENE 108-90-7 B2, D1B, D2B
CHLOROFORM 67-66-3 D2A
DENSITY STANDARD 127-18-4 D1B, D2A
1623 kg/m3
DICHLOROMETHANE 75-09-2 D1B, D2A, D2B
Canada - WHMIS - Ingredient Disclosure List
1,1,1-TRICHLOROETHYLENE
79-01-6 1 % (English Item 1612, French Item 1646)
1,1,2,2-TETRACHLOROETHANE
79-34-5 1 % (English Item 1513, French Item 1575)
1,2-DICHLOROPROPANE 78-87-5 1 % (English Item 1361, French Item 683)
BROMOFORM 75-25-2 1 % (English Item 220, French Item 326)
CARBON 56-23-5 0.1 % (English Item 314, French Item 1579)
TETRACHLORIDE,
99.9%
CHLOROBENZENE 108-90-7 1 % (English Item 346, French Item 414)
CHLOROFORM 67-66-3 0.1 % (English Item 363, French Item 429)
DENSITY STANDARD 127-18-4 1 % (English Item 1249, French Item 1356)
1623 kg/m3
DICHLOROMETHANE 75-09-2 0.1 % (English Item 1044, French Item 508)
.
16. Other Information
space
Disclaimer
The information provided in this Material Safety Data Sheet is based on our present knowledge,
and believed to be correct at the date of publication. However, no representation is made
concerning its accuracy and completeness. It is intended as guidance only, and is not to be
considered a warranty or quality specification. All materials may present unknown hazards, and
should be used with caution. Although certain hazards are described, we cannot guarantee that
these are the only hazards which exist. PerkinElmer Life and Analytical Sciences shall not be held
liable for any damage resulting from handling or from contact with the product.
space
Material ID 17558 Material Name Mix A Method 624
7/ 7
MSDS CANADA
|