Creation Date: 26-06-07
Revision Date: 26-06-07
Version #: 01
SAFETY DATA SHEET
according to EC Directive 2001/58/EC
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE
COMPANY/UNDERTAKING
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1.1. Identification of the Blend -Volatile Organics Combination
Substance or Preparation
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Mixture
CAS #
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N9331047
Item #
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1.2. Use of the
substance/preparation
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Methanol, Carbinol, Methyl Alcohol solution containing trace constituents.
Synonym(s)
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PerkinElmer N.V./S.A.
1.3.
Imperiastraat 8, Bus1
Company/undertaking
1930 Zaventem
identification
Belgium
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Fax (32) 0800 40858
Tel. (32) 0800 40859
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(32) 0800 40859
1.4 Emergency
CHEMTREC 1-703-527-3887
Telephone Number
Material ID 16867 Item # N9331047 Print Date: 26-06-07
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2. Composition / Information on Ingredients
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Ingredients CAS # Percent EU #
BROMOBENZENE 108-86-1 < 0.01 203-623-8
Xi, N
R10, R38, R51, R53
Benzene 71-43-2 < 0.01 200-753-7
Carc. Cat. 1, Muta. Cat. 2, T, F,
R45, R46, R11, R48/23/24/25, R65, R36/38
CHLOROBROMOMETHANE 74-97-5 < 0.01 200-826-3
CARBON TETRACHLORIDE, 99.9% 56-23-5 < 0.01 200-262-8
Carc. Cat. 3, T, N
R40, R23/24/25, R48/23, R52, R53, R59
Chloroform 67-66-3 < 0.01 200-663-8
Carc. Cat. 3, Xi, Xn,
R22, R48/20/22, R38, R40
1,2-DICHLOROBENZENE, ANHYDROUS, 95-50-1 < 0.01 202-425-9
99%
Xi, Xn, N
R22, R36/37/38, R50, R53
CHLOROBENZENE 108-90-7 < 0.01 203-628-5
Xn, N
R10, R20, R51, R53
TERT-BUTYLBENZENE 98-06-6 < 0.01 202-632-4
DICHLOROBROMOMETHANE 75-27-4 < 0.01 200-856-7
BROMOFORM 75-25-2 < 0.01 200-854-6
T, Xi, N
R23, R36/38, R51, R53
n-butylbenzene 104-51-8 < 0.01 203-209-7
SEC-BUTYLBENZENE 135-98-8 < 0.01 205-227-0
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O-CHLOROTOLUENE 95-49-8 < 0.01 202-424-3
Xn, N
R20, R51, R53
P-CHLOROTOLUENE 106-43-4 < 0.01 203-397-0
Xn, N
R20, R51, R53
1,2-DIBROMO-3-CHLOROPROPANE 96-12-8 < 0.01 202-479-3
Carc. Cat. 2, Muta. Cat. 2, Repr. Cat. 1, T
R45, R46, R60, R25, R48/20/22, R52, R53
CHLORODIBROMOMETHANE 124-48-1 < 0.01 204-704-0
1,2-Dibromomethane No Data < 0.01
METHYLENE BROMIDE 74-95-3 < 0.01 200-824-2
Xn,
R20, R52, R53
1,3-DICHLOROBENZENE 541-73-1 < 0.01 208-792-1
Xn, N
R22, R51, R53
P-DICHLOROBENZENE 106-46-7 < 0.01 203-400-5
Carc. Cat. 3, Xi, Xn, N
R36, R40, R50, R53
1,1-DICHLOROETHANE 75-34-3 < 0.01 200-863-5
Xi, Xn, F,
R11, R22, R36/37, R52, R53
1,2-DICHLOROETHANE, ANHYDROUS, 107-06-2 < 0.01 203-458-1
99.8%
Carc. Cat. 2, T, Xi, F,
R45, R11, R22, R36/37/38
VINYLIDENE CHLORIDE 75-35-4 < 0.01 200-864-0
Carc. Cat. 3, Xn, F+
R12, R40, R20
CIS-1,2-DICHLOROETHYLENE 156-59-2 < 0.01 205-859-7
Xn, F,
R11, R20, R52, R53
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trans-1,2-Dichloroethene 156-60-5 < 0.01 205-860-2
Xn, F,
R11, R20, R52, R53
1,2-DICHLOROPROPANE 78-87-5 < 0.01 201-152-2
Xn, F,
R11, R20/22
1,3-DICHLOROPROPANE 142-28-9 < 0.01 205-531-3
PROPANE, 2,2-DICHLORO- 594-20-7 < 0.01 209-832-0
1,1-DICHLOROPROPENE 563-58-6 < 0.01 209-253-3
T, F,
R11, R25, R52, R53
CIS-1,3-DICHLOROPROPENE 10061-01-5 < 0.01 233-195-8
T, Xi, N
R10, R25, R20/21, R36/37/38, R43, R50, R53
TRANS-1,3-DICHLOROPROPENE 10061-02-6 < 0.01
ETHYLBENZENE 100-41-4 < 0.01 202-849-4
Xn, F,
R11, R20
HEXACHLOROBUTADIENE 87-68-3 < 0.01 201-765-5
CUMENE 98-82-8 < 0.01 202-704-5
Xi, Xn, N
R10, R65, R37, R51, R53
P-CYMENE 99-87-6 < 0.01 202-796-7
Methanol 67-56-1 > 90 200-659-6
T, F,
R11, R23/24/25, R39/23/24/25
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Refer to Section 16 for the risk phrases.
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3. Hazards Identification
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T; Toxic: danger of very serious irreversible effects through inhalation, in
Hazard and Risk Codes
contact with skin and if swallowed.(R39/23/24/25), Possible risks of
irreversible effects.(R68)
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4. First Aid Measures
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General advice
Immediate medical attention is required
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First Aid
Skin contact
Wash off immediately with soap and plenty of water removing all contaminated clothes and
shoes. Consult a physician.
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Eye contact
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Consult a
physician.
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Inhalation
Move to fresh air. Oxygen or artificial respiration if needed.
Material ID 16867 Item # N9331047 Print Date: 26-06-07
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Ingestion
Rinse mouth. Never give anything by mouth to an unconscious person. Call a physician
immediately.
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5. Fire Fighting Measures
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Suitable extinguishing media
water spray.
carbon dioxide (CO2), dry powder or foam
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Specific hazards
In the event of fire toxic fumes may be formed.
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Special protective equipment for firefighters
Wear suitable protective equipment
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6. Accidental Release Measures
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Evacuation Procedures
Evacuate personnel to safe areas.
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Personal precautions
Remove all sources of ignition. Ensure adequate ventilation. Use personal protective equipment.
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Methods for cleaning up
Neutralise with dry-lime, sand, or soda ash Clean contaminated surface thoroughly. Keep in
suitable, closed containers for disposal.
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7. Handling and Storage
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7.1 Handling
Use only in area provided with appropriate exhaust ventilation. wear personal protective equipment
Keep away from heat and sources of ignition. Do not breathe vapours or spray mist. Avoid contact
with skin and eyes.
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7.2 Storage
Keep tightly closed. Keep away from heat. Keep in a dry, cool place.
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7.3 Specific Use(s)
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8. Exposure Controls / Personal Protection
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8.1 Exposure Limits Values
Not applicable
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8.2 Exposure Controls
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8.2.1 Occupational Exposure Controls
Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin,
eyes and clothing. Keep away from food and drink. Wash hands before breaks and immediately
after handling the product.
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8.2.1.1 Respiratory Protection
No personal respiratory protective equipment normally required.
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8.2.1.2 Hand Protection
solvent-resistant gloves
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8.2.1.3 Eye Protection
safety glasses with side-shields
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8.2.1.4 Skin Protection
Lab coat.
Remove and wash contaminated clothing before re-use. Discard contaminated shoes.
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8.2.2 Environmental Exposure Controls
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9. Physical & Chemical Properties
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9.1 General Information
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Colour
colorless
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Odour
slight
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Form
liquid
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9.2 Important health, safety and environmental information
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0 estimated
Specific Gravity
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0 % estimated
Volatile Organic
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9.3 Other Information
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10. STABILITY AND REACTIVITY
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10.1 Conditions to Avoid
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10.2 Materials to Avoid
acids; acid chlorides; acid anhydrides; alkali metals; reducing agents
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10.3 Hazardous Decomposition Products
carbon oxides
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11. Toxicological Information
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Acute toxicity
Irritating to eyes, respiratory system and skin.
Toxic by inhalation, in contact with skin and if swallowed.
Methyl Alcohol may be fatal or cause blindness if swallowed.
Cannot be made non-poisonous.
Ingestion may provoke the following symptoms:
nausea, headache, and vomiting
gastrointestinal disturbance, dizziness, weakness, and
Unconsciousness
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12. Ecological Information
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12.1 Ecotoxicity
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12.2 Mobility
Not available
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12.3 Persistence and Degradability
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12.4. Bioaccumulative potential
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12.5 Other Adverse Effects
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13. Disposal Considerations
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Disposal Instructions
In accordance with local and national regulations.
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Waste from residues / unused products
In accordance with local and national regulations.
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14. TRANSPORT INFORMATION
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ADR
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ICAO
Material ID 16867 Item # N9331047 Print Date: 26-06-07
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IMDG
METHANOL
Proper shipping name IMDG
3
Hazard class
UN1230
UN number
II
Packaging group
150
Packaging exceptions
2
Transport Category
IMDG
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IATA
Methanol
Proper shipping name IATA
3
Hazard class
UN1230
UN number
II
Packaging group
150
Packaging exceptions
3
Labels required
Methanol
Proper shipping name
3
Hazard class
UN1230
UN number
IATA
II
Packaging group IATA
150
Packaging exceptions
3
Labels required
IATA
IATA
Methanol
Proper shipping name IATA
3
Hazard class
UN1230
UN number
II
Packaging group
150
Packaging exceptions
3
Labels required
Methanol
Proper shipping name
3
Hazard class
UN1230
UN number
IATA
II
Packaging group IATA
150
Packaging exceptions
3
Labels required
IATA
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15. Regulatory Information
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T
Toxic
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Toxic: danger of very serious irreversible effects through inhalation
Risks
in contact with skin and if swallowed.(R39/23/24/25)
Possible risks of irreversible effects.(R68)
Material ID 16867 Item # N9331047 Print Date: 26-06-07
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Do not breathe spray.(S23)
Safety
Avoid contact with skin and eyes.(S24/25)
Do not empty into drains.(S29)
Wear suitable protective clothing and gloves.(S36/37)
This material and its container must be disposed of as hazardous
waste.(S60)
Material ID 16867 Item # N9331047 Print Date: 26-06-07
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