Creation Date: 16-08-07
Revision Date: 21-09-07
Version #: 01
SAFETY DATA SHEET
according to EC Directive 2001/58/EC
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1. IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND THE
COMPANY/UNDERTAKING
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1.1. Identification of the Surrogate Standard for Method 524.2
Substance or Preparation
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Mixture
CAS #
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N9331051
Item #
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1.2. Use of the
substance/preparation
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Methanol solution containing trace elements
Synonym(s)
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PerkinElmer N.V./S.A.
1.3.
Imperiastraat 8, Bus1
Company/undertaking
1930 Zaventem
identification
Belgium
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Fax (32) 0800 40858
Tel. (32) 0800 40859
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(32) 0800 40859
1.4 Emergency
CHEMTREC 1-703-527-3887
Telephone Number
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2. Composition / Information on Ingredients
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Ingredients CAS # Percent EU #
METHANOL (METHYL ALCOHOL) 67-56-1 > 90 200-659-6
T, F,
R11, R23/24/25, R39/23/24/25
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4-Bromofluorobenzene 460-00-4 0.01 - 0.1 207-300-2
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1,2-Dichlorobenzene-d4 2199-69-1 0.01 - 0.1 218-606-0
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Refer to Section 16 for the risk phrases.
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3. Hazards Identification
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T, F; Highly flammable.(R11), Toxic: danger of very serious irreversible
Hazard and Risk Codes
effects through inhalation, in contact with skin and if
swallowed.(R39/23/24/25), Possible risks of irreversible effects.(R68)
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4. First Aid Measures
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First Aid
Skin contact
If skin irritation persists, call a physician. Wash off immediately with soap and plenty of water
removing all contaminated clothes and shoes.
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Eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
Material ID 17408 Item # N9331051 Print Date: 21-09-07
Material Name SURROGATE STANDARD FOR METHOD 524.2 SDS UK
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Inhalation
Oxygen or artificial respiration if needed. Move to fresh air. Call a physician or Poison Control
Centre immediately.
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Ingestion
If swallowed, seek medical advice immediately and show this container or label. If a person
vomits when lying on his back, place him in the recovery position.
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5. Fire Fighting Measures
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Specific methods
In the event of fire, cool tanks with water spray.
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6. Accidental Release Measures
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Personal precautions
Use personal protective equipment. Keep people away from and upwind of spill/leak.
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Environmental precautions
Prevent further leakage or spillage if safe to do so.
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Methods for cleaning up
Dam up. Soak up with inert absorbent material. Shovel into suitable container for disposal.
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7. Handling and Storage
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7.1 Handling
Keep away from heat and sources of ignition.
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7.2 Storage
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7.3 Specific Use(s)
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8. Exposure Controls / Personal Protection
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8.1 Exposure Limits Values
Material 8hr OEL 15min OEL
Surrogate Standard for Method 524.2 200 ppm 266 250 ppm 333
mg/m3 mg/m3
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8.2 Exposure Controls
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8.2.1 Occupational Exposure Controls
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8.2.1.1 Respiratory Protection
In the case of respirable dust and/or fumes, use self-contained breathing apparatus. Wear a
positive-pressure supplied-air respirator.
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8.2.1.2 Hand Protection
gloves
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8.2.1.3 Eye Protection
goggles If splashes are likely to occur, wear:
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8.2.1.4 Skin Protection
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8.2.2 Environmental Exposure Controls
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9. Physical & Chemical Properties
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9.1 General Information
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9.2 Important health, safety and environmental information
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11 掳C (51.8 掳F) estimated
Flash point
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464 掳C (867.2 掳F) estimated
Auto Ignition
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64.5 掳C (148.1 掳F) estimated
Boiling Point
Material ID 17408 Item # N9331051 Print Date: 21-09-07
Material Name SURROGATE STANDARD FOR METHOD 524.2 SDS UK
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2.1 (butyl acetate = 1)
Evaporation rate
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-98 掳C (-144.4 掳F) estimated
Melting Point
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Characteristic pungent odor
Odour Threshold
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0.9487 estimated
Specific Gravity
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0.79 g/l) 1.1 (air = 1)
Vapor Density
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129.9691 hPa estimated
Vapor Pressure
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99.8 % estimated
Volatile Organic
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9.3 Other Information
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10. STABILITY AND REACTIVITY
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10.1 Conditions to Avoid
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10.2 Materials to Avoid
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10.3 Hazardous Decomposition Products
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11. Toxicological Information
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12. Ecological Information
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12.1 Ecotoxicity
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12.2 Mobility
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12.3 Persistence and Degradability
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12.4. Bioaccumulative potential
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12.5 Other Adverse Effects
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13. Disposal Considerations
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Disposal Instructions
In accordance with local and national regulations.
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14. TRANSPORT INFORMATION
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ADR
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ICAO
Methanol
Proper shipping name ICAO
3
Hazard class
UN1230
UN number
II
Packaging group
IB2, T7, TP2
Special provisions
150
Packaging exceptions
3
Labels required
ICAO
Material ID 17408 Item # N9331051 Print Date: 21-09-07
Material Name SURROGATE STANDARD FOR METHOD 524.2 SDS UK
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IMDG
METHANOL
Proper shipping name IMDG
3
Hazard class
UN1230
UN number
II
Packaging group
150
Packaging exceptions
2
Transport Category
IMDG
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IATA
Methanol
Proper shipping name IATA
3
Hazard class
UN1230
UN number
II
Packaging group
150
Packaging exceptions
3
Labels required
IATA
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Other information
DOT regulated, small quantity provisions apply (see 49CFR173.4) According to IATA respectively
ICAO exempt from regulations up to 1 per inner packaging and 14 per each outer packaging.
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15. Regulatory Information
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T F
Toxic Highly
flammable
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Highly flammable.(R11)
Risks
Toxic: danger of very serious irreversible effects through inhalation
in contact with skin and if swallowed.(R39/23/24/25)
Possible risks of irreversible effects.(R68)
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Keep away from sources of ignition - No smoking.(S16)
Safety
Do not breathe spray.(S23)
Avoid contact with skin and eyes.(S24/25)
Do not empty into drains.(S29)
Wear suitable protective clothing and gloves.(S36/37)
This material and its container must be disposed of as hazardous
waste.(S60)
Keep container in a well-ventilated place.(S9)
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16. Other information
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R11 Highly flammable.
Material Risk Phrase(s)
R39/23/24/25 Toxic: danger of very serious irreversible effects through
inhalation, in contact with skin and if swallowed.
R68 Possible risks of irreversible effects.
Material ID 17408 Item # N9331051 Print Date: 21-09-07
Material Name SURROGATE STANDARD FOR METHOD 524.2 SDS UK
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METHANOL (METHYL ALCOHOL)
Ingredient Risk Phrase(s)
- R11 Highly flammable.
- R23/24/25 Toxic by inhalation, in contact with skin and if swallowed.
- R39/23/24/25 Toxic: danger of very serious irreversible effects
through inhalation, in contact with skin and if swallowed.
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Disclaimer
The information provided in this Material Safety Data Sheet is based on our present knowledge,
and believed to be correct at the date of publication. However, no representation is made
concerning its accuracy and completeness. It is intended as guidance only, and is not to be
considered a warranty or quality specification. All materials may present unknown hazards, and
should be used with caution. Although certain hazards are described, we cannot guarantee that
these are the only hazards which exist. PerkinElmer Life and Analytical Sciences shall not be held
liable for any damage resulting from handling or from contact with the product.
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PerkinElmer LAS (UK) Ltd
Legal Entity Address
Chalfont Road,
Seer Green,
Beaconsfield,
Bucks HP9 2FX
United Kingdom
Tel. (44) 0800-89 60 46
Fax (44) 0800-89 17 14
Material ID 17408 Item # N9331051 Print Date: 21-09-07
Material Name SURROGATE STANDARD FOR METHOD 524.2 SDS UK
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