The MSDS format adheres to the standards and regulatory requirements
of the United States and may not meet regulatory requirements
in other countries.
DuPont Page 1
Material Safety Data Sheet
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"SURLYN" REFLECTION SERIES, SUPERGLOSS MOLDING ALLOYS ALL IN SYNONYM
LIST SUR032
SUR032 Revised 1-JUL-2005
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CHEMICAL PRODUCT/COMPANY IDENTIFICATION
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Material Identification
"SURLYN" is a registered trademark of DuPont.
Tradenames and Synonyms
"SURLYN" SG201BF NC010,
"SURLYN" SG201U NC010, SG201UC NC010, SG201UF NC010,
"SURLYN" SG201UG BK001, SG201UG BK002, SG201UG BK003,
"SURLYN" SG201UG NC010, SG201UK NC010, SG201UM NC010,
"SURLYN" SG201UG NC021, SG201UG NC022, #
"SURLYN" SG201UN BK002, SG201UN NC010,
"SURLYN" SG201US NC010, SG201UT NC010,
"SURLYN" SG202U NC010, SG202UB NC010, SG202UB BK001,
"SURLYN" SG202UG NC010, SG202UH NC010,
"SURLYN" SG210 BK001, SG210 NC010
Company Identification
MANUFACTURER/DISTRIBUTOR
DuPont Packaging & Industrial Polymers
1007 Market Street
Wilmington,DE 19898
PHONE NUMBERS
Product Information : 1-(800)-441-7515
Transport Emergency : 1-(800)-424-9300
Medical Emergency : 1-(800)-441-3637
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COMPOSITION/INFORMATION ON INGREDIENTS
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Components
Material CAS Number %
ETHYLENE/METHACRYLIC ACID COPOLYMER, 28516-43-0 <60
ZINC SALT
NYLON 6 25038-54-4 <60
CAPROLACTAM 105-60-2 <1.5
NON-REGULATED STABILIZERS <3
CARBON BLACK (BK TYPES) 1333-86-4 <2
*ZINC COMPOUNDS 7440-66-6 <5
*ZINC STEARATE 557-05-1 <2
* Disclosure as a toxic chemical is required under Section 313 of
Title III of the Superfund Amendments and Reauthorization Act of 1986
and 40 CFR part 372.
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Material Safety Data Sheet
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HAZARDS IDENTIFICATION
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Potential Health Effects
ADDITIONAL HEALTH EFFECTS
ACUTE OR IMMEDIATE EFFECTS: ROUTES OF ENTRY AND SYMPTOMS
INGESTION No data are available. Ingestion is not a
probable route of exposure. Based on its similarity with
other polymers, Surlyn(R) resins are predicted to have low
toxicity.
SKIN No data are available. However, based on experience
with handling these polymers, contact with resin may cause
mild irritation of the skin. Molten polymer contacting the
skin will cause thermal burns.
EYE Contact with processing vapors may cause severe eye
irritation.
INHALATION Polymer is not respirable as sold. At
processing temperatures above 250 C (482 F), fumes
irritating to the eyes, nose and throat may be produced.
This exposure may result in reddening, tearing, and itching
of the eyes and soreness in the nose and throat together
with coughing.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None known.
NYLON 6
Eye contact with Nylon 6 particles may cause eye irritation with
discomfort, tearing, or blurring of vision.
Significant skin permeation, and systemic toxicity, after contact
appears unlikely. There are no reports of human sensitization.
CARBON BLACK
Immediate effects of overexposure to Carbon Black by inhalation
may include irritation of the nose, throat, and lungs with cough,
difficulty breathing or shortness of breath.
If particles from Carbon Black contact the eye, mechanical
irritation with tearing, pain or blurred vision may result.
Significant skin permeation, and systemic toxicity, after contact
with Carbon Black appears unlikely. There are no reports of human
sensitization.
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Material Safety Data Sheet
(HAZARDS IDENTIFICATION - Continued)
Epidemiologic studies demonstrate no significant risk of human
cancer from exposure to Carbon Black. While some reports cite an
increased incidence of pulmonary abnormalities, such as decreased
pulmonary function and radiological changes among Carbon Black
workers, other reports show no correlation between exposure and
effects on pulmonary function or disease.
Increased susceptibility to the effects of Carbon Black may be
observed in persons with pre-existing disease of the lungs.
CAPROLACTAM
Human experience or case reports have identified the following
potential effects from overexposure by inhalation to Caprolactam:
irritation of the nose and throat with sneezing, sore throat, dry
throat or runny nose; irritation of the gastrointestinal tract
with heartburn or discomfort; liver abnormalities; central nervous
system depression with dizziness, confusion, incoordination,
drowsiness or unconsciousness; convulsions; nosebleed; or bitter
taste. Repeated and/or prolonged inhalation may cause central
nervous system abnormalities. Less frequently, liver
abnormalities have been reported. Exposure to Caprolactam fumes
or dust may cause concentration-related increases in skin, eye,
and upper respiratory tract irritation.
Human experience or case reports have identified the following
potential effects from overexposure by skin contact with
Caprolactam: skin irritation with itching, burning, redness,
swelling or rash; dermatitis with itching or rash; or skin
sensitization. By itself 5% Caprolactam showed no clear evidence
of dermatitis; however, skin sensitization has been reported in
Caprolactam manufacturing facilities. Skin permeation may occur
in amounts capable of producing the effects of systemic toxicity.
Eye contact with Caprolactam may cause eye irritation with
tearing, pain or blurred vision. Prolonged or high exposure may
cause corneal damage.
Increased susceptibility to the effects of this material may be
observed in persons with pre-existing disease of the central
nervous system.
Carcinogenicity Information
The following components are listed by IARC, NTP, OSHA or ACGIH as
carcinogens.
Material IARC NTP OSHA ACGIH
CARBON BLACK (BK TYPES) 2B
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Material Safety Data Sheet
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FIRST AID MEASURES
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First Aid
INHALATION
No specific intervention is indicated as the compound is not
likely to be hazardous by inhalation. Consult a physician if
necessary. If exposed to fumes from overheating or combustion,
move to fresh air. Consult a physician if symptoms persist.
SKIN CONTACT
The compound is not likely to be hazardous by skin contact, but
cleansing the skin after use is advisable. If molten polymer gets
on skin, cool rapidly with cold water. Do not attempt to peel
polymer from skin. Obtain medical treatment for thermal burn.
EYE CONTACT
In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes. Call a physician.
INGESTION
No specific intervention is indicated as compound is not likely to
be hazardous by ingestion.
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FIRE FIGHTING MEASURES
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Flammable Properties
Flash Point : NE
Fire and Explosion Hazards:
The solid polymer can be combusted only with difficulty.
Hazardous gases/vapors produced in fire are aldehydes, ammonia,
carbon dioxide, carbon monoxide, oxides of nitrogen, oxides of
zinc, phosphorous oxides, hydrogen phosphide, and, oxides of
sulfur.
Extinguishing Media
Water, Foam, Dry Chemical, CO2.
Fire Fighting Instructions
Wear self-contained breathing apparatus.
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Material Safety Data Sheet
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ACCIDENTAL RELEASE MEASURES
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Safeguards (Personnel)
NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL)
sections before proceeding with clean-up. Use appropriate
PERSONAL PROTECTIVE EQUIPMENT during clean-up.
Spill Clean Up
Sweep up to avoid slipping hazard.
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HANDLING AND STORAGE
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Handling (Personnel)
See FIRST AID and PERSONAL PROTECTIVE EQUIPMENT SECTIONS.
Storage
Store in a cool, dry place. Keep containers tightly closed to
prevent moisture absorption and contamination.
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EXPOSURE CONTROLS/PERSONAL PROTECTION
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Engineering Controls
VENTILATION: Local ventilation should be used over processing
equipment.
Personal Protective Equipment
EYE/FACE PROTECTION
Wear safety glasses. Wear coverall chemical splash goggles and
face shield when possibility exists for eye and face contact due
to splashing or spraying of molten material.
RESPIRATORS
When temperatures exceed 250 degrees C and ventilation is
inadequate to maintain concentrations below exposure limits, use a
positive pressure air supplied respirator. Air purifying
respirators may not provide adequate protection.
PROTECTIVE CLOTHING
If there is potential contact with hot/molten material, wear heat
resistant clothing and footwear.
# Exposure Guidelines
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Material Safety Data Sheet
Exposure Limits
"SURLYN" REFLECTION SERIES, SUPERGLOSS MOLDING ALLOYS ALL IN
SYNONYM LIST SUR032
PEL (OSHA) : Particulates (Not Otherwise Regulated)
15 mg/m3, 8 Hr. TWA, total dust
5 mg/m3, 8 Hr. TWA, respirable dust
Other Applicable Exposure Limits
CAPROLACTAM
PEL (OSHA) : None Established
TLV (ACGIH) : 5 mg/m3, 8 Hr. TWA, Aerosol, & vapor, A5
AEL * (DuPont) : None Established
CARBON BLACK (BK TYPES)
PEL (OSHA) : 3.5 mg/m3, 8 Hr. TWA
TLV (ACGIH) : 3.5 mg/m3, 8 Hr. TWA, A4
AEL * (DuPont) : 0.5 mg/m3, 8 & 12 Hr.TWA, (Polynuclear
Aromatic Hydrocarbon Content <0.1%)
Includes Channel, Lamp, and Thermal
Black
ZINC STEARATE
PEL (OSHA) : 15 mg/m3, total dust, 8 Hr. TWA
5 mg/m3, respirable dust, 8 Hr. TWA
TLV (ACGIH) : 10 mg/m3, total dust, 8 Hr. TWA
AEL * (DuPont) : None Established
* AEL is DuPont鈥檚 Acceptable Exposure Limit. Where governmentally
imposed occupational exposure limits which are lower than the AEL
are in effect, such limits shall take precedence.
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PHYSICAL AND CHEMICAL PROPERTIES
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Physical Data
Melting Point : NA
% Volatiles : NA
Solubility in Water : Negligible
Odor : Negligible
Color : Natural Color, Pigmented.
Form : Pellets
Specific Gravity : NA
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STABILITY AND REACTIVITY
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Chemical Stability
Stable at normal temperatures and storage conditions.
Conditions to Avoid
Temperatures above 300 C (572 F) .
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Material Safety Data Sheet
(STABILITY AND REACTIVITY - Continued)
Incompatibility with Other Materials
Incompatible or can react with strong acids, oxidizing agents.
Decomposition
Decomposes with heat.
Decomposition temperature: NA
Hazardous gases or vapors can be released, including aldehydes,
ammonia, carbon dioxide, carbon monoxide, oxides of nitrogen,
oxides of zinc, phosphorous oxides, hydrogen phosphide, and,
oxides of sulfur.
Polymerization
Polymerization will not occur.
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TOXICOLOGICAL INFORMATION
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Animal Data
Nylon 6
Inhalation 0.5 hour LC50: 11,000 mg/m3 in mice
Oral LD50: 3,200 mg/kg in rats
Nylon 6 is not a skin irritant, but is an eye irritant in animal
tests.
Repeated ingestion exposures caused slower rate of weight gain and
lower food consumption, but no anatomic injury was observed after
exposure ended.
No animal test reports are available to define carcinogenic,
mutagenic, developmental, or reproductive hazards.
Caprolactam
Skin Absorption LD50: 1410 mg/kg in rabbits
Oral LD50: 1210 mg/kg in rats
Inhalation 4 hour LC50: 8.1 mg/L in rats (as respirable
aerosol)
Caprolactam is a skin irritant, a severe eye irritant, and is a
mild skin sensitizer when tested at very high concentrations in
animals.
Single dermal exposure to near lethal doses caused edema, and
tremors or convulsions.
SUR032 DuPont Page 8
Material Safety Data Sheet
(TOXICOLOGICAL INFORMATION - Continued)
Single ingestion exposure in rats to near lethal doses caused
irritation of the gastrointestinal tract, pathological changes of
the brain and liver, tremors or convulsions, and altered liver
enzyme activity. Repeated dosing of lower concentrations caused
decreased body weight. Effects on kidney function have been
observed but were attributable to a reversible physiologic change.
Long term exposure caused body weight reductions, reduced food
consumption, and anemia.
Single inhalation exposure in rats caused nasal/ocular irritation
and alterations in blood pressure. Repeated inhalation exposure
at high levels caused nasal/ocular irritation, lung and spleen
pathology, and abnormal weight gain in rats. At lower levels,
respiratory tract irritation with pathological changes in the nose
and larynx were observed.
In animal testing Caprolactam has not caused carcinogenicity,
developmental or reproductive toxicity.
There are reports indicating that Caprolactam produced genetic
damage in some animal or mammalian cell culture tests; however,
the majority of in vitro and in vivo reports in the literature
show negative results.
Carbon Black
Oral ALD, rat: > 25,100 mg/kg
Repeated inhalation exposure of animals to Carbon Black caused
inflammation of the respiratory tract, lungs and emphysema.
Repeated exposure to high doses of Carbon Black by ingestion or
skin contact caused no significant toxicological effects.
No adequate studies have been conducted in animals to define the
carcinogenicity of Carbon Black by ingestion. In several skin
painting studies using various Carbon Blacks no carcinogenicity
was observed. Tests by inhalation for carcinogenicity in rats
show significant increases in lung tumors in female rats but not
male rats. In another study using female mice exposed by
inhalation to Carbon Black there was no increase in the incidence
of respiratory tract tumors. Researchers conducting the rat
inhalation studies believe that these effects probably result from
the massive accumulation of small dust particles in the lung which
overwhelm the normal lung clearance mechanisms. This represents
"lung overload" phenomenon, rather than a specific chemical effect
of the dust particle in the lung.
Tests have shown that this material does not cause genetic damage
in bacterial or mammalian cell cultures. Tests in animals for
genetic toxicity have produced mostly negative results. No animal
data are available to define developmental or reproductive
toxicity.
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Material Safety Data Sheet
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ECOLOGICAL INFORMATION
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Ecotoxicological Information
AQUATIC TOXICITY:
No information is available. Toxicity is expected to be low based
on insolubility in water.
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DISPOSAL CONSIDERATIONS
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Waste Disposal
Preferred options for disposal are (1) recycling, (2) incin-
eration with energy recovery, and (3) landfill. The high fuel
value of this product makes option 2 very desirable for material
that cannot be recycled. Treatment, storage, transportation, and
disposal must be in accordance with applicable federal,
state/provincial, and local regulations.
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TRANSPORTATION INFORMATION
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Shipping Information
DOT
Proper Shipping Name : Not regulated
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REGULATORY INFORMATION
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U.S. Federal Regulations
TSCA Inventory Status : In compliance with TSCA Inventory
requirements for commercial purposes.
State Regulations (U.S.)
STATE RIGHT-TO-KNOW
No substances on the state hazardous substances list, for the
states indicated below, are used in the manufacture of products on
this Material Safety Data Sheet, with the exceptions indicated.
SUBSTANCES ON THE PENNSYLVANIA HAZARDOUS SUBSTANCES LIST PRESENT
AT A CONCENTRATION OF 1 % OR MORE (0.01% FOR SPECIAL HAZARDOUS
SUBSTANCES)- Zinc Stearate, Carbon Black, Zinc.
WARNING - SUBSTANCES KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM- Carbon Black (BK
Types).
SUR032 DuPont Page 10
Material Safety Data Sheet
(REGULATORY INFORMATION - Continued)
The State of California, under Proposition 65, regulates Carbon
Black - airborne, unbound particles of respirable size as a
carcinogen. In this product, carbon black is not supplied in the
form regulated in California.
SUBSTANCES ON THE NEW JERSEY WORKPLACE HAZARDOUS SUBSTANCE LIST
PRESENT AT A CONCENTRATION OF 1% OR MORE (O.1% FOR SUBSTANCES
IDENTIFIED AS CARCINOGENS, MUTAGENS OR TERATOGENS)- Zinc Stearate,
Carbon Black, Zinc.
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OTHER INFORMATION
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Additional Information
MEDICAL USE: CAUTION: Do not use in medical applications
involving permanent implantation in the human body. For other
medical applications see DuPont CAUTION Bulletin No. H-50102.
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The data in this Material Safety Data Sheet relates only to the
specific material designated herein and does not relate to use in
combination with any other material or in any process.
Responsibility for MSDS : T. P. PRICE
DUPONT PACKAGING & INDUSTRIAL POLYMERS
Address : CHESTNUT RUN PLAZA 713
WILMINGTON, DE 19880-0713
Telephone : 302-999-4664
# Indicates updated section.
This information is based upon technical information believed to be
reliable. It is subject to revision as additional knowledge and
experience is gained.
End of MSDS
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