The MSDS format adheres to the standards and regulatory requirements
of the United States and may not meet regulatory requirements
in other countries.
DuPont Page 1
Material Safety Data Sheet
----------------------------------------------------------------------
POLYETHYLENE RESINS ALL IN SYNONYM LIST DPE018
DPE018 Revised 5-AUG-2003
----------------------------------------------------------------------
----------------------------------------------------------------------
CHEMICAL PRODUCT/COMPANY IDENTIFICATION
----------------------------------------------------------------------
# Tradenames and Synonyms
DPE 20, 20-6064, 2010, 2020, 2020T,
Company Identification
MANUFACTURER/DISTRIBUTOR
DuPont Packaging & Industrial Polymers
1007 Market Street
Wilmington,DE 19898
PHONE NUMBERS
Product Information : 1-(800)-441-7515
Transport Emergency : 1-(800)-424-9300
Medical Emergency : 1-(800)-441-3637
----------------------------------------------------------------------
COMPOSITION/INFORMATION ON INGREDIENTS
----------------------------------------------------------------------
Components
Material CAS Number %
ETHYLENE HOMOPOLYMER 9002-88-4 >99
Components (Remarks)
Material is not known to contain Toxic Chemicals under Section 313
of Title III of the Superfund Amendments and Reauthorization Act
of 1986 and 40 CFR part 372.
----------------------------------------------------------------------
HAZARDS IDENTIFICATION
----------------------------------------------------------------------
Potential Health Effects
ADDITIONAL HEALTH EFFECTS
Before using DuPont Polyethylene Resins, read the bulletin on the
safe handling of these polymers.
ACUTE OR IMMEDIATE EFFECTS: ROUTES OF ENTRY AND SYMPTOMS
INGESTION Not a probable route of exposure. The LD-50 in rats
of one type of polyethylene is 8 grams/kilogram body weight; this
classifies polyethylene as having low toxicity. Ninety day
feeding tests at the 5% level in rats produced no adverse effects.
DPE018 DuPont Page 2
Material Safety Data Sheet
(HAZARDS IDENTIFICATION - Continued)
SKIN Animal tests with polyethylene showed no evidence for skin
irritation or sensitization. No dermatitis problem is expected
from routine handling of the polymer. Molten polymer contacting
the skin will cause thermal burns.
EYE Mechanical irritation only.
INHALATION Polyethylene pellets are not respirable as sold. At
processing temperatures above 325 C (617 F), fumes irritating to
the eyes, nose and throat may be produced. This exposure may
result in redness, tearing and itching of the eyes and soreness in
the nose and throat together with coughing.
Carcinogenicity Information
None of the components present in this material at concentrations
equal to or greater than 0.1% are listed by IARC, NTP, OSHA or ACGIH
as a carcinogen.
----------------------------------------------------------------------
FIRST AID MEASURES
----------------------------------------------------------------------
First Aid
INHALATION
If exposed to fumes from overheating or combustion, move to fresh
air. Consult a physician.
SKIN CONTACT
The compound is not likely to be hazardous by skin contact but
cleansing the skin after use is advisable.
If molten material gets on skin, cool rapidly with cold water. Do
not attempt to remove material from skin. Obtain medical treatment
for thermal burn.
EYE CONTACT
In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes. Call a physician.
INGESTION
No specific intervention is indicated as compound is not likely to
be hazardous by ingestion. Consult a physician if necessary.
DPE018 DuPont Page 3
Material Safety Data Sheet
----------------------------------------------------------------------
FIRE FIGHTING MEASURES
----------------------------------------------------------------------
Flammable Properties
Flash Point : 341-365 C (646-689 F)
Method : ASTM D1929
Fire and Explosion Hazards:
UNUSUAL FIRE, EXPLOSION HAZARDS The solid polymer can be
combusted only with difficulty. An electrostatic charge can
potentially build up when pouring pellets. Grounding of equipment
is recommended.
HAZARDOUS COMBUSTION PRODUCTS Complete combustion gives carbon
dioxide and water. Incomplete combustion gives in addition carbon
monoxide, organic acids, aldehydes and alcohols.
Extinguishing Media
Water, Foam, Dry Chemical, CO2.
Fire Fighting Instructions
Wear self-contained breathing apparatus (SCBA) and full protective
equipment.
----------------------------------------------------------------------
ACCIDENTAL RELEASE MEASURES
----------------------------------------------------------------------
Safeguards (Personnel)
NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL)
sections before proceeding with clean-up. Use appropriate
PERSONAL PROTECTIVE EQUIPMENT during clean-up.
Spill Clean Up
Sweep up to avoid slipping hazard.
----------------------------------------------------------------------
HANDLING AND STORAGE
----------------------------------------------------------------------
Handling (Personnel)
See FIRST AID and PERSONAL PROTECTIVE EQUIPMENT SECTIONS.
Storage
Store in a cool, dry place. Keep container closed to prevent
contamination.
DPE018 DuPont Page 4
Material Safety Data Sheet
----------------------------------------------------------------------
EXPOSURE CONTROLS/PERSONAL PROTECTION
----------------------------------------------------------------------
Engineering Controls
VENTILATION: Local ventilation should be used over processing
equipment.
Personal Protective Equipment
EYE/FACE PROTECTION
Wear safety glasses. Wear coverall chemical splash goggles and
face shield when possibility exists for eye and face contact due
to splashing or spraying of molten material.
RESPIRATORS
A NIOSH/MSHA approved air purifying respirator with an organic
vapor cartridge with a dust/mist filter may be permissible under
certain circumstances where airborne concentrations are expected
to exceed exposure limits. Use a positive pressure air supplied
respirator if there is any potential for an uncontrolled release,
exposure levels are not known, or any other circumstances where
air purifying respirators may not provide adequate protection.
PROTECTIVE CLOTHING
If there is potential contact with hot/molten material, wear heat
resistant clothing and footwear.
Exposure Guidelines
Exposure Limits
POLYETHYLENE RESINS ALL IN SYNONYM LIST DPE018
PEL (OSHA) : Particulates (Not Otherwise Regulated)
15 mg/m3, 8 Hr. TWA, total dust
5 mg/m3, 8 Hr. TWA, respirable dust
Other Applicable Exposure Limits
ETHYLENE HOMOPOLYMER
PEL (OSHA) : None Established
TLV (ACGIH) : None Established
AEL * (DuPont) : 10 mg/m3, 8 & 12 Hr. TWA, total dust
5 mg/m3, 8 & 12 Hr. TWA, respirable dust
* AEL is DuPont鈥檚 Acceptable Exposure Limit. Where governmentally
imposed occupational exposure limits which are lower than the AEL
are in effect, such limits shall take precedence.
DPE018 DuPont Page 5
Material Safety Data Sheet
----------------------------------------------------------------------
PHYSICAL AND CHEMICAL PROPERTIES
----------------------------------------------------------------------
Physical Data
Melting Point : 110-140 C (230-284 F)
% Volatiles : NA
Solubility in Water : Negligible
Odor : Mild hydrocarbon
Form : Pellets
Color : White
Specific Gravity : 0.90-0.98
----------------------------------------------------------------------
STABILITY AND REACTIVITY
----------------------------------------------------------------------
Chemical Stability
Stable at normal temperatures and storage conditions.
Conditions to Avoid
Temperatures above 325 C (617 F) .
Incompatibility with Other Materials
None reasonably foreseeable.
Decomposition
HAZARDOUS DECOMPOSITION PRODUCTS Carbon monoxide and hydrocarbon
oxidation products including organic acids, aldehydes and alcohols.
Polymerization
Polymerization will not occur.
----------------------------------------------------------------------
ECOLOGICAL INFORMATION
----------------------------------------------------------------------
Ecotoxicological Information
AQUATIC TOXICITY:
No information is available. Toxicity is expected to be low based
on insolubility in water.
----------------------------------------------------------------------
DISPOSAL CONSIDERATIONS
----------------------------------------------------------------------
Waste Disposal
Preferred options for disposal are (1) recycling, (2) incin-
eration with energy recovery, and (3) landfill. The high fuel
value of this product makes option 2 very desirable for material
that cannot be recycled. Treatment, storage, transportation, and
disposal must be in accordance with applicable federal,
DPE018 DuPont Page 6
Material Safety Data Sheet
(DISPOSAL CONSIDERATIONS - Continued)
state/provincial, and local regulations.
----------------------------------------------------------------------
TRANSPORTATION INFORMATION
----------------------------------------------------------------------
Shipping Information
DOT
Proper Shipping Name : Not regulated
----------------------------------------------------------------------
REGULATORY INFORMATION
----------------------------------------------------------------------
U.S. Federal Regulations
TSCA Inventory Status : In compliance with TSCA Inventory
requirements for commercial purposes.
State Regulations (U.S.)
STATE RIGHT-TO-KNOW LAWS
No substances on the state hazardous substances list, for the
states indicated below, are used in the manufacture of products on
this Material Safety Data Sheet.
SUBSTANCES ON THE PENNSYLVANIA HAZARDOUS SUBSTANCES LIST PRESENT
AT A CONCENTRATION OF 1% OR MORE (0.01% FOR SPECIAL HAZARDOUS
SUBSTANCES): None known.
WARNING: SUBSTANCES KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM: None known.
SUBSTANCES ON THE NEW JERSEY WORKPLACE HAZARDOUS SUBSTANCE LIST
PRESENT AT A CONCENTRATION OF 1 % OR MORE (0.1% FOR SUBSTANCES
IDENTIFIED AS CARCINOGENS, MUTAGENS OR TERATOGENS): None known.
----------------------------------------------------------------------
OTHER INFORMATION
----------------------------------------------------------------------
----------------------------------------------------------------------
The data in this Material Safety Data Sheet relates only to the
specific material designated herein and does not relate to use in
combination with any other material or in any process.
Responsibility for MSDS : T. P. PRICE
DUPONT PACKAGING & INDUSTRIAL POLYMERS
Address : CHESTNUT RUN PLAZA 713
WILMINGTON, DE 19880-0713
Telephone : 302-999-4664
# Indicates updated section.
DPE018 DuPont Page 7
Material Safety Data Sheet
(Continued)
This information is based upon technical information believed to be
reliable. It is subject to revision as additional knowledge and
experience is gained.
End of MSDS
|