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MSDS Material Safety Data Sheet
CAS

25750-23-6

File Name: msds_dupont_com---PEN_09004a2f800065a9.asp
 The MSDS format adheres to the standards and regulatory requirements
of the United States and may not meet regulatory requirements
in other countries.

DuPont Page 1
Material Safety Data Sheet

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"SELAR" PA BARRIER RESINS ALL IN SYNONYM LIST SEL003
SEL003 Revised 15-NOV-2006
----------------------------------------------------------------------
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CHEMICAL PRODUCT/COMPANY IDENTIFICATION
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Material Identification

"SELAR" is a registered trademark of DuPont.

Tradenames and Synonyms

"SELAR" PA 2072, PA 3426, PA 3426D, PA 3426L, PA 3427, #
"SELAR" PA 4002, PA 4002L,
"SELAR" PA 5092,

Company Identification

MANUFACTURER/DISTRIBUTOR
DuPont Packaging & Industrial Polymers
1007 Market Street
Wilmington,DE 19898

PHONE NUMBERS
Product Information : 1-(800)-441-7515
Transport Emergency : 1-(800)-424-9300
Medical Emergency : 1-(800)-441-3637

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COMPOSITION/INFORMATION ON INGREDIENTS
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Components

Material CAS Number %
POLYAMIDE 25750-23-6 >99

Components (Remarks)

Material is not known to contain Toxic Chemicals under Section 313
of Title III of the Superfund Amendments and Reauthorization Act
of 1986 and 40 CFR part 372.

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HAZARDS IDENTIFICATION
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Potential Health Effects

Before using "SELAR" PA Barrier Resins, read the bulletin
"Safety in Handling and Use".

ACUTE OR IMMEDIATE EFFECTS: ROUTES OF ENTRY AND SYMPTOMS

INGESTION No data are available. Ingestion is not a
probable route of exposure. Based on its similarity with
other polymers, "SELAR" resins are predicted to have low
SEL003 DuPont Page 2
Material Safety Data Sheet

(HAZARDS IDENTIFICATION - Continued)

toxicity.

SKIN No data are available. However, based on experience
with handling these polymers, contact with resin may cause
mild irritation of skin. Molten polymer contacting the skin
will cause thermal burns.

EYE Contact with processing vapors may cause severe eye
irritation.

INHALATION Polymer is not respirable as sold. At
processing temperatures above 340 degrees C, fumes
irritating to the eyes, nose and throat may be produced.
This exposure may result in reddening, tearing, and itching
of the eyes and soreness in the nose and throat together
with coughing.

MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE None known.

Carcinogenicity Information

None of the components present in this material at concentrations
equal to or greater than 0.1% are listed by IARC, NTP, OSHA or ACGIH
as a carcinogen.

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FIRST AID MEASURES
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First Aid

INHALATION

If inhaled, remove to fresh air. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen.
Call a physician.

If exposed to fumes from overheating or combustion, move to fresh
air. Consult a physician if symptoms persist.

SKIN CONTACT

In case of contact, immediately wash skin with soap and water.
Wash contaminated clothing before reuse.
If molten material gets on skin, cool rapidly with cold water. Do
not attempt to remove material from skin. Obtain medical treatment
for thermal burn.

EYE CONTACT

In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes. Call a physician.

INGESTION
SEL003 DuPont Page 3
Material Safety Data Sheet

(FIRST AID MEASURES - Continued)

Not a probable route. However, in case of accidental ingestion,
call a physician.

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FIRE FIGHTING MEASURES
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Flammable Properties

Flash Point : NE

Fire and Explosion Hazards:

UNUSUAL FIRE, EXPLOSION HAZARDS The solid polymer can be
combusted only with difficulty. An electrostatic charge can
potentially build up when pouring pellets. Grounding of equipment
is recommended.

Like most organic powders or crystals, under severe dusting
conditions, this material may form explosive mixtures in air.

Hazardous gases/vapors produced in fire are aldehydes, ammonia,
carbon monoxide, and, oxides of nitrogen.

Extinguishing Media

Water, Foam, Dry Chemical, CO2.

Fire Fighting Instructions

Keep personnel removed and upwind of fire. Wear self-contained
breathing apparatus (SCBA) and full protective equipment.

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ACCIDENTAL RELEASE MEASURES
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Safeguards (Personnel)

NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL)
sections before proceeding with clean-up. Use appropriate
PERSONAL PROTECTIVE EQUIPMENT during clean-up.

Spill Clean Up

Sweep up to avoid slipping hazard.
SEL003 DuPont Page 4
Material Safety Data Sheet

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HANDLING AND STORAGE
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Handling (Personnel)

See FIRST AID and PERSONAL PROTECTIVE EQUIPMENT SECTIONS.

Storage

Store in a cool, dry place. Keep containers tightly closed to
prevent moisture absorption and contamination.

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EXPOSURE CONTROLS/PERSONAL PROTECTION
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# Engineering Controls

When hot processing this material, use sufficient ventilation to
keep employee exposure to vapors and fumes below recommended
limits.

In cutting or grinding operations with this material, use local
exhaust to control the concentration of dust below exposure limits.

Personal Protective Equipment

EYE/FACE PROTECTION

Wear safety glasses. Wear coverall chemical splash goggles and
face shield when possibility exists for eye and face contact due
to splashing or spraying of molten material.

RESPIRATORS

When temperatures exceed 340 degrees C and ventilation is
inadequate to maintain concentrations below exposure limits, use a
positive pressure air supplied respirator. Air purifying
respirators may not provide adequate protection.

During grinding, sanding, or sawing operations use a NIOSH/MSHA
approved air purifying respirator with dust/mist cartridge or
canister if airborne particulate concentrations are expected to
exceed permissible exposure levels.

PROTECTIVE CLOTHING

If there is potential contact with hot/molten material, wear heat
resistant clothing and footwear.

Exposure Guidelines
SEL003 DuPont Page 5
Material Safety Data Sheet

Exposure Limits
"SELAR" PA BARRIER RESINS ALL IN SYNONYM LIST SEL003
PEL (OSHA) : Particulates (Not Otherwise Regulated)
15 mg/m3, 8 Hr. TWA, total dust
5 mg/m3, 8 Hr. TWA, respirable dust

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PHYSICAL AND CHEMICAL PROPERTIES
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Physical Data

Melting Point : NA
% Volatiles : Negligible
Solubility in Water : Negligible
Odor : None.
Form : Granular.
Specific Gravity : NA

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STABILITY AND REACTIVITY
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Chemical Stability

Stable at normal temperatures and storage conditions.

Conditions to Avoid

Temperatures above 340 C (644 F) .

Incompatibility with Other Materials

Incompatible or can react with strong acids, and, oxidizing agents.

Decomposition

Decomposes with heat.

Decomposition temperature: Not determined

Hazardous gases or vapors can be released, including aldehydes,
ammonia, carbon monoxide, and, oxides of nitrogen.

Polymerization

Polymerization will not occur.

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ECOLOGICAL INFORMATION
----------------------------------------------------------------------
Ecotoxicological Information

AQUATIC TOXICITY:

No information is available. Do not discharge to streams, ponds,
lakes or sewers.
SEL003 DuPont Page 6
Material Safety Data Sheet

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DISPOSAL CONSIDERATIONS
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Waste Disposal

Preferred options for disposal are (1) recycling, (2) incin-
eration with energy recovery, and (3) landfill. The high fuel
value of this product makes option 2 very desirable for material
that cannot be recycled. Treatment, storage, transportation, and
disposal must be in accordance with applicable federal,
state/provincial, and local regulations.

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TRANSPORTATION INFORMATION
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Shipping Information

DOT/IMO/IATA
Not Regulated.

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REGULATORY INFORMATION
----------------------------------------------------------------------
U.S. Federal Regulations

TSCA Inventory Status : In compliance with TSCA Inventory
requirements for commercial purposes.

State Regulations (U.S.)

STATE RIGHT-TO-KNOW

No substances on the state hazardous substances list, for the
states indicated below, are used in the manufacture of products on
this Material Safety Data Sheet, with the exceptions indicated.

SUBSTANCES ON THE PENNSYLVANIA HAZARDOUS SUBSTANCES LIST PRESENT
AT A CONCENTRATION OF 1 % OR MORE (0.01% FOR SPECIAL HAZARDOUS
SUBSTANCES)- None known.

WARNING - SUBSTANCES KNOWN TO THE STATE OF CALIFORNIA TO CAUSE
CANCER, BIRTH DEFECTS OR OTHER REPRODUCTIVE HARM- None known.

SUBSTANCES ON THE NEW JERSEY WORKPLACE HAZARDOUS SUBSTANCE LIST
PRESENT AT A CONCENTRATION OF 1% OR MORE (O.1% FOR SUBSTANCES
IDENTIFIED AS CARCINOGENS, MUTAGENS OR TERATOGENS)- None known.
SEL003 DuPont Page 7
Material Safety Data Sheet

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OTHER INFORMATION
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Additional Information

MEDICAL USE: CAUTION: Do not use in medical applications
involving permanent implantation in the human body. For other
medical applications see DuPont CAUTION Bulletin No. H-50102.

----------------------------------------------------------------------

The data in this Material Safety Data Sheet relates only to the
specific material designated herein and does not relate to use in
combination with any other material or in any process.

Responsibility for MSDS : T. P. PRICE
DUPONT PACKAGING & INDUSTRIAL POLYMERS
Address : CHESTNUT RUN PLAZA 713
WILMINGTON, DE 19880-0713
Telephone : 302-999-4664

# Indicates updated section.

This information is based upon technical information believed to be
reliable. It is subject to revision as additional knowledge and
experience is gained.

End of MSDS

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