The MSDS format adheres to the standards and regulatory requirements
of the United States and may not meet regulatory requirements
in other countries.
DuPont Page 1
Material Safety Data Sheet
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"ZONYL" TA-N Fluorotelomer Intermediate
6115PP Revised 31-AUG-2007
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CHEMICAL PRODUCT/COMPANY IDENTIFICATION
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Material Identification
"Zonyl" is a registered trademark of DuPont.
Corporate MSDS Number : DU008173
Company Identification
MANUFACTURER/DISTRIBUTOR
DuPont
1007 Market Street
Wilmington, DE 19898
PHONE NUMBERS
Product Information : 1-800-441-7515 (outside the U.S.
302-774-1000)
Transport Emergency : CHEMTREC 1-800-424-9300(outside U.S.
703-527-3887)
Medical Emergency : 1-800-441-3637 (outside the U.S.
302-774-1000)
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COMPOSITION/INFORMATION ON INGREDIENTS
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Components
Material CAS Number %
Perfluoroalkylethyl Acrylate Esters 65605-70-1 87-95
Perfluorohexylethyl Acrylate 17527-29-6 1-7
Perfluorooctylethyl Acrylate 27905-45-9 42-56
Perfluorodecylethyl Acrylate 17741-60-5 22-30
Perfluorododecylethyl Acrylate 34395-24-9 6-12
Perfluorotetradecylethyl Acrylate 34362-49-7 1-5
Perfluorohexadecylethyl Acrylate 65150-93-8 0.1-2
Water 7732-18-5 0-1
Perfluoroalkylethyl Alcohol 65530-60-1 0.1-4
678-39-7
1,1,2,2-Tetrahydroperfluoro-1-Decanol 0.1-2
865-86-1
1,1,2,2-Tetrahydroperfluoro-1-Dodecanol 0-1
Perfluoroalkylethyl Acrylate Polymer NOTAVAIL. 0.1-3
71215-70-8
Perfluoroalkylethyl Iodides (Telomer B) 1-4
Perfluorooctylethyl Iodide 2043-53-0 0.5-2
Perfluorodecylethyl Iodide 2043-54-1 0.2-1
6115PP DuPont Page 2
Material Safety Data Sheet
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HAZARDS IDENTIFICATION
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Potential Health Effects
Skin contact with the product may cause irritation.
Eye contact with the product may cause irritation.
The product contains Telomer B. Inhalation of Telomer B may
cause irritation of the upper respiratory passages with
coughing and discomfort.
Based on related products, inhalation of spray or mist may cause
nasal, throat, or lung irritation. Inhalation of large amounts of
respirable particles may be toxic to the lungs. Symptoms may be
modest initially, followed in hours by severe shortness of breath
requiring prompt medical attention.
Carcinogenicity Information
None of the components present in this material at concentrations
equal to or greater than 0.1% are listed by IARC, NTP, OSHA or ACGIH
as a carcinogen.
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FIRST AID MEASURES
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First Aid
INHALATION
If inhaled, remove to fresh air. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen.
Call a physician.
SKIN CONTACT
Flush skin with water after contact. Wash contaminated clothing
before reuse.
EYE CONTACT
In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes. Call a physician.
INGESTION
If swallowed, do not induce vomiting. Immediately give 2 glasses
of water. Never give anything by mouth to an unconscious person.
Call a physician.
6115PP DuPont Page 3
Material Safety Data Sheet
(FIRST AID MEASURES - Continued)
Notes to Physicians
Activated charcoal mixture may be administered. To prepare
activated charcoal mixture, suspend 50 grams activated charcoal in
400 mL water and mix thoroughly. Administer 5 mL/kg, or 350 mL
for an average adult.
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FIRE FIGHTING MEASURES
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Flammable Properties
Flash Point : >110 C (>230 F)
Method : PMCC
Hazardous decomposition products including carbon dioxide, carbon
monoxide, hydrogen fluoride, toxic gases or particles may be
formed during combustion. These products may cause severe eye,
nose, throat, and lung irritation or toxic effects.
Extinguishing Media
Water Spray, Foam, Dry Chemical, CO2.
Fire Fighting Instructions
Evacuate personnel to a safe area. Keep personnel removed and
upwind of fire. Wear self-contained breathing apparatus. Wear
full protective equipment.
Avoid breathing decomposition products.
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ACCIDENTAL RELEASE MEASURES
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Safeguards (Personnel)
NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL)
sections before proceeding with clean-up. Use appropriate
PERSONAL PROTECTIVE EQUIPMENT during clean-up.
Spill Clean Up
Soak up with sawdust, sand, oil dry or other absorbent material.
Shovel or sweep up.
6115PP DuPont Page 4
Material Safety Data Sheet
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HANDLING AND STORAGE
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Handling (Personnel)
Avoid breathing vapors or mist. Avoid contact with eyes, skin, or
clothing. Wash thoroughly after handling. Do not store or
consume food, drink, or tobacco in areas where they may become
contaminated with this material. Avoid circumstances that produce
respirable particles unless suitable ventilation and respirator
are used.
Storage
Keep container in a cool place. Store in a cool place. Keep
container tightly closed.
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EXPOSURE CONTROLS/PERSONAL PROTECTION
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Engineering Controls
Keep container tightly closed. Use only with adequate ventilation.
Vent heated extruder or dryer fumes outside work area. Do not
aerosolize. In spray applications, use airless type pressure
spray equipment at less than 60 psi, and exhaust ducts, drip pans,
or other design features to minimize worker exposure to mists and
overspray.
Personal Protective Equipment
EYE/FACE PROTECTION
Wear safety glasses or coverall chemical splash goggles.
RESPIRATORS
Where there is potential for airborne exposures wear NIOSH
approved respiratory protection.
PROTECTIVE CLOTHING
Where there is potential for skin contact have available and
wear as appropriate impervious gloves, apron, pants, and
jacket.
# Exposure Guidelines
6115PP DuPont Page 5
Material Safety Data Sheet
Applicable Exposure Limits
Perfluoroalkylethyl Alcohol
AEL * (DuPont) : 1 mg/m3, 8 Hr. TWA
0.5 mg/m3, 12 Hr. TWA
* AEL is DuPont鈥檚 Acceptable Exposure Limit. Where governmentally
imposed occupational exposure limits which are lower than the AEL
are in effect, such limits shall take precedence.
Exposure Guideline Comments
No AEL has been established for this product. Other
products with fluorinated material components have an AEL of
0.1 mg/m3 to 1 mg/m3 (8 hour TWA) for respirable size
aerosol particles.
Air monitoring studies conducted at customer sites indicate
that the use of the recommended low pressure (less than 60
psi) airless type, garden type or deck specific hand pump
sprayer with spray tip orifice minimum of 0.031 inches in
diameter does not produce respirable size aerosol particle
concentrations near the AEL.
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PHYSICAL AND CHEMICAL PROPERTIES
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Physical Data
Boiling Point : 100-220 C (212-428 F) @ 10 mm Hg Approx.
Vapor Density : >1 (Air = 1)
Melting Point : 50-60 C (122-140 F)
% Volatiles : <2 WT%
Solubility in Water : 0 WT%
pH : 5-7 @ 20 degC
Odor : Mild acrylic
Form : Semi-solid
Color : Colorless to Amber
Specific Gravity : 1.6 @ 45C
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STABILITY AND REACTIVITY
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Chemical Stability
Stable at normal temperatures and storage conditions.
Air inhibits polymerization.
Incompatibility with Other Materials
Incompatible with peroxides and free radical sources.
6115PP DuPont Page 6
Material Safety Data Sheet
(STABILITY AND REACTIVITY - Continued)
Decomposition
Decomposes with heat. Hazardous decomposition products including
carbon dioxide, carbon monoxide, hydrogen fluoride, toxic gases or
particles may be formed during combustion. These products may
cause severe eye, nose, throat, and lung irritation or toxic
effects.
Polymerization
Polymerization can occur.
Conditions leading to polymerization are free radical
sources, heat and UV light.
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TOXICOLOGICAL INFORMATION
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Animal Data
The product is a slight skin irritant in animals. In a
Bacterial Reverse Mutation Test with an Independent Repeat
Assay, the product did not cause a positive response in the
presence and absence of Aroclor-induced rat liver S9.
"Zonyl" TA-N was negative for the induction of structural
and numerical chromosome aberrations in the in vitro
mammalian chromosome aberration test using human peripheral
lymphocytes. The product was negative in salmonella gene
mutation and mammalian gene mutation assays. Product is not
biodegradable.
The product contains Telomer B.
Telomer B:
Inhalation ALC: 6 mg/L in rats
Oral LD50: >17,000 mg/kg in rats
Telomer B is not a skin irritant, is untested for eye
irritancy, and is not a skin sensitizer in animals. A
single inhalation exposure produced labored respiration,
weight loss, salivation, and prostration. A single
ingestion exposure produced labored respiration, weight
loss, and prostration.
6115PP DuPont Page 7
Material Safety Data Sheet
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DISPOSAL CONSIDERATIONS
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Waste Disposal
Treatment, storage, transportation, and disposal must be in
accordance with applicable Federal, State/Provincial, and Local
regulations.
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TRANSPORTATION INFORMATION
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Shipping Information
Not Regulated as a hazardous material by DOT, IMO, or IATA.
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REGULATORY INFORMATION
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U.S. Federal Regulations
TITLE III HAZARD CLASSIFICATIONS SECTIONS 311, 312
Acute : Yes
Chronic : No
Fire : No
Reactivity : No
Pressure : No
In compliance with TSCA Inventory requirements.
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OTHER INFORMATION
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NFPA, NPCA-HMIS
NPCA-HMIS Rating
Health :2
Flammability :1
Reactivity :1
Personal Protection rating to be supplied by user depending on use
conditions.
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The data in this Material Safety Data Sheet relates only to the
specific material designated herein and does not relate to use in
combination with any other material or in any process.
Responsibility for MSDS : MSDS Coordinator
Address : DuPont Chemical Solutions Enterprise
Wilmington, Delaware 19898
Telephone : 800-441-7515
# Indicates updated section.
6115PP DuPont Page 8
Material Safety Data Sheet
(Continued)
This information is based upon technical information believed to be
reliable. It is subject to revision as additional knowledge and
experience is gained.
End of MSDS
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