Page 1 of 8
MATERIAL SAFETY DATA SHEET CND-N-039
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 3.0 MSDS Revision Date: 01/01/2006
1. PRODUCT IDENTIFICATION
1.1 Product Name:
SUPER SHINEY
1.2 Chemical Name:
SOLVENT MIXTURE
1.3 Synonyms:
NA
1.4 Trade Names:
SUPER SHINEY
1.5 Product Use:
COSMETIC USE ONLY
1.6 Distributor鈥檚 Name:
CREATIVE NAIL DESIGN, INC.
1.7 Distributor鈥檚 Address:
1125 JOSHUA WAY, VISTA, CA USA, 92081
1.8 Emergency Phone:
CHEMTREC: 800-424-9300 / 703-527-3887
1.9 Business Phone:
800-833-NAIL (6245), 760-599-2900
2. HAZARD IDENTIFICATION
2.1 Hazard Identification:
NA
2.2 Routes of Entry: Inhalation: YES Absorption: YES Ingestion: YES
2.3 Effects of Exposure:
INGESTION: If product is swallowed, may cause nausea, vomiting and/or diarrhea and central nervous system depression.
EYES: Mildly to moderately irritating to the eyes. Symptoms of overexposure may include redness, itching, irritation and
watering.
SKIN: May be irritating to skin in some sensitive individuals, especially after prolonged and/or repeated contact.
INHALATION: Vapors of this product may be slightly irritating to the nose, throat and other tissues of the respiratory system.
Symptoms of overexposure can include coughing, wheezing, nasal congestion, and difficulty breathing. Inhalation of
vapors exceeding the levels listed in Section 2 (Composition & Ingredient Information) can cause central nervous
system depression (e.g., drowsiness, dizziness, headaches, nausea).
2.4 Symptoms of Overexposure:
EYES: Overexposure in eyes may cause redness, itching and watering.
SKIN: Symptoms of skin overexposure in some sensitive individuals may include redness, itching, and irritation of affected
areas.
2.5 Acute Health Effects:
EYES: Mild to moderate irritation to eyes near affected areas.
SKIN: Mild to moderate irritation to skin near affected areas.
INHALATION: High concentrations of vapors can cause drowsiness, dizziness, headaches and nausea.
2.6 Chronic Health Effects:
None known.
2.7 Target Organs:
Eyes, skin & respiratory system.
NA = Not Available; ND = Not Determined; NE = Not Established; C = Ceiling Limit; See Section 16 for Additional Definitions of Terms Used
NOTE: all WHMIS required information is included. It is located in appropriate sections based on the ANSI Z400.1-2004 format.
Page 2 of 8
MATERIAL SAFETY DATA SHEET CND-N-039
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 3.0 MSDS Revision Date: 01/01/2006
3. COMPOSITION & INGREDIENT INFORMATION
EXPOSURE LIMITS IN AIR (mg/m3)
ACGIH OSHA OTHER
TLV STEL PEL STEL IDLH
%
EINECS No.
CHEMICAL NAME(S) CAS No. RTECS No. ppm ppm ppm ppm ppm
BUTYL ACETATE 123-86-4 AF7350000 204-658-1 < 40.0 150 200 200 200 1700 150 TWA
TOLUENE 108-88-3 XS5250000 203-625-9 < 30.0 100 NE 150 NE NE
NITROCELLULOSE 9004-70-0 QW0970000 NA < 15.0 (10) NE (10) NE NE
ETHYL ACETATE 141-78-6 AH5425000 201-550-6 < 10.0 400 NE 400 NE 2000 400 TWA
NA
TRIMETHYL PENTANYL SA1420000 NE NE NE NE NE
6846-50-0 < 10.0
DIISOBUTYRATE
ISOPROPYL ALCOHOL 67-63-0 NT8050000 200-661-7 < 10.0 400 500 400 500 2000 400 TWA
NA NA
TOSYLAMIDE/FORMALDEHYDE
25035-71-6 < 5.0 NE NE NE NE NE
RESIN
SUCROSE ACETATE ISOBUTYRATE 126-13-6 WN6550000 204-771-6 < 2.0 NE NE NE NE NE
BENZOPHENONE-1 NA 235-795-5 < 1.0 NE NE NE NE NE
THE REMAINING COMPONENTS DO NOT CONTRIBUTE ANY
OTHER COMPONENTS PRESENT IN LESS THAN 1% CONCENTRATION BAL
SIGNIFICANT ADDITIONAL HAZARDS
4. FIRST AID MEASURES
4.1 First Aid:
INGESTION: DO NOT INDUCE VOMITING. Contact ChemTrec at 703-527-3887 or the nearest Poison Control Center or local
emergency telephone number for assistance and instructions. Seek immediate medical attention. If vomiting occurs
spontaneously, keep victim鈥檚 head lowered (forward) to reduce the risk of aspiration.
EYES: Splashes are not likely; however, if product gets in the eyes, flush with copious amounts of lukewarm water for at least
15 minutes. Open and close eyelid(s) to ensure thorough irrigation. If irritation occurs, contact a physician.
SKIN: If irritation occurs and product is on the skin, rinse thoroughly with lukewarm water, followed by a thorough washing of
the affected area with soap and water. Do not wear contaminated clothing until after it has been properly cleaned. If
irritation, redness or swelling persists, contact a physician immediately.
INHALATION: Remove victim to fresh air at once. Under extreme conditions, if breathing has stopped, perform artificial respiration.
Seek immediate medical attention.
4.2 Medical Conditions Aggravated by Exposure:
None known.
Page 3 of 8
MATERIAL SAFETY DATA SHEET CND-N-039
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 3.0 MSDS Revision Date: 01/01/2006
5. FIREFIGHTING MEASURES
5.1 Flashpoint & Method:
-4 掳C (24 掳F) TCC Estimated based on ethyl acetate.
5.2 Autoignition Temperature:
NA
5.3 Flammability Limits: Lower Explosive Limit (LEL): NE Upper Explosive Limit (UEL): NE
5.4 Fire & Explosion Hazards:
WARNING: Extremely Flammable! Keep away from heat, lit cigarettes, sparks & open flame. Keep
container closed.
5.5 Extinguishing Methods:
CO2, Halon, Dry Chemical, Foam
5.6 Firefighting Procedures:
When involved in a fire, this product will ignite readily and decompose to produce carbon oxides.
First responders should wear eye protection. Structural firefighters must wear SCBAs and full protective
equipment. Use a water spray or fog to reduce or direct vapors. Water may not be effective in actually
extinguishing a fire involving this product.
6. ACCIDENTAL RELEASE MEASURES
6.1 Spills:
Before cleaning any spill or leak, individuals involved in spill cleanup must wear appropriate Personal Protective Equipment.
For small spills (e.g., <1 gallon) wear appropriate personal protective equipment (e.g., goggles, gloves). Maximize ventilation (open
doors and windows) and secure all sources of ignition. Remove spilled material with absorbent material and place into appropriate
closed container(s) for disposal. Dispose of properly in accordance with local, state and federal regulations. Wash all affected areas
and outside of container with plenty of warm water and soap. Remove any contaminated clothing and wash thoroughly before
reuse.
For spills 鈮? 1 gallon, deny entry to all unprotected individuals. Dike and contain spill with inert material (e.g., sand or earth). Use ONLY
non-sparking tools for recovery and cleanup. Transfer liquid to containers for recovery or disposal and solid diking material to
separate containers for proper disposal. Remove contaminated clothing promptly and wash affected skin areas with soap and water.
Keep spills and cleaning runoffs out of municipal sewers and open bodies of water.
7. HANDLING & STORAGE INFORMATION
7.1 Work & Hygiene Practices:
Avoid prolonged contact with the product. Avoid breathing vapors of this product. Use in a well-ventilated location (e.g., local
exhaust ventilation, fans). Do not eat, drink or smoke while handling product.
7.2 Storage & Handling:
Keep this material away from heat, sparks and open flame. Open containers slowly on a stable surface. Keep container closed
tightly when not in use. Empty container may contain residual amounts of this product; therefore, empty containers should be
handled with care.
Store containers in a cool, dry location, away from direct sunlight, other light sources, or sources of intense heat. Store away from
incompatible materials (see Section 10).
7.3 Special Precautions:
Open containers slowly on a stable surface. Keep container tightly closed when not in use. Empty containers may contain residual
amounts of this product; therefore, empty containers should be handled with care.
Page 4 of 8
MATERIAL SAFETY DATA SHEET CND-N-039
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 3.0 MSDS Revision Date: 01/01/2006
8. EXPOSURE CONTROLS & PERSONAL PROTECTION
8.1 Ventilation & Engineering Controls:
When working with large quantities of product, provide adequate ventilation (e.g., local exhaust ventilation, fans). Ensure that an
eyewash station, sink or washbasin is available in case of exposure to eyes.
8.2 Respiratory Protection:
No special respiratory protection is required under typical circumstances of use or handling. If necessary, use only respiratory
protection authorized per U.S. OSHA's requirement in 29 CFR 搂1910.134, or applicable U.S. state regulations, or the appropriate
standards of Canada, its provinces, E.C. member states, or Australia.
8.3 Eye Protection:
None required under normal conditions of use. Avoid eye contact. May cause irritation in some sensitive individuals. When handling
large quantities (e.g., 鈮? 1 gallon), safety glasses with side shields should be used.
8.4 Hand Protection:
None required under normal conditions of use. May cause skin irritation in some sensitive individuals.
When handling large quantities (e.g., 鈮? 1 gallon), wear rubber or impervious plastic gloves.
HEALTH 1
8.5 Body Protection:
No apron required when handling small quantities.
FLAMMABILITY 3
When handling large quantities (e.g., 鈮? 1 gallon), eye wash stations and deluge
showers should be available. Upon completion of work activities involving large
REACTIVITY 0
quantities of this product, wash any exposed areas thoroughly with soap and water.
PROTECTIVE EQUIPMENT
9. PHYSICAL & CHEMICAL PROPERTIES
9.1 Density: 0.948 - 0.984 calculated
9.2 Boiling Point: 171 鈥? 228 掳F calculated
9.3 Melting Point: NA
9.4 Evaporation Rate: 2-3 (n-Butyl Acetate = 1) calculated
9.5 Vapor Pressure: 35 - 42 mm Hg calculated
9.6 Molecular Weight: NA
9.7 Appearance & Color: Violet colored viscous liquid with a strong ester-like odor.
9.8 Odor Threshold: ND
9.9 Solubility: Moderately soluble in water.
9.10 pH NA
9.11 Viscosity: NA
9.12 Other Information: Vapor density 3.2 - 3.6 @ 20 掳C (68 掳F) (air = 1) calculated
10. STABILITY & REACTIVITY
10.1 Stability: Stable under ambient conditions when stored properly (see Section 7, Storage and Handling).
10.2 Hazardous Decomposition Products: If exposed to extremely high temperatures, the products of thermal decomposition may include
irritating vapors and carbon oxide gases (e.g., CO, CO2).
10.3 Hazardous Polymerization: Will not occur.
10.4 Conditions to Avoid: None reported.
10.5 Incompatible Substances: This product is incompatible with strong oxidizers (e.g., peroxides, superoxides), strong acids (e.g.,
hydrochloric or muriatic acids), or strong bases (e.g., lye, potassium hydroxide).
Page 5 of 8
MATERIAL SAFETY DATA SHEET CND-N-039
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 3.0 MSDS Revision Date: 01/01/2006
11. TOXICOLOGICAL INFORMATION
This product has not been tested on animals to obtain toxicological data. There are toxicology data
11.1 Toxicity Data:
for the components of this product, which are found in the scientific literature. These data have not
been presented in this document.
11.2 Acute Toxicity: See Section 3.5
11.3 Chronic Toxicity: See Section 3.6
11.4 Suspected Carcinogen: This product contains Isopropyl Alcohol, which is classified as a Group 3 carcinogen (not classifiable
as a human carcinogen) by the IARC.
11.5 Reproductive Toxicity: This product is not reported to cause reproductive toxicity in humans.
Mutagenicity: This product is not reported to produce mutagenic effects in humans.
Embryotoxicity: This product is not reported to produce embryotoxic effects in humans.
Teratogenicity: This product is not reported to cause teratogenic effects in humans.
Reproductive Toxicity: This product is not reported to cause reproductive effects in humans.
11.6 Irritancy of Product: See Section 3.3
11.7 Biological Exposure Indices: NE
11.8 Physician Recommendations: Treat symptomatically.
12. ECOLOGICAL INFORMATION
12.1 Environmental Stability:
The components of this product will slowly degrade over time into a variety of organic compounds.
Specific environmental data available for the components of this product are as follows:
Butyl Acetate: KOC = 1.82. Water solubility: 120 parts H2O at 25 掳C (77掳F). Bioconcentration Factor = 4-
14. Bioconcentration is not anticipated to be significant. This compound can be removed from
contaminated environments from volatilization, and biodegradation. This compound鈥檚 half-life in
water is 6.1 hours.
Ethyl Acetate: KOC = 0.73. Water solubility: 64,000 mg/l. Bioconcentration Factor = 4-14.
Bioconcentration is not anticipated to be significant. This compound can be removed from
contaminated environments from volatilization, and biodegradation. This compound鈥檚 half-life in
water is 6.1 hours.
Isopropyl Alcohol: Log KOW = 0.05-0.14. Isopropyl alcohol occurs naturally; it is generated during
microbial degradation of plant and animal wastes. When released on land or water, it is apt to
volatilize and biodegrade. The estimated half-life in water is 5.4 days. Isopropyl alcohol is not
expected to bioconcentrate.
12.2 Effects on Plants & Animals: There are no specific data available for this product.
12.3 Effects on Aquatic Life: There are no specific data available for this product; however, very large releases of this product
may be harmful or fatal to overexposed aquatic life.
13. DISPOSAL CONSIDERATIONS
13.1 Waste Disposal:
Waste disposal must be in accordance with appropriate Federal, state, and local regulations.
13.2 Special Considerations:
U.S. EPA WASTE NUMBER: D001 (characteristic - ignitable)
Page 6 of 8
MATERIAL SAFETY DATA SHEET CND-N-039
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 3.0 MSDS Revision Date: 01/01/2006
14. TRANSPORTATION INFORMATION
The basic description (proper shipping name, hazard class & division, ID Number, packing group) is shown for each mode of transportation.
Additional descriptive information may be required by 49 CFR, IATA/ICAO, IMDG and the CTDGR.
14.1 49 CFR (GND):
CONSUMER COMMODITY, ORM-D (鈮? 1.0 L)
PAINT, 3, UN1263, II (> 1.0 L)
14.2 IATA (AIR):
CONSUMER COMMODITY, 9, ID8000 (鈮? 0.5 L)
PAINT, 3, UN1263, II (> 0.5 L)
14.3 IMDG (OCN):
PAINT, 3, UN1263, II, LTD QTY (鈮? 1.0 L)
PAINT, 3, UN1263, II (> 1.0 L)
14.4 TDGR (Canadian GND):
MARK PACKAGE "LIMITED QUANTITY" or "QUANTIT脡 LIMIT脡E" or "LTD QTY" or "QUANT LT脡E" (鈮? 1.0 L)
PAINT, 3, UN1263, II (> 1.0 L)
14.5 ADR/RID (EU):
1263 PAINT, 3, 3 掳(b), ADR, LTD QTY (鈮? 1.0 L)
15. REGULATORY INFORMATION
15.1 SARA Reporting Requirements:
SARA 304 (40 CFR Table 302.4) - Butyl Acetate, Ethyl Acetate
15.2 SARA Threshold Planning Quantity:
There are no specific Threshold Planning Quantities for the components of this product.
15.3 TSCA Inventory Status:
The components of this product are listed on the TSCA Inventory.
15.4 CERCLA Reportable Quantity (RQ):
Butyl Acetate: 5000 lbs.; Toluene: 1000 lbs.
15.5 Other Federal Requirements:
This product complies with the appropriate sections of the Food and Drug Administration's 21 CFR subchapter G (Cosmetics).
15.6 Other Canadian Regulations:
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of
the information required by the CPR. The components of this product are listed on the DSL/NDSL. None
of the components of this product are listed on the Priorities Substances List. Class B2 Flammable Liquid.
15.7 State Regulatory Information:
Toluene, Butyl Acetate, Ethyl Acetate, and Isopropyl Alcohol are covered under specific state criteria. Components of this product
are not listed on the California Proposition 65 lists or they are exempt from the requirements.
15.8 67/548/EEC (European Union) Requirements:
The primary component of this product is not listed in Annex I of EU Directive 67/548/EEC:
Butyl Acetate: Flammable (F). R: Flammable. S: 9-16-33 - Keep container in a well-ventilated place.
Keep away from sources of ignition - No smoking. Take precautionary measures against static
discharges.
Toluene: Flammable, Harmful (F, Xn). R: 11-20-36/37 鈥? Highly flammable. Harmful by inhalation. Irritating
to eyes and respiratory system. S: 2-7-16-24/25/26 鈥? Keep out of the reach of children. Keep container
tightly closed. Avoid contact with skin and eyes. In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice. Do not empty into drains. Take precautionary measures
against static discharges.
Page 7 of 8
MATERIAL SAFETY DATA SHEET CND-N-039
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 3.0 MSDS Revision Date: 01/01/2006
16. OTHER INFORMATION
16.1 Other Information:
WARNING: EXTREMEMLY FLAMMABLE! Keep away from heat or flame. Avoid inhalation. Store in a cool place. Keep out of reach of
children.
16.2 Terms & Definitions:
See page 8 of this MSDS.
16.3 Disclaimer:
This Material Safety Data Sheet is offered pursuant to OSHA鈥檚 Hazard Communication Standard, 29 CFR 搂1910.1200. Other
government regulations must be reviewed for applicability to this product. To the best of ShipMate's & Creative Nail Design's
knowledge, the information contained herein is reliable and accurate as of this date; however, accuracy, suitability or completeness
are not guaranteed and no warranties of any type, either expressed or implied, are provided. The information contained herein
relates only to the specific product(s). If this product(s) is combined with other materials, all component properties must be
considered. Data may be changed from time to time. Be sure to consult the latest edition.
16.4 Prepared for:
Creative Nail Design, Inc.
1125 Joshua Way
Vista, CA 92081
800-833-NAIL (6245) phone
760-599-2900
760-599-4005 fax
http://www.creativenaildesign.com/
16.5 Prepared by:
ShipMate, Inc.
18436 Hawthorne Boulevard, Suite 201
Torrance, CA 90504
310-360-3700 phone
310-360-5700 fax
http://www.shipmate.com/
Page 8 of 8
MATERIAL SAFETY DATA SHEET CND-N-039
Prepared to OSHA, ACC, ANSI, WHMIS & 2001/58 EC Standards MSDS Revision: 3.0 MSDS Revision Date: 01/01/2006
DEFINITION OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these that are commonly used include the following:
GENERAL INFORMATION:
OTHER STANDARD ABBREVIATIONS:
CAS No. Chemical Abstract Service Number
NA Not Available
EXPOSURE LIMITS IN AIR: NR No Results
NE Not Established
ACGIH American Conference on Governmental Industrial Hygienists
ND Not Determined
TLV Threshold Limit Value
ML Maximum Limit
OSHA U.S. Occupational Safety and Health Administration
SCBA Self-Contained Breathing Apparatus
PEL Permissible Exposure Limit
IDLH Immediately Dangerous to Life and Health NATIONAL FIRE PROTECTION ASSOCIATION: NFPA
HAZARD RATINGS:
FIRST AID MEASURES:
FLAMMABILITY
0 Minimal Hazard REACTIVITY
Cardiopulmonary resuscitation - method in which a person 1 Slight Hazard
whose heart has stopped receives manual chest compressions 2 Moderate Hazard
CPR
and breathing to circulate blood and provide oxygen to the 3 Severe Hazard
body.
4 Extreme Hazard
ACD Acidic
HMIS庐
HAZARDOUS MATERIALS IDENTIFICATION
ALK Alkaline
SYSTEM: HMIS SPECIAL
HEALTH
COR Corrosive PRECAUTIONS
HEALTH W Use No Water
HEALTH, FLAMMABILITY & REACTIVITY RATINGS:
OX Oxidizer
FLAMMABILITY
0 Minimal Hazard
TOXICOLOGICAL INFORMATION:
1 Slight Hazard
2 Moderate Hazard REACTIVITY Lethal Dose (solids & liquids) which kills 50% of the
LD50
3 Severe Hazard exposed animals s
4 Extreme Hazard PERSONAL PROTECTION
Lethal concentration (gases) which kills 50% of the
LC50
exposed animal
NCCHL44T 漏 NPCA Printed by Labelmaster, A, American Labelmark Co., Chicago, IL 60646 (800) 621-5808
PERSONAL PROTECTION RATINGS: Concentration expressed in parts of material per million
ppm
parts
TDlo Lowest dose to cause a symptom
A G
TCLo Lowest concentration to cause a symptom
TDlo, LDlo, & LDo or Lowest dose (or concentration) to cause lethal or toxic
B H TC, TCo, LClo, & LCo effects
IARC International Agency for Research on Cancer
NTP National Toxicology Program
C I
RTECS Registry of Toxic Effects of Chemical Substances
BCF Bioconcentration Factor
D J TLm Median threshold limit
log KOW or log KOC Coefficient of Oil/Water Distribution
E K
REGULATORY INFORMATION:
Consult your supervisor or S.O.P. WHMIS Canadian Workplace Hazardous Material Information System
F X
for special handling directions. DOT U.S. Department of Transportation
TC Transport Canada
EPA U.S. Environmental Protection Agency
DSL Canadian Domestic Substance List
NDSL Canadian Non-Domestic Substance List
Face Shield &
Safety Glasses Splash Goggles Gloves PSL Canadian Priority Substances List
Eye Protection
TSCA U.S. Toxic Substance Control Act
EU European Union (European Union Directive 67/548/EEC)
CPR Canada鈥檚 Controlled Product Regulations
Synthetic Apron
Boots Full Suit Dust Respirator
EC INFORMATION:
Full Face
Dust & Vapor Airline
Vapor Respirator Respirator Respirator Hood/Mask or
Note: the dotted circle indicates that this respiratory
protective equipment is required for high concentrations
C E F N O T+ Xi Xn
or for large volume spills or releases of product.
Corrosive Explosive Flammable Harmful Oxidizing Toxic Irritant Harmful
FLAMMABILITY LIMITS IN AIR:
WHMIS INFORMATION:
Autoignition Minimum temperature required to initiate combustion in air
Temperature with no other source of ignition
Lower Explosive Limit - lowest percent of vapor in air, by
LEL volume, that will explode or ignite in the presence of an
ignition source
Upper Explosive Limit - highest percent of vapor in air, by A B C D1 D2 D3 E F
volume, that will explode or ignite in the presence of an
UEL Compressed Flammable Oxidizing Toxic Irritation Infectious Corrosive Reactive
ignition source
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