REVISION DATE: August 2006
SAFETY DATA SHEET
FERROIN INDICATOR SOLUTION
1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND COMPANY/UNDERTAKING
PRODUCT NAME FERROIN INDICATOR SOLUTION
PRODUCT NO. 1122
APPLICATION General chemical reagent
SUPPLIER Reagent Chemical Services
18 Aston Fields Road
Whitehouse Industrial Estate
Runcorn
Cheshire WA7 3DL
T: 01928 716903
F: 01928 716425
E: info@reagent.co.uk
2 COMPOSITION/INFORMATION ON INGREDIENTS
Name EC No. CAS-No. Content Classification
1,10-PHENANTHROLINE 200-629-2 66-71-7 1-5% T;R25 N;R50/53
IRON II SULPHATE LRG 231-729-4 7782-63-0 <1 Xn;R22.
The Full Text for all R-Phrases are Displayed in Section 16
3 HAZARDS IDENTIFICATION
Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
CLASSIFICATION R52/53.
4 FIRST-AID MEASURES
INHALATION
Remove victim immediately from source of exposure. Provide rest, warmth and fresh air. Get medical attention if any discomfort
continues.
INGESTION
Do not induce vomiting. Immediately rinse mouth and drink plenty of water (200-300 ml). Get medical attention immediately!
SKIN CONTACT
Immediately remove contaminated clothing. Wash the skin immediately with soap and water. Get medical attention if irritation persists
after washing.
EYE CONTACT
Promptly wash eyes with plenty of water or eye wash solution while lifting the eyelids.If possible remove any contact lenses and continue to
wash. Get medical attention.
5 FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA
The product is non-combustible. Use fire-extinguishing media appropriate for surrounding materials.
SPECIFIC HAZARDS
In cases of fire, toxic fumes may be formed.
PROTECTIVE MEASURES IN FIRE
Self contained breathing apparatus and full protective clothing must be worn in case of fire.
6 ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS
Wear protective clothing as described in Section 8 of this safety data sheet.
SPILL CLEAN UP METHODS
Small Spillages Absorb with sand or other inert absorbent. Large Spillages Dam and absorb spillages with sand, earth or other
non-combustible material. Collect spillage in containers, seal securely and deliver for disposal according to local regulations. Flush area
clean with lots of water. Be aware of potential for surfaces to become slippery.
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FERROIN INDICATOR SOLUTION
7 HANDLING AND STORAGE
USAGE PRECAUTIONS
Avoid spilling, skin and eye contact.
STORAGE PRECAUTIONS
Store in tightly closed original container in a dry and cool place.
STORAGE CLASS
Chemical storage.
8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Name Std LT - ppm LT - mg/m3 ST - ppm ST - mg/m3
IRON II SULPHATE LRG 1 as Fe mg/m3 2 as Fe mg/m3
ENGINEERING MEASURES
Provide adequate ventilation.
RESPIRATORY EQUIPMENT
No specific recommendation made, but respiratory protection may still be required under exceptional circumstances when excessive air
contamination exists.
HAND PROTECTION
Wear protective gloves. Rubber or plastic The most suitable glove must be chosen in consultation with the gloves supplier, who can inform
about the breakthrough time of the glove material.
EYE PROTECTION
Wear safety glasses. If risk of splashing, wear safety goggles or face shield.
HYGIENE MEASURES
Wash at the end of each work shift and before eating, smoking and using the toilet. Wash promptly if skin becomes wet or contaminated.
Promptly remove any clothing that becomes wet or contaminated. When using do not eat, drink or smoke.
9 PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE Liquid
COLOUR Red
ODOUR Odourless
SOLUBILITY Miscible with water.
BOILING POINT (掳C) 100 RELATIVE DENSITY 1.01
pH-VALUE, CONC. SOLUTION 4-7
10 STABILITY AND REACTIVITY
STABILITY
Stable under normal temperature conditions.
11 TOXICOLOGICAL INFORMATION
HEALTH WARNINGS
Although not classified as hazardous, the product should be treated with the care and attention appropriate to chemicals.
12 ECOLOGICAL INFORMATION
ECOTOXICITY
Harmful to aquatic organisms, may cause long term adverse effects in the aquatic environment.
13 DISPOSAL CONSIDERATIONS
DISPOSAL METHODS
Dispose of waste and residues in accordance with local authority requirements.
14 TRANSPORT INFORMATION
No transport warning sign required.
ADR CLASS MARINE POLLUTANT No.
Not classified for
transportation.
15 REGULATORY INFORMATION
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REVISION DATE: August 2006
FERROIN INDICATOR SOLUTION
RISK PHRASES
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
SAFETY PHRASES
S60 This material and its container must be disposed of as hazardous waste.
STATUTORY INSTRUMENTS
Chemicals (Hazard Information and Packaging) Regulations. Control of Substances Hazardous to Health.
APPROVED CODE OF PRACTICE
Classification and Labelling of Substances and Preparations Dangerous for Supply. COSHH essentials: Easy steps to control chemicals.
Control of Substances Hazardous to Health Regulations.
GUIDANCE NOTES
Occupational Exposure Limits EH40. Introduction to Local Exhaust Ventilation HS(G)37.
NATIONAL REGULATIONS
Control of Substances Hazardous to Health Regulations 2002 (as amended)
16 OTHER INFORMATION
REVISION COMMENTS
Changes to sections 4, 5, 6 and 8.
REVISION DATE August 2006
REV. NO./REPL. SDS GENERATED Supercedes issue March 2004
SDS NO. 10704
SAFETY DATA SHEET STATUS
Approved.
RISK PHRASES IN FULL
R22 Harmful if swallowed.
R25 Toxic if swallowed.
R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
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