UNITED 31
MATERIAL SAFETY DATA SHEET
320 37th Avenue, St. Charles, Illinois 60174 鈥? 214 Dolomite Drive, Downsview, Ontario M3J2N2 To Reorder Call:
www.unitedlabsinc.com 800-323-2594
1. PRODUCT AND COMPANY IDENTIFICATION FOR MEDICAL AND TRANSPORTATION EMERGENCIES
24 Hour INFOTRAC (US and CANADA): 800-535-5053
PRODUCT NAME USE/DESCRIPTION REVISION DATE
UNITED 31 NoCRAX Rubberized Crack Filler February 23, 2006
1 0
HEALTH (0 = Maximum Safety) REACTIVITY (0 = Maximum Safety)
Always follow Label Directions and Cautions.
Susceptible to Release of Energy.
Always follow Label Directions and Cautions.
Always follow Label Directions and Cautions.
4 May detonate-vacate area if 2 Violent chemical change
4 Extreme 3 High 2 Moderate 1 Slight 0 Minimal
4 materials are exposed to fire. possible-use hose stream
3 Strong shock of heat may from distance
See Hazards Identification Section of this MSDS
detonate-use monitors from 1 Unstable if heated-use
for more detailed information.
behind explosion resistant precaution.
barriers. 0 Normally stable.
0
FLAMMABILITY (0 = Maximum Safety)
Susceptibility of Material to Burning.
PERSONAL PROTECTION
4 Extremely flammable. 1 Must be preheated
3 Ignites at normal temperature. to burn.
2 Ignites when moderately heated. 0 Will not burn.
2. COMPOSITION/INFORMATION ON INGREDIENTS
ACGIH OSHA LD50 LC50
Hazardous Ingredients CAS# %Range (TLV) (STEL) (Species/Route) (Species)
0.5 mg/m3 10 mg/m3
Petroleum asphalt 8052-42-4 < 35% NE NE
(Fumes) (Fumes)
Polymer 9003-55-8 < 15% NE NE NE NE
3. HAZARDS IDENTIFICATION
Eyes: May cause irritation, blurred vision.
Skin: Prolonged or repeated contact may cause irritation.
Inhalation: Massive exposure may cause headache, dizziness, and/or drowsiness.
Ingestion: May cause vomiting, nausea, and diarrhea. Aspiration of material into the lungs during vomiting may cause chemical
pneumonitis.
4. FIRST AID MEASURES
Eyes: Immediately flush with plenty of water for at least 15 minutes. Get prompt medical attention.
Skin: Wash with soap and plenty of water. If symptoms develop, seek medical attention.
Inhalation: Remove to fresh air. If symptoms develop, seek medical attention. If not breathing, give artificial respiration.
Ingestion: DO NOT induce vomiting. Get medical attention immediately. If vomiting occurs, have victim lean forward to reduce risk of
aspiration.
5. FIRE FIGHTING MEASURES
Flash Point (TCC): 460 F/238 C Explosive Limits: Lower (LEL): ND Upper (UEL): ND
Flame Projection (Aerosol): NA
Hazardous Products of Combustion: When strongly heated, as in a fire, this product may produce oxides of carbon and nitrogen.
Fire and Explosion Hazards: Water sprayed on burning material may cause frothing, steam and eruptions. Closed containers may
explode when exposed to extreme heat.
Extinguishing Media: Dry chemical, Dry foam, Carbon dioxide
Fire Fighting Instructions: Wear self-contained breathing apparatus w/full protective clothing. Containers should be cooled with water
to prevent vapor pressure build up.
6. ACCIDENTAL RELEASE MEASURES
Small Spills: Soak up with an inert absorbent and place in designated disposal container. Wash area thoroughly.
Large Spills: Remove sources of ignition. Soak up with an inert absorbent and place in designated disposal container. Wash area
thoroughly.
-1-
7. HANDLING AND STORAGE
Keep containers tightly closed when not in use. Store in a cool, dry, well-ventilated area. Protect from freezing.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Eyes: Safety glasses recommended
Skin: Chemical resistant gloves recommended
Respiratory: None required if good ventilation is maintained.
Engineering Controls: Mechanical ventilation recommended when handling in enclosed/tight spaces.
9. PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point: 212F/100C Specific Gravity: 1.32 (H2O=1) Vapor Pressure: ND Melting Point: ND
Vapor Density: >1 (Air=1) Evaporation Rate: <1 (Ether=1) Solubility in Water: Soluble pH: NA
Appearance and Odor: Brown/Black emulsion with slight petroleum scent.
10. STABILITY AND REACTIVITY
Hazardous Polymerization: NA
Hazardous Decomposition: When strongly heated, as in a fire, this product may produce oxides of carbon and nitrogen.
Chemical Stability: Stable
Incompatibility: Oxidizing agents such as bleach.
11. TOXICOLOGICAL INFORMATION
Carcinogenicity (NTP/IARC/OSHA): Carbon Black and Crystalline Silica by IARC. Evidence from respirable carbon black in animals.
Inadequate evidence of such effects in humans. Neither are present in respirable form.
California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth
defects or other reproductive harm? Yes, contains detectable amounts.
12. ECOLOGICAL INFORMATION
ND
13. DISPOSAL CONSIDERATIONS
Consult your local, state and federal regulations for proper disposal guidelines. Disposal regulations may be different for each state
and/or locality.
14. TRANSPORT INFORMATION
DOT: Available upon request.
TDG: Available upon request.
UN: Available upon request.
15. REGULATORY INFORMATION
VOC(Volatile Organic Compounds): ND
TSCA (Toxic Substances Control Act): Listed
SARA Title III Section 302 EHS: ND
SARA Title III Section 311/312: ND
SARA Title III Section 313 Toxic Chemicals: None
WHMIS Classification:
This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations/ WHMIS) and the
MSDS contains all the information required by the CPR.
16. OTHER INFORMATION
Read and follow all label directions and precautions before using this product. These products are intended for industrial and institutional
use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF REACH OF CHILDREN.
UNITED 31 NoCRAX PREPARED BY:Nancy Sherrel
-2-
UNITED 31 (Tubes)
MATERIAL SAFETY DATA SHEET
320 37th Avenue, St. Charles, Illinois 60174 鈥? 214 Dolomite Drive, Downsview, Ontario M3J2N2 To Reorder Call:
www.unitedlabsinc.com 800-323-2594
1. PRODUCT AND COMPANY IDENTIFICATION FOR MEDICAL AND TRANSPORTATION EMERGENCIES
24 Hour INFOTRAC (US and CANADA): 800-535-5053
PRODUCT NAME USE/DESCRIPTION REVISION DATE
UNITED 31 NoCRAX (Tubes) Rubberized Crack Filler February 22, 2006
2 0
HEALTH (0 = Maximum Safety) REACTIVITY (0 = Maximum Safety)
Always follow Label Directions and Cautions.
Susceptible to Release of Energy.
Always follow Label Directions and Cautions.
Always follow Label Directions and Cautions.
4 May detonate-vacate area if 2 Violent chemical change
4 Extreme 3 High 2 Moderate 1 Slight 0 Minimal
4 materials are exposed to fire. possible-use hose stream
3 Strong shock of heat may from distance
See Hazards Identification Section of this MSDS
detonate-use monitors from 1 Unstable if heated-use
for more detailed information.
behind explosion resistant precaution.
barriers. 0 Normally stable.
3
FLAMMABILITY (0 = Maximum Safety)
Susceptibility of Material to Burning.
PERSONAL PROTECTION
4 Extremely flammable. 1 Must be preheated
3 Ignites at normal temperature. to burn.
2 Ignites when moderately heated. 0 Will not burn.
2. COMPOSITION/INFORMATION ON INGREDIENTS
ACGIH OSHA LD50 LC50
Hazardous Ingredients CAS# %Range (TLV) (STEL) (Species/Route) (Species)
4300 mg/kg 5000 ppm
Xylol 1330-20-7 10-30 100 ppm 150 ppm
(Rat/oral) 4 hr. Rat
MICA 12001-26-2 10-20 10 mg/m3 * NE NE NE
3500 mg/kg
Ethylbenzene 100-41-4 1-5 100 ppm 125 ppm NE
(Rat/oral)
Carbon black 1333-86-4 5-10 3.5 mg/m3 NE NE NE
* As respirable fraction of dust.
3. HAZARDS IDENTIFICATION
Eyes: May cause slight irritation.
Skin: Prolonged or repeated contact may cause irritation.
Inhalation: Massive exposure may cause headache, dizziness, and/or drowsiness.
Ingestion: May cause vomiting, nausea, and diarrhea. Aspiration of material into the lungs during vomiting may cause chemical
pneumonitis. Overexposure to xylol has been suggested as a cause of the following effects in humans: Cardiac abnormality, liver and
kidney damage.
4. FIRST AID MEASURES
Eyes: Immediately flush with plenty of water for at least 15 minutes. Get prompt medical attention.
Skin: Wash with soap and plenty of water. If symptoms develop, seek medical attention.
Inhalation: Remove to fresh air. If symptoms develop, seek medical attention. If not breathing, give artificial respiration.
Ingestion: DO NOT induce vomiting. Get medical attention immediately. If vomiting occurs, have victim lean forward to reduce risk of
aspiration.
5. FIRE FIGHTING MEASURES
Flash Point (TCC): 80 F/26 C Explosive Limits: Lower (LEL): ND Upper (UEL): ND
Flame Projection (Aerosol): NA
Hazardous Products of Combustion: When strongly heated, as in a fire, this product may produce oxides of carbon and nitrogen.
Fire and Explosion Hazards: Water sprayed on burning material may cause frothing, steam and eruptions. Closed containers may
explode when exposed to extreme heat.
Extinguishing Media: Dry chemical, Dry foam, Carbon dioxide
Fire Fighting Instructions: Wear self-contained breathing apparatus w/full protective clothing. Containers should be cooled with water
to prevent vapor pressure build up.
-1-
6. ACCIDENTAL RELEASE MEASURES
Small Spills: Soak up with an inert absorbent and place in designated disposal container. Wash area thoroughly.
Large Spills: Remove sources of ignition and ventilate area. Soak up with an inert absorbent and place in designated disposal
container. Wash area thoroughly.
7. HANDLING AND STORAGE
Keep containers tightly closed when not in use. Store in a cool, dry, well-ventilated area. Protect from freezing.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Eyes: Safety glasses recommended
Skin: Chemical resistant gloves recommended
Respiratory: None required if good ventilation is maintained.
Engineering Controls: Mechanical ventilation recommended when handling in enclosed/tight spaces.
9. PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point: 275F/135C Specific Gravity: 1.031 (H2O=1) Vapor Pressure: ND Melting Point: ND
Vapor Density: >1 (Air=1) Evaporation Rate: <1 (Ether=1) Solubility in Water: Insoluble pH: NA
Appearance and Odor: Black paste with xylol scent.
10. STABILITY AND REACTIVITY
Hazardous Polymerization: NA
Hazardous Decomposition: When strongly heated, as in a fire, this product may produce oxides of carbon and nitrogen.
Chemical Stability: Stable
Incompatibility: Oxidizing agents such as bleach.
11. TOXICOLOGICAL INFORMATION
Carcinogenicity (NTP/IARC/OSHA): None
California Proposition 65: Does this product contain chemical(s) known to the State of California to cause cancer and/or to cause birth
defects or other reproductive harm? None
12. ECOLOGICAL INFORMATION
ND
13. DISPOSAL CONSIDERATIONS
Consult your local, state and federal regulations for proper disposal guidelines. Disposal regulations may be different for each state
and/or locality.
14. TRANSPORT INFORMATION
DOT: Available upon request.
TDG: Available upon request.
UN: Available upon request.
15. REGULATORY INFORMATION
VOC(Volatile Organic Compounds): < 45% by volume
TSCA (Toxic Substances Control Act): Listed
SARA Title III Section 302 EHS: ND
SARA Title III Section 311/312: ND
SARA Title III Section 313 Toxic Chemicals: Xylol C# 1330-20-7; Ethylbenzene C# 100-41-4
WHMIS Classification:
This product has been classified in accordance with the hazard criteria of the CPR (Controlled Products Regulations/ WHMIS) and the
MSDS contains all the information required by the CPR.
16. OTHER INFORMATION
Read and follow all label directions and precautions before using this product. These products are intended for industrial and institutional
use only. NOT FOR HOUSEHOLD USE OR RESALE. KEEP OUT OF REACH OF CHILDREN.
UNITED 31 NoCRAX (Tubes) PREPARED BY:Nancy Sherrel
-2-
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