Good News Spray #111 http://www.weito.com/spray111.htm
WEI T'O庐 ASSOCIATES, INC.
MATERIAL SAFETY DATA SHEET
GOOD NEWS SPRAY NO. 111
IDENTIFICATION
PRODUCT NAME WEI T'O庐 GOOD NEWS SPRAY NO. 111
MANUFACTURER Wei T'o庐 Associates, Inc.
21750 Main Street, Unit 27
Matteson, IL 60443-3702
TEL: 708/747-6660 FAX: 708/747-6639
PRODUCT INFORMATION NUMBER
E-Mail: weito@weito.com
CHEMTREC: 800/424-9300
EMERGENCY PHONE
PHYSICAL DATA
-13oF (-25oC) 99%
BOILING POINT PERCENT VOLATILE BY WEIGHT
0.70 g/cc at 25oC
LIQUID DENSITY OZONE DEPLETION POTENTIAL 0
140
3.0 at 25oC
VAPOR DENSITY (Air=1) GLOBAL WARMING POTENTIAL
(100 yr. Integrated Time Horizon)
Yes
APPEARANCE VOLATILE ORGANIC COMPOUND
Clear, colorless liquid.
Faint solvent odor.
63 psig at 70oF
VAPOR PRESSURE
INGREDIENTS
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Materials CAS Number % By Weight Exposure Limits
Isopentanes 78-78-4 >85 600 ppm (ACGIH)
1000 ppm (Dupont AEL,
1,1,Difluoroethane 75-37-6 >5
WEEL-AIHA)
Other Name: HFC-152a
400 ppm (ACGIH, OSHA,
Isopropanol 67-63-0 <10
NIOSH, DFG MAKs)
Other Names :
Rubbing Alcohol
Isopropyl Alcohol
2-Propanol, Isopropyl
1000 ppm, (ACGIH, OSHA,
Ethanol 64-17-5 <<1
NIOSH, DFG MAKs)
Other Name : Ethyl Alcohol
Isopropyl/ethyl magnesium carbonates >2 None established
HAZARDOUS REACTIVITY
INSTABILITY
Material is stable. However, avoid open flames and high temperatures.
INCOMPATIBILITY
Alkali or alkaline earth metals - powdered Al, Zinc, Beryllium, etc.
DECOMPOSITION
This compound can be decomposed by high temperatures (open flames, glowing metal surfaces, etc.) forming
hydrofluoric acid, and possibly carbonyl halides.
POLYMERIZATION
Will not occur.
FIRE AND EXPLOSION DATA
FLASH POINT FLAMMABLE LIMITS (% by VOLUME IN AIR)
o LEL: 1.4, UEL: 8.3
<-60 F
AUTOIGNITION TEMPERATURE AUTODECOMPOSITION TEMPERATURE
Not determined Not determined
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FIRE AND EXPLOSION HAZARD
Carbon oxides formed when burned. Highly flammable vapors which are heavier than air may accumulate in
low areas and/or spread along ground away from handling site. Flash back along vapor trail is possible.
FIRE EXTINGUISHING MEDIA
Dry chemical, Foam, or Carbon Dioxide (CO2)
SPECIAL FIREFIGHTING INSTRUCTIONS
Evacuate area of all unnecessary personnel. Wear appropriate safety equipment for fire conditions including
NIOSH/MSHA(1) self-contained breathing apparatus (SCBA). Shut off source if possible. Water fog or spray
may be used to cool exposed containers and equipment. Do not spray water directly on fire - product will float
and could be reignited on surface of water.
HEALTH HAZARD INFORMATION
EFFECTS OF SINGLE OVEREXPOSURE
An unlikely route of exposure, but frostbite of the lips and mouth may result from
SWALLOWING:
contact with the liquid. If swallowed, may be aspirated resulting in inflammation and
(INGESTION)
possible fluid accumulation in the lungs.
Prolonged or widespread skin contact with the liquid may result in frost bite or
SKIN
absorption of harmful amounts of material. Vapors are not irritating. Prolonged or
ABSORPTION:
repeated exposure may cause defatting of the skin leading to skin irritation.
Vapors may be mildly irritating. High concentrations may cause dizziness,
INHALATION:
disorientation, headache, excitation, anesthesia, and central nervous system
depression. The inhalation LC50 (rats) for isopentane is greater than 4094.27 ppm
for a four hour exposure period and fourteen days post-exposure observation period.
Liquid may cause frostbite. Vapors are not irritating.
SKIN CONTACT:
Vapors may be mildly irritating.
EYE CONTACT:
EFFECTS OF REPEATED OVEREXPOSURE
No evidence of adverse effects from available information.
OTHER EFFECTS OF OVEREXPOSURE
At very high concentrations may produce cardiac arrhythmia's or arrest due to sensitization of the heart to
adrenaline and noradrenaline. Exposure to fluorocarbon thermal decomposition products may produce flu-like
symptoms including chills, fever, weakness, muscular aches, headache, chest discomfort, sore throat, and dry
cough. Complete recovery usually occurs within 24 hours after exposure.
MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE
A knowledge of the available toxicology information and of the physical and chemical properties of the material
suggests that overexposure is unlikely to aggravate existing medical conditions.
SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN HEALTH HAZARD
EVALUATION
None currently known.
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CARCINOGEN CITY INFORMATION
None of the components present in this material at concentrations equal to or greater than 0.1% are listed by
IARC, NTP, OSHA, or ACGIH as a carcinogen.
HEALTH HAZARD CATEGORIES
Animal Human
Known Carcinogen _____ _____
_____ _____
Suspect Carcinogen
Mutagen _____ _____
_____ _____
Teratogen
Allergic Sensitizer _____ _____
_____ _____
Highly Toxic
Toxic _____ _____
_____ _____
Corrosive
Irritant _____ _____
Target Organ Toxin __X__ __X__
Specify - Lung Aspiration Hazard If Ingested
EMERGENCY AND FIRST AID PROCEDURES
If a large volume (several ounces) has been swallowed, obtain immediate medical
SWALLOWING:
attention. Do not induce vomiting.
(INGESTION)
For exposure to liquid, immediately warm frostbite area with warm water (not to
SKIN:
exceed 105oF). In case of massive exposure, remove clothing while showering with
warm water. Obtain medical attention.
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Remove to fresh air. Give artificial respiration if not breathing. Oxygen may be given
INHALATION:
by qualified personnel if breathing is difficult. Obtain medical attention.
Immediately flush eyes thoroughly with water and continue washing for at least 15
EYES:
minutes. Obtain medical attention, preferably from an ophthalmologist, urgently.
NOTES TO PHYSICIAN
1. Do not administer adrenaline due to the sensitizing effect of fluorocarbons on the
myocardium. Treatment of overexposure should be directed at the control of symptoms
and the clinical condition of the patient. Exposure to fluorocarbon pyrolysis products should
be considered in the diagnostic evaluation of occupationally related fever of short duration
and unknown origin. Signs of exposure include tachycardia, hyperpnoea, and pharyngeal
congestion; investigation may reveal pulmonary edema and leucocytes.
2. Gastric lavage using a cuffed endotracheal tube may be performed at your discretion.
PROTECTION INFORMATION
GENERALLY APPLICABLE CONTROL MEASURES
Normal ventilation for standard manufacturing procedures is generally adequate. Local exhaust should be used
when large amounts are released. Mechanical ventilation should be used in low places.
PERSONAL PROTECTIVE EQUIPMENT
Neoprene, nitrile or lined butyl gloves should be used to avoid prolonged or repeated exposure. Face shield or
Monogoggles should be worn as needed to prevent eye contact. Other protective equipment required: eye
bath, safety shower, chemical apron. Under normal use conditions, no respiratory protection is required when
using this product. Self-contained breathing apparatus (SCBA) is required if a large spill occurs.
SPILL, LEAK, AND DISPOSAL PROCEDURES
PRECAUTIONS REQUIRED IF MATERIAL IS RELEASED OR SPILLED:
Evacuate area of all unnecessary personnel. Wear protective equipment and/or garments described in Section
on "Protection Information" above if exposure conditions warrant. Shut off source, if possible and contain spill.
Protect from ignition. Keep out of water sources and sewers. Absorb in a dry, inert material (sand, clay, etc.).
Transfer to disposal drums using non-sparking equipment.
WASTE DISPOSAL (INSURE CONFORMITY WITH ALL APPLICABLE DISPOSAL REGULATIONS):
Incinerate or place in permitted waste management facility. Recycle for reclamation of fluorocarbons.
DOT TRANSPORTATION
Shipping Name: Aerosols, Flammable
Hazard Class: 2.1
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UN 1950
ID Number:
Packing Group: NONE
Marking: Aerosols, Flammable, UN 1950
Label: Flammable Gas
Flammable Gas /1950
Placard:
Hazardous Substance/RQ: Not Applicable
Aerosols, Flammable, 2.1 (Flammable Gas),
Shipping Description:
UN 1950, PG. NONE
Packaging References: 49 CFR, 172.101, 173.306
CONSUMER COMMODITY PACKAGING INFORMATION
Packaging References: Consumer Commodity, ORM-D, I.D. None, PG None, Label None, 49 CFR 172.101,
173.306, Passenger/Cargo Aircraft 75/150 kg gross.
Wei T'o庐 offers this product for shipment packaged inside a pint size, aerosol spray, tin free welded steel can
packed in a strong corrugated paper carton containing one to six or twelve cans with outside packaging
marked "ORM-D CONSUMER COMMODITY."
RCRA CLASSIFICATION - UNADULTERATED PRODUCT AS A WASTE
Ignitable (D001)
Prior to disposal, consult your environmental contact to determine if TCLP (Toxicity) Characteristic Leaching
Procedure, (EPA Test Method 1311) is required. Reference 40 CFR Part 261.
PROTECTION REQUIRED FOR WORK ON CONTAMINATED EQUIPMENT
Contact immediate supervisor for specific instructions before work is initiated. Wear protective equipment
and/or garments described in Section on "Protection Information" above if exposure conditions warrant.
HAZARD CLASSIFICATION
This product meets the following hazard definition(s) as defined by the Occupational Safety and
Health Hazard Communication Standard (29 CFR Section 1910.1200):
_X_
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___ Combustible Liquid _X_Flammable Aerosol ___ Oxidizer
___ Compressed Gas ___ Explosive ___ Pyrophoric
___ Flammable Gas _X_ Health Hazard * ___ Unstable
___ Flammable Liquid ___ Organic Peroxide ___ Water Reactive
___ Flammable Solid
____ Based on information presently available, this product does not meet any of the hazard definitions
of 29 CFR Section 1910.1200.
* See Section on "Health Hazard Information," particularly "Health Hazard Categories."
REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS
TSCA INVENTORY STATUS: Report/Included
TITLE III HAZARD CLASSIFICATIONS SECTIONS 311,312
Acute: Yes
Chronic: No
Fire: Yes
Reactivity: No
Pressure: Yes
LISTS:
SARA Extremely Hazardous Substance -No
CERCLA Hazardous Substance -(*)
SARA Toxic Chemical -No
*See "Spill, Leak, and Disposal Procedures"
HFC-152a is a flammable gas as defined by OSHA in 29CFR 1910.1200(c). Use of this product may
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require compliance with 29CFR 1910.119, Process Safety Management of Highly Hazardous
Chemicals.
OTHER INFORMATION
NFPA, NPCA-HMIS
NPCA-HMIS Rating
Health: 1
Flammability: 4
Reactivity: 1
Personal Protection rating to be supplied by user depending on use conditions.
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