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MSDS Material Safety Data Sheet
CAS

9003-20-7
108-05-4

File Name: talasonline_com---ayatpolymer.asp
                           MATERIAL SAFETY DATA SHEET
EFFECTIVE DATE: 09/13/88
===============================================================================
I. IDENTIFICATION
===============================================================================
PRODUCT NAME: UNION CARBIDE Vinyl Acetate Polymer AYAT
CHEMICAL NAME: Acetic acid ethenyl ester, homopolymer
CHEMICAL FAMILY: Vinyl Resin
FORMULA: (CH2:CHOCOCH3)n MOLECULAR WEIGHT: Polymer
SYNONYMS: None
CAS # and 9003-20-7
CAS NAME: Acetic acid ethenyl ester, homopolymer
===============================================================================
II. PHYSICAL DATA (Determined on typical material)
===============================================================================
BOILING POINT, 760 mm Hg: Not applicable
SPECIFIC GRAVITY (H2O = 1): Bulk density, 42.0-46.9 lb/f
VAPOR DENSITY (air = 1): N/A
EVAPORATION RATE N/A
(Butyl Acetate = 1):
FREEZING POINT: Softening pt 118-122F(48-50C)
VAPOR PRESSURE at 20'C: N/A
SOLUBILITY IN WATER, by wt.: N/A
APPEARANCE AND ODOR
White solid; mild characteristic odor.
===============================================================================
III. INGREDIENTS
===============================================================================
MATERIAL % TLV (Units) HAZARD
-------------------------------------------------------------------------------
Polyvinylacetate 100 None established See Section V
Vinyl Acetate <2 See Section V See Section V
CAS 108-05-4
===============================================================================
IV. FIRE AND EXPLOSION HAZARD DATA
===============================================================================
FLASH POINT Not applicable
(test method(s)):

FLAMMABLE LIMITS IN AIR, LOWER: Not applicable
% by volume: UPPER: Not applicable

EXTINGUISHING MEDIA: Apply alcohol-type or all-purpose-type foams by
manufacturer's recommended techniques for large
fires. Use CO2 or dry chemical media for small
fires.

SPECIAL FIRE FIGHTING Do not direct a solid stream of water or foam
PROCEDURES: into burning molten material; this may cause
spattering and spread the fire. Use self-
contained breathing apparatus and body-covering
protective clothing.

UNUSUAL FIRE AND Avoid dispersion of dust in air to reduce
EXPLOSION HAZARDS: potential for dust explosions.
===============================================================================
V. HEALTH HAZARD DATA
===============================================================================
TLV AND SOURCE:
10 ppm, 20 ppm STEL for vinyl acetate, ACGIH 1987-88
-------------------------------------------------------------------------------
EFFECTS OF SINGLE OVEREXPOSURE:
-------------------------------
SWALLOWING: No evidence of adverse effects from available
information.

SKIN ABSORPTION: No evidence of adverse effects from available
information.

INHALATION: May cause irritation of the eyes and upper
respiratory tract.

SKIN CONTACT: No evidence of adverse effects from available
information.

EYE CONTACT: Vapors and liquid may cause minimal irritation.
-------------------------------------------------------------------------------
EFFECTS OF REPEATED OVEREXPOSURE:
This product contains residual vinyl acetate monomer. Repeated
exposure to high concentrations of vinyl acetate vapors
(approximately 200 ppm and greater) produced evidence of respiratory
tract irritation in laboratory animals.

MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE:
A knowledge of the available toxicology information and of the
physical and chemical properties of the material suggests that
overexposure is unlikely to aggravate existing medical conditions.

SIGNIFICANT LABORATORY DATA WITH POSSIBLE RELEVANCE TO HUMAN
HEALTH HAZARD EVALUATION:
Life-time exposure to high vapor concentrations (600 ppm) of vinyl
acetate caused tumors of the respiratory tract of laboratory animals;
this response possibly being associated with the irritant effect. No
carcinogenic effects were observed when laboratory animals received
vinyl acetate in drinking water (up to 0.5%) with exposure taking
place from the period of embryofetal development and continuing
throughout a major portion of their life span. There is no evidence
that vinyl acetate has caused cancer in humans. There should be
minimal risk when used with ventilation adequate to keep the
atmospheric concentration of vinyl acetate below the recommended
exposure limit. Male rats receiving vinyl acetate at high
concentrations in drinking water (0.5%) for two generations possibly
demonstrated a decreased ability to produce offspring.

OTHER EFFECTS OF OVEREXPOSURE:
None currently known.
-------------------------------------------------------------------------------
EMERGENCY AND FIRST AID PROCEDURES:
-----------------------------------
SWALLOWING: No harmful effects expected.

SKIN: Wash skin with soap and water.
INHALATION: Remove to fresh air.

EYES: Flush thoroughly with water. Seek medical
attention if irritation persists.

NOTES TO PHYSICIAN: Toxicology studies have shown similar materials
to be of very low acute toxicity and non-
irritant. There is no specific antidote.
Treatment of overexposure should be directed at
the control of symptoms and the clinical
condition.
===============================================================================
VI. REACTIVITY DATA
===============================================================================
STABILITY: Stable

CONDITIONS TO AVOID:
None
INCOMPATIBILITY (materials to avoid):
None

HAZARDOUS COMBUSTION OR DECOMPOSITION PRODUCTS:
Burning can produce oxides of carbon.

HAZARDOUS POLYMERIZATION: Will Not Occur

CONDITIONS TO AVOID:
None
===============================================================================
VII. SPILL OR LEAK PROCEDURES
===============================================================================
STEPS TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
Collect for disposal.

WASTE DISPOSAL METHOD:
Bury in a landfill where permitted under appropriate Federal, State
and local regulations.
===============================================================================
VIII. SPECIAL PROTECTION INFORMATION
===============================================================================
RESPIRATORY PROTECTION (specify type):
None required in normal use.

VENTILATION: General mechanical room ventilation is satisfactory for
normal handling and storage.

PROTECTIVE GLOVES: Plastic

EYE PROTECTION: Safety glasses

OTHER PROTECTIVE EQUIPMENT:
Eye bath and safety shower
===============================================================================
IX. SPECIAL PRECAUTIONS
===============================================================================
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE
FOR INDUSTRY USE ONLY
WARNING! Contains vinyl acetate - possible cancer hazard
-------------------------------------------------------------------------------
OTHER PRECAUTIONS
None

Prepared by: Russell P. Hill

UNION CARBIDE is a trademark of Union Carbide Corporation USA.

Date: 07/14/86
Revision Date: 09/20/88
PC: 76511
F NUMBER: U0499B

ISN: 102563

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