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Material Safety Data Sheet MSDS# 15-0432
Section 1. Chemical Product and Company Identification
ETHOMEEN庐 C/12
Product name
: Surfactant.
Material Uses In Case of Emergency
AKZO NOBEL SURFACE CHEMISTRY LLC CHEMTREC: 800-424-9300
Supplier/
525 West Van Buren CANUTEC: 613-996-6666
Manufacturer
Chicago, IL 60607-3823 Medical/Handling: 914-693-6946
Product/Technical: 800-906-9977
AKZO NOBEL CHEMICALS LTD.
1 City Centre Drive, Suite 318
Mississauga, Ontario L5B 1M2
Canada
Section 2. Composition, Information on Ingredients
Name CAS # % by Weight
Ethanol, 2,2'-iminobis-, n-coco alkyl derivs. 61791-31-9 97-100
Amines, coco alkyl 61788-46-3 0.001-3
N-(2-hydroxyethyl)cocoalkylamines Not Assigned 0.001-3
Poly(oxy-1,2-ethanediyl), a-hydroxy-w-hydroxy- 25322-68-3 0.001-2
Section 3. Hazards Identification
Liquid.
Physical State
Colorless to light yellow.
Color
Amine like.
Odor
DANGER!
Emergency Overview
CAUSES SKIN BURNS.
VERY TOXIC TO AQUATIC ORGANISMS.
CAUSES SEVERE EYE IRRITATION.
MAY BE HARMFUL IF SWALLOWED.
MAY CAUSE ALLERGIC SKIN REACTION.
Do not get on skin or clothing. Avoid contact with eyes. Do not ingest. Avoid breathing vapor or mist.
Avoid prolonged or repeated contact with skin. Keep container closed. Use only with adequate
ventilation. Wash thoroughly after handling. Avoid contact of spilled material and runoff with soil and
surface waterways.
Ethanol, 2,2'-iminobis-, n-coco alkyl derivs.: IARC, NTP, OSHA, ACGIH: Not listed.
Possible Carcinogenic
Amines, coco alkyl: IARC, NTP, OSHA, ACGIH: Not listed.
Effects
N-(2-hydroxyethyl)cocoalkylamines: IARC, NTP, OSHA, ACGIH: Not listed.
Poly(oxy-1,2-ethanediyl), a-hydroxy-w-hydroxy-: IARC, NTP, OSHA, ACGIH: Not listed.
Absorbed through skin. Dermal contact. Eye contact.
Routes of Entry
See Toxicological Information (section 11)
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ETHOMEEN庐 C/12
Section 4. First Aid Measures
Check for and remove any contact lenses. In case of contact, immediately flush eyes with plenty of
Eye Contact
water for at least 15 minutes. Cold water may be used. Get medical attention immediately.
In case of contact, immediately flush skin with plenty of water for at least 15 minutes while removing
Skin Contact
contaminated clothing and shoes. Wash clothing before reuse. Thoroughly clean shoes before reuse.
Get medical attention immediately.
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give
Inhalation
oxygen. Get medical attention.
Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by mouth
Ingestion
to an unconscious person. If large quantities of this material are swallowed, call a physician
immediately. Loosen tight clothing such as a collar, tie, belt or waistband.
Repeated or prolonged exposure is not known to aggravate medical condition.
Medical Conditions
Aggravated by
Overexposure
Section 5. Fire Fighting Measures
May be combustible at high temperature.
Flammability of the
Product
The lowest known value is >150掳C (302掳F) (Poly(oxy-1,2-ethanediyl), a-hydroxy-w-hydroxy-).
Auto-ignition
Temperature
Closed cup: >100掳C (212掳F). (Pensky-Martens.)
Flash Points
These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...).
Products of Combustion
SMALL FIRE: Use DRY chemical powder.
Fire Fighting Media
LARGE FIRE: Use water spray, fog or foam. Do not use water jet.
and Instructions
Be sure to use an approved/certified respirator or equivalent.
Protective Clothing (Fire)
Section 6. Accidental Release Measures
Absorb with an inert material and put the spilled material in an appropriate waste disposal. If necessary:
Small Spill and Leak
Use suitable protective equipment (Section 8).
Absorb with an inert material and put the spilled material in an appropriate waste disposal. Use suitable
Large Spill and Leak
protective equipment (Section 8).
Section 7. Handling and Storage
Avoid contact with eyes. Do not ingest. Avoid breathing vapors or spray mists. Avoid prolonged or
Handling
repeated contact with skin. Do not get on skin or clothing. Keep container closed. Use only with
adequate ventilation. Wash thoroughly after handling. Avoid contact of spilled material and runoff with
soil and surface waterways.
Keep container tightly closed. Keep container in a cool, well-ventilated area.
Storage
Section 8. Exposure Controls, Personal Protection
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors
Engineering Controls
below their respective occupational exposure limits. Ensure that eyewash stations and safety showers
are proximal to the work-station location.
Personal Protection
Splash goggles.
Eyes
Lab coat.
Body
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ETHOMEEN庐 C/12
Wear appropriate respirator when ventilation is inadequate.
Respiratory
Gloves.
Hands
Not applicable.
Feet
Protective Clothing
(Pictograms)
Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult
Personal Protection in
a specialist BEFORE handling this product.
Case of a Large Spill
Ingredient Name Exposure Limits United States
Ethanol, 2,2'-iminobis-, n-coco alkyl derivs. Not available.
Amines, coco alkyl Not available.
N-(2-hydroxyethyl)cocoalkylamines Not available.
Poly(oxy-1,2-ethanediyl), Not available.
a-hydroxy-w-hydroxy-
Section 9. Physical and Chemical Properties
Liquid.
Physical State
Colorless to light yellow.
Color
Amine like.
Odor
Not applicable.
Molecular Weight
Not applicable.
Molecular Formula
11 [Basic.]
pH
268掳C (514.4掳F)
Boiling/Condensation
Point
6掳C (42.8掳F)
Melting/Freezing Point
5oC
Cloud Point
8oC
Pour Point
0.899 g/cm3 (32掳C / 89.6掳F)
Density
<0.01 kPa (<0.1 mmHg) (at 20掳C)
Vapor Pressure
The highest known value is >10 (Air = 1) (Poly(oxy-1,2-ethanediyl), a-hydroxy-w-hydroxy-).
Vapor Density
Weighted average: 0.89compared to Butyl acetate.
Evaporation Rate
Very slightly soluble in cold water.
Solubility
Not available.
Dispersion Properties
Viscosity = 130cp @ 20oC; 75cp @ 30oC; 50cp @ 40oC; 34cp @ 50oC; 25cp @ 60oC; 18cp @ 80oC.
Physical Chemical
Comments
Section 10. Stability and Reactivity
The product is stable.
Stability and Reactivity
Reactive with OXIDIZING AGENTS, acids.
Incompatibility with
Various Substances
Will not occur.
Hazardous
Polymerization
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ETHOMEEN庐 C/12
Section 11. Toxicological Information
Toxicity to Animals
Ingredient Name or Product Test Result Route Species
name
Ethanol, 2,2'-iminobis-, n-coco alkyl LD50 6600 mg/kg Oral Rat based on data for:
derivs. (similar material)
Amines, coco alkyl LD50 1300 mg/kg Oral Rat
LD50 >2000 mg/kg Dermal Rabbit
Poly(oxy-1,2-ethanediyl), LD50 28000 mg/kg Oral Rat
a-hydroxy-w-hydroxy- LD50 31000 mg/kg Oral Mouse
LD50 14000 mg/kg Oral Rabbit
LD50 >20000 mg/kg Dermal Rabbit
Ethanol, 2,2'-iminobis-, n-coco alkyl derivs.: INHALATION LC50 = 88 ppm @ 1 hour(s) Rat
Special Remarks on
Amines, coco alkyl: INHALATION LC50 > 0.099 mg/L, 1 hour(s) Rat
Toxicity to Animals
Corrosive to the skin. May cause sensitization by skin contact. Practically non-toxic in contact with
Acute Effects Skin
skin.
Severely irritating to the eyes.
Acute Effects Eyes
:
Special Remarks on
Other Toxic Effects on
Humans
Section 12. Ecological Information
Ecotoxicity
Ingredient Name or Product name Species Period Result
Ethanol, 2,2'-iminobis-, n-coco alkyl Fish (LC50) 96 hour(s) 0.28 mg/l
derivs.
Amines, coco alkyl daphnia based on data for: 48 hour(s) 0.032 mg/l
(similar material) (EC50)
Poly(oxy-1,2-ethanediyl), Daphnia (EC50) 48 hour(s) >10000 mg/l
a-hydroxy-w-hydroxy- Fish (LC50) 24 hour(s) >5000 mg/l
Biodegradability and Ethanol, 2,2'-iminobis-, n-coco alkyl derivs.: 60% @ 28 day(s) CBT based on data for: (similar
Ecotoxicity Remarks material)
Amines, coco alkyl: 56% @ 28 day(s) CBT 74% @ 42 day(s) CBT
Poly(oxy-1,2-ethanediyl), a-hydroxy-w-hydroxy-: 5% @ 5 day(s) CBT 38% @ 10 day(s) CBT 70%
@ 20 day(s) CBT
Readily biodegradable.
Biodegradable/OECD
These products are carbon oxides (CO, CO2) and water, nitrogen oxides (NO, NO2...).
Products of Degradation
Section 13. Disposal Considerations
Waste must be disposed of in accordance with federal, state and local environmental control
Waste Information
regulations.
Consult your local or regional authorities.
Section 14. Transport Information
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ETHOMEEN庐 C/12
Regulatory UN Proper shipping name Class Packing Label Additional information
Information number Group
UN2735 Amines, liquid, corrosive, 8 III -
DOT
n.o.s. (Alkoxylated fatty
Classification CORROSIVE
amines) 8
-
UN2735 AMINES, LIQUID, 8 III
TDG Special Provisions
CORROSIVE, N.O.S.
Classification Classified in Accordance with
(Alkoxylated fatty amines) UN Recomendations
8
-
8 III
UN2735 AMINES, LIQUID, -
IMDG Class
CORROSIVE, N.O.S.
(Alkoxylated fatty amines) 8
-
UN2735 8
Amines, liquid, corrosive, III -
IATA-DGR
n.o.s. (Alkoxylated fatty
Class
amines) 8
-
Section 15. Regulatory Information
Corrosive Material
HCS Classification
TSCA: All intentionally present components are listed on the TSCA inventory.
U.S. Federal Regulations
DSL: All intentionally present components are listed on the DSL.
CERCLA: Hazardous substances.: No products were found.
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: No products were found.
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No products were found.
SARA 313 Form R Reporting Requirements
No products were found.
SARA 313 Supplier Notification
No products were found.
No products were found.
State Regulations
California prop. 65: No products were found.
Class E: Corrosive liquid.
WHMIS (Canada)
CEPA DSL: Ethanol, 2,2'-iminobis-, n-coco alkyl derivs.; Amines, coco alkyl; Poly(oxy-1,2-ethanediyl),
a-hydroxy-w-hydroxy-
Component EC Number EC Status EC Annex
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ETHOMEEN庐 C/12
Ethanol, 2,2'-iminobis-, n-coco alkyl 263-163-9 Not available. Not available.
European Union
derivs.
Amines, coco alkyl 262-977-1 Not available. Not available.
N-(2-hydroxyethyl)cocoalkylamines Not available. Not available. Not available.
Poly(oxy-1,2-ethanediyl), Not available. Not available. Not available.
a-hydroxy-w-hydroxy-
Australia (NICNAS): Ethanol, 2,2'-iminobis-, n-coco alkyl derivs.; Amines, coco alkyl;
Other International Lists
Poly(oxy-1,2-ethanediyl), a-hydroxy-w-hydroxy-
Japan (MITI): Amines, coco alkyl; Poly(oxy-1,2-ethanediyl), a-hydroxy-w-hydroxy-
Korea (TCCL): Ethanol, 2,2'-iminobis-, n-coco alkyl derivs.; Amines, coco alkyl;
Poly(oxy-1,2-ethanediyl), a-hydroxy-w-hydroxy-
Philippines (RA6969): Ethanol, 2,2'-iminobis-, n-coco alkyl derivs.; Amines, coco alkyl;
Poly(oxy-1,2-ethanediyl), a-hydroxy-w-hydroxy-
Section 16. Other Information
Hazardous Material 3 National Fire
Health
Fire Hazard
1
Information System Protection
1
Fire Hazard
3 0
Health Reactivity
(U.S.A.) Association
0
Reactivity
(U.S.A.) Specific Hazard
J
Personal Protection
Ethomeen庐 is a registered trademark of Akzo Nobel or affiliated companies and is registered in one or
Other Information
more countries including the United States.
Validation Date 12/29/2003. Validated by Gabrielle Brite
No Previous Validation. 12/29/2003.
Previous Validation Date Print Date
Phone Number 312-544-7038
Notice to Reader
The information in the material safety data sheet should be provided to all who will use, handle, store, transport or otherwise be exposed
to this product. All information concerning this product and/or suggestions for handling and use contained herein are offered in good
faith and are believed to be reliable as of the date of publication. However, no warranty is made as to the accuracy of and/or sufficiency of
such information and/or suggestions or as to the product鈥檚 merchantability or fitness for any particular purpose, or that any suggested
use will not infringe any patent. Nothing contained herein shall be construed as granting or extending any license under any patent. Buyer
must determine for himself, by preliminary tests or otherwise, the suitability of this product for his purposes, including mixing with other
products. The information contained herein supersedes all previously issued bulletins on the subject matter covered. If the date on this
document is more than three years old, call to make certain that this sheet is current.
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