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MSDS Material Safety Data Sheet
CAS

111-46-6
112-34-5
112-35-6
112-50-5
143-22-6
1559-34-8
23783-42-8
25322-68-3
9004-77-7
9038-95-3
111-77-3
111-90-0

File Name: technicalchemical_com---2312-6.asp
                                                   MATERIAL SAFETY DATA SHEET

Johnsens Manual Clutch Fluid
Trade Name:
2312-6
MSDS NO.
Revision Date: 12/28/2001


1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Trade Name: Johnsens Manual Clutch Fluid
Chemical Family: GLYCOL ETHER
Synonyms: None
Emergency Telephone (24 hr.): CHEMTREC 1-800-424-9300 During normal business hours CST 817-645-6088.
Supplier:
Technical Chemical Company, P.O. Box 139, Cleburne, Texas 76033


2. COMPOSITION/INFORMATION ON INGREDIENTS


Ingredient/CAS No. wt. % OSHA PEL OSHA PEL ACGIH TLV ACGIH TLW
TWA Ceiling Limits TWA STEL
Diethylene Glycol 5-15 None Known None Known None Known None Known
111-46-6
Diethylene Glycol Monobutyl Ether 5-20 None Known None Known None Known None Known
112-34-5
Triethylene Glycol Monomethyl Ether 5-50 None Known None Known None Known None Known
112-35-6
Triethylene Glycol Monoethyl Ether 5-50 None Known None Known None Known None Known
112-50-5
Triethylene Glycol Monobutyl Ether 5-50 None Known None Known None Known None Known
143-22-6
Tetraethylene Glycol Monobutyl 5-20 None Known None Known None Known None Known
Ether
1559-34-8
Polyalkylene Glycol Monomethyl 5-20 None Known None Known None Known None Known
Ether
23783-42-8
Polyethylene Glycol 5-20 None Known None Known None Known None Known
25322-68-3
Polyalkylene Glycol Monobutyl Ether 5-20 None Known None Known None Known None Known
9004-77-7
Polyalkylene Glycols 5-20 None Knwon None Known None Knwon None Known
9038-95-3
Diethylene Glycol Monomethyl Ether <5 None Known None Known None Known None Known
111-77-3
Diethylene Glycol Monoethyl Ether <5 None Known None Known None Known None Known
111-90-0
Trade Secret : <3 None Known None Known None Known None Known
Trade Secret Inhibitor Package


3. HAZARDS IDENTIFICATION

Emergency Overview: Danger: May be fatal if swallowed. This material is an eye irritant. May cause allergic skin reaction. Vapors are mildly to
markedly irritating to the lungs depending on the exposure level. Ingestion may cause abdominal discomfort, nausea, and
vomiting. May produce central nervous system depression and kidney damage.
4. FIRST AID MEASURES
Eye Contact: In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get
medical attention immediately after flushing.
Ingestion: Induce vomiting immediately as directed by medical personnel. Never give fluids or induce vomiting if the victim is
unconscious or having convulsions.
Inhalation: If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably mouth-to-mouth. If breathing is difficult
give oxygen. Get medical attention. Vapors or mists from this material can irritate the nose, throat and lungs, and cause
signs and sysmptoms of central nervous system depression, depending on the concentration and duratin of exposure.
Skin Contact: Wash with soap and water. Remove contaminated clothing and launder before reuse. Get medical attention if irritation
persists.



Page 1 of 5
Trade Name: Johnsens Manual Clutch Fluid MSDS NO. 2312-6
5. FIRE FIGHTING MEASURES
Flammable Properties
Flash Point 掳F(掳C): >135C. (>275 F.)
Flash Point Method: TAG Closed Cup
Flammable Limits in Air - Lower (%): Not Determined
Flammable Limits in Air - Upper (%): Not Determined
Autoignition Temperature 掳F(掳C): Not Determined
Extinguishing Media: Water fog, carbon dioxide, foam, dry chemical DO NOT use straight water streams.
Protection Of Fire-Fighters:
Special Fire-Fighting Procedures: Wear approved positive-pressure self-contained breathing apparatus and protective clothing. Do not
realse runoff from fire control methods to sewers or waterways. Fight from a maximum distance or
use unmanned hose holders or monitor nozzles. Containers can build up pressure if exposed to heat;
cool with flooding quantities of water until well after the fire is out. Withdraw immediately in case of
rising sound from venting safety devices or discoloration of vessel.
Hazardous Combustion Products: Carbon Dioxide. Carbon Monoxide. Unidentified organic compounds.
Aerosol Comments: Not Applicable
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions: Wear appropriate protective clothing and equipment to prevent skin and eye contact.
Spill Procedures: Avoid all sources of ignition; heat, sparks and open flames. Contain any liquid from leaking containers. Wear
protective equipment specified. Ventilate spill area. Soak up material with absorbent and place in chemical waste
container.
If clean-up is not immediate, cover spill with plastic or canvas to keep dry.
Environmental Precautions: Do not allow to enter sanitary drains, sewer or surface and subsurface waters.
7. HANDLING AND STORAGE
Handling and Do Not Swallow. Store in a cool, dry place. Use only in a well ventilated area. Keep container closed when not in use to prevent
Storage: contact with acidic, basic or oxidizing materials.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls: Exhaust ventilation. Eyewash stations. Showers.
Eyes: Chemical goggles; also wear a face shield if splashing hazard exists.
Skin Protection: Avoid skin contact. Wear protective clothing and gloves. Rubber, Neoprene or Vinyl.
Respiratory Protection: An approved respirator (i.e. NIOSH, etc.) should be worn when exposures are expected to exceed the
applicable limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Clear, yellow to amber colloidal liquid
Odor: MILD pH Value: 10 - 11.5
Vapor Pressure: Not Determined Vapor Density (Air=1): Not Determined
Boiling Point (掳F): 480 F. (249 C) Melting/Freezing Point: -58 F. (-50 C.)
Solubility in Water: SOLUBLE Bulk Density at 20掳C: 8.33 - 9.02 lb/gal
Molecular Weight: Mixture Evaporation Rate: <.01
Viscosity: Not determined. Specific Gravity (H20=1): 1.000 - 1.070 @ 4 C.
VOC Content(%): Not determined. Decomposition Temperature: Not Known
10. STABILITY AND REACTIVITY
Chemical Stability: STABLE.
Conditions to Avoid: Keep away from heat,sparks and flame.
Materials to Avoid: Avoid contact with acidic, basic or oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide. Carbon dioxide. Unknown organic compounds.
Hazardous Polymerization: WILL NOT OCCUR
11. TOXICOLOGICAL INFORMATION

Toxicological Data:



Ingredient/CAS No. wt. % Route Species Dose


Diethylene Glycol 5-15 Oral Rats LD50 12565 mg/kg
111-46-6
Diethylene Glycol Monobutyl Ether 5-20 Oral Rats LD50 5660 mg/kg
112-34-5
Triethylene Glycol Monomethyl Ether 5-50 Oral Rats LD50 11300 uL/kg
112-35-6
Triethylene Glycol Monoethyl Ether 5-50 Oral Rats LD50 7750 mg/kg
112-50-5




Page 2 of 5
Trade Name: Johnsens Manual Clutch Fluid MSDS NO. 2312-6
Triethylene Glycol Monobutyl Ether 5-50 Oral Rats LD50 5300 mg/kg
143-22-6
Tetraethylene Glycol Monobutyl 5-20 NA NA Not Known
Ether
1559-34-8
Polyalkylene Glycol Monomethyl 5-20 NA NA NA
Ether
23783-42-8
Polyethylene Glycol 5-20 Oral Rats LD50 28 gm/kg
25322-68-3
Polyalkylene Glycol Monobutyl Ether 5-20 NA NA NA
9004-77-7
Polyalkylene Glycols 5-20 Oral Rats LD50 12300 uL/kg
9038-95-3
Diethylene Glycol Monomethyl Ether <5 Oral Rats LD50 4 mL/kg
111-77-3
Diethylene Glycol Monoethyl Ether <5 Oral Rats LD50 5500 mg/kg
111-90-0
Trade Secret : <3 Oral Rats >2000 mg/kg
Trade Secret Inhibitor Package



Carcinogenicity:



Ingredient/CAS No. wt. % IARC NTP OSHA


Diethylene Glycol 5-15 Not Listed Not Listed Not Listed
111-46-6
Diethylene Glycol Monobutyl Ether 5-20 Not Listed Not Listed Not Listed
112-34-5
Triethylene Glycol Monomethyl Ether 5-50 Not Listed Not Listed Not Listed
112-35-6
Triethylene Glycol Monoethyl Ether 5-50 Not Listed Not Listed Not Listed
112-50-5
Triethylene Glycol Monobutyl Ether 5-50 Not Listed Not Listed Not Listed
143-22-6
Tetraethylene Glycol Monobutyl 5-20 Not Listed Not Listed Not Listed
Ether
1559-34-8
Polyalkylene Glycol Monomethyl 5-20 Not Listed Not Listed Not Listed
Ether
23783-42-8
Polyethylene Glycol 5-20 Not Listed Not Listed Not Listed
25322-68-3
Polyalkylene Glycol Monobutyl Ether 5-20 Not Listed Not Listed Not Listed
9004-77-7
Polyalkylene Glycols 5-20 Not Listed Not Listed Not Listed
9038-95-3
Diethylene Glycol Monomethyl Ether <5 Not Listed Not Listed Not Listed
111-77-3
Diethylene Glycol Monoethyl Ether <5 Not Listed Not Listed Not Listed
111-90-0
Trade Secret : <3 Not Known Not Known Not Known
Trade Secret Inhibitor Package


12. ECOLOGICAL INFORMATION

Ecological testing has not been conducted on this product.

13. DISPOSAL CONSIDERATION

Waste Classification: No specific component of this material is listed as a Hazardous Substance CERCLA (40 CFR 261). However,
this product contains various ethylene glycols and glycol ethers which are each included as a broad category on
the CERCLA Hazardous substances list.


Page 3 of 5
Trade Name: Johnsens Manual Clutch Fluid MSDS NO. 2312-6

Waste Management: Not determined.

Disposal should be made in accordance with federal, state and local regulations.



14. TRANSPORTATION INFORMATION

U.S. DOT:
Proper Shipping Name: Not Applicable
Hazard Class: Not Regulated
UN/NA Number: Not Applicable
DOT Packing Group: Not Applicable
IMDG:
Proper Shipping Name: Not Applicable
Hazard Class: Non-Hazardous
Hazard Subclass: Not Applicable
UN No.: Not Applicable
Packing Group: Not Applicable
Marine Pollutant: No
15. REGULATORY INFORMATION

US Federal Regulations:



Ingredient/CAS No. wt. % SARA 313 SARA 302 RQ TPQ


Diethylene Glycol 5-15 Not Listed Not Listed NA NA
111-46-6
Diethylene Glycol Monobutyl Ether 5-20 Not Listed Not Listed NA NA
112-34-5
Triethylene Glycol Monomethyl Ether 5-50 Not Listed Not Listed NA NA
112-35-6
Triethylene Glycol Monoethyl Ether 5-50 Not Listed Not Listed NA NA
112-50-5
Triethylene Glycol Monobutyl Ether 5-50 Not Listed Not Listed NA NA
143-22-6
Tetraethylene Glycol Monobutyl 5-20 Not Listed Not Listed NA NA
Ether
1559-34-8
Polyalkylene Glycol Monomethyl 5-20 Not Listed Not Listed NA NA
Ether
23783-42-8
Polyethylene Glycol 5-20 Not Listed Not Listed NA NA
25322-68-3
Polyalkylene Glycol Monobutyl Ether 5-20 Not Listed Not Listed NA NA
9004-77-7
Polyalkylene Glycols 5-20 Not Listed Not Listed NA NA
9038-95-3
Diethylene Glycol Monomethyl Ether <5 Not Listed Not Listed NA NA
111-77-3
Diethylene Glycol Monoethyl Ether <5 Not listed Not Listed NA NA
111-90-0
Trade Secret : <3 Not Known Not Known NA NA
Trade Secret Inhibitor Package



No specific component of this material is listed as a Hazardous Substance CERCLA (40 CFR 261). However, this product
contains various ethylene glycols and glycol ethers which are each included as a broad category on the CERCLA Hazardous
substances list.
SARA 311/312 Hazard Catagories: Delayed

State Regulations:




Page 4 of 5
Trade Name: Johnsens Manual Clutch Fluid MSDS NO. 2312-6

Ingredient/CAS No. wt. % California Prop. 65 California Prop. 65 California Prop. 65 California Prop. 65
Cancer list Developmental Reproductive Female Reproductive Male
Toxicity
Diethylene Glycol 5-15 Not Listed Not Listed Not Listed Not Listed
111-46-6
Diethylene Glycol Monobutyl Ether 5-20 Not Listed Not Listed Not Listed Not Listed
112-34-5
Triethylene Glycol Monomethyl Ether 5-50 Not Listed Not Listed Not Listed Not Listed
112-35-6
Triethylene Glycol Monoethyl Ether 5-50 Not Listed Not Listed Not Listed Not Listed
112-50-5
Triethylene Glycol Monobutyl Ether 5-50 Not Listed Not Listed Not Listed Not Listed
143-22-6
Tetraethylene Glycol Monobutyl 5-20 Not Listed Not Listed Not Listed Not Listed
Ether
1559-34-8
Polyalkylene Glycol Monomethyl 5-20 Not Listed Not Listed Not Listed Not Listed
Ether
23783-42-8
Polyethylene Glycol 5-20 Not Listed Not Listed Not Listed Not Listed
25322-68-3
Polyalkylene Glycol Monobutyl Ether 5-20 Not Listed Not Listed Not Listed Not Listed
9004-77-7
Polyalkylene Glycols 5-20 Not Listed Not Listed Not Listed Not Listed
9038-95-3
Diethylene Glycol Monomethyl Ether <5 Not Listed Not Listed Not Listed Not Listed
111-77-3
Diethylene Glycol Monoethyl Ether <5 Not Listed Not Listed Not Listed Not Listed
111-90-0
Trade Secret : <3 Not Listed Not Listed Not Listed Not Listed
Trade Secret Inhibitor Package



U.S. TSCA: The components of this product are listed on the TSCA Inventory.
16. OTHER INFORMATION

General Notes: Do not allow undiluted material or large quantities to reach groundwater, bodies of water or sewer system.
Disclaimer:
The information and recommendations contained herein are based upon tests believed to be reliable. However, Technical Chemical Company does not
guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR
IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS FOR A
PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. Technical Chemical Company assumes no
responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of these data. No warranty
against infringement of any patent, copyright or trademark is made or implied.




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