MATERIAL SAFETY DATA SHEET
Trade Name: Johnsens Silicone Spray
MSDS NO. 4603
Revision Date: 11/13/2007
Date Printed 11/13/2007
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Trade Name: Johnsens Silicone Spray
Chemical Family: SILICONE POLYMER SOLUTION
Synonyms: None
Emergency Telephone (24 hr.): 24-Hour Emergency Information: CHEMTREC (800) 424-9300
Supplier: Technical Chemical Company, P.O. Box 139, Cleburne, Texas 76033
2. COMPOSITION/INFORMATION ON INGREDIENTS
Weight % OSHA TWA OSHA STEL OSHA SKIN
Component
8-12 Not Listed Not Listed Not Listed
Butane
106-97-8
36-40 Not Listed Not Listed Not Listed
Heptane
142-82-5
2-4 Not Listed Not Listed Not Listed
Silicon
63148-62-9
38-42 Not Listed Not Listed Not Listed
Dimethyl ketone
67-64-1
6-8 Not Listed Not Listed Not Listed
Propane
74-98-6
Weight % OSHA Z PEL OSHA Z TWA OSHA Z Ceiling
Component
3
8-12 Not Listed 1900 mg/m 800 ppm Not Listed
Butane
106-97-8
3 3
36-40 2000 mg/m 500 ppm 1600 mg/m 400 ppm Not Listed
Heptane
142-82-5
2-4 Not Listed Not Listed Not Listed
Silicon
63148-62-9
3 3
38-42 2400 mg/m 1000 ppm 1800 mg/m 750 ppm Not Listed
Dimethyl ketone
67-64-1
3 3
6-8 1800 mg/m 1000 ppm 1800 mg/m 1000 ppm Not Listed
Propane
74-98-6
ACGIH TLV TWA ACGIH TLV STEL ACGIH TLV Ceiling
Component
1000 ppm Not Listed Not Listed
Butane
106-97-8
400 ppm 500 ppm Not Listed
Heptane
142-82-5
Not Listed Not Listed Not Listed
Silicon
63148-62-9
500 ppm 750 ppm Not Listed
Dimethyl ketone
67-64-1
1000 ppm Not Listed Not Listed
Propane
74-98-6
Other: This product does not contain Normal Hexane (N-Hexane).
3. HAZARDS IDENTIFICATION
Page 1 of 6
MATERIAL SAFETY DATA SHEET
Trade Name: Johnsens Silicone Spray
MSDS NO. 4603
Revision Date: 11/13/2007
Date Printed 11/13/2007
3. HAZARDS IDENTIFICATION
Emergency Overview: Warning: Extremely Flammable. Content under pressure. This material is an eye and skin irritant. Keep
away from heat, sparks and flame. Gross inhalation overexposure may cause: Central nervous system
depression with dizziness, confusion, incoordination, drowsiness or unconsciousness or death. Causes
respiratory irritation. This product contains dimethylpolysiloxane which can generate small amounts of
formaldehyde as a byproduct of oxidative thermal decomposition beginning at approximately 150 C (300
F). Exposure to formaldehdye can cause adverse effects such as skin and respiratory sensitization and
eye and throat irritation. Formaldehyde is a potential cancer hazard. Use good industrial hygiene
practices to evaluate and control exposure to formaldehyde when warranted by conditions of use. This
material is readily absorbed through the skin in liquid or vapor phase.
HMIS Classification: Health: *2 Flammability: 4 Physical Hazard: 2
NFPA Rating: Health: 2 Flammability: 4 Reactivity: 0
4. FIRST AID MEASURES
Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting
the upper and lower lids. Seek medical attention if irritation persists.
Ingestion: If swallowed, do NOT induce vomiting. Call a physician immediately. Never give anything by mouth to an
unconscious person. Get medical attention! If vomiting occurs, keep head lower than hips to prevent
aspiration.
Inhalation: If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably mouth-to-mouth. If
breathing is difficult give oxygen. Get medical attention.
Skin Contact: Wash with soap and water for 15 minutes. If irritation persists or signs of toxicity occur, seek medical
attention. Remove contaminated clothing and shoes, and launder before reuse.
5. FIRE FIGHTING MEASURES
Flammable Properties
Flash Point 掳F(掳C): 15 F (Lowest Component)
Flash Point Method: TAG Closed Cup
Flammable Limits in Air - Lower (%): 1.2% (Lowest Component)
Flammable Limits in Air - Upper (%): 6.7% (Lowest Component)
Autoignition Temperature 掳F(掳C): Not Determined
Extinguishing Media: Dry chemical. Carbon dioxide. Use water spray to keep containers cool that are exposed to heat or flames.
Foam.
Protection Of Fire-Fighters:
Special Fire-Fighting Procedures: Wear approved positive-pressure self-contained breathing apparatus and protective clothing. Vapor may
cause flash fire.
Hazardous Combustion Products: Carbon Dioxide. Carbon Monoxide.
Aerosol Comments: NFPA Level 3 Aerosol
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions: Wear appropriate protective clothing and equipment to prevent skin and eye contact.
Spill Procedures: Contain any liquid from leaking containers. Avoid all sources of ignition; heat, sparks and open flames.
Action to be taken if material is released Do not puncture or incinerate container. Contents under pressure. Wear proper protective equipment as
or spilled: specified in the protective equipment section. Remove sources of ignition. Leaking containers should be
removed to an isolated, well-ventilated area and transferred to other suitable containers. Wipe, scrape, or
soak up in an inert material and put in a container intended for flammable materials for disposal.
Environmental Precautions: Do not allow to enter sanitary drains, sewer or surface and subsurface waters. Keep out of lakes, ponds or
streams.
7. HANDLING AND STORAGE
Handling and Storage: Caution: Contents under pressure. Keep away from heat and open flame. Use only in a well ventilated
area. Avoid breathing vapors, if exposed to high vapor concentration, leave area at once. Avoid contact
with skin and eyes. Do not puncture, incinerate or store above 120 F. Exposure to high temperatures may
cuase bursting. DO NOT store in the passenger compartment of an automobile.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls: Use in a well ventilated area. Local exhaust ventilation as necessary to maintain exposures to within
applicable limits.
Page 2 of 6
MATERIAL SAFETY DATA SHEET
Trade Name: Johnsens Silicone Spray
MSDS NO. 4603
Revision Date: 11/13/2007
Date Printed 11/13/2007
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Eyes: Chemical goggles; also wear a face shield if splashing hazard exists.
Skin Protection: Avoid skin contact. Wear protective clothing and gloves.
Respiratory Protection: Do not breath mist or vapor. Use in a well ventilated area. Appropriate respiratory protection shall be worn
when applied engineering controls are not adequate to protect against inhalation exposure.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Colorless to pale yellow liquid
Odor: MILD
pH Value: Not Determined
Vapor Pressure: 2.3 psia @ 100 F
Vapor Density (Air=1): 3.5 Approximate
Boiling Point (掳F): 195 F (Lowest Component)
Melting/Freezing Point: Not determined.
Solubility in Water: NEGLIGIBLE
Bulk Density at 20掳C: Not Determined
Molecular Weight: Mixture
Specific Gravity (H20=1): .69 - .79 @ 60 F
Viscosity: Not Determined.
Evaporation Rate: >1
VOC Content(%): 59
Decomposition Temperature: Not Determined
10. STABILITY AND REACTIVITY
Chemical Stability: STABLE.
Conditions to Avoid: Keep away from heat,sparks and flame. Avoid any source of ignition. Do not expose to heat or store at
temperatures above 120 F.
Materials to Avoid: Contact with oxidizing agents. Strong bases. Strong acids.
Hazardous Decomposition Products: Carbon monoxide. Silica. Formaldehyde is a byproduct of oxidative thermal decomposition.
Hazardous Polymerization: WILL NOT OCCUR
11. TOXICOLOGICAL INFORMATION
Toxicological Data:
Component
Route Species Dose
3
Inhalation Rats LC50, 658 gm/m /4H
Butane
106-97-8
3
Inhalation Rats LC50 103 gm/m /4H
Heptane
142-82-5
Inhalation Rats Not known.
Silicon
63148-62-9
3
Inhalation Rats LC50 50100 mg/m /8H
Dimethyl ketone
67-64-1
NA NA Not known.
Propane
74-98-6
Carcinogenicity:
Page 3 of 6
MATERIAL SAFETY DATA SHEET
Trade Name: Johnsens Silicone Spray
MSDS NO. 4603
Revision Date: 11/13/2007
Date Printed 11/13/2007
Component
IARC NTP OSHA
Not Listed Not Listed Not Listed
Butane
106-97-8
Not Listed Not Listed Not Listed
Heptane
142-82-5
Not Listed Not Listed Not Listed
Silicon
63148-62-9
Not Listed Not Listed Not Listed
Dimethyl ketone
67-64-1
Not Listed Not Listed Not Listed
Propane
74-98-6
12. ECOLOGICAL INFORMATION
Remarks: Ecological testing has not been conducted on this product.
13. DISPOSAL CONSIDERATION
Waste Classification: Residues and spilled material are hazardous waste due to ignitability.
Waste Management: Not determined.
Disposal Method: Disposal should be made in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
U.S. DOT:
Proper Shipping Name: ORM-D CONSUMER COMMODITY
Hazard Class: ORM-D
UN/NA Number: Not Applicable
DOT Packing Group: Not Applicable
IMDG:
Proper Shipping Name: Aeroslols (Limited Quantity)
Hazard Class: 2.1
Hazard Subclass: Not determined.
UN No.: UN1950
Packing Group: PG II
Marine Pollutant: No
15. REGULATORY INFORMATION
US Federal Regulations:
SARA 313 SARA 302 TPQ RQ
Component
Not Listed Not Listed Not Listed Not Listed
Butane
106-97-8
Not Listed Not Listed Not Listed Not Listed
Heptane
142-82-5
Not Listed Not Listed Not Listed Not Listed
Silicon
63148-62-9
Not Listed Not Listed Not Listed Not Listed
Dimethyl ketone
67-64-1
Not Listed Not Listed Not Listed Not Listed
Propane
74-98-6
US OSHA HEALTH CLASSIFICATION: Hazardous per OSHA 29 CFR 1910.1200
SARA 311/312 Hazard Catagories: Not Determined.
State Regulations:
Page 4 of 6
MATERIAL SAFETY DATA SHEET
Trade Name: Johnsens Silicone Spray
MSDS NO. 4603
Revision Date: 11/13/2007
Date Printed 11/13/2007
California Prop. 65 California - Prop 65 California Prop. 65 California Prop. 65
Component
Cancer list Developmental Toxicity Reproductive Female Reproductive Male
Not Listed Not Listed Not Listed Not Listed
Butane
106-97-8
Not Listed Not Listed Not Listed Not Listed
Heptane
142-82-5
Not Listed Not Listed Not Listed Not Listed
Silicon
63148-62-9
Not Listed Not Listed Not Listed Not Listed
Dimethyl ketone
67-64-1
Not Listed Not Listed Not Listed Not Listed
Propane
74-98-6
New Jersey Right-to-Know List:
Component
Substance no. 0273
Butane
Substance no. 2422
106-97-8
Substance no. 2423
Substance no. 2425
Substance no. 2426
Substance no. 2427
Substance no. 2428
Substance no. 2429
Substance no. 2430
Substance no. 2422
Heptane
Substance no. 2423
142-82-5
Substance no. 2425
Substance no. 2426
Substance no. 2427
Substance no. 2428
Substance no. 2429
Substance no. 2430
Substance no. 1339
Substance no. 0006
Dimethyl ketone
Listed
67-64-1
Substance no. 2422
Substance no. 2423
Substance no. 2425
Substance no. 2426
Substance no. 2427
Substance no. 2428
Substance no. 2429
Substance no. 2430
Substance no. 2422
Propane
Substance no. 2423
74-98-6
Substance no. 2425
Substance no. 2426
Substance no. 2427
Substance no. 2428
Substance no. 2429
Substance no. 2430
Substance no. 1594
U.S. TSCA: The components of this product are listed on the TSCA Inventory.
Canadian Inventory: The components of this product are listed on the Canadian DSL or NDSL Inventory.
16. OTHER INFORMATION
General Notes: Do not allow undiluted material or large quantities to reach groundwater, bodies of water or sewer system.
Page 5 of 6
MATERIAL SAFETY DATA SHEET
Trade Name: Johnsens Silicone Spray
MSDS NO. 4603
Revision Date: 11/13/2007
Date Printed 11/13/2007
16. OTHER INFORMATION
Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable.
However, the manufacturer/distributor of this product does not guarantee their accuracy or completeness
NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR
IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE
FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions
of usage may be required. The manufacturer/distributor assumes no responsibility for results obtained or
for incidental or consequential damages, including lost profits, arising from the use of these data. No
warranty against infringement of any patent, copyright or trademark is made or implied.
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