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MSDS Material Safety Data Sheet
CAS

67-56-1
127087-87-0

File Name: technicalchemical_com---2943.asp
                                        MATERIAL SAFETY DATA SHEET

Trade Name: Johnsen's Windshield Washer Concentrate for California
MSDS NO. 2943
Revision Date: 04/11/2006
Date Printed 01/31/2007
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION

Trade Name: Johnsen's Windshield Washer Concentrate for California
Synonyms: None
Emergency Telephone (24 hr.): CHEMTREC 1-800-424-9300

Supplier: Technical Chemical Company, P.O. Box 139, Cleburne, Texas 76033


2. COMPOSITION/INFORMATION ON INGREDIENTS

Weight % OSHA TWA OSHA STEL OSHA SKIN
Component
5-10 Not Listed Not Listed Not Listed
Methyl Alcohol
67-56-1
<1 Not Listed Not Listed Not Listed
Poly(oxy-1,2-ethanediyl),
alpha-(4-nonylphenyl)-
omega-hydroxy-, branched
127087-87-0


Weight % OSHA Z PEL OSHA Z TWA OSHA Z Ceiling
Component
3 3
5-10 260 mg/m 200 ppm 260 mg/m 200 ppm Not Listed
Methyl Alcohol
67-56-1
<1 Not Listed Not Listed Not Listed
Poly(oxy-1,2-ethanediyl),
alpha-(4-nonylphenyl)-
omega-hydroxy-, branched
127087-87-0


ACGIH TLV TWA ACGIH TLV STEL ACGIH TLV Ceiling
Component
200 ppm 250 ppm Not Listed
Methyl Alcohol
67-56-1
Not Listed Not Listed Not Listed
Poly(oxy-1,2-ethanediyl),
alpha-(4-nonylphenyl)-
omega-hydroxy-, branched
127087-87-0

3. HAZARDS IDENTIFICATION

Emergency Overview: Danger: Poison. Ingestion of even small amounts of methyl alcohol can cause blindness and death.
Cannot be made nonpoisonous. Keep away from heat, sparks and flame. Combustible Liquid. May cause
eye injury which may persist for several days. Liquid and vapor in high concentrations, causes eye
irritation, tearing and burning sensations.

HMIS Classification: Health: *2 Flammability: 3 Physical Hazard: 0
NFPA Rating: Health: 1 Flammability: 3 Reactivity: 0


4. FIRST AID MEASURES

Eye Contact: In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes
and get medical attention immediately after flushing.
Ingestion: If swallowed, induce vomiting immediately by giving two glasses of water and sticking fingers down throat;
never give anything to an unconscious person. Get medical attention. Drink a large amount of water, milk
or sodium bicarbonate to dilute material in stomach.
Inhalation: If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably mouth-to-mouth. If
breathing is difficult give oxygen. Get medical attention.
Page 1 of 5
MATERIAL SAFETY DATA SHEET

Trade Name: Johnsen's Windshield Washer Concentrate for California
MSDS NO. 2943
Revision Date: 04/11/2006
Date Printed 01/31/2007
4. FIRST AID MEASURES
Skin Contact: Wash with soap and water. Remove contaminated clothing and shoes, and launder before reuse. Get
medical attention if irritation persists.


5. FIRE FIGHTING MEASURES

Flammable Properties
Flash Point 掳F(掳C): 175 F
Flash Point Method: TAG Closed Cup
Flammable Limits in Air - Lower (%): 6% (lowest Component)
Flammable Limits in Air - Upper (%): 36% (Lowest Component)
Autoignition Temperature 掳F(掳C): 475 F. (Lowest Component)
Extinguishing Media: Alcohol foam. Foam. Dry chemical. Carbon dioxide.
Protection Of Fire-Fighters:
Special Fire-Fighting Procedures: Wear approved positive-pressure self-contained breathing apparatus and protective clothing. Avoid water
streams which may splash and spread flaming liquid. Water spray can be used to reduce the intensity of
the flames and dilute spills to a non-flammable mixture. Vapor may cause flash fire. Methanol and water
mixtures will burn unless very dilute. Mixtures with 25% or more Methanol are OSHA Class 1 Flammable
Liquids.
Hazardous Combustion Products: Carbon Dioxide. Carbon Monoxide. Acrid smoke and irritating fumes.
Aerosol Comments: Not Applicable


6. ACCIDENTAL RELEASE MEASURES

Personal Precautions: Wear appropriate protective clothing and equipment to prevent skin and eye contact. Avoid breathing
vapor. When airborne exposure limits are exceeded use NIOSH approved respiratory protection
equipment appropriate to the material and/or its components.
Spill Procedures: Wear protective equipment specified. Only trained and qualified personel should handle any spilled or
leaked product.
Action to be taken if material is released Remove sources of ignition. Increase area ventilation. Stop release at source. Dike area and contain.
or spilled: Absorb spills on inert material such as perlite, vermiculite, sand or dirt. Place in double polyethylene bags.
Isolate from other waste materials.
Environmental Precautions: Do not allow to enter sanitary drains, sewer or surface and subsurface waters.


7. HANDLING AND STORAGE

Handling and Storage: Keep container closed when not in use. Avoid breathing vapors, if exposed to high vapor concentration,
leave area at once. Avoid contact with skin and eyes. Use only in a well ventilated area. Keep away from
food and smoking materials. Wash hands before eating and smoking. Keep away from heat and open
flame. Avoid extreme temperatures.


8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering Controls: Use local exhaust. Eyewash stations. Showers.
Eyes: Safety glasses with side shields.
Skin Protection: Use chemical resistant gloves for prolonged skin contact. Wash hands and other exposed areas with mild
soap and water before eating, drinking, smoking and when leaving work. Launder contaminated clothing
before reuse.
Respiratory Protection: Appropriate respiratory protection shall be worn when applied engineering controls are not adequate to
protect against inhalation exposure. Organic vapor cartridge respirators NOT recommended for methanol
vapor exposures.



9. PHYSICAL AND CHEMICAL PROPERTIES

Appearance: Topical: blue liquid
Odor: MILD-ALCOHOL
pH Value: approx. 7
Vapor Pressure: Not Determined
Vapor Density (Air=1): Not Determined
Page 2 of 5
MATERIAL SAFETY DATA SHEET

Trade Name: Johnsen's Windshield Washer Concentrate for California
MSDS NO. 2943
Revision Date: 04/11/2006
Date Printed 01/31/2007
9. PHYSICAL AND CHEMICAL PROPERTIES
Boiling Point (掳F): <212 F
Melting/Freezing Point: 27 F
Solubility in Water: SOLUBLE
Bulk Density at 20掳C: 8.16 lb/gal
Molecular Weight: Mixture
Specific Gravity (H20=1): .979 @ 60 F
Viscosity: Not determined.
Evaporation Rate: Not Determined
VOC Content(%): 8%
Decomposition Temperature: Not Known


10. STABILITY AND REACTIVITY

Chemical Stability: STABLE.
Conditions to Avoid: Avoid any source of ignition.
Materials to Avoid: Strong oxidizing agents. Chromic anhydride, lead perchlorate and perchloric acids.
Hazardous Decomposition Products: Carbon monoxide. Carbon dioxide. Acrid smoke with irritating fumes.
Hazardous Polymerization: WILL NOT OCCUR


11. TOXICOLOGICAL INFORMATION
Toxicological Data:

Component
Route Species Dose
Inhalation Rats LC50 64,000 ppm
Methyl Alcohol
67-56-1
Oral Rats LD50 2.52 ml/kg 24 Hr.
Poly(oxy-1,2-ethanediyl),
alpha-(4-nonylphenyl)-
omega-hydroxy-, branched
127087-87-0

Carcinogenicity:

Component
IARC NTP OSHA
Not Listed Not Listed Not Listed
Methyl Alcohol
67-56-1
Not Listed Not Listed Not Listed
Poly(oxy-1,2-ethanediyl),
alpha-(4-nonylphenyl)-
omega-hydroxy-, branched
127087-87-0

12. ECOLOGICAL INFORMATION

Remarks: Ecological testing has not been conducted on this product.


13. DISPOSAL CONSIDERATION

Waste Classification: Not determined.
Waste Management: Not determined.
Disposal Method: Disposal should be made in accordance with federal, state and local regulations.


14. TRANSPORTATION INFORMATION
U.S. DOT:
Proper Shipping Name: Not regulated
Hazard Class: Not applicable
UN/NA Number: Not Applicable

Page 3 of 5
MATERIAL SAFETY DATA SHEET

Trade Name: Johnsen's Windshield Washer Concentrate for California
MSDS NO. 2943
Revision Date: 04/11/2006
Date Printed 01/31/2007
14. TRANSPORTATION INFORMATION
DOT Packing Group: Not Applicable

IMDG:
Proper Shipping Name: Not regulated
Hazard Class: Not applicable
Hazard Subclass: Not applicable
UN No.: Not applicable
Packing Group: Not applicable
Marine Pollutant: No


15. REGULATORY INFORMATION

US Federal Regulations:

SARA 313 SARA 302 TPQ RQ
Component
Listed. Not Listed Not Listed Not Listed
Methyl Alcohol
67-56-1
Not Listed Not Listed Not Listed Not Listed
Poly(oxy-1,2-ethanediyl),
alpha-(4-nonylphenyl)-
omega-hydroxy-, branched
127087-87-0

SARA 311/312 Hazard Catagories: Not Determined.

State Regulations:

California Prop. 65 California - Prop 65 California Prop. 65 California Prop. 65
Component
Cancer list Developmental Toxicity Reproductive Female Reproductive Male
Not Listed Not Listed Not Listed Not Listed
Methyl Alcohol
67-56-1
Not Listed Not Listed Not Listed Not Listed
Poly(oxy-1,2-ethanediyl),
alpha-(4-nonylphenyl)-
omega-hydroxy-, branched
127087-87-0


New Jersey Right-to-Know List:
Component
Substance no. 2079
Methyl Alcohol
Substance no. 2422
67-56-1 Substance no. 2423
Substance no. 2425
Substance no. 2426
Substance no. 2427
Substance no. 2428
Substance no. 2429
Substance no. 2430
Substance no. 1222


U.S. TSCA: The components of this product are listed on the TSCA Inventory.
Canadian Inventory: The components of this product are listed on the Canadian DSL or NDSL Inventory.


16. OTHER INFORMATION

General Notes: Do not allow undiluted material or large quantities to reach groundwater, bodies of water or sewer system.




Page 4 of 5
MATERIAL SAFETY DATA SHEET

Trade Name: Johnsen's Windshield Washer Concentrate for California
MSDS NO. 2943
Revision Date: 04/11/2006
Date Printed 01/31/2007
16. OTHER INFORMATION
Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable.
However, the manufacturer/distributor of this product does not guarantee their accuracy or completeness
NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR
IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE
FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions
of usage may be required. The manufacturer/distributor assumes no responsibility for results obtained or
for incidental or consequential damages, including lost profits, arising from the use of these data. No
warranty against infringement of any patent, copyright or trademark is made or implied.




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