MATERIAL SAFETY DATA SHEET
Johnsens DOT 4 Brake Fluid
Trade Name:
5034
MSDS NO.
Revision Date: 05/21/2003
Date Printed 06/21/2004
Trade Name: Johnsens DOT 4 Brake Fluid MSDS NO. 5034
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Trade Name: Johnsens DOT 4 Brake Fluid
Chemical Family: Glycol Ethers and Alkyl Ethers
Synonyms: Dow 460 Brake Fluid
Emergency Telephone (24 hr.): CHEMTREC 1-800-424-9300 During normal business hours CST 817-645-6088.
Supplier: Technical Chemical Company, P.O. Box 139, Cleburne, Texas 76033
2. COMPOSITION/INFORMATION ON INGREDIENTS
Ingredient/CAS No. wt. % OSHA PEL OSHA PEL ACGIH TLV ACGIH TLW
TWA Ceiling Limits TWA STEL
Alkyl Ester 30-50 Not Determined Not Determined Not Determined Not Determined
proprietary
Triethylene glycol monobutyl ether 10-40 None Known None Known None Known None Known
143-22-6
Triethylene glycol monomethyl ether 0-20 None Known None Known None Known None Known
112-35-6
Polyethylene glycol monomethyl 0-20 Not Known Not Known Not Known Not Known
ether
9004-74-4
Polyethylene glycol monobutyl ether 0-20 None Known None Known None Known None Known
9004-77-7
Poly(ethylene oxide) 5-15 2 mg/m3 Not Determined 2 mg/m3 Not Determined
25322-68-3
Inhibitor Package 1-3 Not Determined Not Determined Not Determined Not Determined
proprietary
3. HAZARDS IDENTIFICATION
Emergency Overview: This material is irritating to skin, eyes and mucous membranes. Absorption through skin or inhalation of heated vapor and
mist may result in central nervous system and adverse reproductive effects. Animal studies indicate high doses may
cause adverse reproductive effects.
HMIS Classification: Health: 2 Flammability: 1 Physical Hazard: 0
NFPA Rating: Health: 2 Flammability: 1 Reactivity: 0
4. FIRST AID MEASURES
Eye Contact: In case of contact, immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and
lower lids. Seek medical attention if irritation persists.
Ingestion: If swallowed, induce vomiting immediately by giving two glas ses of water and sticking fingers down throat; never give
anything to an unconscious person. Get medical attention.
Inhalation: If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably mouth-to-mouth. If breathing is difficult
give oxygen. Get medical attention. Vapors or mists from this material can irritate the nose, throat and lungs, and cause
signs and sysmptoms of central nervous system depression, depending on the concentration and duration of exposure.
Skin Contact: Remove contaminated clothing and shoes, and launder before reuse. Flush with copious amounts of water. If irritation
persists or signs of toxicity occur, seek medical attention.
5. FIRE FIGHTING MEASURES
Flammable Properties
Flash Point 掳F(掳C): 135 C. (275 F.)
Flash Point Method: PMCC
Flammable Limits in Air - Lower (%): Not Determined
Flammable Limits in Air - Upper (%): Not Determined
Autoignition Temperature 掳F(掳C): Not Determined
Extinguishing Media: Alcohol foam. Dry chemical. Halon. Carbon dioxide. Water fog. Water. Water fog and foam may cause
frothing and spattering.
Protection Of Fire-Fighters:
Page 1 of 5
MATERIAL SAFETY DATA SHEET
Johnsens DOT 4 Brake Fluid
Trade Name:
5034
MSDS NO.
Revision Date: 05/21/2003
Date Printed 06/21/2004
Trade Name: Johnsens DOT 4 Brake Fluid MSDS NO. 5034
Special Fire-Fighting Procedures: Wear approved positive-pressure self-contained breathing apparatus and protective clothing.
Hazardous Combustion Products: Carbon Dioxide. Carbon Monoxide.
Aerosol Comments: Not Applicable
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions: Wear appropriate protective clothing and equipment to prevent skin and eye contact.
Spill Procedures: Avoid all sources of ignition; heat, sparks and open flames. Contain any liquid from leaking containers. Wear
protective equipment specified. Ventilate spill area. Soak up material with absorbent and place in chemical waste
container.
If clean-up is not immediate, cover spill with plastic or canvas to keep dry.
Environmental Precautions: Do not allow to enter sanitary drains, sewer or surface and subsurface waters.
7. HANDLING AND STORAGE
Handling and Do Not Swallow. Store in a cool, dry place. Use only in a well ventilated area. Keep container closed when not in use to prevent
Storage: contact with acidic, basic or oxidizing materials. Avoid open heating or agitation, this may generate vapors or mists.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls: Exhaust ventilation. Eyewash stations. Showers.
Eyes: Chemical goggles; also wear a face shield if splashing hazard exists.
Skin Protection: Avoid skin contact. Wear protective clothing and gloves. Rubber, Neoprene or Vinyl. Wash hands and other
exposed areas with mild soap and water before eating, drinking, smoking and when leaving work.
Respiratory Protection: An approved respirator (i.e. NIOSH, etc.) should be worn when exposures are expected to exceed the
applicable limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Transparent pale yellow
Odor: MILD, ETHEREAL pH Value: Not Applicable
Vapor Pressure: <0.01 mm Hg @ 20C Vapor Density (Air=1): 9
Boiling Point (掳F): >200C (>392F) Melting/Freezing Point: Pour Point -59C (-75F)
Solubility in Water: <0.5% Bulk Density at 20掳C: Not Determined
Molecular Weight: Mixture Evaporation Rate: <0.01 (Butyl Acetate = 1)
Viscosity: Not Determined. Specific Gravity (H20=1): 1.047 20C/20C
VOC Content(%): 0.5 wt%Decomposition Temperature: Not Known
10. STABILITY AND REACTIVITY
Chemical Stability: STABLE.
Conditions to Avoid: Keep away from heat,sparks and flame. Avoid open heating or agitation , this may generate vapors or mists.
Materials to Avoid: Contact with oxidizing agents. May form peroxides if in contact with air for long periods and these can
explode spontaneously or when heated.
Hazardous Decomposition Products: Oxides of carbon and nitrogen
Hazardous Polymerization: WILL NOT OCCUR
11. TOXICOLOGICAL INFORMATION
Toxicological Data:
Ingredient/CAS No. wt. % Route Species Dose
Alkyl Ester 30-50 Inhalation Rats Not known.
proprietary
Triethylene glycol monobutyl ether 10-40 Oral Rats LD50 5300 mg/kg
143-22-6
Triethylene glycol monomethyl ether 0-20 Oral Rats LD50 11300 uL/kg
112-35-6
Polyethylene glycol monomethyl 0-20 Oral Rats LD50 39800 uL/kg
ether
9004-74-4
Polyethylene glycol monobutyl ether 0-20 NA NA NA
9004-77-7
Poly(ethylene oxide) 5-15 Inhalation Rats Not known.
25322-68-3
Inhibitor Package 1-3 Inhalation Rats Not known.
proprietary
Page 2 of 5
MATERIAL SAFETY DATA SHEET
Johnsens DOT 4 Brake Fluid
Trade Name:
5034
MSDS NO.
Revision Date: 05/21/2003
Date Printed 06/21/2004
Trade Name: Johnsens DOT 4 Brake Fluid MSDS NO. 5034
Carcinogenicity:
Ingredient/CAS No. wt. % IARC NTP OSHA
Alkyl Ester 30-50 Not Listed Not Listed Not Listed
proprietary
Triethylene glycol monobutyl ether 10-40 Not Listed Not Listed Not Listed
143-22-6
Triethylene glycol monomethyl ether 0-20 Not Listed Not Listed Not Listed
112-35-6
Polyethylene glycol monomethyl 0-20 Not Listed Not Listed Not Listed
ether
9004-74-4
Polyethylene glycol monobutyl ether 0-20 Not Listed Not Listed Not Listed
9004-77-7
Poly(ethylene oxide) 5-15 Not Listed Not Listed Not Listed
25322-68-3
Inhibitor Package 1-3 Not Listed Not Listed Not Listed
proprietary
Some minor components have been shown not to interfere with reproduction, although slightly toxic to the offspring or
decreased pup weights were observed in the animal studies. This substance appears to be of low toxicity, except for
possible mild irritant effects in humans. A high dose may produce central nervous system depression, but there are no
reports of adverse health effects from occupational exposure.
12. ECOLOGICAL INFORMATION
Low to moderate toxicity is expected to aquatic and terrestrial organisms. There is limited information available
on evnironmental fate and effects. Due caution should be exercised to avoid the accidental release of this
material to aquatic and terretrial environments. This mixture is not expected to bioconcentrate in significant
amounts.
13. DISPOSAL CONSIDERATION
Waste Classification: Not determined.
Waste Management: Not determined.
Disposal should be made in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
U.S. DOT:
Proper Shipping Name: Not Applicable
Hazard Class: Not Regulated
UN/NA Number: Not Applicable
DOT Packing Group: Not Applicable
IMDG:
Proper Shipping Name: Not Applicable
Hazard Class: Not Regulated
Hazard Subclass: Not Applicable
UN No.: Not Applicable
Packing Group: Not Applicable
Marine Pollutant: No
15. REGULATORY INFORMATION
US Federal Regulations:
Page 3 of 5
MATERIAL SAFETY DATA SHEET
Johnsens DOT 4 Brake Fluid
Trade Name:
5034
MSDS NO.
Revision Date: 05/21/2003
Date Printed 06/21/2004
Trade Name: Johnsens DOT 4 Brake Fluid MSDS NO. 5034
Ingredient/CAS No. wt. % SARA 313 SARA 302 RQ TPQ
Alkyl Ester 30-50 Not Listed Not Listed Not Listed Not Determined
proprietary
Triethylene glycol monobutyl ether 10-40 Listed Not Listed NA NA
143-22-6
Triethylene glycol monomethyl ether 0-20 Listed Not Listed NA NA
112-35-6
Polyethylene glycol monomethyl 0-20 Not Listed Not Listed NA NA
ether
9004-74-4
Polyethylene glycol monobutyl ether 0-20 Not Listed Not Listed NA NA
9004-77-7
Poly(ethylene oxide) 5-15 Not Listed Not Listed Not Listed Not Listed
25322-68-3
Inhibitor Package 1-3 Not Listed Not Listed Not Listed Not Determined
proprietary
No specific component of this material is listed as a Hazardous Substance CERCLA (40 CFR 261). However, this product
contains various ethylene glycols and glycol ethers which are each included as a broad category on the CERCLA Hazardous
substances list.
SARA 311/312 Hazard Catagories: Immediate Health: Yes, Delayed Health: Yes, Fire: No, Reactive: No, Pressure: No.
State Regulations:
Ingredient/CAS No. wt. % California Prop. 65 California Prop. 65 California Prop. 65 California Prop. 65
Cancer list Developmental Reproductive Female Reproductive Male
Toxicity
Alkyl Ester 30-50 Not Listed Not Listed Not Listed Not Listed
proprietary
Triethylene glycol monobutyl ether 10-40 Not Listed Not Listed Not Listed Not Listed
143-22-6
Triethylene glycol monomethyl ether 0-20 Not Listed Not Listed Not Listed Not Listed
112-35-6
Polyethylene glycol monomethyl 0-20 Not Listed Not Listed Not Listed Not Listed
ether
9004-74-4
Polyethylene glycol monobutyl ether 0-20 Not Listed Not Listed Not Listed Not Listed
9004-77-7
Poly(ethylene oxide) 5-15 Not Listed Not Listed Not Listed Not Listed
25322-68-3
Inhibitor Package 1-3 Not Listed Not Listed Not Listed Not Listed
proprietary
U.S. TSCA: The components of this product are listed on the TSCA Inventory.
This product contains the following chemical known to the State of California to cause birth defects
and/or other reproductive harm: Ethylene glycol monomethyl ether (cas#109-86-4; Present at less
than 0.01%).
16. OTHER INFORMATION
General Notes: Do not allow undiluted material or large quantities to reach groundwater, bodies of water or sewer system.
Disclaimer:
The information and recommendations contained herein are based upon tests believed to be reliable. However, the manufacturer/distributor of this
Page 4 of 5
MATERIAL SAFETY DATA SHEET
Johnsens DOT 4 Brake Fluid
Trade Name:
5034
MSDS NO.
Revision Date: 05/21/2003
Date Printed 06/21/2004
Trade Name: Johnsens DOT 4 Brake Fluid MSDS NO. 5034
product does not guarantee their accuracy or completeness NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER
EXPRESSED OR IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE FITNESS OF THE GOODS
FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions of usage may be required. The manufacturer/distributor assumes no
responsibility for results obtained or for incidental or consequential damages, including lost profits, arising from the use of these data. No warranty
against infringement of any patent, copyright or trademark is made or implied.
Page 5 of 5
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