MATERIAL SAFETY DATA SHEET
Trade Name: Johnsens De-Icer
MSDS NO. 3282
Revision Date: 11/13/2007
Date Printed 11/13/2007
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Trade Name: Johnsens De-Icer
Chemical Family: ALCOHOL
Synonyms: None
Emergency Telephone (24 hr.): CHEMTREC 1-800-424-9300
Supplier: Technical Chemical Company, P.O. Box 139, Cleburne, Texas 76033
2. COMPOSITION/INFORMATION ON INGREDIENTS
Weight % OSHA TWA OSHA STEL OSHA SKIN
Component
55-65 Not Listed Not Listed Not Listed
Methyl Alcohol
67-56-1
15-25 Not Listed Not Listed Not Listed
Ethylene Glycol
107-21-1
5-15 Not Listed Not Listed Not Listed
Propane
74-98-6
0-10 Not Listed Not Listed Not Listed
Butane
106-97-8
0-10 Not Listed Not Listed Not Listed
Isopropyl Alcohol
67-63-0
0-10 Not Listed Not Listed Not Listed
Iso-Butane
75-28-5
Weight % OSHA Z PEL OSHA Z TWA OSHA Z Ceiling
Component
3 3
55-65 260 mg/m 200 ppm 260 mg/m 200 ppm Not Listed
Methyl Alcohol
67-56-1
3
15-25 Not Listed Not Listed 125 mg/m 50 ppm
Ethylene Glycol
107-21-1
3 3
5-15 1800 mg/m 1000 ppm 1800 mg/m 1000 ppm Not Listed
Propane
74-98-6
3
0-10 Not Listed 1900 mg/m 800 ppm Not Listed
Butane
106-97-8
3 3
0-10 980 mg/m 400 ppm 980 mg/m 400 ppm Not Listed
Isopropyl Alcohol
67-63-0
0-10 Not Listed Not Listed Not Listed
Iso-Butane
75-28-5
ACGIH TLV TWA ACGIH TLV STEL ACGIH TLV Ceiling
Component
200 ppm 250 ppm Not Listed
Methyl Alcohol
67-56-1
3
Not Listed Not Listed 100 mg/m Aerosol.
Ethylene Glycol
107-21-1
1000 ppm Not Listed Not Listed
Propane
74-98-6
1000 ppm Not Listed Not Listed
Butane
106-97-8
200 ppm 400 ppm Not Listed
Isopropyl Alcohol
67-63-0
1000 ppm Not Listed Not Listed
Iso-Butane
75-28-5
Page 1 of 7
MATERIAL SAFETY DATA SHEET
Trade Name: Johnsens De-Icer
MSDS NO. 3282
Revision Date: 11/13/2007
Date Printed 11/13/2007
3. HAZARDS IDENTIFICATION
Emergency Overview: Danger: Extremely flammable. Danger: Poison. Content under pressure. This material is an eye and skin
irritant. Ingestion of even small amounts of methyl alcohol can cause blindness and death. Possible
redness and defatting may result from prolonged skin exposure to this matieral. Ingestion can cause
irreversible nervous system damage and death. Absorption through skin increases exposure. Gross
inhalation overexposure may cause: respiratory track irritation, kidney damage, blood, liver damage, lung
damage and central nervous system depression. Repeated exposure over TLV can cause blindness.
HMIS Classification: Health: *2 Flammability: 4 Physical Hazard: 2
NFPA Rating: Health: 2 Flammability: 4 Reactivity: 0
4. FIRST AID MEASURES
Eye Contact: In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes
and get medical attention immediately after flushing.
Ingestion: Induce vomiting promptly using physician's instructions or by having patient stick finger down throut. After
vomiting has been induced, give two teaspoonsful of baking soda in a glass of water. Seek immediate
medical attention. Never give fluids or induce vomiting if the victim is unconscious or having convulsions.
Inhalation: If inhaled, remove to fresh air. If not breathing give artificial respiration, preferably mouth-to-mouth. If
breathing is difficult give oxygen. Get medical attention.
Skin Contact: Wash with soap and water for 15 minutes. If irritation persists or signs of toxicity occur, seek medical
attention. Remove contaminated clothing and shoes, and launder before reuse.
5. FIRE FIGHTING MEASURES
Flammable Properties
Flash Point 掳F(掳C): -200 F (Propellant)
Flash Point Method: TAG Closed Cup
Flammable Limits in Air - Lower (%): 1.1%
Flammable Limits in Air - Upper (%): Not Determined
Autoignition Temperature 掳F(掳C): 650 F (Lowest Component)
Extinguishing Media: Carbon dioxide. Use water spray to keep containers cool that are exposed to heat or flames. Foam.
Protection Of Fire-Fighters:
Special Fire-Fighting Procedures: Wear approved positive-pressure self-contained breathing apparatus and protective clothing. Vapor may
cause flash fire. Warning!! Contents under pressure. Container may rupture under fire conditions.
Decomposition may occur.
Hazardous Combustion Products: Carbon Dioxide. Carbon Monoxide.
Aerosol Comments: NFPA Level 2 Aerosol
6. ACCIDENTAL RELEASE MEASURES
Personal Precautions: Wear appropriate protective clothing and equipment to prevent skin and eye contact.
Spill Procedures: Contain any liquid from leaking containers. Avoid all sources of ignition; heat, sparks and open flames.
Action to be taken if material is released Do not puncture or incinerate container. Contents under pressure. Wear proper protective equipment as
or spilled: specified in the protective equipment section. Remove sources of ignition. Leaking containers should be
removed to an isolated, well-ventilated area and transferred to other suitable containers. Wipe, scrape, or
soak up in an inert material and put in a container intended for flammable materials for disposal.
Environmental Precautions: Do not allow to enter sanitary drains, sewer or surface and subsurface waters. Keep out of lakes, ponds or
streams.
7. HANDLING AND STORAGE
Handling and Storage: Caution: Contents under pressure. Keep away from heat and open flame. Use only in a well ventilated
area. Avoid breathing vapors, if exposed to high vapor concentration, leave area at once. Avoid contact
with skin and eyes. Do not puncture, incinerate or store above 120 F. Exposure to high temperatures may
cuase bursting. DO NOT store in the passenger compartment of an automobile.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls: Use in a well ventilated area. Local exhaust ventilation as necessary to maintain exposures to within
applicable limits.
Eyes: Chemical goggles; also wear a face shield if splashing hazard exists.
Page 2 of 7
MATERIAL SAFETY DATA SHEET
Trade Name: Johnsens De-Icer
MSDS NO. 3282
Revision Date: 11/13/2007
Date Printed 11/13/2007
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Skin Protection: Avoid skin contact. Wear protective clothing and gloves.
Respiratory Protection: Do not breath mist or vapor. Use in a well ventilated area. Appropriate respiratory protection shall be worn
when applied engineering controls are not adequate to protect against inhalation exposure.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Colorless to light yellow liquid
Odor: SLIGHT ALCOHOL
pH Value: Not Determined
Vapor Pressure: 63.9 mm of Hg @ 20C (liquid)
Vapor Density (Air=1): 1.1 (liquid)
Boiling Point (掳F): 160-389 F (liquid)
Melting/Freezing Point: Not Determined.
Solubility in Water: Solubility in Water:
Bulk Density at 20掳C: 7.239 lb/gal
Molecular Weight: Mixture
Specific Gravity (H20=1): .869 @ 60 F (liquid)
Viscosity: Not Determined.
Evaporation Rate: Not Determined
VOC Content(%): Not determined.
Decomposition Temperature: Not Determined
10. STABILITY AND REACTIVITY
Chemical Stability: STABLE.
Conditions to Avoid: Keep away from heat,sparks and flame. Avoid any source of ignition. Do not expose to heat or store at
temperatures above 120 F.
Materials to Avoid: Contact with oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide. Carbon dioxide. and other asphxiants.
Hazardous Polymerization: WILL NOT OCCUR
11. TOXICOLOGICAL INFORMATION
Toxicological Data:
Component
Route Species Dose
Inhalation Rats LC50 64,000 ppm
Methyl Alcohol
67-56-1
Inhalation Rats LC50 10876 mg/kg
Ethylene Glycol
107-21-1
NA NA Not known.
Propane
74-98-6
3
Inhalation Rats LC50, 658 gm/m /4H
Butane
106-97-8
Inhalation Rats LC50 16,000 ppm
Isopropyl Alcohol
67-63-0
Inhalation Rats LC50 57 pph/15M
Iso-Butane
75-28-5
Carcinogenicity:
Page 3 of 7
MATERIAL SAFETY DATA SHEET
Trade Name: Johnsens De-Icer
MSDS NO. 3282
Revision Date: 11/13/2007
Date Printed 11/13/2007
Component
IARC NTP OSHA
Not Listed Not Listed Not Listed
Methyl Alcohol
67-56-1
Not Listed Not Listed Not Listed
Ethylene Glycol
107-21-1
Not Listed Not Listed Not Listed
Propane
74-98-6
Not Listed Not Listed Not Listed
Butane
106-97-8
Not Listed Not Listed Not Listed
Isopropyl Alcohol
67-63-0
Not Listed Not Listed Not Listed
Iso-Butane
75-28-5
12. ECOLOGICAL INFORMATION
Remarks: Ecological testing has not been conducted on this product.
13. DISPOSAL CONSIDERATION
Waste Classification: Not determined.
Waste Management: Not determined.
Disposal Method: Disposal should be made in accordance with federal, state and local regulations.
14. TRANSPORTATION INFORMATION
U.S. DOT:
Proper Shipping Name: ORM-D CONSUMER COMMODITY
Hazard Class: ORM-D
UN/NA Number: Not Applicable
DOT Packing Group: Not Applicable
IMDG:
Proper Shipping Name: Aeroslols (Limited Quantity)
Hazard Class: 2.1
Hazard Subclass: Not determined.
UN No.: UN1950
Packing Group: PG II
Marine Pollutant: No
15. REGULATORY INFORMATION
US Federal Regulations:
SARA 313 SARA 302 TPQ RQ
Component
Listed. Not Listed Not Listed Not Listed
Methyl Alcohol
67-56-1
Listed. Not Listed Not Listed Not Listed
Ethylene Glycol
107-21-1
Not Listed Not Listed Not Listed Not Listed
Propane
74-98-6
Not Listed Not Listed Not Listed Not Listed
Butane
106-97-8
Listed. Not Listed Not Listed Not Listed
Isopropyl Alcohol
67-63-0
Not Listed Not Listed Not Listed Not Listed
Iso-Butane
75-28-5
Page 4 of 7
MATERIAL SAFETY DATA SHEET
Trade Name: Johnsens De-Icer
MSDS NO. 3282
Revision Date: 11/13/2007
Date Printed 11/13/2007
US OSHA HEALTH CLASSIFICATION: Hazardous per OSHA 29 CFR 1910.1200
SARA 311/312 Hazard Catagories: Not Determined.
State Regulations:
California Prop. 65 California - Prop 65 California Prop. 65 California Prop. 65
Component
Cancer list Developmental Toxicity Reproductive Female Reproductive Male
Not Listed Not Listed Not Listed Not Listed
Methyl Alcohol
67-56-1
Not Listed Not Listed Not Listed Not Listed
Ethylene Glycol
107-21-1
Not Listed Not Listed Not Listed Not Listed
Propane
74-98-6
Not Listed Not Listed Not Listed Not Listed
Butane
106-97-8
Not Listed Not Listed Not Listed Not Listed
Isopropyl Alcohol
67-63-0
Not Listed Not Listed Not Listed Not Listed
Iso-Butane
75-28-5
Page 5 of 7
MATERIAL SAFETY DATA SHEET
Trade Name: Johnsens De-Icer
MSDS NO. 3282
Revision Date: 11/13/2007
Date Printed 11/13/2007
New Jersey Right-to-Know List:
Component
Substance no. 2079
Methyl Alcohol
Substance no. 2422
67-56-1
Substance no. 2423
Substance no. 2425
Substance no. 2426
Substance no. 2427
Substance no. 2428
Substance no. 2429
Substance no. 2430
Substance no. 1222
Substance no. 0878
Ethylene Glycol
107-21-1
Substance no. 2422
Propane
Substance no. 2423
74-98-6
Substance no. 2425
Substance no. 2426
Substance no. 2427
Substance no. 2428
Substance no. 2429
Substance no. 2430
Substance no. 1594
Substance no. 0273
Butane
Substance no. 2422
106-97-8
Substance no. 2423
Substance no. 2425
Substance no. 2426
Substance no. 2427
Substance no. 2428
Substance no. 2429
Substance no. 2430
Substance no. 1076
Isopropyl Alcohol
Substance no. 2079
67-63-0
Substance no. 2422
Substance no. 2423
Substance no. 2425
Substance no. 2426
Substance no. 2427
Substance no. 2428
Substance no. 2429
Substance no. 2430
Substance no. 2381
Substance no. 2422
Iso-Butane
Substance no. 2423
75-28-5
Substance no. 2425
Substance no. 2426
Substance no. 2427
Substance no. 2428
Substance no. 2429
Substance no. 2430
Substance no. 1040
U.S. TSCA: The components of this product are listed on the TSCA Inventory.
Canadian Inventory: The components of this product are listed on the Canadian DSL or NDSL Inventory.
16. OTHER INFORMATION
General Notes: Do not allow undiluted material or large quantities to reach groundwater, bodies of water or sewer system.
Disclaimer: The information and recommendations contained herein are based upon tests believed to be reliable.
However, the manufacturer/distributor of this product does not guarantee their accuracy or completeness
NOR SHALL ANY OF THIS INFORMATION CONSTITUTE A WARRANTY, WHETHER EXPRESSED OR
IMPLIED, AS TO THE SAFETY OF THE GOODS, THE MERCHANTABILITY OF THE GOODS, OR THE
FITNESS OF THE GOODS FOR A PARTICULAR PURPOSE. Adjustment to conform to actual conditions
of usage may be required. The manufacturer/distributor assumes no responsibility for results obtained or
for incidental or consequential damages, including lost profits, arising from the use of these data. No
warranty against infringement of any patent, copyright or trademark is made or implied.
Page 6 of 7
MATERIAL SAFETY DATA SHEET
Trade Name: Johnsens De-Icer
MSDS NO. 3282
Revision Date: 11/13/2007
Date Printed 11/13/2007
Page 7 of 7
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