Material Safety Data Sheet
1.0 Product and Company Identification
Identification of the preparation: 51640A 鈥? No 40 Black
Use of the preparation: Inkjet printing
Hewlett-Packard Company
Company Identification:
1000 NE Circle Boulevard
Corvallis, Oregon 97330-4239
United States
1-800-457-4209 (USA and Canada)
Emergency telephone number
503-494-7199 (USA direct)
Hewlett-Packard Health Effects Line:
Singapore: +001-800-332-13321
208-323-2551 (USA direct)
General information telephone
number:
Local Contact Information: Ireland
Liffey Park Technology Campus
Barnhall Road,
Leixlip, Co. Kildare
Phone: 01 6150000
United Kingdom
Hewlett-Packard, Ltd.
Cain Road, Amen Corner
Bracknell, Berkshire, RG12 1HN
Phone: 1344 36-0000
Hazard Rating NFPA/HMIS
Health 1
Flammability 1
Instability/Reactivity 0
Special none
2.0 Composition/Information on Hazardous Ingredients
This ink supply contains an aqueous ink formulation
Component/Substance CAS Number EU Number % by EU Classification
Weight
Diethylene glycol 111-46-6 203-872-2 <6 Xn; R22
Carbon black 1333-86-4 215-609-9 <4 not classified
Water 7732-18-5 231-791-2 > 50 not classified
3.0 Hazard Identification
This ink is not classified according to EU Directive 1999/45/EC.
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Material Safety Data Sheet
Routes of Exposure: Potential routes of overexposure to this product are skin
and eye contact.
Inhalation of vapor and ingestion are not expected to be
significant routes of exposure for this product under
normal use conditions.
Complete toxicity data are not available for this specific
formulation.
Acute Health Hazards: Any potential hazards are presumed to be due to
exposure to the components.
Diethylene glycol: Harmful if swallowed. May cause
kidney and liver damage. May depress the central
nervous system.
Chronic Health Hazards: Carbon Black: Chronic inhalation studies performed
with fine dust particles resulted in lung tumors in
animals. The IARC classification was based upon these
results. IARC also concluded 鈥渢here is inadequate
evidence in humans for the carcinogenicity of carbon
black.鈥? Inhalation of fine dust particles is not expected
to occur during normal conditions of use of this ink.
Carcinogenicity: Carbon black has been classified by the International
Agency for Research on Cancer (IARC) as Group 2B
(possibly human carcinogen). None of the other
ingredients have been classified as carcinogens
according to EU, IARC, MAK, NTP or OSHA.
4.0 First Aid Measures
1-800-457-4209 (USA and Canada)
Emergency telephone number
503-494-7199 (USA direct)
Hewlett-Packard Health Effects
Singapore: +001-800-332-13321
Line:
Inhalation: Remove to fresh air. If symptoms persist, consult a
physician.
Ingestion: If stomach upset persists, consult a physician.
Skin: Wash affected areas thoroughly with soap and
water. If irritation persists, consult a physician.
Eyes: Do not rub eyes. Immediately flush with large
amounts of clean, lukewarm water (low pressure) for
at least 15 minutes or until particles are removed. If
irritation persists, consult a physician.
5.0 Fire Fighting Measures
Extinguishing media: Water, dry chemical, carbon dioxide, foam
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Material Safety Data Sheet
None known
Unsuitable Extinguishing
Media:
None known
Special Firefighting
Procedures:
No special hazards known
Unusual fire and explosion
hazards:
Not determined
Auto-ignition temperature:
Flashpoint (method): > 200o F, > 93.3o C (US EPA Method 1020)
Hazardous Combustion Refer to section 10
Products:
6.0 Accidental release measures
Spill or Leak Procedures: Standard eye and skin protection is recommended.
Environmental precautions: Do not discharge into drains (See also Section 13,
Disposal considerations)
7.0 Handling and Storage
Storage Temperature: 59oF to 95oF; 15oC to 35oC
Handling and Storage Keep out of the reach of children.
precautions: Keep away from extreme heat or cold.
Shelf Life: 1 year
Special Sensitivity: None
8.0 Exposure control/ personal protection
Exposure Limit Values: Diethylene glycol: Austria, Germany, Sweden,
Switzerland, TWA=10ppm; Ireland, UK
TWA=23ppm; Denmark TWA=2.5ppm
Carbon black: OSHA, ACGIH, Canada, Denmark,
Finland, France, Ireland, Italy, Netherlands,
Norway, UK TWA = 3.5mg/m3; Belgium
TWA=3.6mg/m3; Germany TWA=6mg/m3
Exposure Controls: Standard eye and skin protection for laboratory
chemical safety is recommended. Use in well
ventilated area.
9.0 Physical and chemical properties
7.9 鈥? 8.5
pH:
Not Determined
Boiling point:
> 200o F, > 93.3o C
Flash point:
US NFPA/HMIS Flammability rating = 1
Flammability:
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Material Safety Data Sheet
Not applicable
Explosive properties:
Not applicable
Oxidizing properties:
Not applicable
Vapor Pressure:
Specific Gravity 1.0 to 1.2
Relative density:
Soluble in water
Solubility:
Not determined
Partition coefficient:
Not determined
Viscosity:
>1 (air = 1.0)
Vapor density:
Not applicable
Evaporation rate:
Not applicable
Other:
10.0 Stability and reactivity
Stable under normal storage conditions
Stability:
Strong oxidizers and bases
Incompatibilities:
Oxides of carbon/nitrogen/sulfur, water
Thermal decomposition
products:
None
Hazardous polymerization:
11.0 Toxicological information
Refer to Section 3 for potential heath effects and Section 4 for first aid measures
Skin sensitization: Non-sensitizer in guinea pig (OECD 406). Not classified as a skin
sensitizer according to EU Directives 67/548/EEC and 1999/45/EC.
12.0 Ecological information
Ink Formulation:
96 Hour LC50 LC50 > 750 mg/L Fathead minnow
13.0 Disposal considerations
Dispose in accordance with all applicable US Federal, state, local, and country laws.
14.0 Transportation information
Not a regulated article under United States DOT, IATA, ADR, or RID.
Not applicable
UN Number:
Not applicable
Class:
Not applicable
Proper Shipping Name:
Not applicable
Packing Group:
Not listed
Marine Pollutant:
None noted
Special Precautions:
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Material Safety Data Sheet
15.0 Regulatory information
US EPA TSCA Inventory: All ingredients are listed or exempt.
US EPA TSCA 12(b): Contains 1-methyl-2-pyrrolidone (CAS
872-50-4).
EU Notification: All ingredients are listed on EINECS
and/or ELINCS or exempt.
EU Hazard Label (1999/45/EC): This product does not require a label
according to EU Directive 1999/45/EC.
16.0 Other information
Date Prepared: July 18, 2002
HP-DMS Document Control 09000de78022b35a-eng
Number:
Revision Information: This document replaces all prior versions of the
MSDS.
EU Risk (R) Phrase definitions: R22: Harmful if swallowed
Other Information: This MSDS was prepared in compliance with EU
Directive 91/155/EEC as amended by 2001/58/EC
and USA OSHA Hazard Communication Standard
(29CFR1910.1200).
DISCLAIMER: This Material Safety Data Sheet (MSDS) is provided without charge to
customers of Hewlett-Packard. Data is the most current known to Hewlett-Packard at
the time of preparation of this MSDS and is believed to be accurate. It should not be
construed as guaranteeing specific properties of the products as described or suitability
for a particular application.
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