Page 1 of 6
MSDS #: TC1150-0101
MATERIAL SAFETY DATA SHEET Product Code: 1474A / F41-4102
SECTION 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE
COMPANY/UNDERTAKING
Canon Cartridge A30 (Black)
Product Name:
1474A / F41-4102
Product Code:
Manufacturer: Canon Inc.,30-2, Shimomaruko 3-Chome, Ohta-ku, Tokyo, Japan, Ph # 03-3758-2111
Canon USA, Inc., One Canon Plaza, Lake Success, NY, 11042, USA
Supplier:
Phone #: 1-800-OK-CANON 24 Hr. Emergency CHEMTREC # 1-800-424-9300
SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS
< Ingredient(s) >
CAS # / Weight EU Symbol/ USA
Chemical Name / ACGIH TLV EU ILV DFG MAK
EC # % R-Phrase OSHA PEL
Generic name
Styrene acrylate Confidential 50-60 None/ None Not established Not established Not established Not established
copolymer
Iron oxide 1317-61-9/ 30-40 None/ None Not established Not established Not established Not established
215-277-5
Styrene polymer Confidential 5-10 None/ None Not established Not established Not established Not established
< Carcinogen >
Chemical Name CAS # Reference
No component of this toner is listed as a human carcinogen or a potential
carcinogen in IARC Monographs, NTP, OSHA regulations or Annex I to
Directive 67/548/EEC.
SECTION 3 HAZARDS IDENTIFICATION
EU Classification:
Not classified as dangerous.
Emergency Overview:
Black fine powder, slight plastic odor.
Potential Health Effects and Symptoms:
Inhalation:
Exposure to excessive amounts of dust may cause physical irritation to respiratory tract.
Ingestion:
Practically non-toxic. Ingestion is a minor route of entry for intended use of this product.
Eye:
May cause transient slight irritation.
Skin:
May be non-irritant.
Chronic Effects:
Prolonged inhalation of excessive amounts of dust may cause lung damage. Use of this product as intended does
not result in inhalation of excessive amounts of dust.
Medical Conditions Generally known to be Aggravated by Exposure:
Not determined
Date of Issue: August 18, 1987 Revised: October 6, 2003
Page 2 of 6
MSDS #: TC1150-0101
MATERIAL SAFETY DATA SHEET Product Code: 1474A / F41-4102
SECTION 4 FIRST AID MEASURES
First Aid Measures:
Inhalation:
If symptoms are experienced, move victim to fresh air and obtain medical advice.
Ingestion:
Rinse mouth. Drink 1 or 2 glasses of water. If irritation or discomfort occurs, obtain medical advice immediately.
Eye:
Do not allow victim to rub eye(s). Flush with lukewarm, gently flowing water for 5 minutes or until particle is
removed. If irritation persists, obtain medical attention.
Skin:
Wash with soap and water. If irritation persists, obtain medical advice.
Note to Physicians:
None
SECTION 5 FIRE FIGHTING MEASURES
Fire Fighting Measures:
Extinguishing Media:
CO2, water, dry chemicals
Unsuitable Extinguishing Media:
None
Special Fire Fighting Procedures:
None
Unusual Fire and Explosion Hazards:
Can form explosive dust-air mixtures when finely dispersed in air.
Fire and Explosive Properties (See also Section 9):
Hazardous Combustion Products:
CO2, CO
Other Properties:
Not available
SECTION 6 ACCIDENTAL RELEASE MEASURES
Personal Precautions:
Avoid breathing dust.
Environmental Precautions:
Do not wash away into sewer.
Method for Cleaning Up:
Sweep slowly spilled powder on to paper, and carefully transfer into a waste container. Clean remainder with wet
paper, wet cloth or a vacuum cleaner.
If a vacuum cleaner is used, it must rate as a dust explosion-proof type. Fine powder can form explosive dust-air
mixtures.
SECTION 7 HANDLING AND STORAGE
Handling:
Avoid breathing dust.
Use with adequate ventilation.
Storage:
Keep out of the reach of children.
Keep away from oxidizing materials.
Specific Uses:
Toner for electrophotographic apparatus.
For more information, please refer to the instruction of this product.
Date of Issue: August 18, 1987 Revised: October 6, 2003
Page 3 of 6
MSDS #: TC1150-0101
MATERIAL SAFETY DATA SHEET Product Code: 1474A / F41-4102
SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines:
USA OSHA PEL (TWA): 15 mg/m3 (Total dust), 5 mg/m3 (Respirable fraction)
10 mg/m3 (Inhalable fraction), 3 mg/m3 (Respirable fraction)
ACGIH TLV (TWA):
4 mg/m3 (Inhalable fraction), 1.5 mg/m3 (Respirable fraction)
DFG (MAK):
(Also refer to SECTION 2)
Engineering Controls:
Use adequate ventilation.
Personal Protection Equipment(s):
Respiratory Protection: Required
Not Required
Required
Eye/Face Protection:
Not Required
Required
Skin Protection:
Not Required
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Black fine powder
Slight plastic odor
Odor:
Not applicable
pH:
Boiling Point/Range(掳C): Not applicable
100 - 150 (Softening point)
Melting Point/Range(掳C):
Decomposition Temperature(掳C): >200
Not applicable
Flash Point(掳C):
Flammable (Explosive) Limits: Not applicable
Not available
Autoignition Temperature(掳C):
Not-flammable (Test method : Directive 92/69/EEC, A10 Flammability
Flammability:
(Solids))
Can form explosive dust-air mixtures when finely dispersed in air.
Explosive Properties:
Oxidizing Properties: Not available
Not applicable
Vapor Pressure:
Not applicable
Vapor Density:
1.4 - 1.6
Density / Specific Gravity:
Water Solubility: Negligible
Partially soluble in toluene and xylene.
Fat Solubility:
Partition Coefficient (n-Octanol/Water): Not applicable
Percent Volatile: Negligible
Not applicable
Evaporation Rate:
Not applicable
Viscosity (mPa s):
Date of Issue: August 18, 1987 Revised: October 6, 2003
Page 4 of 6
MSDS #: TC1150-0101
MATERIAL SAFETY DATA SHEET Product Code: 1474A / F41-4102
SECTION 10 STABILITY AND REACTIVITY
Stable
Stability:
Unstable
None
Conditions to Avoid:
Strong oxidizers
Materials to Avoid:
Hazardous Decomposition Products: CO, CO2
Hazardous Polymerization: May Occur
Will Not Occur
None
Conditions to Avoid:
SECTION 11 TOXICOLOGICAL INFORMATION
Acute Toxicity:
Inhalation:
Not available
Ingestion:
Estimate: Rat, LD50> 5000 mg/kg
Eye:
Estimate: Rabbit, transient slight conjunctival irritation only.
Skin:
Estimate: Rabbit, non-irritant
Sensitization:
Guinea pig, skin : Non-sensitizing
Mutagenicity:
Ames Test (S. typhimurium): Negative
Reproductive Toxicity:
Not available
Carcinogenicity:
Not available
Others:
Chronic effects:
Muhle et al. reported pulmonary response upon chronic inhalation exposure in rats to a toner enriched in
respirable-sized particles compared to commercial toner. No pulmonary change was found at 1 mg/m3 which is
most relevant to potential human exposure. A minimal to mild degree of fibrosis was noted in 22% of the
animals at 4 mg/m3, and a mild to moderate degree of fibrosis was observed in 92% of the animals at 16 mg/m3.
These findings are attributed to "lung overloading", a generic response to excessive amounts of any dust retained
in the lung for a prolonged interval.
Date of Issue: August 18, 1987 Revised: October 6, 2003
Page 5 of 6
MSDS #: TC1150-0101
MATERIAL SAFETY DATA SHEET Product Code: 1474A / F41-4102
SECTION 12 ECOLOGICAL INFORMATION
Not available
Mobility:
Persistence / Degradability: Not available
Bioaccumulation: Not available
Not available
Ecotoxicity:
Not available
Other Adverse Effects:
SECTION 13 DISPOSAL CONSIDERATION
Method of Disposal:
DO NOT put toner or toner container into fire; heated toner may cause severe burns. DO NOT shred a toner
container, unless dust-explosion preventing measures are taken. Finely dispersed particles form explosive mixtures
in air. Disposal should be subject to federal, state and local laws.
SECTION 14 TRANSPORT INFORMATION
By ship:None By air:Not identified
UN #:
UN Shipping Name: By ship:None By air:Not identified
UN Classification: By ship:None By air:Not identified
UN Packing Group: By ship:None By air:Not identified
Yes Chemical name (wt%):
Marine Pollutant:
No
Special Precautions: None
SECTION 15 REGULATORY INFORMATION
< EU Information >
Information on the Label:
Symbol & Indication: Not required
R-Phrase:
Not required
S-Phrase:
Not required
Dangerous Component(s):
None
Special Precautions under 1999/45/EC Annex V:
Not required
Specific Provisions in Relation to Protection of Man or the Environment:
76/769/EEC: Not regulated
(EC)2037/2000: Not regulated
Not regulated
(EC)304/2003:
None
Others:
< USA Information >
Information on the Label:
Signal Word: Not required
Hazard warning:
Not required
Date of Issue: August 18, 1987 Revised: October 6, 2003
Page 6 of 6
MSDS #: TC1150-0101
MATERIAL SAFETY DATA SHEET Product Code: 1474A / F41-4102
Safety Advice:
Not required
Hazardous Component(s):
None
SARA Title III 搂313:
Chemical Name Weight %
None
California Proposition 65:
Chemical Name Weight %
None
< Canada Information >
WHMIS Controlled Product: Not applicable (Manufactured article)
< Australia Information >
Not classified as hazardous according to criteria of NOHSC.
Statement of Hazardous Nature:
SECTION 16 OTHER INFORMATION
Revised information from the previous version:
Entirely revised
Literature Reference:
- U.S. Department of Labor, 29CFR Part 1910
- U.S. Environmental Protection Agency, 40CFR Part 372
- U.S. Consumer Product Safety Commission, 16CFR Part 1500
- ACGIH, Threshold Limit Values for Chemical Substances and Physical Agents and Biological Exposure Indices
- U.S. Department of Health and Human Services National Toxicology Program, Annual Report on Carcinogens
- World Health Organization International Agency for Research on Cancer, IARC Monographs on the Evaluation on the Carcinogenic Risk of
Chemicals to Humans
- DFG, List of MAK and BAT Values
- EU Directive 76/769/EEC, 67/548/EEC, 1999/45/EC
- EU Regulation (EC)2037/2000, (EC)304/2003
- Canada Workplace Hazardous Materials Information System
- Australia National Occupational Health and Safety Commission's Approved Criteria for Classifying Hazardous Substances[NOHSC:1008]
Abbreviations:
EU: European Union.
OSHA PEL: PEL(Permissible Exposure Limit) under Occupational Safety and Health Administration (USA).
ACGIH TLV: TLV(Threshold Limit Value) under American Conference of Governmental Industrial Hygienists.
EU ILV: Indicative Limit Values for Occupational Exposure under EU Directive 91/322/EEC and 2000/39/EC.
DFG MAK: MAK(Maximale Arbeitsplatz-Konzentration) under Deutsche Forschungsgemeinschaft.
TWA: Time Weighted Average.
STEL: Short Term Exposure Limit.
IARC: International Agency for Research on Cancer.
NTP: National Toxicology Program (USA).
OSHA HCS: Occupational Safety and Health Act, Hazard Communication Standard (USA).
FHSA: Federal Hazardous Substances Act (USA).
WHMIS: Workplace Hazardous Materials Information System.
NOHSC: National Occupational Health and Safety Commission.
The information, data and recommendations set forth herein (the "Information") are presented in good faith and are believed to be correct as of the
date hereof. The company/manufacturer makes no representations as to the completeness or accuracy of the Information and disclaims
responsibility for any reliance thereon. The Information is provided upon the condition that the persons receiving same will make their own
determination as to its suitability for their purposes prior to use. Any use of the Information must be determined by the user to be in accordance
with applicable Federal, state and local laws and regulations. In no event will the company/manufacturer be responsible for damages of any
nature whatsoever resulting from the use or reliance upon the Information.
NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, OF MERCHANTABILITY, FITNESS FOR A
PARTICULAR PURPOSE OR OF ANY OTHER NATURE ARE MADE WITH RESPECT TO THE INFORMATION OR THE PRODUCT
TO WHICH THE INFORMATION REFERS.
Date of Issue: August 18, 1987 Revised: October 6, 2003
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