SIGMA-ALDRICH
MATERIAL SAFETY DATA SHEET
Date Printed: 12/02/2004
Date Updated: 08/13/2004
Version 1.5
Section 1 - Product and Company Information
Product Name ALLYL BROMIDE, 99%
Product Number A29585
Brand ALDRICH
Company Sigma-Aldrich
Street Address 3050 Spruce Street
City, State, Zip, Country SAINT LOUIS MO 63103 US
Technical Phone: 314 771 5765
Emergency Phone: 414 273 3850 Ext. 5996
Fax: 800 325 5052
Section 2 - Composition/Information on Ingredient
Substance Name CAS # SARA 313
3-BROMOPROPENE, 99% (STABILIZED) 106-95-6 No
(ALLYLBROMIDE)
Formula C3H5Br
Synonyms Bromallylene * 1-Bromo-2-propene * 3-Bromopropene
* 3-Bromopropylene
RTECS Number: UC7090000
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Flammable (USA) Highly Flammable (EU). Toxic. Dangerous for the
environment.
Highly flammable. Toxic by inhalation and if swallowed. Causes
burns. Very toxic to aquatic organisms.
Lachrymator. Target organ(s): Kidneys. Liver.
HMIS RATING
HEALTH: 3*
FLAMMABILITY: 3
REACTIVITY: 0
NFPA RATING
HEALTH: 3
FLAMMABILITY: 3
REACTIVITY: 0
*additional chronic hazards present.
For additional information on toxicity, please refer to Section 11.
Section 4 - First Aid Measures
ORAL EXPOSURE
If swallowed, wash out mouth with water provided person is
conscious. Call a physician immediately. Do not induce vomiting.
INHALATION EXPOSURE
If inhaled, remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
DERMAL EXPOSURE
In case of skin contact, flush with copious amounts of water for
at least 15 minutes. Remove contaminated clothing and shoes.
Call a physician.
EYE EXPOSURE
In case of contact with eyes, flush with copious amounts of
water for at least 15 minutes. Assure adequate flushing by
separating the eyelids with fingers. Call a physician.
Section 5 - Fire Fighting Measures
FLAMMABLE HAZARDS
Flammable Hazards: Yes
EXPLOSION HAZARDS
Vapor may travel considerable distance to source of ignition and
flash back. Container explosion may occur under fire conditions.
FLASH POINT
30.2 藲F -1 藲C Method: closed cup
EXPLOSION LIMITS
Lower: 4.4 % Upper: 7.3 %
AUTOIGNITION TEMP
290 藲C
FLAMMABILITY
N/A
EXTINGUISHING MEDIA
Suitable: Carbon dioxide, dry chemical powder, or appropriate
foam.
FIREFIGHTING
Protective Equipment: Wear self-contained breathing apparatus
and protective clothing to prevent contact with skin and eyes.
Specific Hazard(s): Emits toxic fumes under fire conditions.
Flammable liquid.
Section 6 - Accidental Release Measures
PROCEDURE TO BE FOLLOWED IN CASE OF LEAK OR SPILL
Evacuate area. Shut off all sources of ignition. Use nonsparking
tools.
PROCEDURE(S) OF PERSONAL PRECAUTION(S)
Wear self-contained breathing apparatus, rubber boots, and heavy
rubber gloves.
METHODS FOR CLEANING UP
Cover with dry lime or soda ash, pick up, keep in a closed
container, and hold for waste disposal. Ventilate area and wash
spill site after material pickup is complete.
Section 7 - Handling and Storage
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HANDLING
User Exposure: Do not breathe vapor. Do not get in eyes, on
skin, on clothing. Avoid prolonged or repeated exposure.
STORAGE
Suitable: Keep tightly closed. Keep away from heat, sparks, and
open flame.
Store at 2-8藲C
Section 8 - Exposure Controls / PPE
ENGINEERING CONTROLS
Use only in a chemical fume hood. Safety shower and eye bath. Use
nonsparking tools.
PERSONAL PROTECTIVE EQUIPMENT
Respiratory: Government approved respirator.
Hand: Compatible chemical-resistant gloves.
Eye: Chemical safety goggles.
Other: Faceshield (8-inch minimum).
GENERAL HYGIENE MEASURES
Wash contaminated clothing before reuse. Discard contaminated
shoes. Wash thoroughly after handling.
Section 9 - Physical/Chemical Properties
Appearance Physical State: Liquid
Color: Colorless
Property Value At Temperature or Pressure
Molecular Weight 120.98 AMU
pH N/A
BP/BP Range 70 - 71 藲C
MP/MP Range -119 藲C
Freezing Point N/A
Vapor Pressure N/A
Vapor Density 4.2 g/l
Saturated Vapor Conc. N/A
SG/Density 1.43 g/cm3
Bulk Density N/A
Odor Threshold N/A
Volatile% N/A
VOC Content N/A
Water Content N/A
Solvent Content N/A
Evaporation Rate N/A
Viscosity N/A
Surface Tension N/A
Partition Coefficient Log Kow: 1.79
Decomposition Temp. N/A
Flash Point 30.2 藲F -1 藲C Method: closed cup
Explosion Limits Lower: 4.4 %
Upper: 7.3 %
Flammability N/A
Autoignition Temp 290 藲C
Refractive Index 1.469
Optical Rotation N/A
Miscellaneous Data N/A
Solubility Solubility in Water:4 mg/ml H2O
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N/A = not available
Section 10 - Stability and Reactivity
STABILITY
Stable: Stable.
Materials to Avoid: Strong oxidizing agents, Strong bases.
HAZARDOUS DECOMPOSITION PRODUCTS
Hazardous Decomposition Products: Carbon monoxide, Carbon dioxide,
Hydrogen bromide gas.
HAZARDOUS POLYMERIZATION
Hazardous Polymerization: Will not occur
Section 11 - Toxicological Information
ROUTE OF EXPOSURE
Skin Contact: Causes burns.
Skin Absorption: May be harmful if absorbed through the skin.
Eye Contact: Causes burns.
Inhalation: Toxic if inhaled. Material is extremely destructive
to the tissue of the mucous membranes and upper respiratory
tract.
Ingestion: Toxic if swallowed.
TARGET ORGAN(S) OR SYSTEM(S)
Liver. Kidneys.
SIGNS AND SYMPTOMS OF EXPOSURE
Material is extremely destructive to tissue of the mucous
membranes and upper respiratory tract, eyes, and skin.
Inhalation may result in spasm, inflammation and edema of the
larynxand bronchi, chemical pneumonitis, and pulmonary edema.
Symptoms of exposure may include burning sensation, coughing,
wheezing, laryngitis, shortness of breath, headache, nausea, and
vomiting. To the best of our knowledge, the chemical, physical,
and toxicological properties have not been thoroughly
investigated. Depending on the intensity and duration of
exposure, effects may vary from mild irritation to severe
destruction of tissue.
TOXICITY DATA
Oral
Rat
120 mg/kg
LD50
Inhalation
Rat
10,000 mg/m3
LC50
Intraperitoneal
Mouse
48 MG/KG
LD50
Inhalation
Mammal
4,110 mg/m3
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LC50
CHRONIC EXPOSURE - MUTAGEN
Species: Human
Dose: 500 UMOL/L
Cell Type: HeLa cell
Mutation test: Unscheduled DNA synthesis
Section 12 - Ecological Information
ACUTE ECOTOXICITY TESTS
Test Type: LC50 Fish
Species: Carassius auratus (Goldfish)
Time: 24 h
Value: < 0.8 mg/l
Section 13 - Disposal Considerations
APPROPRIATE METHOD OF DISPOSAL OF SUBSTANCE OR PREPARATION
Contact a licensed professional waste disposal service to dispose
of this material. Dissolve or mix the material with a combustible
solvent and burn in a chemical incinerator equipped with an
afterburner and scrubber. Observe all federal, state, and local
environmental regulations.
Section 14 - Transport Information
DOT
Proper Shipping Name: Allyl bromide
UN#: 1099
Class: 3
Packing Group: Packing Group I
Hazard Label: Flammable liquid
Hazard Label: Toxic substances.
PIH: Not PIH
IATA
Proper Shipping Name: Allyl bromide
IATA UN Number: 1099
Hazard Class: 3
Packing Group: I
Not Allowed - Aircraft: Cargo aircraft only. Not
permitted on passenger aircraft.
Section 15 - Regulatory Information
EU ADDITIONAL CLASSIFICATION
Symbol of Danger: F T N
Indication of Danger: Highly Flammable. Toxic. Dangerous for the
environment.
R: 11 23/25 34 50
Risk Statements: Highly flammable. Toxic by inhalation and if
swallowed. Causes burns. Very toxic to aquatic organisms.
S: 16 26 36/37/39 45 60 61
Safety Statements: Keep away from sources of ignition - no
smoking. In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice. Wear suitable
protective clothing, gloves, and eye/face protection. In case of
accident or if you feel unwell, seek medical advice immediately
(show the label where possible). This material and its container
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must be disposed of as hazardous waste. Avoid release to the
environment. Refer to special instructions/safety data sheets.
US CLASSIFICATION AND LABEL TEXT
Indication of Danger: Flammable (USA) Highly Flammable (EU).
Toxic. Dangerous for the environment.
Risk Statements: Highly flammable. Toxic by inhalation and if
swallowed. Causes burns. Very toxic to aquatic organisms.
Safety Statements: In case of contact with eyes, rinse
immediately with plenty of water and seek medical advice. Wear
suitable protective clothing, gloves, and eye/face protection.
In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible). This material and
its container must be disposed of as hazardous waste. Avoid
release to the environment. Refer to special instructions/safety
data sheets.
US Statements: Lachrymator. Target organ(s): Kidneys. Liver.
UNITED STATES REGULATORY INFORMATION
SARA LISTED: No
TSCA INVENTORY ITEM: Yes
CANADA REGULATORY INFORMATION
WHMIS Classification: This product has been classified in
accordance with the hazard criteria of the CPR, and the MSDS
contains all the information required by the CPR.
DSL: Yes
NDSL: No
Section 16 - Other Information
DISCLAIMER
For R&D use only. Not for drug, household or other uses.
WARRANTY
The above information is believed to be correct but does not
purport to be all inclusive and shall be used only as a guide. The
information in this document is based on the present state of our
knowledge and is applicable to the product with regard to
appropriate safety precautions. It does not represent any
guarantee of the properties of the product. Sigma-Aldrich Inc.,
shall not be held liable for any damage resulting from handling or
from contact with the above product. See reverse side of invoice
or packing slip for additional terms and conditions of sale.
Copyright 2004 Sigma-Aldrich Co. License granted to make unlimited
paper copies for internal use only.
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