Material 24 Hour Emergency Phone Numbers:
Medical: 1-800 -327-3874
1-513-558 -5111
Safety Transportation:
1-800-535 -5053
1-352-323 -3500
Data
Sheet
NOTE: National Response Center emergency numbers to be used only in the
event of chemical emergencies involving a spill, leak, fire, exposure or accident
involving chemicals
IMPORTANT: Read this MSDS before handling or disposing of this product, and provide this information to the employees, customers, and users of this
product. This product is covered by the OSHA Hazard Communication Standard and this document has been prepared in accordance with requirements of
this standard. All abbreviated terms used in this MSDS are further described in Section 16.
Section 1 - Chemical Product / Company Information
This Material Safety Data Sheet is available in Canadian French and Spanish upon request.
Esta hoja de datos de la seguridad de los materiales est谩 disponible en franc茅s canadiense y en espa帽ol a su solicitud.
Los Datos de Serguridad del Producto pueden obtenerse en Espanol si lo riquiere.
Product Name: LTX WINDOW GLAZING - 12049 Revision Date: 11/17/2003
Product UPC Number: 7079812108 7079812049 7079870980 Supercedes: 12/28/1999
Product Use/Class: Latex Caulk 00010404001
MSDS Number:
Manufacturer: DAP Inc.
2400 Boston Street Suite 200
Baltimore, MD 21224-4723
888 -327-5477 ( non-emergency matters )
Section 2 - Composition / Information On Ingredients
Chemical Name CASRN WT% ACGIH TWA ACGIH STEL ACGIH CEIL OSHA TWA OSHA STEL OSHA CEIL SKIN
Di(C9) ester branched & linear Proprietary 1-5 N.E. N.E. N.E. N.E. N.E. N.E. No
Di(c7) ester branch & linear Proprietary 1-5 N.E. N.E. N.E. N.E. N.E. N.E. No
Ester Branched & Linear(C7&C9) Proprietary 1-5 N.E. N.E. N.E. N.E. N.E. N.E. No
Ethylene glycol 107-21-1 0.5-1.5 N.E. N.E. 100 MGM3 N.E. N.E. N.E. No
Silica, crystalline 14808-60-7 0.1-1.0 0.05 MGM3 N.E. N.E. N.E. N.E. N.E. No
Formaldehyde 50 -00-0 <0.02 N.E. N.E. 0.3 PPM 0.75 PPM 2 PPM N.E. No
Acetaldehyde 75 -07-0 <0.002 N.E. N.E. 25 PPM 200 PPM N.E. N.E. No
Acrylonitrile 107-13-1 <0.0002 2 PPM N.E. N.E. 2 PPM 10 PPM N.E. Yes
Exposure Notes:
CASRN Exposure Note
14808-60 -7 The 2002 ACGIH Threshold Limit Values for Chemical Substances and Physical Agents lists the median Respirable Particulate Mass (RPM)
point for crystalline silica at 4.0 microns in terms of the particle's aerodynamic diameter.
The TLVs for crystalline silica represent the respirable fraction.
OSHA PEL TLV for Quartz is calculated using the following formula: 10 mg/m3/(% SiO2 + 2). Both concentration and percent quartz for the
application of this limit are to be determined from the fraction passing a size selector with the following characteristics.
|--------------------------------------------------------------------------------------------------------------------------- |-----------------------------------|
| .................................... Aerodynamic diameter ( unit density sphere ) .....................................| Percent passing selector |
| 2 ................................................................................................................................................|.................90....................|
| 2.5 .............................................................................................................................................|..................75...................|
| 3.5 .............................................................................................................................................|..................50...................|
| 5.0 .............................................................................................................................................|..................25...................|
| 10 ..............................................................................................................................................|...................0....................|
50-00-0 Formaldehyde is a specially regulated substance for which an OSHA chemical-specific exposure standard exits. Detailed information
regarding this substance may be found in 29 CFR 1910.1048. Medical surveillance information regarding this substance may be found in
Appendix C to 29 CFR 1910.1048.
107-13-1 Acrylonitrile is a specially regulated substance for which an OSHA chemical -specific exposure standard exits. Detailed information regarding
this substance may be found in 29 CFR 1910.1045. Medical surveillance information regarding this substance may be found in Appendix C to
29 CFR 1910.1045.
Important: Listed Permissible Exposure Levels (PEL) are from the U.S. Dept. of Labor OSHA Final Rule Limits (CFR 29 1910.1000); these limits may vary between
states.
Note: An employee's skin exposure to substances having a "YES" in the "SKIN" column in the table above shall be prevented or reduced to the extent necessary under
the circumstances through the use of gloves, coveralls, goggles or other appropriate personal protective equipment, engineering controls or work practices
Section 3 - Hazards Identification
Emergency Overview: A(n) White to Off-White Paste product. WARNING! Harmful if swallowed or absorbed through the skin.
This product contains ethylene glycol. May cause eye, skin, nose, throat and respiratory tract irritation.
Refer to other MSDS sections for other detailed information.
Effects Of Overexposure - Eye Contact: Causes eye irritation.
Effects Of Overexposure - Skin Contact: Causes skin irritation. Prolonged or repeated contact with skin may cause irritation.
May cause allergic skin reaction or sensitization. Harmful if absorbed through the skin.
Effects Of Overexposure - Inhalation: Harmful if inhaled. Causes nose and throat irritation. Causes lung irritation. Vapor
harmful. May affect the brain or nervous system causing dizziness, headache or nausea. Inhalation may cause irritation to the
respiratory tract (nose, mouth, mucous membranes).
Effects Of Overexposure - Ingestion: Harmful or fatal if swallowed. Ingestion of ethylene glycol can cause gastrointestinal
irritation, nausea, vomiting, diarrhea and if ingested in sufficient quantities, death.
Effects Of Overexposure - Chronic Hazards: Studies have shown that repeated inhalation of ethylene glycol has produced
adverse cardiovascular changes in laboratory animals. Ethylene Glycol may cause kidney and liver damage upon prolonged and
repeated overexposures. Repeated or prolonged exposure may cause respiratory system damage. Prolonged and repeated skin
contact may cause irritation and possibly dermatitis. Formaldehyde vapor is a known animal carcinogen IARC and NTP and is
considered possibly carcinogenic to humans by inhalation. Ethylene glycol has been shown to cause birth defects in laboratory
animals. Overexposure may cause kidney, cardiovascular, skin and liver damage.
Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation
Medical Conditions which May be Aggravated by Exposure: None known.
Section 4 - First Aid Measures
First Aid - Eye Contact: In case of contact, immediately flush eyes with large quantities of water for at least 15 minutes until
irritation subsides. Get medical attention immediately.
First Aid - Skin Contact: Wash off immediately with soap and plenty of water. Remove and wash contaminated clothing.
First Aid - Inhalation: If inhaled, remove to fresh air. If breathing is difficult, leave the area to obtain fresh air. If continued
breathing difficulty is experienced, get medical attention immediately.
First Aid - Ingestion: If swallowed, DO NOT INDUCE VOMITING. Get medical attention immediately.
Note to Physician: No Information.
COMMENTS: Call Medical Emergency at 1-800-327-3874 if any irritation or complication arise from any of the above routes of
entry.
Section 5 - Fire Fighting Measures
Flash Point, F: > 200 Fahrenheit Lower Explosive Limit, %: Not Established
Method: (Seta Closed Cup) Upper Explosive Limit, %: Not Established
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: No special protective measures against fire required.
Special Firefighting Procedures: Wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent)
and full protective gear. Use water spray to cool exposed surfaces.
Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Wear proper protective equipment as specified in Section 8. Use
absorbent material or scrape up dried material and place in container.
Section 7 - Handling And Storage
Handling: DO NOT TAKE INTERNALLY. KEEP OUT OF REACH OF CHILDREN! Use only with adequate ventilation. Ensure
fresh air entry during application and drying. Avoid breathing vapor and contact with eyes, skin and clothing. Wash thoroughly
after handling.
Storage: Close container after each use. Store containers away from excessive heat and freezing. Store away from caustics and
oxidizers. Do not store at temperatures above 120 degrees F.
Section 8 - Exposure Controls / Personal Protection
Precautionary Measures: No Information.
Engineering Controls: Good general ventilation should be sufficient to control airborne levels. Ensure adequate ventilation,
especially in confined areas. Local ventilation of emission sources may be necessary to maintain ambient concentrations below
recommended exposure limits.
Respiratory Protection: In case of insufficient ventilation, wear suitable respiratory equipment. A NIOSH-approved air purifying
respirator with an organic vapor cartridge or canister may be necessary under certain circumstances where airborne
concentrations are expected to exceed exposure limits. A respiratory protection program that meets the OSHA 1910.134 and
ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use.
Skin Protection: Rubber gloves.
Eye Protection: Goggles or safety glasses with side shields.
Other protective equipment: Not required under normal use.
Hygienic Practices: Remove and wash contaminated clothing before re-use. Wash hands before breaks and at the end of
workday.
Section 9 - Physical And Chemical Properties
Boiling Range: Not Established Vapor Density: Not Established
Odor: Not Established Odor Threshold: Not Established
Appearance: A white to off white paste product Evaporation Rate: Not Established
Solubility in H2O: Not Established Specific Gravity: 1.826
Freeze Point: Not Established pH: Between 7.0 and 12.0
Vapor Pressure: Not Established Viscosity: Not Established
Physical State: Paste
(See section 16 for abbreviation legend)
Section 10 - Stability And Reactivity
Conditions To Avoid: Excessive heat and freezing.
Incompatibility: Incompatible with strong bases and oxidizing agents.
Hazardous Decomposition Products: Normal decomposition products, i.e. COx, NOx.
Hazardous Polymerization: Hazardous polymerization will not occur under normal conditions.
Stability: Stable under recommended storage conditions.
Section 11 - Toxicological Information
Product LD50: Not Established Product LC50: Not Established
CASRN Chemical Name LD50 LC50
107-21-1 Ethylene glycol Rat:4700 mg/kg Rat:10876 mg/kg
50-00-0 Formaldehyde ------------- Rat:203 mg/m3
107-13-1 Acrylonitrile Oral Rat:78 mg/kg Rat:425 ppm/4H
Carcinogenity:
CAS No. Chemical Name ACGIH OSHA IARC NTP
14808-60 -7 Silica, crystalline Suspected human carcinogen. ----- ----- Known carcinogen.
50-00-0 Formaldehyde Suspected human carcinogen. Potential cancer hazard. Probable carcinogen. Anticipated carcinogen.
Confirmed animal carcinogen with
107-13-1 Acrylonitrile Cancer hazard. Possible carcinogen. Anticipated carcinogen.
unknown relevance to humans.
Confirmed animal carcinogen with
75-07-0 Acetaldehyde ----- Possible carcinogen. Anticipated carcinogen.
unknown relevance to humans.
Significant Data with Possible Relevance to Humans: This product contains trace amounts of free formaldehyde. OSHA, NTP
and IARC identify formaldehyde as a potential carcinogen. Formaldehyde has been shown to cause mutations in a variety of in-
vitro test systems, the significance of which to humans is unknown. In a two-year inhalation study, rats showed carcinogenic
effects in the respiratory system at 15 ppm of formaldehyde. There should be minimal risk when used with ventilation adequate to
keep the atmospheric concentration of formaldehyde below the recommended exposure limits. Maintain adequate ventilation to
prevent exposure above current OSHA / ACGIH exposure limits. Workplace monitoring of the air to define formaldehyde exposure
levels may be necessary.
Section 12 - Ecological Information
Ecological Information: Ecological injuries are not known or expected under normal use.
Section 13 - Disposal Information
Disposal Information: Dispose of material in accordance with all federal, state and local regulations. State and Local
regulations/restrictions are complex and may differ from Federal regulations. Responsibility for proper waste disposal is with the
owner of the waste.
EPA Waste Code if Discarded (40 CFR Section 261): This product does not meet the definition of a hazardous waste according
to U.S. EPA Hazardous Waste Management Regulation, 40 CFR Section 261.
Section 14 - Transportation Information
DOT Proper Shipping Name: Not Regulated Packing Group: N.A.
DOT Technical Name: N.A. Hazard Subclass: N.A.
DOT Hazard Class: N.A. DOT UN/NA Number: N.A.
Section 15 - Regulatory Information
CERCLA - SARA Hazard Category:
This product has been reviewed according to the EPA 'Hazard Categories' promulgated under Sections 311and 312 of the
Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet
the following categories:
Immediate Health Hazard, Chronic Health Hazard
SARA Section 313:
This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund
Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
Chemical Name CAS Number
Ethylene glycol 107-21-1
Toxic Substances Control Act:
All ingredients in this product are either on TSCA inventory list, or otherwise exempt.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if exported from the
United States:
None
U.S. State Regulations:
New Jersey Right-to-Know:
The following materials are non-hazardous, but are among the top five components in this product:
Chemical Name CAS Number
Non-Hazardous Polymer Proprietary
Water 7732-18-5
Pennsylvania Right-to-Know:
The following non-hazardous ingredients are present in the product at greater than 3%:
Chemical Name CAS Number
Non-Hazardous Polymer Proprietary
Water 7732-18-5
California Proposition 65:
Warning: The following ingredients present in the product are known to the State of California to cause cancer:
Chemical Name CAS Number Definition Date Listed
Silica, crystalline 14808-60 -7 Carcinogenic. Listed: October 1, 1988
Formaldehyde 50-00-0 Carcinogenic. Listed: January 1, 1988
Acrylonitrile 107-13-1 Carcinogenic. Listed: July 1, 1987
Acetaldehyde 75-07-0 Carcinogenic. Listed: April 1, 1988
Warning: The following ingredients present in the product are known to the State of California to cause birth defects or other
reproductive harm.
None
Section 16 - Other Information
HMIS Ratings:
Health: Flammability: Reactivity: Personal Protection:
VOLATILE ORGANIC COMPOUNDS, GR/LTR: 48.7 LB/GAL: 0.4 WT%: 2.2
REASON FOR REVISION:
Legend: N.A. 鈥? Not Applicable ACGIH 鈥? American Conference of Governmental Industrial Hygienists
N.E. 鈥? Not Established SARA 鈥? Superfund Amendments and Reauthorization Act of 1986
N.D. 鈥? Not Determined NJRTK 鈥? New Jersey Right-to-Know Law
VOC 鈥? Volatile Organic Compound OSHA 鈥? Occupational Safety and Health Administration
PEL 鈥? Permissible Exposure Limit HMIS 鈥? Hazardous Materials Identification System
TLV 鈥? Threshold Limit Value NTP 鈥? National Toxicology Program
STEL 鈥? Short Term Exposure Limit CEIL 鈥? Ceiling Exposure Limit
LD50 鈥? Lethal Dose 50 LC50 鈥? Lethal Concentration 50
F 鈥? Degree Fahrenheit C 鈥? Degree Celcius
CASRN 鈥? The Chemical Abstracts Service Registry Number MSDS 鈥? Material Safety Data Sheet
DAP believes the data and statements contained herein are accurate as of the date hereof. They are offered in good faith as typical values and
not as a product specification. NO WARRANTY OF MERCHANTABILITY, WARRANTY OF FITNESS FOR ANY PARTICULAR
PURPOSE OR ANY OTHER WARRANTY, EXPRESS OR IMPLIED, IS MADE WITH REGARD TO THE INFORMATION
HEREIN PROVIDED OR THE PRODUCT TO WHICH THE INFORMATION REFERS. Since this document is intended only as a
guide to the appropriate use and precautionary handling of the referenced product by a properly trained person, it is therefore the responsibility
of the user to (i) review the recommendations with due consideration for the specific context of the intended use and (ii) determine if they are
appropriate.
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